Astrophysics and Astronomy Commons^™

Photoionization Energetics And Dissociation Pathways Of Hydroperoxyethyl Formate Produced In The Reaction Of Ch3Choo + Formic Acid, Vincent J. Esposito, Trent A. Mchenry, Marsha I. Lester

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

The bimolecular reaction of Criegee intermediates, zwitterionic carbonyl oxide species produced in alkene ozonolysis, with organic acids leads to formation of functional hydroperoxides implicated in the generation of atmospheric aerosols. This theoretical study using high-level explicitly correlated coupled-cluster theory examines the low energy conformers of hydroperoxyethyl formate [HOOCH(CH₃)OCHO, HPEF] formed in the bimolecular reaction of CH₃CHOO, a simple alkyl-substituted Criegee intermediate, with formic acid, and the detection of HPEF via photoionization. The vertical and adiabatic ionization energies of HPEF are computed, along with the pathways for dissociative ionization that produce HO₂ or OCHO fragments with …

A New Wave Of “Space Nationalism” In The United States: Why Are Evangelicals Good With It?, Andrea Molle

Political Science Faculty Articles and Research

Despite evidence that shows how the support for space programs correlates with liberal political views and a lower level of religiosity, recent data suggest that more conservative positions may have an even more substantial effect under the appropriate conditions. Using the available data from Pew's American Trends Panel, we seek to clarify this interactional effect of political and religious preferences on the level of interest in the space programs and commitment to space politics support among Evangelicals as it changed during Trump's presidency. Our research hypothesizes that during this time, the simultaneous presence of nationalist views in both accounts of …

Spectroscopic Properties Of The Astrochemical Molecules [Al, O, Si]X (X = 0, +1), Jacqueline M. Friskey, Vincent J. Esposito, Tarek Trabelsi, Joseph S. Francisco

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Aluminum and silicon are present in large quantities in the interstellar medium, making the triatomic species consisting of both elements intriguing with regard to the foundations of astrochemistry. Spectroscopic parameters have been calculated via high-level ab initio methods to assist with laboratory and observational detection of [Al, O, Si]^x(x = 0,+1). All [Al, O, Si]M^x(x = 0,+1) isomers exist in the linear geometry, with linear AlOSi (X ²Π) and linear AlOSi⁺ (X¹Δ) being the most stable neutral and cationic species, respectively. Formation of the neutral species most likely occurs via reaction of …

The Photoionization Dynamics, Electronic Spectroscopy, And Excited State Photochemistry Of Alco And Aloc, Vincent J. Esposito, Joseph S. Francisco

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

The high cosmic abundance of carbon monoxide (CO) and the ubiquitous nature of aluminum-coated dust grains sets the stage for the production of weakly bound triatomic molecules AlCO (X ²Π) and AlOC (X ²Π) in circumstellar envelopes of evolved stars. Following desorption of cold AlCO and AlOC from the dust grain surface, incoming stellar radiation in the 2–9 eV wavelength range (visible to vacuum ultraviolet) will drive various photochemical processes. Ionization to the singlet cation state will cause an immediate Al–X (X = C, O) bond dissociation to form Al⁺ (¹S) and CO (X ^{1 …}

Aloso: Spectroscopy And Structure Of A New Group Of Astrochemical Molecules, Vincent J. Esposito, Tarek Trabelsi, Joseph S. Francisco

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

No abstract provided.

Spectroscopic Properties Relevant To Astronomical And Laboratory Detection Of Mch And Mch+ (M = Al, Mg), Vincent J. Esposito, Tarek Trabelsi, Joseph S. Francisco

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

New spectroscopic parameters have been calculated to aid in the laboratory and observational detection of AlCH, AlCH⁺, MgCH, MgCH⁺, and their deuterated analogs. All species exist in linear geometry except for AlCH+, which exhibits a bent structure. Rotational frequencies have been calculated and the transition with maximum intensity is discussed for three temperature regions present in space: 100 K for a central circumstellar envelope (CSE), 30 K for an outer CSE, and 3 K indicative of the interstellar medium. Pertinent frequencies range from 25 to 250 GHz, depending on the species. At 30 K, the most …

Photochemistry Of Nh2No2 And Implications For Chemistry In The Atmosphere, Vincent J. Esposito, Tarek Trabelsi, Joseph S. Francisco

