Physical Sciences and Mathematics Commons^™

Long-Term Droughtiness And Drought Tolerance Of Eastern Us Forests Over Five Decades, Matthew P. Peters, Louis R. Iverson, Stephen N. Matthews

United States Department of Agriculture, Forest Service / University of Nebraska-Lincoln: Faculty Publications

Droughts can influence forest composition directly by limiting water or indirectly by intensifying other stressors that affect establishment, growth, and mortality. Using community assemblages of eastern US tree species and drought tolerance characteristics assessed from literature, we examine recent drought conditions in relation to the spatial distribution of species and their tolerance to drought. First we calculate and compare a cumulative drought severity index (CDSI) for the conterminous US for the periods 1960–1986 and 1987–2013 using climate division Palmer Drought Severity Index (PDSI) values and a gridded self-calibrated PDSI dataset. This comparison indicates that drought conditions in the East tend …

Mega-Electron-Volt Ultrafast Electron Diffraction At Slac National Accelerator Laboratory, Stephen Weathersby, G. Brown, Martin Centurion, T. F. Chase, Ryan Coffee, Jeff Corbett, J. P. Eichner, J. C. Frisch, A. R. Fry, M. Gühr, Nick Hartmann, Carsten Hast, R. Hettel, R. K. Jobe, E. N. Jongewaard, J. R. Lewandowski, R. K. Li, A. M. Lindenberg, Igor Makasyuk, J. E. May, D. Mccormick, M. N. Nguyen, Alexander Reid, Xiaozhe Shen, K. Sokolowski-Tinten, Theodore Vecchione, Sharon Vetter, J. Wu, Jie Yang, H. A. Dürr, Xijie Wang

Martin Centurion Publications

Ultrafast electron probes are powerful tools, complementary to x-ray free-electron lasers, used to study structural dynamics in material, chemical, and biological sciences. High brightness, relativistic electron beams with femtosecond pulse duration can resolve details of the dynamic processes on atomic time and length scales. SLAC National Accelerator Laboratory recently launched the Ultrafast Electron Diffraction (UED) and microscopy Initiative aiming at developing the next generation ultrafast electron scattering instruments. As the first stage of the Initiative, a mega-electron-volt (MeV) UED system has been constructed and commissioned to serve ultrafast science experiments and instrumentation development. The system operates at 120-Hz repetition rate …

Self-Assembly Of Strongly Dipolar Molecules On Metal Surfaces, Donna A. Kunkel, James Hooper, Scott Simpson, Daniel P. Miller, Lucie Routaboul, Pierre Braunstein, Bernard Doudin, Sumit Beniwal, Peter A. Dowben, Ralph Skomski, Eva Zurek, Axel Enders

Axel Enders Publications

The role of dipole-dipole interactions in the self-assembly of dipolar organic molecules on surfaces is investigated. As a model system, strongly dipolar model molecules, p-benzoquinonemonoimine zwitterions (ZI) of type C6H2(· · · NHR)2(· · · O)2 on crystalline coinage metal surfaces were investigated with scanning tunneling microscopy and first principles calculations. Depending on the substrate, the molecules assemble into small clusters, nano gratings, and stripes, as well as in two-dimensional islands. The alignment of the molecular dipoles in those assemblies only rarely assumes the lowest electrostatic energy configuration. Based on calculations of the electrostatic energy for various experimentally observed molecular …

Low Trap-State Density And Long Carrier Diffusion In Organolead Trihalide Perovskite Single Crystals, Dong Shi, Valerio Adinolfi, Riccardo Comin, Mingjian Yuan, Erkki Alarousu, Andrei Buin, Yin Chen, Sjoerd Hoogland, Alexander Rothenberger, Khabiboulakh Katsiev, Yaroslav B. Losovyj, Xin Zhang, Peter A. Dowben, Omar F. Mohammed, Edward H. Sargent, Osman M. Bakr

Peter Dowben Publications

The fundamental properties and ultimate performance limits of organolead trihalide MAPbX₃ (MA = CH₃NH₃ +; X = Br^– or I^–) perovskites remain obscured by extensive disorder in polycrystalline MAPbX₃ films. We report an antisolvent vapor-assisted crystallization approach that enables us to create sizable crack-free MAPbX₃ single crystals with volumes exceeding 100 cubic millimeters. These large single crystals enabled a detailed characterization of their optical and charge transport characteristics. We observed exceptionally low trap-state densities on the order of 10⁹ to 10¹⁰ per cubic centimeter in MAPbX₃ single crystals …

