Physical Sciences and Mathematics Commons^™

Tunable Monoenergetic Electron Beams From Independently Controllable Laser-Wakefield Acceleration And Injection, Grigory V. Golovin, Shouyuan Chen, Nathan D. Powers, Cheng Liu, Sudeep Banerjee, J Zhang, M Zeng, Z Sheng, Donald P. Umstadter

Donald Umstadter Publications

We report the results of experiments on laser-wakefield acceleration in a novel two-stage gas target with independently adjustable density and atomic-composition profiles.We were able to tailor these profiles in a way that led to the separation of the processes of electron injection and acceleration and permitted independent control of both. This resulted in the generation of stable, quasimonoenergetic electron beams with central energy tunable in 50–300 MeV range. For the first time, we are able to independently control the beam charge and energy spread over the entire tunability range.

Growth Factor And Ultrasound-Assisted Bioreactor Synergism For Human Mesenchymal Stem Cell Chondrogenesis, Sanjukta Guha Thakurta, Gaurav Budhiraja, Anuradha Subramanian

Department of Chemical and Biomolecular Engineering: Faculty Publications

Ultrasound at 5.0 MHz was noted to be chondro-inductive, with improved SOX-9 gene and COL2A1 protein expression in constructs that allowed for cell-to-cell contact. To achieve tissue-engineered cartilage using macroporous scaffolds, it is hypothesized that a combination of ultrasound at 5.0 MHz and transforming growth factor-β3 induces human mesenchymal stem cell differentiation to chondrocytes. Expression of miR-145 was used as a metric to qualitatively assess the efficacy of human mesenchymal stem cell conversion. Our results suggest that in group 1 (no transforming growth factor-β3, no ultrasound), as anticipated, human mesenchymal stem cells were not efficiently differentiated into chondrocytes, judging by …

Recyclable Magnetite Nanoparticle Catalyst For One-Pot Conversion Of Cellobiose To 5-Hydroxymethylfurfural In Water, Anuja Bhalkikar, Zane C. Gernhart, Chin Li Cheung

Department of Chemistry: Faculty Publications

Environmentally benign and easily recoverable magnetite nanoparticles (Fe₃O₄ NPs) were demonstrated to catalyze the one-pot conversion of cellobiose, a glucose disaccharide, to 5-hydroxymethylfurfural (5-HMF).Theconversion was achieved in water under hydrothermal conditions.The catalytic activity of Fe₃O₄ NPs surpassed those of iron (II) and iron (III) chlorides in this reaction. Optimized cellobiose conversion reactions catalyzed with Fe₃O₄ NPs gave the highest 5-HMF yields of 23.4 ± 0.6% at 160^∘C for 24 hours. After three reuses, the Fe₃O₄ NP catalyst retained its catalytic activity with similar 5-HMF yields, demonstrating …

Simulation Evidence Of Hexagonal-To-Tetragonal Znse Structure Transition: A Monolayer Material With A Wide-Range Tunable Direct Bandgap, Lei Li, Pengfei Li, Ning Lu, Jun Dai, Xiao Cheng Zeng

Department of Chemistry: Faculty Publications

2D material with tunable direct bandgap in the intermediate region (i.e., ≈2–3 eV) is key to the achievement of high efficiency in visible-light optical devices. Herein, a simulation evidence of structure transition of monolayer ZnSe from the experimental pseudohexagonal structure to the tetragonal structure (t-ZnSe) under lateral pressure is shown, suggesting a possible fabrication route to achieve the t-ZnSe monolayer. The as-produced t-ZnSe monolayer exhibits highly tunable bandgap under the biaxial strains, allowing strain engineering of t-ZnSe’s bandgap over a wide range of 2–3 eV. Importantly, even under the biaxial strain up to 7%, the t-ZnSe monolayer still keeps its …

Synthetic Studies Of Ambruticin: Preparation Of The C1-C8 Tetrahydropyran And The C17-C24 Dihydropyran Segments, Luping Liu, Julie L. Wondergem, William A. Donaldson

Chemistry Faculty Research and Publications

The C1-C8 tetrahydropyran and the C17-C24 dihdropyran segments of ambruticin were prepared from L-arabinose in 11 steps, 7.6% overall yield and from (S)-ethyl lactate in 8 steps, 22.2% overall yield respectively.

