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Articles 271 - 300 of 378

Full-Text Articles in Astrophysics and Astronomy

Simulations Of The Instability Of The M = 1 Self-Shielding Diocotron Mode In Finite-Length Non-Neutral Plasmas, Grant W. Mason, Ross L. Spencer Aug 2002

Simulations Of The Instability Of The M = 1 Self-Shielding Diocotron Mode In Finite-Length Non-Neutral Plasmas, Grant W. Mason, Ross L. Spencer

Faculty Publications

The "self-shielding" m = 1 diocotron mode in Malmberg-Penning traps has been known for over a decade to be unstable for finite length non-neutral plasmas with hollow density profiles. Early theoretical efforts were unsuccessful in accounting for the exponential growth and/or the magnitude of the growth rate. Recent theoretical work has sought to resolve the discrepancy either as a consequence of the shape of the plasma ends or as a kinetic effect resulting from a modified distribution function as a consequence of the protocol used to form the hollow profiles in experiments. Both of these finite length mechanisms have been …


Vibrational Modes Of Thin Oblate Clouds Of Charge, Thomas G. Jenkins, Ross L. Spencer Jul 2002

Vibrational Modes Of Thin Oblate Clouds Of Charge, Thomas G. Jenkins, Ross L. Spencer

Faculty Publications

A numerical method is presented for finding the eigenfunctions (normal modes) and mode frequencies of azimuthally symmetric non-neutral plasmas confined in a Penning trap whose axial thickness is much smaller than their radial size. The plasma may be approximated as a charged disk in this limit; the normal modes and frequencies can be found if the surface charge density profile sigma(r) of the disk and the trap bounce frequency profile wz(r) are known. The dependence of the eigenfunctions and equilibrium plasma shapes on nonideal components of the confining Penning trap fields is discussed. The results of the calculation are compared …


Negative Band Gap Bowing In Epitaxial Inas/Gaas Alloys And Predicted Band Offsets Of The Strained Binaries And Alloys On Various Substrates, Gus L. W. Hart, Kwiseon Kim, Alex Zunger Feb 2002

Negative Band Gap Bowing In Epitaxial Inas/Gaas Alloys And Predicted Band Offsets Of The Strained Binaries And Alloys On Various Substrates, Gus L. W. Hart, Kwiseon Kim, Alex Zunger

Faculty Publications

We use pseudopotential theory to provide (1) the band offsets of strained GaAs and InAs on various substrates and (2) the energies Ev(x) of the valence and conduction bands of InxGa1-xAs alloy, as a function of composition. Results are presented for both the bulk alloy and for the alloy strained on InP or GaAs. We predict that while Ex(x) bows downward for relaxed bulk alloys, it bows upward for strained epitaxial alloys. The calculated alloy offsets are used to discuss electron and hole localization in this system.


Origins Of Nonstoichiometry And Vacancy Ordering In Sc1-X□Xs, Gus L. W. Hart, Alex Zunger Dec 2001

Origins Of Nonstoichiometry And Vacancy Ordering In Sc1-X□Xs, Gus L. W. Hart, Alex Zunger

Faculty Publications

Whereas nearly all compounds AnBm obey Dalton's rule of integer stoichiometry (n:m, both integer), there is a class of systems, exemplified by the rocksalt structure Sc1-x□xS, that exhibits large deviations from stoichiometry via vacancies, even at low temperatures. By combining first-principles total energy calculations with lattice statistical mechanics, we scan an astronomical number of possible structures, identifying the stable ground states. Surprisingly, all have the same motifs: (111) planes with (112) vacancy rows arranged in (110) columns. Electronic structure calculations of the ground states (identified out of ~3 × 10^6 structures) reveal the remarkable origins of nonstoichiometry.


Statistics And Supermetallicity: The Metallicity Of Mu Leonis, B. J. Taylor Oct 2001

Statistics And Supermetallicity: The Metallicity Of Mu Leonis, B. J. Taylor

Faculty Publications

For the often-studied "SMR" giant µ Leo, Smith & Ruck (2000) have recently found that [Fe/H] approximately + 0.3 dex. Their conclusion is tested here in a "statistical" paradigm, in which statistical principles are used to select published high-dispersion µ Leo data and assign error bars to them. When data from Smith & Ruck and from Takeda et al. (1998) are added to a data base compiled in 1999, it is found that conclusions from an earlier analysis (Taylor 1999c) are essentially unchanged: the mean value of [Fe/H] approximately + 0.23 ± 0.025 dex, and values ≤ + 0.2 dex …