Toric Varieties, Monoid Schemes And Cdh Descent, Guillermo Cortiñas, C. Haesemeyer, Mark E. Walker, Charles Weibel

Department of Mathematics: Faculty Publications

We give conditions for the Mayer–Vietoris property to hold for the algebraic K-theory of blow-up squares of toric varieties and schemes, using the theory of monoid schemes. These conditions are used to relate algebraic K-theory to topological cyclic homology in characteristic p. To achieve our goals, we develop many notions for monoid schemes based on classical algebraic geometry, such as separated and proper maps and resolution of singularities.

Crosscap Number: Handcuff Graphs And Unknotting Number, Anne Kerian

Department of Mathematics: Dissertations, Theses, and Student Research

Many types of invariants are used in the study of knots. Some are based on polynomials, some are purely algebraic, and some have their origins in geometry. One of the best known geometric knot invariants is the genus of a knot. A closely related but lesser-known invariant, crosscap number, was first introduced by Bradd Evans Clark in 1978. This thesis primarily concerns crosscap number two knots. Starting with a list of knots found to have crosscap number two by Burton and Ozlen using a linear programing approach, we verify, though are unable to expand, this list using a computer search. …

Diatoms At >5000 Meters In The Quelccaya Summit Dome Glacier, Peru, Sherilyn C. Fritz, Bruce E. Brinson, W. E. Billups, Lonnie G. Thompson

Department of Earth and Atmospheric Sciences: Faculty Publications

Diatoms were found in late Holocene age ice-core samples recovered from the Quelccaya Summit Dome in the tropical Andes of Peru and were imaged by environmental scanning electron microscopy and identified. Freshwater diatoms in the genera Hantzschia, Pinnularia, and Aulacoseira were the most common taxa in the samples and indicate a freshwater source for the material, which also is suggested by the presence of the freshwater alga Volvox. The overall species composition of the diatoms suggests that the majority of taxa originated from a high-elevation lake or wetland in the cordillera surrounding the ice cap. The abundant …

First Report On Dinosaur Tracks From The Burro Can Yon Formation, San Juan County, Utah, Usa – Evidence Of A Diverse, Hitherto Un Known Lower Cretaceous Dinosaur Fauna, Jesper Milan, Luis M. Chiappe, David B. Loope, James I. Kirkland, Martin G. Lockley

Department of Earth and Atmospheric Sciences: Faculty Publications

The newly discovered White Mesa tracksite in the Burro Canyon Formation represents a snap shot of a diverse, Lower Cretaceous dinosaur fauna from south-eastern Utah. The tracks were found at a construction site where the sand stone had been bull dozed and broken up. All tracks were found as deep, well-preserved natural casts on the under side of the sand stone slabs. Individual theropod tracks are 19–57 cm in length; one peculiar track shows evidence of a possible pathological swelling in the middle of digit III and an apparently didactyl track is tentatively as signed to a dromaeosaurid. Individual sauropod …

The Footprints Of Ancient Co2-Driven Flow Systems: Ferrous Carbonate Concretions Below Bleached Sandstone, David B. Loope, Richard M. Kettler

Department of Earth and Atmospheric Sciences: Faculty Publications

Iron-rich carbonates and the oxidized remains of former carbonates (iron-oxide concretions) underlie bleached Navajo Sandstone over large portions of southern Utah. Iron in the carbonates came from hematite rims on sand grains in the upper Navajo that were dissolved when small quantities of methane accumulated beneath the sealing Carmel Formation. As a second buoyant gas (CO₂ derived from Oligocene–Miocene magmas) reached the seal and migrated up dip, it dissolved in the underlying water, enhancing the solution’s density. This water carried the released ferrous iron and the methane downward. Carbonates precipitated when the descending, reducing water degassed along fractures. The …

Diagenetic Incorporation Of Sr Into Aragonitic Bivalve Shells: Implications For Chronostratigraphic And Palaeoenvironmental Interpretations, Maria C. Marcano, Tracy D. Frank, Samuel B. Mukasa, Kyger C. Lohmann, Marco Taviani