Affinity Chromatography: A Historical Perspective, David S. Hage, Ryan E. Matsuda

David Hage Publications

Affinity chromatography is one of the most selective and versatile forms of liquid chromatography for the separation or analysis of chemicals in complex mixtures. This method makes use of a biologically related agent as the stationary phase, which provides an affinity column with the ability to bind selectively and reversibly to a given target in a sample. This review examines the early work in this method and various developments that have lead to the current status of this technique. The general principles of affinity chromatography are briefly described as part of this discussion. Past and recent efforts in the generation …

Chromatographic Immunoassays: Strategies And Recent Developments In The Analysis Of Drugs And Biological Agents, Ryan E. Matsuda, Elliott Rodriguez, Doddavenkatanna Suresh, David S. Hage

David Hage Publications

A chromatographic immunoassay is a technique in which an antibody or antibodyrelated agent is used as part of a chromatographic system for the isolation or measurement of a specific target. Various binding agents, detection methods, supports and assay formats have been developed for this group of methods, and applications have been reported that range from drugs, hormones and herbicides to peptides, proteins and bacteria. This review discusses the general principles and applications of chromatographic immunoassays, with an emphasis being given to methods and formats that have been developed for the analysis of drugs and biological agents. The relative advantages or …

Evaluating The Long-Term Effects Of Logging Residue Removals In Great Lakes Aspen Forests, Michael I. Premer

Dissertations, Master's Theses and Master's Reports

Commercial aspen (Populus spp.) forests of the Great Lakes region are primarily managed for timber products such as pulp fiber and panel board, but logging residues (topwood and non-merchantable bolewood) are potentially important for utilization in the bioenergy market. In some regions, pulp and paper mills already utilize residues as fuel in combustion for heat and electricity, and progressive energy policies will likely cause an increase in biomass feedstock demand. The effects of removing residues, which have a comparatively high concentration of macronutrients, is poorly understood when evaluating long-term site productivity, future timber yields, plant diversity, stand dynamics, and …

Drought Monitoring And Assessment: Remote Sensing And Modeling Approaches For The Famine Early Warning Systems Network, G B. Senay, N M. Velpuri, S Bohms, M Budde, C Young, J Rowland, J P. Verdin

United States Geological Survey: Staff Publications

Drought monitoring is an essential component of drought risk management. It is usually carried out using drought indices/indicators that are continuous functions of rainfall and other hydrometeorological variables. This chapter presents a few examples of how remote sensing and hydrologic modeling techniques are being used to generate a suite of drought monitoring indicators at dekadal (10-day), monthly, seasonal, and annual time scales for several selected regions around the world. Satellite-based rainfall estimates are being used to produce drought indicators such as standardized precipitation index, dryness indicators, and start of season analysis. The Normalized Difference Vegetation Index is being used to …

On Underestimation Of Global Vulnerability To Tree Mortality And Forest Die-Off From Hotter Drought In The Anthropocene, Craig D. Allen, David D. Breshears, Nate G. Mcdowell

United States Geological Survey: Staff Publications

Patterns, mechanisms, projections, and consequences of tree mortality and associated broadscale forest die-off due to drought accompanied by warmer temperatures—‘‘hotter drought’’, an emerging characteristic of the Anthropocene—are the focus of rapidly expanding literature. Despite recent observational, experimental, and modeling studies suggesting increased vulnerability of trees to hotter drought and associated pests and pathogens, substantial debate remains among research, management and policy-making communities regarding future tree mortality risks. We summarize key mortalityrelevant findings, differentiating between those implying lesser versus greater levels of vulnerability. Evidence suggesting lesser vulnerability includes forest benefits of elevated [CO2] and increased water-use efficiency; observed and modeled increases …