Chemical Bonding, Elasticity, And Valence Force Field Models: A Case Study For Α-Pt2si And Ptsi, Gus L. W. Hart, J. E. Klepeis, O. Beckstein, O. Pankratov Sep 2001

Chemical Bonding, Elasticity, And Valence Force Field Models: A Case Study For Α-Pt2si And Ptsi, Gus L. W. Hart, J. E. Klepeis, O. Beckstein, O. Pankratov

Faculty Publications

We have carried out a detailed study of the chemical bonding for two room-temperature stable platinum silicide phases, tetragonal α-Pt2Si. These elements of the bonding are further analyzed by constructing valence force field models using the results from recent first principles calculations of the six (nine) independent, nonzero elastic constants of α-Pt2Si (PtSi). The resulting volume-, radial-, and angular-dependent force constants provide insight into the relative strength of various bonding elements as well as the trends observed in the elastic constants themselves. The valence force field analysis yields quantitative information about the nature of the chemical bonding that is not …


Poynting's Theorem And Luminal Total Energy Transport In Passive Dielectric Media, Scott Glasgow, Michael Ware, Justin Peatross Sep 2001

Poynting's Theorem And Luminal Total Energy Transport In Passive Dielectric Media, Scott Glasgow, Michael Ware, Justin Peatross

Faculty Publications

Without approximation the energy density in Poynting's theorem for the generally dispersive and passive dielectric medium is demonstrated to be a system total dynamical energy density. Thus the density in Poynting's theorem is a conserved form that by virtue of its positive definiteness prescribes important qualitative and quantitative features of the medium-field dynamics by rendering the system dynamically closed. This fully three-dimensional result, applicable to anisotropic and inhomogeneous media, is model independent, relying solely on the complex-analytic consequences of causality and passivity. As direct applications of this result, we show 1 that a causal medium responds to a virtual, instantaneous …


Statistics And Supermetallicity: The Metallicity Of Ngc 6791, B. J. Taylor Aug 2001

Statistics And Supermetallicity: The Metallicity Of Ngc 6791, B. J. Taylor

Faculty Publications

For the old galactic cluster NGC 6791, Peterson & Green (1998a) and Chaboyer et al. (1999) have found that [Fe/H] approximately + 0.4 dex. A second look at that conclusion is taken in this paper. Zero-point problems are reviewed for a high-dispersion analysis done by Peterson & Green, and it is found that accidental errors have not been determined rigorously for the results of that analysis. It is also noted that in a color-magnitude analysis performed by Chaboyer et al., the important metallicity range between 0.0 and + 0.3 dex is not explored and hence is not ruled out. Moreover, …


Formation Of Rydberg Atoms In An Expanding Ultracold Neutral Plasma, Scott D. Bergeson, T. C. Killian, M. J. Lim, S. Kulin, R. Dumke, S. L. Rolston Apr 2001

Formation Of Rydberg Atoms In An Expanding Ultracold Neutral Plasma, Scott D. Bergeson, T. C. Killian, M. J. Lim, S. Kulin, R. Dumke, S. L. Rolston

Faculty Publications

We study the formation of Rydberg atoms in expanding plasmas at temperatures of 1–1000 K and densities from 10^5–10^10 cm^-3. Up to 20% of the initially free charges recombine in about 100 us, and the binding energy of the Rydberg atoms approximately equals the increase in the kinetic energy of the remaining free electrons. Three-body recombination is expected to dominate in this regime, yet most of our results are inconsistent with this mechanism.


What Determines The Emission Peak Energy Of The Blue Luminescence In Highly Mg-Doped P-Gan?, John S. Colton, P. Y. Yu Apr 2001

What Determines The Emission Peak Energy Of The Blue Luminescence In Highly Mg-Doped P-Gan?, John S. Colton, P. Y. Yu

Faculty Publications

We report a study of the 2.8 eV blue luminescence (BL) in heaviliy Mg-doped p-GaN via resonant excitation with a tunable blue dye laser. The dependence of the BL on the excitation photon energy (Eex) is unlike that of the yellow luminescence found in n-type GaN. An Urbach-type band tail, with Urbach parameter of 33 meV is observed in the vicinity of the BL energy. We propose that the peak energy of the BL marks the transition from localized states to delocalized states within this band tail.