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Recent studies have indicated that nitramide (NH₂NO₂) may be formed more plentifully in the atmosphere than previously thought, while also being a missing source of the greenhouse gas nitrous oxide (N₂O) via catalyzed isomerization. To validate the importance of NH₂NO₂ in the Earth’s atmosphere, the ground and first electronic excited states of NH₂NO₂ were characterized and its photochemistry was investigated using multireference and coupled cluster methods. NH₂NO₂ is non-planar and of singlet multiplicity in the ground state while exhibiting large out-of-plane rotation in the triplet …

High Level Ab Initio Study Of The Energetic And Spectroscopic Properties Of [Al,S,O]X (X=0,+1) And Its Potential For Detection In Space, Vincent J. Esposito, Tarek Trabelsi, Joseph S. Francisco

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Highly reliable molecular properties have been computed for the [Al, S, O]^x (x = 0, +1) molecular system. Spectroscopic parameters are predicted from analysis of each isomer’s 3D potential energy surface calculated using the explicitly correlated multireference configuration interaction method, including the Davidson correction (MRCI-F12+Q). These parameters provide an accurate prediction of spectroscopic data that can be used in laboratory and observational studies of these molecules. Linear-SAlO is expected to have a large permanent dipole moment suitable for detection in the circumstellar envelopes of large, evolved, oxygen-rich stars such as VY Canis Majoris, IK Tauri, and R Doradus. …

Astromimetics: The Dawn Of A New Era For (Bio)Materials Science?, Vuk Uskoković, Victoria M. Wu

Pharmacy Faculty Articles and Research

Composite, multifunctional fine particles are likely to be at the frontier of materials science in the foreseeable future. Here we present a submicron composite particle that mimics the stratified structure of the Earth by having a zero-valent iron core, a silicate/silicide mantle, and a thin carbonaceous crust resembling the biosphere and its biotic deposits. Particles were formulated in a stable colloidal form and made to interact with various types of healthy and cancer cells in vitro. A selective anticancer activity was observed, promising from the point of view of the intended use of the particles for tumor targeting across the …

Knotty Inflation And The Dimensionality Of Spacetime, Arjun Berera, Roman V. Buniy, Thomas W. Kephart, Heinrich Päs, João G. Rosa

Mathematics, Physics, and Computer Science Faculty Articles and Research

We suggest a structure for the vacuum comprised of a network of tightly knotted/linked flux tubes formed in a QCD-like cosmological phase transition and show that such a network can drive cosmological inflation. As the network can be topologically stable only in three space dimensions, this scenario provides a dynamical explanation for the existence of exactly three large spatial dimensions in our Universe.

Numerical Solutions Of Hawking's Equations For Gravitational Waves In Evolutionary Universe, Pablo Abramian Barco, Armen Gulian

Mathematics, Physics, and Computer Science Faculty Books and Book Chapters

Search for fast growing infinitesimal perturbations in the Friedmann-Lemaître- Robertson-Walker universe within Einstein’s General Relativity is regarded as very important for explanation of observational inhomogeneities like nebulae and clusters of galaxies. However, despite a lot of efforts no fast growing mode has been obtained in exploring density perturbations, rotations, and gravitational waves in initially homogeneous and isotropic cosmological model. That left modern cosmological paradigm with finite initial inhomogeneities of ill-defined origin, requiring also strong preponderance of even more undetermined “dark matter”, to explain the observational universe.

Here we report on numerical solutions of Hawking’s equations for gravitational waves in evolutionary …

The Statistical Mechanics Of Solar Wind Hydroxylation At The Moon, Within Lunar Magnetic Anomalies, And At Phobos, W. M. Farrell, D. M. Hurley, Vincent J. Esposito, J. L. Mclain, M. I. Zimmerman

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

We present a new formalism to describe the outgassing of hydrogen initially implanted by the solar wind protons into exposed soils on airless bodies. The formalism applies a statistical mechanics approach similar to that applied recently to molecular adsorption onto activated surfaces. The key element enabling this formalism is the recognition that the interatomic potential between the implanted H and regolith-residing oxides is not of singular value but possess a distribution of trapped energy values at a given temperature, F(U,T). All subsequent derivations of the outward diffusion and H retention rely on the specific properties of this distribution. We …

Elvis: Exploring The Local Volume In Simulations, Shea Garrison-Kimmel, Michael Boylan-Kolchin, James S. Bullock, Kyle Lee