Another Possible Source Of Archeological Maize Found In Chaco Canyon, Nm: The Tohatchi Flats Area, Nm, Usa, Deanna Grimstead, Sharon M. Buck, Bradley J. Vierra, Larry V. Benson

United States Geological Survey: Staff Publications

Understanding the linkage and relationship between Chaco Canyon and its residents to surrounding communities has been a primary research question for several decades. This research has focused on identifying the Chacoan road systems, similar architectural designs, and the sourcing of economic and non-economic goods to outlier communities of origin. Extensive fieldwork has been completed to identify potential source regions of Chacoan corncobs, but the San Juan Basin and surrounding regions are vast and many potential agricultural features remain uninvestigated. One such region is the Tohatchi Flats, located near modern day Gallup, New Mexico. This paper uses ⁸⁷Sr/⁸⁶Sr …

Developing A 30-M Grassland Productivity Estimation Map For Central Nebraska Using 250-M Modis And 30-M Landsat-8 Observations, Yingxin Gu, Bruce K. Wylie

United States Geological Survey: Staff Publications

Accurately estimating aboveground vegetation biomass productivity is essential for local ecosystem assessment and best land management practice. Satellite-derived growing season time-integrated Normalized Difference Vegetation Index (GSN) has been used as a proxy for vegetation biomass productivity. A 250-m grassland biomass productivity map for the Greater Platte River Basin had been developed based on the relationship between Moderate Resolution Imaging Spectroradiometer (MODIS) GSN and Soil Survey Geographic (SSURGO) annual grassland productivity. However, the 250-m MODIS grassland biomass productivity map does not capture detailed ecological features (or patterns) andmay result in only generalized estimation of the regional total productivity. Developing a high …

At-Grade Stabilization Structure Impact On Surface Water Quality Of An Agricultural Watershed, Kyle R. Minks, Matthew D. Ruark, Birl Lowery, Fred W. Madison, Dennis Frame, Todd D. Stuntebeck, Matthew J. Komiskey, George J. Kraft

United States Geological Survey: Staff Publications

Decades of farming and fertilization of farm land in the unglaciated/Driftless Area (DA) of southwestern Wisconsin have resulted in the build-up of P and to some extent, N, in soils. This build-up, combined with steep topography and upper and lower elevation farming (tiered farming), exacerbates problems associated with runoff and nutrient transport in these landscapes. Use of an at-grade stabilization structure (AGSS) as an additional conservation practice to contour strip cropping and no-tillage, proved to be successful in reducing organic and sediment bound N and P within an agricultural watershed located in the DA. The research site was designed as …

Late Quaternary Sea-Level History And The Antiquity Of Mammoths (Mammuthus Exilis And Mammuthus Columbi), Channel Islands National Park, California, Usa, Daniel R. Muhs, Kathleen R. Simmons, Lindsey T. Groves, John Mcgeehin, R. Randall Schumann, Larry D. Agenbroad

United States Geological Survey: Staff Publications

Fossils of Columbian mammoths (Mammuthus columbi) and pygmymammoths (Mammuthus exilis) have been reported from Channel Islands National Park, California. Most date to the last glacial period (Marine Isotope Stage [MIS] 2), but a tusk of M. exilis (or immature M. columbi) was found in the lowest marine terrace of Santa Rosa Island. Uranium-series dating of corals yielded ages from 83.8 ± 0.6 ka to 78.6 ± 0.5 ka, correlating the terrace withMIS 5.1, a time of relatively high sea level.Mammoths likely immigrated to the islands by swimming during the glacial periodsMIS 6 (~150 ka) orMIS 8 (~250 ka),when sea levelwas …

Sea Level, Paleogeography, And Archeology On California's Northern Channel Islands, Leslie Reeder- Myers, Jon Erlandson, Daniel R. Muhs, Torben Rick

