Physical Sciences and Mathematics Commons^™

Związki Siarki Emitowane Z Procesu Wielkopiecowego, Marian Mazur, Marek Bogacki, Robert Oleniacz

Robert Oleniacz

The article describes the problem of the presence of sulfur in the blast furnace process and identifies emission sources of sulfur compounds in this process. On the basis of the measurements and calculations, the types and quantities of these compounds emitted to the air were determined. It was found that pig iron smelting in a blast furnace causes emissions of COS, SO2 and H2S. These emissions occur by losses of blast furnace gas (COS and SO2), transport of blast furnace slag inside the furnace hall (SO2) and treatment of the slag by granulation (H2S). However, the most important are only …

Spalanie Odpadów W Procesie Skojarzonym Z Produkcją Klinkieru Cementowego - Problem Emisji Zanieczyszczeń, Robert Oleniacz

Robert Oleniacz

The paper presents a review of emissions of main gaseous pollutants (including acidic constituents), some organic compounds (including dioxins and furans), particulates and heavy metals from cement kilns burning waste fuels.

A widely employed method to reduce the cost of cement production is the substitution of traditional fuels used in cement kilns with alternative and waste-derived fuels. Cement industry offers the most acceptable method of waste (especially hazardous waste) thermal treatment and disposal at much lower cost than commercial incinerators. Characteristic for cement kilns high temperatures and long residence time of exhaust gas ensure almost complete destruction of organic compounds …

Spalanie Odpadów Niebezpiecznych W Piecach Cementowych. Część 2. Destrukcja Paliwa I Emisja Zanieczyszczeń, Robert Oleniacz

Robert Oleniacz

Conditions occurring in cement rotary kilns assure high destruction and removal efficiency (DRE) of the most stable substances, efficacious dry sorption of acid gases in the alkaline raw meal and heavy metals bounding in the clinker. Adequate operation of hazardous waste incineration in the process connected with cement clinker production does not cause increasing air pollutant emissions. Magnitude of the emissions often does not depend of this if there are using wastes in the cement kiln at all. The work presents a review of DRE levels and stack emissions for selected flue-gas constituents during hazardous waste co-combustion in cement kilns …

Emisja Związków Fluoru Z Procesów Hutnictwa Żelaza, Marian Mazur, Marek Bogacki, Robert Oleniacz

Robert Oleniacz

The paper presents the results of a comprehensive study of issues related to emissions of fluorine compounds from ferrous metallurgy processes carried out over the last few years. As part of this study raw materials used in these processes were analyzed in terms of fluorine content and its impact on the amount of air emissions of fluorine compounds. Also determined by measuring the concentration levels and emissions of fluorine in the gaseous and solid phase, including water-soluble compounds (considered to be toxic).

English title: Emissions of fluorine compounds from the processes of ferrous metallurgy.

Piece Cementowe - Konkurencja Dla Spalarni Odpadów, Robert Oleniacz

Robert Oleniacz

The paper presents the advantages of cement kilns and the possibility of their use for thermal waste utilization. The most common types of waste incinerated in these kilns and the possible degree of replacing traditional fuels with waste fuels have also been characterized. The work also discusses the problem of air pollutant emissions from the process of waste co-incineration in cement kilns. Attention has been paid to the possible increase in the use of Polish cement industry in the waste management, system, especially in the field of energy recovery from solid municipal waste, waste tires and waste from the refinery …

Emisja Zanieczyszczeń Ze Spalania Odpadów Niebezpiecznych W Piecu Obrotowym, Robert Oleniacz, Marian Mazur, Marek Bogacki

Robert Oleniacz

The article presents measurement results of air pollutant emissions from incineration of selected hazardous wastes in a full-scale rotary kiln equipped with afterburner and a wet installation for flue gas cleaning. This type of kiln is suitable for thermal disposal of many sorts of wastes, both solid and liquid. Four groups of waste were being incinerated during the tests: coke tars, medical (hospital) and pharmaceutical wastes added to greased cleaning materials, a sawdust and used gloves, varnish and lubrication wastes, as well as waste rubber and resins. The study was performed in order to answer the question: is the process …