Mathematics, Physics, and Computer Science Faculty Articles and Research

We introduce a set of high-resolution dissipationless simulations that model the Local Group (LG) in a cosmological context: Exploring the Local Volume in Simulations (ELVIS). The suite contains 48 Galaxy-size haloes, each within high-resolution volumes that span 2-5 Mpc in size, and each resolving thousands of systems with masses below the atomic cooling limit. Half of the ELVIS galaxy haloes are in paired configurations similar to the Milky Way (MW) and M31; the other half are isolated, mass-matched analogues. We find no difference in the abundance or kinematics of substructure within the virial radii of isolated versus paired hosts. On …

Closed String Thermodynamics And A Blue Tensor Spectrum, Robert H. Brandenberger, Ali Nayeri, Subodh P. Patil

Mathematics, Physics, and Computer Science Faculty Articles and Research

The BICEP-2 team has recently reported the positive detection of cosmic microwave background Bmode polarization. Although uncertainties due to galactic dust foregrounds remain, it is a constructive exercise to work out the implications of presuming some part of the detected B-mode signal to be due to primordial gravitational waves. Were a positive detection of a tensor-to-scalar ratio larger than r greater than or similar to O(10(-2)) confirmed, detecting a tilt in the tensor spectrum comparable to that observed for the scalar power spectrum becomes in principle possible. We wish to explore in this brief paper the possibility of there being …

Practical Approach To Cosmological Perturbations In Modified Gravity, Alessandra Silvestri, Levon Pogosian, Roman V. Buniy

Mathematics, Physics, and Computer Science Faculty Articles and Research

The next generation of large scale surveys will not only measure cosmological parameters within the framework of general relativity, but will also allow for precision tests of the framework itself. At the order of linear perturbations, departures from the growth in the standard cosmological model can be quantified in terms of two functions of time and Fourier number k. We argue that in local theories of gravity, in the quasistatic approximation, these functions must be ratios of polynomials in k, with the numerator of one function being equal to the denominator of the other. Moreover, the polynomials are even and …

Toward Solving The Cosmological Constant Problem By Embedding, Roman V. Buniy, Thomas W. Kephart

Mathematics, Physics, and Computer Science Faculty Articles and Research

The typical scalar field theory has a cosmological constant problem. We propose a generic mechanism by which this problem is avoided at tree level by embedding the theory into a larger theory. The metric and the scalar field coupling constants in the original theory do not need to be fine-tuned, while the extra scalar field parameters and the metric associated with the extended theory are fine-tuned dynamically. Hence, no fine-tuning of parameters in the full Lagrangian is needed for the vacuum energy in the new physical system to vanish at tree level. The cosmological constant problem can be solved if …

Everything Is Entangled, Roman V. Buniy, Stephen D. H. Hsu

Mathematics, Physics, and Computer Science Faculty Articles and Research

We show that big bang cosmology implies a high degree of entanglement of particles in the universe. In fact, a typical particle is entangled with many particles far outside our horizon. However, the entanglement is spread nearly uniformly so that two randomly chosen particles are unlikely to be directly entangled with each other - the reduced density matrix describing any pair is likely to be separable.

Superluminal Neutrinos At Opera Confront Pion Decay Kinematics, Ramanath Cowsick, Shmuel Nussinov, Utpal Sarkar

Mathematics, Physics, and Computer Science Faculty Articles and Research

Violation of Lorentz invariance (VLI) has been suggested as an explanation of the superluminal velocities of muon neutrinos reported by OPERA. In this Letter, we show that the amount of VLI required to explain this result poses severe difficulties with the kinematics of the pion decay, extending its lifetime and reducing the momentum carried away by the neutrinos. We show that the OPERA experiment limits alpha = (upsilon(v) - c)/c < 4 x 10(-6). We then take recourse to cosmic-ray data on the spectrum of muons and neutrinos generated in Earth's atmosphere to provide a stronger bound on VLI: (upsilon - c)/c < 10(-12).

Limit On Continuous Neutrino Emission From Neutron Stars, Itzhak Goldman, Shmuel Nussinov

Mathematics, Physics, and Computer Science Faculty Articles and Research

The timing data of the binary pulsar PSR1913+16, are used to establish an upper limit on the rate of continuous neutrino emission from neutron stars. Neutrino emission from each of the neutron stars of the binary system, increases the star binding energy and thus translates to a decrease in their masses. This in turn implies an increase with time of the binary period. Using the pulsar data we obtain an upper limit on the allowed rate of mass reduction: vertical bar M vertical bar < 1.1 x 10(-12) yr(-1) M, where M is the total mass of the binary. This constrains exotic nuclear equations of state that predict continuous neutrino emissions. The limit applies also to other channels of energy loss, e. g. axion emission. Continued timing measurements of additional binary pulsars, should yield a stronger limit in the future.