United States Geological Survey: Staff Publications

Sea-level rise during the late Pleistocene and early Holocene inundated nearshore areas in many parts of the world, producing drastic changes in local ecosystems and obscuring significant portions of the archeological record. Although global forces are at play, the effects of sea-level rise are highly localized due to variability in glacial isostatic adjustment (GIA) effects. Interpretations of coastal paleoecology and archeology require reliable estimates of ancient shorelines that account for GIA effects. Here we build on previous models for California's Northern Channel Islands, producing more accurate late Pleistocene and Holocene paleogeographic reconstructions adjusted for regional GIA variability. This region has …

The Distribution Of Selected Elements And Minerals In Soil Of The Conterminous United States, Laurel Woodruff, William F. Cannon, David B. Smith, Federico Solano

United States Geological Survey: Staff Publications

In 2007, the U.S. Geological Survey initiated a low-density (1 site per 1600 km², 4857 sites) geochemical andmineralogical survey of soil of the conterminous United States as part of the North American Soil Geochemical Landscapes Project. Three soil samples were collected, if possible, from each site; (1) a sample from a depth of 0 to 5 cm, (2) a composite of the soil A-horizon, and (3) a deeper sample from the soil C-horizon or, if the top of the C-horizon was at a depth greater than 100 cm, from a depth of approximately 80–100 cm. The <2 mm fraction of each sample was analysed for a suite of 45 major and trace elements following near-total multi-acid digestion. The major mineralogical components in samples from the soil A- and C-horizons were determined by a quantitative X-ray diffraction method using Rietveld refinement. Sampling ended in 2010 and chemical and mineralogical analyses were completed in May 2013.Maps of the conterminous United States showing predicted element and mineral concentrations were interpolated from actual soil data for each soil sample type by an inverse distance weighted (IDW) technique using ArcGIS software. Regional- and national-scale map patterns for selected elements and minerals apparent in interpolated maps are described here in the context of soil-forming factors and possible human inputs. These patterns can be related to (1) soil parent materials, for example, in the distribution of quartz, (2) climate impacts, for example, in the distribution of feldspar and kaolinite, (3) soil age, for example, in the distribution of carbonate in young glacial deposits, and (4) possible anthropogenic loading of phosphorus (P) and lead (Pb) to surface soil. This new geochemical and mineralogical data set for the conterminous United States represents a major step forward from prior national-scale soil geochemistry data and provides a robust soil data framework for the United States now and into the future.

Toxicity Reference Values For Chlorophacinone And Their Application For Assessing Anticoagulant Rodenticide Risk To Raptors, Barnett A. Rattner, Katherine E. Horak, Rebecca S. Lazarus, Sandra L. Schultz, Susan Knowles, Benjamin G. Abbo, Steven F. Volker

United States Geological Survey: Staff Publications

Despite widespread use and benefit, there are

growing concerns regarding hazards of second-generation

anticoagulant rodenticides to non-target wildlife which

may result in expanded use of first-generation compounds,

including chlorophacinone (CPN). The toxicity of CPN

over a 7-day exposure period was investigated in American

kestrels (Falco sparverius) fed either rat tissue mechanically-

amended with CPN, tissue from rats fed Rozol bait

(biologically-incorporated CPN), or control diets (tissue

from untreated rats or commercial bird of prey diet)

ad libitum. Nominal CPN concentrations in the formulated

diets were 0.15, 0.75 and 1.5 µg/g food wet weight, and

measured concentrations averaged 94 …

Decadal Re-Evaluation Of Contaminant Exposure And Productivity Of Ospreys (Pandion Haliaetus) Nesting In Chesapeake Bay Regions Of Concern, Rebecca S. Lazarus, Barnett A. Rattner, Peter C. Mcgowan, Robert C. Hale, Sandra L. Schultz, Natalie K. Karouna-Renier, Mary Ann Ottinger

