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Full-Text Articles in Numerical Analysis and Computation
Elucidating The Properties And Mechanism For Cellulose Dissolution In Tetrabutylphosphonium-Based Ionic Liquids Using High Concentrations Of Water, Brad Crawford
Graduate Theses, Dissertations, and Problem Reports
The structural, transport, and thermodynamic properties related to cellulose dissolution by tetrabutylphosphonium chloride (TBPCl) and tetrabutylphosphonium hydroxide (TBPH)-water mixtures have been calculated via molecular dynamics simulations. For both ionic liquid (IL)-water solutions, water veins begin to form between the TBPs interlocking arms at 80 mol % water, opening a pathway for the diffusion of the anions, cations, and water. The water veins allow for a diffusion regime shift in the concentration region from 80 to 92.5 mol % water, providing a higher probability of solvent interaction with the dissolving cellulose strand. The hydrogen bonding was compared between small and large …
Determination Of Kinetic Parameters From The Thermogravimetric Data Set Of Biomass Samples, Karol Postawa, Wojciech M. Budzianowski
Determination Of Kinetic Parameters From The Thermogravimetric Data Set Of Biomass Samples, Karol Postawa, Wojciech M. Budzianowski
Wojciech Budzianowski
This article describes methods of the determination of kinetic parameters from the thermogravimetric data set of biomass samples. It presents the methodology of the research, description of the needed equipment, and the method of analysis of thermogravimetric data. It describes both methodology of obtaining quantitative data such as kinetic parameters as well as of obtaining qualitative data like the composition of biomass. The study is focused mainly on plant biomass because it is easy in harvesting and preparation. Methodology is shown on the sample containing corn stover which is subsequently pyrolysed. The investigated sample show the kinetic of first order …