Emisja Metali Ciężkich Ze Spalania Odpadów Niebezpiecznych, Robert Oleniacz, Marian Mazur, Marek Bogacki

Robert Oleniacz

The paper presents the results of measurements of air emissions of heavy metals from hazardous waste incineration in a multiple hearth furnace and a rotary kiln incinerator equipped with a single wet flue gas cleaning systems. In the multiple hearth furnace an industrial sewage sludge (from coke industry) was being incinerated. In the rotary kiln such wastes were being incinerated as: waste paints, varnish and lubricant, coal tars waste, contaminated cleaning rags, sawdust and used gloves, waste resins and plastics, rubber waste, outdated pharmaceuticals and medicines, and hospital waste. The research allowed us to determine the levels of pollutant concentrations …

Zastosowanie Modelu "Skrzynki" Do Oceny Poziomu Stężeń Zanieczyszczeń Komunikacyjnych W Przyziemnej Warstwie Atmosfery, Marek Bogacki, Marian Mazur, Robert Oleniacz

Robert Oleniacz

Road transport is an essential source of nitrogen oxides (NOx), carbon monoxide (CO) and reactive hydrocarbons (RHC) emissions to atmosphere. Quantity and chemical constitution of emitted substances and meteorological conditions determine the level of ozon (O3) concentration forming as a result of photochemical reactions. The method presented in the paper consists in designation of quantity and chemical constitution of substances emitted from mo-bile sources and special mathematical modeling of physical and chemical transformations that take place in the lowest atmospheric layer.

English title: The use of box model to estimate the size of traffic pollutant concentrations in the lowest atmospheric …

Emisja Zanieczyszczeń Podczas Składowania I Termicznej Utylizacji Osadów Ściekowych Z Przemysłu Koksochemicznego / Emissions During Storage And Thermal Utilization Of Sewage Sludge From Coke-Chemical Industry, Robert Oleniacz, Marian Mazur, Marek Bogacki

Robert Oleniacz

Both storage and thermal disposal of sewage sludge from industrial wastewater treatment plants are a significant source of air pollutant emissions. The study included the sludge generated in the coke-chemical industry. The paper presents the results of measurements of emissions of selected substances during storage of the waste in a closed storage hall with natural ventilation and during incineration of the mechanically dewatered sludge in a multiple hearth furnace.

Spalanie Odpadów Poszpitalnych I Farmaceutycznych W Piecu Obrotowym / Incineration Of Hospital And Pharmaceutical Wastes In A Rotary Kiln Incinerator, Robert Oleniacz, Marian Mazur, Marek Bogacki

Robert Oleniacz

The paper presents selected results of research on hospital and pharmaceutical waste incineration in a full-scale rotary kiln with variable loads of the kiln. As part of these studies measurements of air pollutant concentrations in flue gases and leaching tests of solid combustion products were carried out. Based on these studies, the maximum dose of hospital and pharmaceutical waste was proposed in the mixture with industrial wastes, which does not cause excessive air emissions. The average emission factors for the waste mixture loading were also determined.

Koncepcja Monitoringu Zanieczyszczeń Powietrza Wokół Elektrowni “Jaworzno Iii” Mobilną Stacją Pomiarową, Marian Mazur, Robert Oleniacz, Marek Bogacki, Ryszard Kozakiewicz

Robert Oleniacz

The paper presents the concept of air pollution monitoring around the Power Plant "Jaworzno III" (Poland) with the use of the mobile station. Aim of the new monitoring system is to provide information about the current state of air pollution and to enable an assessment of the environmental implications of the use of low-emission burners, run the installation of flue gas desulphurisation and changes in the way of releasing flue gases into the atmosphere. Due to economic, technical and practical the monitoring system was based on a single mobile station. Measurements will be carried out in a random scheme at …

Spalarnia Odpadów Lobbe W Dąbrowie Górniczej, Marian Mazur, Robert Oleniacz, Ryszard Januszek

Robert Oleniacz

This paper is a general characteristic of the industrial and hazardous waste incineration plant which was operated in Dąbrowa Górnicza (Poland) in the 90. The waste incineration plant is based on two incinerators - a rotary kiln and a multiple hearth furnace. Levels of selected air pollutant emissions presented in the work allow to assess the potential impact of this facility on air quality.