Department of Earth and Atmospheric Sciences: Faculty Publications

Aragonite is easily altered during diagenesis, therefore presumed pristine when present. In effect, beyond polymorphic transformation to calcite, alteration paths of aragonite remain poorly understood despite heavy reliance on such material to produce palaeoenvironmental and chronostratigraphic interpretations. Previous work on core material from Southern McMurdo Sound, Antarctica, showed that unlike their calcitic counterparts, seemingly unaltered aragonite shell fragments invariably produced older than expected ⁸⁷Sr/⁸⁶Sr ages. In this study, we pursued additional analyses of these aragonite shells and of the porewater of the core to understand this discrepancy. Aragonite mineralogy was reconfirmed and elemental mapping of shell fragments …

Elasticity Of Differentiated And Undifferentiated Human Neuroblastoma Cells Characterized By Atomic Force Microscopy, Shijia Zhao, Alexander B. Stamm, Jeong Soon Lee, Alexei Gruverman, Jung Yul Lim, Linxia Gu

Department of Mechanical and Materials Engineering: Faculty Publications

Human neuroblastoma (SH-SY5Y) cells, with its ability to differentiate into neurons, have been widely used as the in vitro cell culture model for neuroscience research, especially in studying the pathogenesis of Parkinson’s disease (PD) and developing therapeutic strategies. Cellular elasticity could potentially serve as a biomarker to quantitatively distinguish undifferentiated and differentiated SH-SY5Y cells. The goal of this work is to characterize the retinoic acid (RA) induced alternations of elastic properties of SH-SY5Y cells using atomic force microscopy (AFM). The elasticity was measured at multiple points of a single cell. Results have shown that the differentiation of SH-SY5Y cell led …

Acoustic Nonlinearity Parameters For Transversely Isotropic Polycrystalline Materials, Christopher M. Kube, Joseph A. Turner

Department of Mechanical and Materials Engineering: Faculty Publications

This article considers polycrystalline materials with macroscopic elastic anisotropy and the effect of the anisotropy on the quadratic nonlinearity parameter used to describe second harmonic generation in solids. The polycrystal is assumed to have transversely isotropic elastic symmetry, which leads to a directional dependence of the nonlinearity parameters. Additionally, the anisotropy leads to second harmonic generation from an input shear wave. Estimates of the longitudinal and shear wave nonlinearity parameters are given as a function of single-crystal elastic constants, macroscopic anisotropy constants, and propagation direction. An inverse model is presented that relates measured nonlinearity parameters to the macroscopic anisotropy constants. …

Interfacial Electronic Structure At The Ch3nh3pbi3/Moox Interface, Peng Liu, Xiaoliang Liu, Lu Lyu, Haipeng Xie, Hong Zhang, Dongmei Niu, Han Huang, Cheng Bi, Zhengguo Xiao, Jinsong Huang, Yongli Gao

Department of Mechanical and Materials Engineering: Faculty Publications

Interfacial electronic properties of the CH₃NH₃PbI₃ (MAPbI₃)/M_oOx interface are investigated using ultraviolet photoemission spectroscopy and X-ray photoemission spectroscopy. It is found that the pristine MAPbI₃ film coated onto the substrate of poly (3,4-ethylenedioxythiophene) poly(styrenesulfonate)/indium tin oxide by two-step method behaves as an n-type semiconductor, with a band gap of ~1.7 eV and a valence band edge of 1.40 eV below the Fermi energy (EF). With the MoOx deposition of 64A ° upon MAPbI3, the energy levels of MAPbI3 shift toward higher binding energy by 0.25 eV due to electron transfer …

The Operation Mechanism Of Poly(9,9-Dioctylfluorenyl-2,7-Diyl) Dots In High Efficiency Polymer Solar Cells, Chunyu Liu, Yeyuan He, Xinyuan Zhang, Zhiqi Li, Liang Shen, Zhihui Zhang, Wenbin Guo, Shengping Ruan

