Physical Sciences and Mathematics Commons^™

The Late Ordovician Biogeochemical Carbon Cycle, John Garrecht Metzger

Arts & Sciences Graduate Student Theses and Dissertations

The isotopic composition of the carbonate carbon (δ13Ccarb) is one of the best tools for understanding the biogeochemical carbon cycle through Earth history. δ13Ccarb is also used to chemostratigraphically correlate coeval strata. This dissertation has three main foci that all utilize δ13Ccarb as the common data type. The geologic interval investigated was the Late Ordovician (458-444 Ma) with emphasis on the Guttenberg δ13C excursion, a globally correlated, positive ~3 / event that is ~400 kyr in duration. In the first topic we evaluate post-depositional alteration (i.e., diagenesis) of δ13Ccarb signals. In the second topic, we make reconstructions of sea level …

Mono-N-Acyl-2,6-Diaminopimelic Acid Derivatives: Analysis By Electromigration And Spectroscopic Methods And Examination Of Enzyme Inhibitory Activity, Jan Hlaváček, Miloslava Vítovcová, Petra Sázelová, Jan Pícha, Václav Vaněk, Miloš Buděšínský, Jiří Jiráček, Danuta M. Gillner, Richard C. Holz, Ivan Mikšík, Václav Kašička

Chemistry Faculty Research and Publications

Thirteen mono-N-acyl derivatives of 2,6-diaminopimelic acid (DAP)—new potential inhibitors of the dapE-encoded N-succinyl-l,l-diaminopimelic acid desuccinylase (DapE; EC 3.5.1.18)—were analyzed and characterized by infrared (IR) and nuclear magnetic resonance (NMR) spectroscopies and two capillary electromigration methods: capillary zone electrophoresis (CZE) and micellar electrokinetic chromatography (MEKC). Structural features of DAP derivatives were characterized by IR and NMR spectroscopies, whereas CZE and MEKC were applied to evaluate their purity and to investigate their electromigration properties. Effective electrophoretic mobilities of these compounds were determined by CZE in acidic and alkaline background electrolytes (BGEs) and by MEKC in acidic and alkaline BGEs …

Integrating Path-Dependent Functionals On Yeh-Wiener Space, Ian Pierce, David Skough

Department of Mathematics: Faculty Publications

Denote by Ca,b(Q) the generalized two-parameter Yeh-Wiener space with associated Gaussian measure. We investigate several scenarios in which integrals of functionals on this space can be reduced to integrals of related functionals over an appropriate single-parameter generalized Wiener space Cˆa,ˆb[0, T ]. This extends some interesting results of R. H. Cameron and D. A. Storvick.

Kinetic Analysis And Inhibition Studies Of Iron-Dependent Histone Demethylases, Barbara Gordon Cascella

Arts & Sciences Graduate Student Theses and Dissertations

The research presented herein focuses on the kinetics and inhibition of the KDM4 subfamily of Jumonji C (JmjC) domain-containing histone demethylases (HDMs). Belonging to the larger class of alpha-ketoglutarate (alpha-KG)-dependent, non-heme iron monooxygenases, the JmjC-HDMs remove methyl groups from mono-, di-, and tri-methylated histone lysine residues through an Fe(IV)-oxo-catalyzed hydroxylation reaction. JmjC-HDMs have been found to play integral roles in the maintenance of genomic integrity as well as in the regulation of transcription. Three KDM4 members were studied: the mixed H3K9/H3K36 demethylases KDM4A and KDM4C, and the pure H3K9 demethylase KDM4E. KDM4C is a hypoxia-inducible factor 1 (HIF-1) target gene …

Study Of Ii-Vi Colloidal Semiconductor Magic-Size Nanoclusters And Crystalline Quantum Platelets, Yuanyuan Wang