English title: The LOBBE incineration plant in Dąbrowa Górnicza.

Emisja Zanieczyszczeń Ze Spalania Odpadów Ściekowych W Piecu Półkowym, Robert Oleniacz, Marian Mazur, Marek Bogacki

Robert Oleniacz

The article presents incineration tests of silty-tar sludge produced in the wastewater treatment plant for coke industry. Sewage sludges were incinerated in a full-scale multiple hearth incinerator equipped with a wet flue-gas cleaning system (alkaline scrubber). Measurements of air pollutant emissions were carried out both before and after the cleaning system. The obtained results allow to conclude that the thermal utilization of sewage sludge in this type of installation might be just a little cumbersome for the environment, using the appropriate equipment for the purification of exhaust gases. The paper also specifies minimum exhaust gas cleaning performance that guarantees compliance …

Wdrażanie Monitoringu Zanieczyszczeń Powietrza Atmosferycznego W Kielcach, Marian Mazur, Robert Oleniacz, Marek Bogacki

Robert Oleniacz

Assumptions for regional environmental monitoring in the province of Kielce were developed as early as 1992. Since the beginning of particular attention were monitoring the air. The article presents the next step in the implementation of this monitoring, associated with verification of the location and the measuring range of points to measure the concentrations of air pollutants in Kielce. As a result of analysis and calculations, it was found that the original location is not always correct and does not reflect the spatial differentiation of pollutant concentrations. The proposed changes in the position of monitoring points or measurement methods were …

Zastosowanie Metody Obliczeniowo-Pomiarowej Do Oceny Stanu Zanieczyszczenia Powietrza W Nowym Sączu, Marian Mazur, Marek Bogacki, Robert Oleniacz

Robert Oleniacz

Assessment of the state of air pollution in the urban area is a difficult and complex task. Depending on the method of assessment the procedure requires a comprehensive research and calculations of air emissions from all sources occurring in the area and the use of atmospheric dispersion models or large-scale implementation of direct measurements of air pollutant concentrations. Both of these methods may also be applied simultaneously to their mutual verification.

The article presents the results of such a comprehensive assessment of air pollution on the example of the city of Nowy Sacz (Poland). This involved determining the emissions of …

Obliczanie Emisji Par Węglowodorów Z Przemysłu Rafineryjnego, Marian Mazur, Robert Oleniacz, Marek Bogacki

Robert Oleniacz

The negative effects of the refining industry for ambient air quality is mainly related to emissions of hydrocarbon vapors. Calculation methodology and estimates, the level of emissions from several years has been the research subject of many institutions and environmental agencies, including The Oil Companies’ European association for health, safety and environment in refining and distribution (CONCAWE) and American Petroleum Institute (API).

The article describes the main sources of emissions of hydrocarbons occurring in a typical refinery. In summary form also shows how to calculate the volume of a mixture of hydrocarbons emissions from these sources based on empirically validated …

Badania Emisji Chlorowodoru I Związków Fluoru Podczas Spalania Odpadów Niebezpiecznych, Marian Mazur, Robert Oleniacz, Marek Bogacki

Robert Oleniacz

The paper presents the results of measurements of the concentration of hydrogen chloride (HCl) and fluoride compounds (as HF) in raw and purified combustion gases discharged from the incineration of selected hazardous wastes. The study included two installations operating on an industrial scale: a multiple hearth furnace and a rotary kiln incinerator equipped with a single wet flue gas cleaning systems. In the multiple hearth furnace was being incinerated sludge from coke industry. In the rotary kiln were being incinerated coal (coke) tars, contaminated cleaning rags, sawdust, used gloves, outdated pharmaceuticals and medicines, hospital waste, waste paints, varnish and lubricant, …