First-Principles Elastic Constants And Electronic Structure Of Α-Pt2si And Ptsi, Gus L. W. Hart, O. Beckstein, J. E. Klepeis, O. Pankratov Mar 2001

First-Principles Elastic Constants And Electronic Structure Of Α-Pt2si And Ptsi, Gus L. W. Hart, O. Beckstein, J. E. Klepeis, O. Pankratov

Faculty Publications

We have carried out a first-principles study of the elastic properties and electronic structure for two room-temperature stable Pt silicide phases, tetragonal α-Pt2Si, and orthorhomic PtSi. We have calculated all of the equilibrium structural parameters for both phases; the a and c lattice constants for α-Pt2Si and the a, b, and c lattice constants and four internal structural parameters for PtSi. These results agree closely with experimental data. We have also calculated the zero-pressure elastic constants, confirming prior results for pure Pt and Si and predicting values for the six (nine) independent, nonzero elastic constants of α-Pt2Si (PtSi). These calculations …


Plasma Oscillations And Expansion Of An Ultracold Neutral Plasma, Scott D. Bergeson, S. Kulin, T. C. Killian, S. L. Rolston Jul 2000

Plasma Oscillations And Expansion Of An Ultracold Neutral Plasma, Scott D. Bergeson, S. Kulin, T. C. Killian, S. L. Rolston

Faculty Publications

We report the observation of plasma oscillations in an ultracold neutral plasma. With this collective mode we probe the electron density distribution and study the expansion of the plasma as a function of time. For classical plasma conditions, i.e., weak Coulomb coupling, the expansion is dominated by the pressure of the electron gas and is described by a hydrodynamic model. Discrepancies between the model and observations at low temperature and high density may be due to strong coupling of the electrons.


Electronic Structure Of Bas And Boride Iii-V Alloys, Gus L. W. Hart, Alex Zunger Jun 2000

Electronic Structure Of Bas And Boride Iii-V Alloys, Gus L. W. Hart, Alex Zunger

Faculty Publications

Boron arsenide, the typically ignored member of the Group-III–V arsenide series BAs-AlAs-GaAs-InAs is found to resemble silicon electronically: its Γ conduction-band minimum is p-like (Γ15), not s-like (Γ1c), it has an X1c-like indirect band gap, and its bond charge is distributed almost equally on the two atoms in the unit cell, exhibiting nearly perfect covalency. The reasons for these are tracked down to the anomalously low atomic p orbital energy in the boron and to the unusually strong s–s repulsion in BAs relative to most other Group-III–V compounds. We find unexpected valence-band offsets of BAs with respect to GaAs and …


Average Energy Flow Of Optical Pulses In Dispersive Media, Scott Glasgow, Michael Ware, Justin Peatross Mar 2000

Average Energy Flow Of Optical Pulses In Dispersive Media, Scott Glasgow, Michael Ware, Justin Peatross

Faculty Publications

The arrival time of a light pulse at a point in space is defined using a time expectation integral over the Poynting vector. The delay between pulse arrival times at two distinct points is shown to consist of two parts: a spectral superposition of group delays (inverse of group velocity) and a delay due to spectral reshaping via absorption or amplification. The result provides a context wherein group velocity is always meaningful even for broad band pulses and when the group velocity is superluminal or negative. The result imposes luminality on sharply defined pulses.


Electronic Structure Of Cu1-Xnixrh2s4 And Curh2se4: Band-Structure Calculations, X-Ray Photoemission, And Fluorescence Measurements, Gus L. W. Hart, W. E. Pickett, E. Z. Kurmaev, M. Neumann, D. Hartmann, A. Moewes, D. L. Ederer, R. Endoh, K. Taniguchi, S. Nagata Feb 2000

Electronic Structure Of Cu1-Xnixrh2s4 And Curh2se4: Band-Structure Calculations, X-Ray Photoemission, And Fluorescence Measurements, Gus L. W. Hart, W. E. Pickett, E. Z. Kurmaev, M. Neumann, D. Hartmann, A. Moewes, D. L. Ederer, R. Endoh, K. Taniguchi, S. Nagata

Faculty Publications

The electronic structure of spinel-type Cu1-xNixRh2S4 (x=0.0, 0.1, 0.3, 0.5, 1.0) and CuRh2Se4 compounds has been studied by means of x-ray photoelectron (SPS) and fluorescent spectroscopy. Cu L3, Ni L3, S L2,3, and Se M2,3 x-ray emission spectra (XES) were measured near thresholds at Beamline 8.0 of the Lawrence Berkeley Laboratory's Advanced Light Source. XES measurements of the constituent atoms of these compounds, reduced to the same binding energy scale, are found to be in excellent agreement with XPS valence bands. The calculated XES spectra which include dipole matrix elements show that the partial density of states reproduce experimental spectra …