Can Large Scintillators Be Used For Solar-Axion Searches To Test The Cosmological Axion-Photon Oscillation Proposal?, F. T. Avignone Iii, R. J. Creswick, Shmuel Nussinov

Mathematics, Physics, and Computer Science Faculty Articles and Research

Solar-axion interaction rates in Nal, Csl and Xe scintillators via the axio-electric effect were calculated. A table is presented with photo-electric and axio-electric cross sections, solar-axion fluxes, and the interaction rates from 2.0 to 10.0 keV. The results imply that annual-modulation data of large Nal and Csl arrays, and large Xe scintillation detectors, might be made sensitive enough to probe coupling to photons at levels required to explain axion-photon oscillation phenomena proposed to explain the survival of high-energy photons traveling cosmological distances. The DAMA/LIBRA data are used to demonstrate the power of the model-independent annual modulation due to the seasonal …

The Recent High State Of The Bl Lacertae Object Ao 0235 And Cross-Correlations Between Optical And Radio Bands, M. Roy, I. E. Papadikis, E. Ramos-Colon, R. Sambruna, K. Tsinganos, J. Papamastorkis, Menas Kafatos

Mathematics, Physics, and Computer Science Faculty Articles and Research

We present new optical (B, V , R, I) and radio (at 14.5, 8.5, and 4.8 GHz) observations of the γ-ray- loud blazar AO 0235+164 obtained during the high state of 1997 December-1998 January. The data were combined with historical light curves from the literature to study correlated optical and radio variations over a time span of more than 20 years. Flux variability with large and energy-dependent amplitude is observed at both wave bands, with the source varying over all timescales sampled (years-months- days), in agreement with previous reports. We have performed a cross-correlation analysis of optical and radio light …

Contemporaneous Iue, Euve, And High-Energy Observations Of 3c 273, E. Ramos, Menas Kafatos, A. Fruscione, F. C. Bruhweiler, I. M. Mchardy, R. C. Hartman, L. G. Titarchuk, C. Von Montigny

Mathematics, Physics, and Computer Science Faculty Articles and Research

We present the results of our 1994 January and 1995 January observations of the quasar 3C 273 obtained with the International Ultraviolet Explorer (IUE) and the Extreme-Ultraviolet Explorer (EUV E). These observations were part of a large multiwavelength campaign to observe 3C 273 from radio through γ-rays. Our 1995 January photometric observations with the EUV E Lexan/B Deep Survey (DS) instrument indicate strong evidence for variability, at a 99% confidence level, during the 12 day observing period. We have utilized ROSAT PSPC soft X-ray power-law models to correlate with EUV E count rates. Besides variations in the normalization level between …

Lateral Shock Of The R Aquarii Jet, J. M. Hollis, J. A. Pedelty, Menas Kafatos

Mathematics, Physics, and Computer Science Faculty Articles and Research

The R Aqr jet was observed with the VLA B-configuration at two epochs separated by ~13.2 yr. Comparison of the resulting 6 cm continuum images show that the radio jet has undergone a lateral counterclockwise rotation of ~6-12 on the plane of the sky. The model of jet parcels on independent trajectories is difficult to reconcile with these observations and leads us to consider a path-oriented jet (i.e., younger parcels follow the same path as older parcels). Comparison of the most recent radio image with a nearly contemporaneous HST /FOC ultraviolet image at ~2330 A suggests that the ultraviolet emission …

Multiwavelength Blazar Studies, Menas Kafatos

Mathematics, Physics, and Computer Science Faculty Articles and Research

The present report concerns the following projects 'High energy emission from hot accretion disks from active galactic nuclei'; 'OSSE spectral timing and monitoring observations of Cygnus X- 1'; 'OSSE observations of blazars'; and 'Search for correlated time variations of bright EGRET blazars'. The most favored model for the central engine inAGNs is the supermassive black hole hypothesis (Rees 1978). The observed luminosities range from approx. 10 logical and 44-45 erg /s for objects such as Mk 421 and Seyferts to as much as approx. 10logical and 47 for powerful QSOs such as 3C 273 and 3C 279, a large fraction …