Emisja Zanieczyszczeń Ze Spalania Odpadów Farmaceutycznych I Poszpitalnych W Piecu Obrotowym, Robert Oleniacz, Marian Mazur, Marek Bogacki

Robert Oleniacz

The work presents the problem of management and thermal treatment of medicines and hospital wastes and investigation results of incineration of these waste in the full-scale rotary kiln with wet gas cleaning equipment (alkaline scrubber). On the basis of measurements of air pollutant concentrations in combustion gases, maximum dose of these wastes in the feed to the kiln was specified in order to ensure a relatively low stack emissions using the hypothetical high-efficiency flue-gas treatment system.

English title: Pollutant emissions from incineration of pharmaceutical and hospital waste in a rotary kiln.

Emisja Zanieczyszczeń Ze Spalania Odpadów Przemysłowych W Piecu Obrotowym, Robert Oleniacz, Marian Mazur, Marek Bogacki

Robert Oleniacz

The paper presents the results of measurements of the concentration of selected pollutants in the flue gases from the incineration of industrial wastes in a full-scale rotary kiln. The study included three waste mixtures introduced into the kiln: 1) coal tar waste (tar origin of coke); 1) waste paints, varnish and lubricant; 3) resin and rubber waste. The article also assesses the effectiveness of the existing wet flue gas cleaning system (alkaline scrubber) and specifies minimum exhaust gas purifying performance guarantees compliance with European emission standards for waste incineration.

English title: Pollutant emissions from incineration of industrial waste in a …

Emisja Związków Siarki Z Procesu Wielkopiecowego, Marian Mazur, Marek Bogacki, Robert Oleniacz

Robert Oleniacz

The paper describes the problem of the presence of sulfur in the blast furnace process and identifies emission sources of sulfur compounds in this process. On the basis of the measurements and calculations, the types and quantities of these compounds emitted to the air were determined. It was found that pig iron smelting in a blast furnace causes emissions of COS, SO2 and H2S. These emissions occur by losses of blast furnace gas (COS and SO2), transport of blast furnace slag inside the furnace hall (SO2) and treatment of the slag by granulation (H2S). However, the most important are only …

Wpływ Komponentów Alkalicznych W Procesach Spiekania I Wielkopiecowym Na Technologię I Emisję Zanieczyszczeń, Marian Mazur, Ryszard Benesch, Andrzej Łędzki, Robert Oleniacz

Robert Oleniacz

The paper presents the impact of alkali metals on sintering and blast furnace processes and air pollutant emissions including particulate matter. On the basis of the balance calculations, it was found that the main source of alkali (Na2O and K2O) in the sintering process is a raw mixture unweathered. The calculations showed that the level of dust emissions from the sinter strand to a large extent depends on: the total alkali content in a mixture of sinter, ash content in coke breeze, K2O concentration in coke ash and alkalinity of the produced sinter. Alkali metals are introduced into the blast …

Monitoring Zanieczyszczeń Powietrza Wokół Elektrowni "Jaworzno Iii", Marian Mazur, Robert Oleniacz, Marek Bogacki, Ryszard Kozakiewicz

Robert Oleniacz

The article presents the concept of system of monitoring of air pollution around the Power Plant "Jaworzno III" in Jaworzno (Poland), whose objective is to evaluate the impact of this object on air quality. This system is based on a few measuring points and a mobile station should also allow for the assessment of ecological effects associated with the use of low-emission burners in power boilers (reduction of NOx emission) and run the wet installation of flue gas desulfurization (reduction of SO2 emission). An additional aim of the measurements is to identify the possible effects of a changes in the …

Kompleksowa Ocena Jakości Powietrza W Nowym Sączu Przy Pomocy Metody Obliczeniowo-Pomiarowej, Marian Mazur, Marek Bogacki, Robert Oleniacz

Robert Oleniacz

The paper presents the results of a comprehensive assessment of air pollution in the city of Nowy Sącz (Poland). This involved determining the emissions of selected pollutants from various sources with their percentages of the total emission and immission on the area under consideration. As a result of measurement of concentrations of particulate matter and benzo(a)pyrene in several parts of the city were verified results of theoretical calculations and determined the size of the inflow of pollutants from outside the area in question.