United States Geological Survey: Staff Publications

The last large-scale ecotoxicological study of ospreys (Pandion haliaetus) in Chesapeake Bay was conducted in 2000-2001 and focused on U.S. EPA-designated Regions of Concern (ROCs; Baltimore Harbor/ Patapsco, Anacostia/middle Potomac, and Elizabeth Rivers). In 2011-2012, ROCs were re-evaluated to determine spatial and temporal trends in productivity and contaminants. Concentrations of p,p'-DDE were low in eggs and below the threshold associated with eggshell thinning. Eggs from the Anacostia/ middle Potomac Rivers had lower total PCB concentrations in 2011 than in 2000; however, concentrations remained unchanged in Baltimore Harbor. Polybrominated diphenyl ether flame retardants declined by 40%, and five alternative …

Interactive Effects Of Climate Change With Nutrients, Mercury, And Freshwater Acidification On Key Taxa In The North Atlantic Landscape Conservation Cooperative Region, Alfred E. Pinkney, Charles T. Driscoll, David C. Evers, Michael J. Hooper, Jeffrey Horan, Jess W. Jones, Rebecca S. Lazarus, Harold G. Marshall, Andrew Milliken, Barnett A. Rattner, John Schmerfeld, Donald W. Sparling

United States Geological Survey: Staff Publications

The North Atlantic Landscape Conservation Cooperative LCC (NA LCC) is a public–private partnership that provides information to support conservation decisions that may be affected by global climate change (GCC) and other threats. The NA LCC region extends from southeast Virginia to the Canadian Maritime Provinces. Within this region, the US National Climate Assessment documented increases in air temperature, total precipitation, frequency of heavy precipitation events, and rising sea level, and predicted more drastic changes. Here, we synthesize literature on the effects of GCC interacting with selected contaminant, nutrient, and environmental processes to adversely affect natural resources within this region. Using …

Global Change And Conservation Triage On National Wildlife Refuges, Fred Johnson, Mitchell J. Eaton, Gerard Mcmahon, Raye Nilius, Michael R. Bryant, Dave Case, Julien Martin, Nathan Wood, Laura Taylor

United States Geological Survey: Staff Publications

National Wildlife Refuges (NWRs) in the United States play an important role in the adaptation of social-ecological systems to climate change, land-use change, and other global-change processes. Coastal refuges are already experiencing threats from sea-level rise and other change processes that are largely beyond their ability to influence, while at the same time facing tighter budgets and reduced staff. We engaged in workshops with NWR managers along the U.S. Atlantic coast to understand the problems they face from global-change processes and began a multidisciplinary collaboration to use decision science to help address them. We are applying a values-focused approach to …

A Bird’S- Eye View Of The Usa National Phenology Network: An Off-The-Shelf Monitoring Program, Jherime Kellerman, Caroline A. F. Enquist, Diana L. Humple, Nathaniel E. Seavy, Alyssa Rosemartin, Renée L. Cormier, Lorianne Barnett

United States Geological Survey: Staff Publications

Phenology is central to the biology and ecology of organisms and highly sensitive to climate. Differential responses to climate change are impacting phenological synchrony of inter- acting species, which has been implicated in the decline of migratory birds that rely on seasonal resources. However, few studies explicitly measure phenology of seasonal habitat resources on the breeding and wintering grounds and at stopover sites. While avian monitoring methods are widely standardized, methods of monitoring resource phenology can be highly variable and difficult to integrate. The USA National Phenology Network (USA- NPN) has developed standardized plant and animal phenology protocols and a …

Is Shallow Water A Suitable Surrogate For Assessing Efforts To Address Pallid Sturgeon Population Declines?, T R. Gemeinhardt, N.J C. Gosch, D M. Morris, M L. Miller, T L. Welker, J L. Bonneau

United States Army Corps of Engineers, Omaha District

It is hypothesized that slow, shallow water habitats benefit larval pallid sturgeon Scaphirhynchus albus; however, testing this hypothesis is difficult, given the low number of larval pallid sturgeon present in large rivers. In contrast, relatively large numbers of age-0 shovelnose sturgeon Scaphirhynchus platorynchus have been sampled, providing a potentially useful baseline to assess the importance of slow, shallow water to age-0 sturgeon of both species (hereafter age-0 sturgeon) in the lower Missouri River. Thus, we investigated the potential relationships between the prevalence of shallow water <1.5m and the age-0 sturgeon catch rates at multiple scales. Age-0 sturgeon were usually sampled in water >1.5 m, and catch rates were usually highest in the upper half [i.e. river kilometer …