Creation Of An Ultracold Neutral Plasma, Scott D. Bergeson, T. C. Killian, S. Kulin, L. A. Orozco, C. Orzel, S. L. Rolston Dec 1999

Creation Of An Ultracold Neutral Plasma, Scott D. Bergeson, T. C. Killian, S. Kulin, L. A. Orozco, C. Orzel, S. L. Rolston

Faculty Publications

We report the creation of an ultracold neutral plasma by photoionization of laser-cooled xenon atoms. The charge carrier density is as high as 2×10^9 cm^-3, and the temperatures of electrons and ions are as low as 100 mK and 10 uK, respectively. Plasma behavior is evident in the trapping of electrons by the positive ion cloud when the Debye screening length becomes smaller than the size of the sample. We produce plasmas with parameters such that both electrons and ions are strongly coupled.


Dual Function Euv Multilayer Mirrors For The Image Mission, David D. Allred, R. Steven Turley, Matthew B. Squires Nov 1999

Dual Function Euv Multilayer Mirrors For The Image Mission, David D. Allred, R. Steven Turley, Matthew B. Squires

Faculty Publications

We have developed a new family of EUV multilayer mirror coatings using uranium. Using this approach we have coated a set of six mirrors for the EUV Imager, a component of the IMAGE mission. This mission is a Medium Explorer (MIDEX) program, which is scheduled for launch early in 2000. The EUV Imager will study the distribution of He+ in the Earth's plasmasphere by detecting its resonantly scattered emission at 30.4 nm (41 eV) and will produce images of the structure and dynamics of the cold plasma on a global scale. There is, however, a bright at 58.4 nm (21 …


Selective Excitation And Thermal Quenching Of The Yellow Luminescence Of Gan, John S. Colton, P. Y. Yu, K. L. Teo, E. R. Weber, P. Perlin, I. Grzegory, K. Uchida Nov 1999

Selective Excitation And Thermal Quenching Of The Yellow Luminescence Of Gan, John S. Colton, P. Y. Yu, K. L. Teo, E. R. Weber, P. Perlin, I. Grzegory, K. Uchida

Faculty Publications

We report the observation of narrower structures in the yellow luminescence of bulk and thin-film n-type GaN, using the technique of selective excitation. These fine structures exhibit thermal quenching associated with an activated behavior. We attribute these fine structures to phonons and electronic excitations of a shallow donor-deep acceptor complex, and determine its activation energy for delocalization. Our results suggest that in addition to distant donor-acceptor pairs, the yellow luminescence can also involve emission complexes of shallow donors and deep acceptors.


Phonon And Elastic Instabilities In Moc And Mon, Gus L. W. Hart, Barry M. Klein Oct 1999

Phonon And Elastic Instabilities In Moc And Mon, Gus L. W. Hart, Barry M. Klein

Faculty Publications

We present several results related to the instability of MoC and MoN in the B1 (sodium chloride) structure. These compounds were proposed as potential superconductors with moderately high transition temperatures. We show that the elastic instability in B1-structure MoN, demonstrated several years ago, persists at elevated pressures, thus offering little hope of stabilizing this material without chemical doping. For MoC, another material for which stoichiometric fabrication in the B1 structure has not proven possible, we find that all of the cubic elastic constants are positive, indicating elastic stability. Instead, we find X-point phonon instabilities in MoC (and in MoN as …


Metallicity Calibration Of A Ddo Cn Index And Other Low-Resolution Indices For G And K Stars, B. J. Taylor May 1999

Metallicity Calibration Of A Ddo Cn Index And Other Low-Resolution Indices For G And K Stars, B. J. Taylor

Faculty Publications

Metallicity calibrations of low-resolution parameters are potentially useful for (at least) two problems: the properties of moving groups, and the supermetallicity problem in K giants. In this paper, metallicity calibrations are derived for six sets of parameters. One of these parameters is the DDO CN index deltaCN. This parameter and three others are calibrated for use with evolved G and K stars. Two additional sets of low-resolution parameters are calibrated for use with G and K dwarfs. The calibrations are derived by comparing the input data with two catalogs of homogenized high-dispersion results from diverse authors (see Taylor 1995, 1999a). …