Multifrequency Studies, Menas Kafatos

Mathematics, Physics, and Computer Science Faculty Articles and Research

The present report concerns the following projects 'Multifrequency observations of the BL Lacertae object MK 421"; "EUVE and multifrequency observations of the quasars 3C 273 and 3C 279"; "EUVE observations of the symbiotic star RAquarii"; and "Morphology of the local HI void and ionization of He in the local ISM". The common theme of the above projects is UV observations and analysis of a wide range of astrophysical classes or objects, from the diffuse interstellar medium, to symbiotic stars (R Aqr), to active galactic nuclei (AGNs). Understanding the local (primarily neutral hydrogen or HI) interstellar medium is of great importance …

Ion Viscosity Mediated By Tangled Magnetic Fields: An Application To Black Hole Accretion Disks, P. Subramanian, P. A. Becker, Menas Kafatos

Mathematics, Physics, and Computer Science Faculty Articles and Research

We examine the viscosity associated with the shear stress exerted by ions in the presence of a tangled magnetic field. As an application, we consider the effect of this mechanism on the structure of black hole accretion disks. We do not attempt to include a self-consistent description of the magnetic field. Instead, we assume the existence of a tangled field with coherence length λcob• which is the average distance between the magnetic "kinks" that scatter the particles. For simplicity, we assume that the field is self-similar, and take λcob to be a fixed fraction ξ of the local disk height …

Shock Study In Fully Relativistic Isothermal Flows. Ii, Ruixin Yang, Menas Kafatos

Mathematics, Physics, and Computer Science Faculty Articles and Research

The isothermal shocks and their stabilities in fully relativistic accretion wedge flows onto black holes are studied. The jump condition across the shock is modified by the relativistic effects when the sound speed is comparable to the speed of light. With a new kind of instability analysis, it is found that only one of the two possible shocks is stable. The results are applied to the QPO behavior in galactic black hole candidates such as Cygnus X-1.

Ultraviolet Temporal Variability Of The Peculiar Star R Aquarii, S. R. Meier, Menas Kafatos

Mathematics, Physics, and Computer Science Faculty Articles and Research

This paper is a comprehensive study of all far-UV spectra obtained with the International Ultraviolet Explorer (IUE) satellite of the symbiotic star R Aquarii (R Aqr) covering a 13 yr period between 1979 and 1992. We have analyzed the ultraviolet emission for the compact H II region and the NE and SW extended "jetlike" filamentary structures. The results of our ultraviolet analysis indicate that the H II region and features A, B, and D of the NE jet are increasing in intensity, while the SW counterjet, feature A', has declined in intensity. We have found much stronger evidence that the …

Osse Observations In Blazars, K. Mcnaron-Brown, W. N. Johnson, G. V. Jung, R. L. Kinzer, J. D. Kurfess, M. S. Strickman, C. D. Dermer, D. A. Grabelsky, W. R. Purcell, M. P. Ulmer, Menas Kafatos, P. A. Becker, R. Staubert, M. Maisack

Mathematics, Physics, and Computer Science Faculty Articles and Research

Results are reported on observations obtained with the Oriented Scintillation Spectrometer Experiment (OSSE) instrument on the Compton Gamma Ray Observatory (CGRO) of 17 active galactic nuclei (AGNs) known to exhibit blazar properties at other wavelengths. These observations span the period from 1991 June through 1994 May. Of the 33 high-confidence EGRET detections of blazars during CGRO observing phases 1 and 2 (1991 May 16-1993 September 7), OSSE has observed eight and detected five, namely 3C 273, 3C 279, PKS 0528+134, CTA 102, and 3C 454.3. Additionally, OSSE has detected the BL Lac sources H1517+65.6 and PKS 2155-304, which were not …

Implications Of Gamma-Ray Transparency Constraints In Blazars: Minimum Distances And Gamma-Ray Collimation, P. A. Becker, Menas Kafatos

Mathematics, Physics, and Computer Science Faculty Articles and Research

We develop a general expression for the γ-γ absorption coefficient, αγγ, for γ-rays propagating in an arbitrary direction at an arbitrary point in space above an X-ray-emitting accretion disk. The X-ray intensity is assumed to vary as a power law in energy and radius between the outer disk radius, R0 , and the inner radius, Rm., which is the radius of marginal stability for a Schwarzschild black hole. We use our result for αγγ to calculate the γ-γ optical depth, Tγγ, for γ-rays created at height z and propagating at angle Φ relative to the disk axis, and we show …