Department of Mechanical and Materials Engineering: Faculty Publications

The highly efficient polymer solar cells were realized by doping poly(9,9-dioctylfluorenyl-2,7-diyl) (PFO) dots into active layer. The dependence of doping amount on devices performance was investigated and a high efficiency of 7.15% was obtained at an optimal concentration, accounting for a 22.4% enhancement. The incorporation of PFO dots (Pdots) is conducted to the improvement of Jsc and fill factor mainly due to the enhancement of light absorption and charge transport property. Pdots blended in active layer provides an interface for charge transfer and enables the formation of percolation pathways for electron transport. The introduction of Pdots was proven an effective …

Surface Analytical Investigation On Organometal Triiodide Perovskite, Chengong Wang, Xiaoliang Liu, Congcong Wang, Zhengguo Xiao, Cheng Bi, Yuchuan Shao, Jinsong Huang, Yongli Gao

Department of Mechanical and Materials Engineering: Faculty Publications

In a little over a year, there has been an unexpected breakthrough and rapid evolution of highly efficient solid-state hybrid solar cells based on organometal trihalide perovskite materials. This technology has the potential to produce solar cells with the very highest efficiencies while retaining the very lowest cost. The authors have measured the electronic density of states of CH₃NH₃PbI₃ using ultraviolet photoemission spectroscopy (UPS), inverse photoemission spectroscopy (IPES), and x-ray photoemission spectroscopy (XPS). The valence band maximum and conduction band minimum positions are obtained from the UPS and IPES spectra, respectively, by linear extrapolation of …

The Effect Of Basement Fault Reactivation On The Triassic—Recent Geology Of Kurdistan, North Iraq, Caroline M. Burberry

Department of Earth and Atmospheric Sciences: Faculty Publications

The Zagros orogenic belt is underlain by a complex faulted Precambrian basement. Major fault trends originating in this basement have been invoked to explain large-scale structural changes along the strike of the orogen, e.g. the development of the Kirkuk Embayment (Kurdistan, Iraq) and the Lurestan Salient (Iran). However, within the Kirkuk Embayment, these structural trends have not previously been considered as an interacting group of faults which are periodically reactivated. This contribution first presents a revised basement fault map for the Kirkuk Embayment, created from interpreted gravity data, existing fault maps and remote sensing lineament analyses. This map is then …

Temporal And Spatial Variability In Dune Reactivation Across The Nebraska Sand Hills, Usa, Rebecca L. Schmeisser Mckean, Ronald J. Goble, Joseph B. Mason, James Swinehart, David B. Loope

Department of Earth and Atmospheric Sciences: Faculty Publications

The Nebraska Sand Hills is a stabilized dune field on the Great Plains of North America. Although it is well known that this dune field, like several others on the Great Plains, last experienced widespread activity during the Medieval Climatic Anomaly (MCA, ~AD 900–1300), spatial variation in the timing and nature of drought development is poorly constrained. To elucidate spatial trends in dune reactivation, samples potentially representing MCA activity across the Sand Hills were collected and dated using optically stimulated luminescence (OSL). Ages from the older part of the MCA were obtained from eolian sediments in the northwestern Sand Hills, …

Global Analysis Of Saturation Artifacts In The Viirs Infrared Channels And The Effects Of Sample Aggregation, Thomas N. Polivka, Edward Hyer, Jun Wang, David A. Peterson

Department of Earth and Atmospheric Sciences: Faculty Publications

Unlike previous spaceborne Earth observing sensors, the Visible Infrared Imaging Radiometer Suite (VIIRS) employs onboard sample aggregation to reduce downlink bandwidth requirements and preserve spatial resolution across the scan. To examine the potentially deleterious impacts of onboard sample aggregation when encountering detector saturation, nearly four months of the National Oceanic and Atmospheric Administration’s Nightfire product are analyzed, which contains a subset of the hottest observed nighttime pixels. An empirical method for identifying saturation is devised. The M12 band (3.69 μm) is the most frequently saturating band with 0.15% of the Nightfire pixels at or near the ~359-K detector saturation limit; …

Patterns Of Terrestrial And Limnologic Development In The Northern Greater Yellowstone Ecosystem (Usa) During The Late-Glacial/Early-Holocene Transition, Teresa R. Krause, Yanbin Lu, Cathy Whitlock, Sherilyn C. Fritz, Kenneth L. Pierce