Modes And Quasi-Modes For M = 1,2 In A Gyrokinetic Model For A Non-Neutral Plasma, S. Neil Rasband, Ross L. Spencer May 1999

Modes And Quasi-Modes For M = 1,2 In A Gyrokinetic Model For A Non-Neutral Plasma, S. Neil Rasband, Ross L. Spencer

Faculty Publications

Modes and quasi-modes for m = 1,2 are studied in a gyro-kinetic model for a pure-electron plasma. Only z-independent perturbations are considered. Numerical methods are used to solve the relevant differential equations for smooth, analytic density profiles. Different temperatures and representative profiles are considered and comparison is made with the familiar cold fluid model from which the results depart but little, except at higher temperatures. A continuum component to the spectrum, present in the cold-fluid model, remains in the gyro-kinetic model to the order considered.


A Zero Point And Accidental Errors For Published Values Of [Fe/H] For Cool Giants, B. J. Taylor Sep 1998

A Zero Point And Accidental Errors For Published Values Of [Fe/H] For Cool Giants, B. J. Taylor

Faculty Publications

This paper is one of a series based on published values of [Fe/H] for late-type evolved stars. Only values of [Fe/H] from high-dispersion spectroscopy or related techniques are used. The narrative in this paper begins at a point where mean values of [Fe/H] have been derived for xiVir, alphaBoo, betaGem, and the Hyades giants. By using these stars as standard stars when necessary, a zero-point data base is assembled. This data base is then expanded into its final version by correcting and adding additional data in a step-by-step process. As that process proceeds, data comparisons are used to establish rms …


An Analysis Of Temperature Dependent Photoluminescence Line Shapes In Ingan, John S. Colton, K. L. Teo, P. Y. Yu, E. R. Weber, M. F. Li, W. Lui, K. Uchida, H. Tokunaga, N. Akutsu, K. Matsumoto Sep 1998

An Analysis Of Temperature Dependent Photoluminescence Line Shapes In Ingan, John S. Colton, K. L. Teo, P. Y. Yu, E. R. Weber, M. F. Li, W. Lui, K. Uchida, H. Tokunaga, N. Akutsu, K. Matsumoto

Faculty Publications

Photoluminescence (PL) line shapes in InGaN multiple quantum well structures have been studied experimentally and theoretically between 10 and 300 K. The higher temperature PL spectra can be fitted qualitatively with a thermalized carrier distribution and a broadened joint-density-of-states. The low temperature PL line shapes suggest that carriers are not thermalized, as a result of localization by band-gap fluctuations. We deduce a localization energy of ~7 meV as compared with an activation energy of ~63 meV from thermal quenching of the PL intensity. We thus conclude that this activation energy and the band-gap fluctuation most likely have different origins.


Catalogs Of Temperatures And [Fe/H] Averages For Evolved G And K Stars, B. J. Taylor Sep 1998

Catalogs Of Temperatures And [Fe/H] Averages For Evolved G And K Stars, B. J. Taylor

Faculty Publications

A catalog of mean values of [Fe/H] for evolved G and K stars is described. The zero point for the catalog entries has been established by using differential analyses. Literature sources for those entries are included in the catalog. The mean values are given with rms errors and numbers of degrees of freedom, and a simple example of the use of these statistical data is given. For a number of the stars with entries in the catalog, temperatures have been determined. A separate catalog containing those data is briefly described.


Thermal Equilibrium Of Warm Clouds Of Charge With Small Aspect Ratio, Deborah L. Paulson, Ross L. Spencer Feb 1998

Thermal Equilibrium Of Warm Clouds Of Charge With Small Aspect Ratio, Deborah L. Paulson, Ross L. Spencer

Faculty Publications

Global thermal equilibrium computations are presented for non-neutral plasmas whose radial size is much larger than their axial thickness. Axial and radial density profiles are computed for both ideal and nonideal Penning trap fields. Simple results are obtained in the limits of both low and high central density. Comparison is made to the grid calculations of Mason et al. [Phys. Plasmas 3 (5), 1502 (1996)].