Monthly Land Cover-Specific Evapotranspiration Models Derived From Global Eddy Flux Measurements And Remote Sensing Data, Yuan Fang, Ge Sun, Peter Caldwell, Steven G. Mcnulty, Asko Noormets, Jean-Christophe Domec, John King, Zhiqiang Zhang, Xudong Zhang, Guanghui Lin, Guangsheng Zhou, Jingfeng Xiao, Jiquan Chen

United States Department of Agriculture, Forest Service / University of Nebraska-Lincoln: Faculty Publications

Evapotranspiration (ET) is arguably the most uncertain ecohydrologic variable for quantifying watershed water budgets. Although numerous ET and hydrological models exist, accurately predicting the effects of global change on water use and availability remains challenging because of model deficiency and/or a lack of input parameters. The objective of this study was to create a new set of monthly ET models that can better quantify landscape-level ET with readily available meteorological and biophysical information. We integrated eddy covariance flux measurements from over 200 sites, multiple year remote sensing products from the Moderate Resolution Imaging Spectroradiometer (MODIS), and statistical modelling. Through examining …

Scarification And Gap Size Have Interacting Effects On Northern Temperate Seedling Establishment, John L. Willis, Michael B. Walters, Kurt W. Gottschallk

United States Department of Agriculture, Forest Service / University of Nebraska-Lincoln: Faculty Publications

After decades focused on promoting economically valuable species, management of northern temperate forests has increasingly become focused on promoting tree species diversity. Unfortunately, many formerly common species that could contribute to diversity including yellow birch (Betula alleghaniensis Britton.), paper birch (Betula papyrifera Marsh), eastern hemlock (Tsuga canadensis L.), and eastern white pine (Pinus strobus L.) are now uncommon in the seedling layer, raising concerns about our ability to use these species to increase diversity. In this study, two related seed addition experiments conducted in 45 variably-sized harvest gaps (unharvested to 6500 m^2) in adjacent mesic northern hardwood stands, Emmet County, …

Long-Term Droughtiness And Drought Tolerance Of Eastern Us Forests Over Five Decades, Matthew P. Peters, Louis R. Iverson, Stephen N. Matthews

United States Department of Agriculture, Forest Service / University of Nebraska-Lincoln: Faculty Publications

Droughts can influence forest composition directly by limiting water or indirectly by intensifying other stressors that affect establishment, growth, and mortality. Using community assemblages of eastern US tree species and drought tolerance characteristics assessed from literature, we examine recent drought conditions in relation to the spatial distribution of species and their tolerance to drought. First we calculate and compare a cumulative drought severity index (CDSI) for the conterminous US for the periods 1960–1986 and 1987–2013 using climate division Palmer Drought Severity Index (PDSI) values and a gridded self-calibrated PDSI dataset. This comparison indicates that drought conditions in the East tend …

Mega-Electron-Volt Ultrafast Electron Diffraction At Slac National Accelerator Laboratory, Stephen Weathersby, G. Brown, Martin Centurion, T. F. Chase, Ryan Coffee, Jeff Corbett, J. P. Eichner, J. C. Frisch, A. R. Fry, M. Gühr, Nick Hartmann, Carsten Hast, R. Hettel, R. K. Jobe, E. N. Jongewaard, J. R. Lewandowski, R. K. Li, A. M. Lindenberg, Igor Makasyuk, J. E. May, D. Mccormick, M. N. Nguyen, Alexander Reid, Xiaozhe Shen, K. Sokolowski-Tinten, Theodore Vecchione, Sharon Vetter, J. Wu, Jie Yang, H. A. Dürr, Xijie Wang