Department of Earth and Atmospheric Sciences: Faculty Publications

A high-resolution record of pollen, charcoal, diatom, and lithologic data from Dailey Lake in south-western Montana describes postglacial terrestrial and limnologic development from ice retreat ca. 16,000 cal yr BP through the early Holocene. Following deglaciation, the landscape surrounding Dailey Lake was sparsely vegetated, and erosional input into the lake was high. As summer insolation increased and ice recessional processes subsided, Picea parkland developed and diatoms established in the lake at 13,300 cal yr BP. Closed subalpine forests of Picea, Abies, and Pinus established at 12,300 cal yr BP followed by the development of open Pinus and Pseudotsuga forests at …

Spatial And Temporal Variation In Penetrative Strain During Compression: Insights From Analog Models, Caroline M. Burberry

Department of Earth and Atmospheric Sciences: Faculty Publications

Penetrative strain constitutes the proportion of the total shortening across an orogen that is not accommodated by the development of macroscale structures such as folds and thrusts. The accommodation of shortening by penetrative strain is widely considered to be an important process during compression, but variation in the distribution of penetrative strain during a deformation sequence is not well understood. This study provides some first-order constraints on magnitude, timing, and distribution of penetrative strain during deformation. Eight simple models, each with a geometrically and mechanically similar starting configuration, within the limits of sandbox models, were shortened to different amounts. Model …

Atmospheric Circulation Processes Contributing To A Multidecadal Variation In Reconstructed And Modeled Indian Monsoon Precipitation, Qianru Wu, Qi Hu

Department of Earth and Atmospheric Sciences: Faculty Publications

An analysis of the recently reconstructed gridded May–September total precipitation in the Indian monsoon region for the past half millennium discloses significant variations at multidecadal timescales. Meanwhile, paleo-climate modeling outputs from the National Center for Atmospheric Research Community Climate System Model 4.0 show similar multidecadal variations in the monsoon precipitation. One of those variations at the frequency of 40–50 years per cycle is examined in this study. Major results show that this variation is a product of the processes in that the meridional gradient of the atmospheric enthalpy is strengthened by radiation loss in the high-latitude and polar region. Driven …

Temporal Dynamics Of Groundwater-Dissolved Inorganic Carbon Beneath A Drought-Affected Braided Stream: Platte River Case Study, Audrey R. Boerner, John B. Gates

Department of Earth and Atmospheric Sciences: Faculty Publications

Impacts of environmental changes on groundwater carbon cycling are poorly understood despite their potentially high relevance to terrestrial carbon budgets. This study focuses on streambed groundwater chemistry during a period of drought-induced river drying and consequent disconnection between surface water and groundwater. Shallow groundwater underlying vegetated and bare portions of a braided streambed in the Platte River (Nebraska, USA) was monitored during drought conditions in summer 2012. Water temperature and dissolved inorganic carbon (dominated by HCO₃^-) in streambed groundwater were correlated over a 3 month period coinciding with a decline in river discharge from 35 to 0 …

Hydrophobic Organic Contaminant Transport Property Heterogeneity In The Borden Aquifer, Richelle M. Allen-King, Indra Kalinovich, David F. Dominic, Guohui Wang, Reid Polmanteer, Dana Divine

Conservation and Survey Division: Faculty and Staff Publications

We determined that the spatial heterogeneity in aquifer properties governing the reactive transport of volatile organic contaminants is defined by the arrangement of lithofacies. We measured permeability (k) and perchloroethene sorption distribution coefficient (K_d) for lithofacies that we delineated for samples from the Canadian Forces Base Borden Aquifer. We compiled existing data and collected 57 new cores to characterize a 30 m section of the aquifer near the test location of Mackay et al. (1986). The k and K_d were measured for samples taken at six elevations from all cores to create a data …

Nebraska Statewide Groundwater-Level Monitoring Report 2015, A. R. Young, M. E. Burbach, L. M. Howard

Conservation and Survey Division: Faculty and Staff Publications

No abstract provided.