English title: A comprehensive assessment of air quality in Nowy Sącz using computational and measuring methods.

Emisja Chlorowodoru I Związków Fluoru Ze Spalania Odpadów Niebezpiecznych, Marian Mazur, Robert Oleniacz, Marek Bogacki

Robert Oleniacz

The paper presents the results of measurements of the concentration of hydrogen chloride (HCl) and fluoride compounds (as HF) in raw and purified combustion gases discharged from the incineration of selected hazardous wastes. The study included two installations operating on an industrial scale: a multiple hearth furnace and a rotary kiln incinerator equipped with a single wet flue gas cleaning systems. In the multiple hearth furnace was being incinerated sludge from coke industry. In the rotary kiln were being incinerated coal (coke) tars, contaminated cleaning rags, sawdust, used gloves, outdated pharmaceuticals and medicines, hospital waste, waste paints, varnish and lubricant, …

Termiczna Utylizacja Odpadów W Spalarni "Lobbe" W Dąbrowie Górniczej – Problemy Emisji Zanieczyszczeń, Marian Mazur, Ryszard Januszek, Robert Oleniacz

Robert Oleniacz

The paper presents selected results of comprehensive studies of air quality impact assessment carried out for the „LOBBE” incineration plant in Dąbrowa Górnicza (Poland) in 1995. It focused mainly on air emissions problems. Stack concentrations and emissions of selected air pollutants formed during thermal treatment processes of different kinds of waste materials and incinerators is performed. The study covered both sludge and slime incinerated in a multiple hearth furnace and four example groups of waste materials incinerated in a rotary furnace. The research have helped confirm the levels of air emissions as a function of the type of incinerated waste …

Zanieczyszczenie Powietrza Kotliny Sądeckiej Przez Przemysł Elektrodowy, Marian Mazur, Marek Bogacki, Robert Oleniacz

Robert Oleniacz

The article evaluates the impact of electrode industry (production of carbon and graphite electrodes in the plant Polgraph SA) on air quality in the Kotlina Sądecka valley and the city Nowy Sącz (Poland). The work presents completed so far environmental investments and the level of emissions of selected air pollutants characteristic of the analyzed facility, including PAHs emissions. Based on the modeling of the dispersion of pollutants in ambient air was determined the levels of pollutant concentrations in the air and location of most affected areas. The calculation results were compared with the results of direct measurements. Particular attention was …

Ocena I Weryfikacja Lokalizacji Stanowisk Pomiarowych Imisji Zanieczyszczeń Powietrza W Województwie Kieleckim, Marian Mazur, Robert Oleniacz

Robert Oleniacz

The paper presents the implementation of air pollution monitoring in the province of Kielce (Poland), associated with verification of the location and the measuring range of points to measure the concentrations of air pollutants. For this purpose were used calculations of the pollutants dispersion and statistical analysis of measurement results obtained on existing measuring stations. In the statistical calculations were used analysis of variance homogeneity, based on Cochran, Bartlett and Hartley tests. As a result of analysis and calculations, it was found that the original location is not always correct and does not reflect the spatial differentiation of pollutant concentrations. …

A Proposal For United States/Polish Collaboration On Energy And The Environment, Carole B. Szpunar

Chemistry: Faculty Publications and Other Works

Argonne National Laboratory, a U.S. Department of Energy facility that is operated by the University of Chicago and located southwest of Chicago, Illinois, has proposed a collaborative effort by the United States and Poland to conduct applied research on energy and environmental topics of common interest. Through this collaboration, evaluative studies on energy and environmental assessment issues could be developed and implemented by Argonne and one or more sister institutions in Poland, which could lead to active research, development, and demonstration joint activities. The objective of this initiative is to produce strategies and options for review by Poland's decision makers …