Martin Centurion Publications

Ultrafast electron probes are powerful tools, complementary to x-ray free-electron lasers, used to study structural dynamics in material, chemical, and biological sciences. High brightness, relativistic electron beams with femtosecond pulse duration can resolve details of the dynamic processes on atomic time and length scales. SLAC National Accelerator Laboratory recently launched the Ultrafast Electron Diffraction (UED) and microscopy Initiative aiming at developing the next generation ultrafast electron scattering instruments. As the first stage of the Initiative, a mega-electron-volt (MeV) UED system has been constructed and commissioned to serve ultrafast science experiments and instrumentation development. The system operates at 120-Hz repetition rate …

Self-Assembly Of Strongly Dipolar Molecules On Metal Surfaces, Donna A. Kunkel, James Hooper, Scott Simpson, Daniel P. Miller, Lucie Routaboul, Pierre Braunstein, Bernard Doudin, Sumit Beniwal, Peter A. Dowben, Ralph Skomski, Eva Zurek, Axel Enders

Axel Enders Publications

The role of dipole-dipole interactions in the self-assembly of dipolar organic molecules on surfaces is investigated. As a model system, strongly dipolar model molecules, p-benzoquinonemonoimine zwitterions (ZI) of type C6H2(· · · NHR)2(· · · O)2 on crystalline coinage metal surfaces were investigated with scanning tunneling microscopy and first principles calculations. Depending on the substrate, the molecules assemble into small clusters, nano gratings, and stripes, as well as in two-dimensional islands. The alignment of the molecular dipoles in those assemblies only rarely assumes the lowest electrostatic energy configuration. Based on calculations of the electrostatic energy for various experimentally observed molecular …

Low Trap-State Density And Long Carrier Diffusion In Organolead Trihalide Perovskite Single Crystals, Dong Shi, Valerio Adinolfi, Riccardo Comin, Mingjian Yuan, Erkki Alarousu, Andrei Buin, Yin Chen, Sjoerd Hoogland, Alexander Rothenberger, Khabiboulakh Katsiev, Yaroslav B. Losovyj, Xin Zhang, Peter A. Dowben, Omar F. Mohammed, Edward H. Sargent, Osman M. Bakr

Peter Dowben Publications

The fundamental properties and ultimate performance limits of organolead trihalide MAPbX₃ (MA = CH₃NH₃ +; X = Br^– or I^–) perovskites remain obscured by extensive disorder in polycrystalline MAPbX₃ films. We report an antisolvent vapor-assisted crystallization approach that enables us to create sizable crack-free MAPbX₃ single crystals with volumes exceeding 100 cubic millimeters. These large single crystals enabled a detailed characterization of their optical and charge transport characteristics. We observed exceptionally low trap-state densities on the order of 10⁹ to 10¹⁰ per cubic centimeter in MAPbX₃ single crystals …

Toric Varieties, Monoid Schemes And Cdh Descent, Guillermo Cortiñas, C. Haesemeyer, Mark E. Walker, Charles Weibel

Department of Mathematics: Faculty Publications

We give conditions for the Mayer–Vietoris property to hold for the algebraic K-theory of blow-up squares of toric varieties and schemes, using the theory of monoid schemes. These conditions are used to relate algebraic K-theory to topological cyclic homology in characteristic p. To achieve our goals, we develop many notions for monoid schemes based on classical algebraic geometry, such as separated and proper maps and resolution of singularities.

Crosscap Number: Handcuff Graphs And Unknotting Number, Anne Kerian

Department of Mathematics: Dissertations, Theses, and Student Research

Many types of invariants are used in the study of knots. Some are based on polynomials, some are purely algebraic, and some have their origins in geometry. One of the best known geometric knot invariants is the genus of a knot. A closely related but lesser-known invariant, crosscap number, was first introduced by Bradd Evans Clark in 1978. This thesis primarily concerns crosscap number two knots. Starting with a list of knots found to have crosscap number two by Burton and Ozlen using a linear programing approach, we verify, though are unable to expand, this list using a computer search. …