B27−: Appearance Of The Smallest Planar Boron Cluster Containing A Hexagonal Vacancy, Wei-Li Li, Rhitankar Pal, Zachary A. Piazza, Xiao Cheng Zeng, Lai-Sheng Wang

Xiao Cheng Zeng Publications

Photoelectron spectroscopy and ab initio calculations have been carried out to probe the structures and chemical bonding of the B₂₇⁻ cluster. Comparison between the experimental spectrum and the theoretical results reveals a two-dimensional (2D) global minimum with a triangular lattice containing a tetragonal defect (I) and two low-lying 2D isomers (II and III), each with a hexagonal vacancy. All three 2D isomers have 16 peripheral boron atoms and 11 inner boron atoms. Isomer I is shown to be mainly responsible for the observed photoelectron spectrum with isomers II and III as minor contributors. Chemical bonding analyses of these …

Unraveling The Mechanism Of Selective Ion Transport In Hydrophobic Subnanometer Channels, Hui Li, Joseph S. Francisco, Xiao Cheng Zeng

Xiao Cheng Zeng Publications

Recently reported synthetic organic nanopore (SONP) can mimic a key feature of natural ion channels, i.e., selective ion transport. However, the physical mechanism underlying the K⁺/Na⁺ selectivity for the SONPs is dramatically different from that of natural ion channels. To achieve a better understanding of the selective ion transport in hydrophobic subnanometer channels in general and SONPs in particular, we perform a series of ab initio molecular dynamics simulations to investigate the diffusivity of aqua Na⁺ and K⁺ ions in two prototype hydrophobic nanochannels: (i) an SONP with radius of 3.2 Å, and (ii) single-walled …

High-Performance Simulations Of Coherent Synchrotron Radiation On Multicore Gpu And Cpu Platforms, B. Terzić, A. Godunov, K. Arumugam, D. Ranjan, M. Zubair

Physics Faculty Publications

Coherent synchrotron radiation (CSR) is an effect of self-interaction of an electron bunch as it traverses a curved path. It can cause a significant emittance degradation and microbunching. We present a new high-performance 2D, particle-in-cell code which uses massively parallel multicore GPU/GPU platforms to alleviate computational bottlenecks. The code formulates the CSR problem from first principles by using the retarded scalar and vector potentials to compute the self-interaction fields. The speedup due to the parallel implementation on GPU/CPU platforms exceeds three orders of magnitude, thereby bringing a previously intractable problem within reach. The accuracy of the code is verified against …

Room-Temperature Distance Measurements Of Immobilized Spin-Labeled Protein By Deer/Peldor, Virginia Meyer, Michael A. Swanson, Laura J. Clouston, Przemysław J. Boratyński, Richard A. Stein, Hassane S. Mchaourab, Andrzej Rajca, Sandra S. Eaton, Gareth R. Eaton

Andrzej Rajca Publications

Nitroxide spin labels are used for double electron-electron

resonance (DEER) measurements of distances between sites in

biomolecules. Rotation of gem-dimethyls in commonly used

nitroxides causes spin echo dephasing times (T_m) to be too

short to perform DEER measurements at temperatures between

∼80 and 295 K, even in immobilized samples. A spirocyclohexyl

spin label has been prepared that has longer T_m between 80

and 295 K in immobilized samples than conventional labels. Two

of the spirocyclohexyl labels were attached to sites on T4 lysozyme introduced by site-directed spin labeling. Interspin

distances up to ∼4 nm were …

North-Central Nebraska Geology: Niobrara River Valley In Brown, Cherry, And Keya Paha Counties, R. M. Joeckel, L. M. Howard, S T. Tucker

Conservation and Survey Division: Faculty and Staff Publications

No abstract provided.

Estimation Of Daily Air Temperature Based On Modis Land Surface Temperature Products Over The Corn Belt In The Us, Linglin Zeng, Brian D. Wardlow, Tsegaye Tadesse, Jie Shan, Michael Hayes, Deren Li, Daxiang Xiang

Center for Advanced Land Management Information Technologies: Publications

Air temperature (Ta) is a key input in a wide range of agroclimatic applications. Moderate Resolution Imaging Spectroradiometer (MODIS) Ts (Land Surface Temperature (LST)) products are widely used to estimate daily Ta. However, only daytime LST (Ts-day) or nighttime LST (Ts-night) data have been used to estimate Tmax/Tmin (daily maximum or minimum air temperature), respectively. The relationship between Tmax and Ts-night, and the one between Tmin and Ts-day has not been studied. In this study, both the ability of Ts-night data to estimate Tmax and the ability of Ts-day data to estimate Tmin were tested and studied in the Corn …