Time-Resolved Studies Of Ultracold Ionizing Collisions, Scott D. Bergeson, C. Orzel, S. Kulin, S. L. Rolston Jan 1998

Time-Resolved Studies Of Ultracold Ionizing Collisions, Scott D. Bergeson, C. Orzel, S. Kulin, S. L. Rolston

Faculty Publications

Using 40 ns laser pulses, we probe the real-time dynamics of ultracold ionizing collisions in metastable xenon. We time resolve both shielding and enhancement effects, and observe the production of Xe2^+ molecular ions through associative ionization. We estimate the rate of molecule formation in excited-state collisions, and directly measure the role of both flux enhancement and excited state survival in the collisional enhancement process. Conceptually simple theoretical models are used to predict the dynamics of the collisional shielding.


Unfolding Of The Period-Two Bifurcation In A Fiber Laser Pumped With Two Modulation Tones, Scott Glasgow, T. C. Newell, A. Gavrielides, V. Kovanis, D. Sukow, T. Erneux Dec 1997

Unfolding Of The Period-Two Bifurcation In A Fiber Laser Pumped With Two Modulation Tones, Scott Glasgow, T. C. Newell, A. Gavrielides, V. Kovanis, D. Sukow, T. Erneux

Faculty Publications

The effect of a small second frequency component on a pump modulated neodymium fiber laser is investigated experimentally and theoretically. This term, whose frequency is exactly half the primary driver, incites an unfolding of the attractor. It breaks the period two pitchfork bifurcation and splits the period one orbit. The modification of the bifurcation diagram is studied analytically by employing a map derived from the class B laser rate equations. We determine specific conditions and scaling laws for this phenomenon. Our analytical predictions are in good agreement with recorded experimental data.


System For Electron Paramagnetic Resonance Measurements At High Pressure And Low Temperature, Ke Huang, Daniel L. Decker, H. Mark Nelson, J. Dean Barnett Oct 1997

System For Electron Paramagnetic Resonance Measurements At High Pressure And Low Temperature, Ke Huang, Daniel L. Decker, H. Mark Nelson, J. Dean Barnett

Faculty Publications

Major improvements have been made on the sensitive high pressure electron paramagnetic resonance (EPR) system developed previously in 1978 at this laboratory. These changes allow low temperature measurements and provide a more stable signal. The high pressure EPR cell is placed inside a vacuum chamber to provide thermal isolation, so that the system may be cooled by a closed cycle refrigerator to temperatures between 45 and 60 K, depending on the energy input to the modulation coil. The combination of high pressure and low temperature greatly expands the thermodynamic range over which EPR measurements can be made. An improved and …


Damped Diocotron Quasi-Modes Of Non-Neutral Plasmas And Inviscid Fluids, S. Neil Rasband, Ross L. Spencer Jan 1997

Damped Diocotron Quasi-Modes Of Non-Neutral Plasmas And Inviscid Fluids, S. Neil Rasband, Ross L. Spencer

Faculty Publications

Computations of damped diocotron oscillations (quasi-modes) are described for non-neutral plasmas and inviscid fluids. The numerical method implements a suggestion made by Briggs, Daugherty, and Levy some 25 years ago [Phys. Fluids 13, 421 (1970)] to push the branch line that forms the continuum into the complex w-plane by solving the mode equation in the complex r-plane. For the special case of power-law density profiles the calculation finds the same quasi-mode frequencies found recently by Corngold [Phys. Plasmas 2, 620 (1995)]. It is found that the feature of the continuum eigenfunctions which indicates the presence of a nearby quasi-mode is …


Structural Phase Transition And Tc Distribution In Hf-Doped Lamno3 Investigated Using Perturbed-Angular-Correlation Spectroscopy, William E. Evenson, David D. Allred, Gary L. Catchen Aug 1996

Structural Phase Transition And Tc Distribution In Hf-Doped Lamno3 Investigated Using Perturbed-Angular-Correlation Spectroscopy, William E. Evenson, David D. Allred, Gary L. Catchen

Faculty Publications

Using perturbed-angular-correlation (PAC) spectroscopy, via the Hf-->Ta probe, we have measured Mn-site electric-field gradients (EFG's) at Ta nuclei in ceramic samples of LaMnO3. Two crystallographic phases coexist over a temperature interval of ≈16 K near the orthorhombic-to-rhombohedral transition at ≈724 K, which shows a thermal hysteresis of ≈1.7±0.2 K. Concurrently, in the two phases, we determined the temperature dependence of the EFG parameters, Vzz, ƞ, and δ, and the ratio of the probe concentrations A1/A2. To explain the apparent coexistence of two phases in this weakly first-order transition, we present a model that assumes a spatial distribution of Tc …