Arts & Sciences Graduate Student Theses and Dissertations

The main objective of this project is to prepare and isolate the smallest, discrete, magic-size nanoclusters of cadmium selenide (CdSe) and to grow crystalline, wurtzite CdSe quantum platelets (QPs) at room temperature. The achievement of these goals enables us to provide a general synthesis of II-VI semiconductor magic-size nanoclusters and low-temperature routes to well-passivated nanocrystals having a range of compositions and morphologies.The magic-size nanocluster (CdSe)13 is grown in a lamellar-bilayer soft template at room temperature. The results described in this thesis strongly suggest that [(CdSe)13(n-octylamine)13] is the most thermodynamically stable nanocluster and serves as a key intermediate in the formation …

Synthesis And Characterization Of Pbs Quantum Sheets Through Lamellar Assembly, And Updates To The Cdse Quantum Wire Synthesis, Paul James Morrison

Arts & Sciences Graduate Student Theses and Dissertations

This dissertation reports the novel synthesis of PbS quantum plates (QPs) via a reaction executed at low temperatures. The PbS QPs are grown in a template-assisted mechanism, with the first excitonic peak observed in the visible region of light at ~620 nm (2.0 eV), at an energy radically different than the band gap of bulk PbS (~3000 nm, 0.42eV). The large energy shift is due to the extremely thin dimension of these nanoplates, which is determined to be ~1 nm in thickness. Thickness measurements are made in a powder X-ray diffractometer (XRD) at low angles (between 2-15º 2θ). These measurements …

Isotope Harvesting At Heavy-Ion Fragmentation Facilities, Tara Elise Mastren

Arts & Sciences Graduate Student Theses and Dissertations

Isotope harvesting from heavy-ion fragmentation facilities is a potential source of isotopes of interest for applications research. With the upgrade of the National Superconducting Cyclotron Laboratory (NSCL) to the Facility for Rare Isotope Beams (FRIB) usable quantities of many isotopes of interest will be produced and available for harvest from an aqueous beam dump. If available, these isotopes would be of interest to a broad range of applications such as medicine, geology, and stockpile stewardship. Preliminary experiments were performed at the NSCL in order to determine the feasibility of isotope harvesting at (FRIB).A water target station that consisted of a …

Polyol Synthesis Of Silver Nanowires By Heterogeneous Nucleation And Mechanistic Aspects Influencing Its Length And Diameter, Waynie M. Schuette

Arts & Sciences Graduate Student Theses and Dissertations

Various additives are employed in the polyol synthesis of silver nanowires (Ag NWs), which are typically halide salts such as NaCl. A variety of mechanistic roles have been suggested for these additives. My research showed that the early addition of NaCl in the polyol synthesis of Ag NWs from AgNO3 in ethylene glycol results in the rapid formation of AgCl nanocubes, which induce the heterogeneous nucleation of metallic Ag upon their surfaces. Ag NWs subsequently grow from these nucleation sites. The conclusions are supported by studies using ex-situ generated AgCl nanocubes.Additionally, the final mean silver nanowire diameter is found to …

X-Ray Polarimetry With X-Calibur, Qingzhen Guo

Arts & Sciences Graduate Student Theses and Dissertations

ABSTRACT X-Ray Polarimetry with X-Calibur by Qingzhen Guo Doctor of Philosophy in Physics, Washington University in St. Louis, September, 2014. Professor Henric Krawczynski, Chair X-ray polarimetry is a prime tool to investigate the unexplored compact sources and to provide crucial information that other techniques can not produce. By measuring the degree and orientation of the polarization of radiation from a cosmic source, unique inferences about the morphology and the magnetic field structure can be made. Krawczysnki's group at Washington University is working on a uniquely sensitive scattering polarimeter, X-Calibur, to be used in the focal plane of a focusing X-ray …

Applications Of Nonlinear Optimization, Yao Xie

Arts & Sciences Graduate Student Theses and Dissertations

We apply an interior point algorithm to two nonlinear optimization problems and achieve improved results. We also devise an approximate convex functional alternative for use in one of the problems and estimate its accuracy. The first problem is maximum variance unfolding in machine learning. The traditional method to solve this problem is to convert it to a semi-definite optimization problem by defining a kernel matrix. We obtain better unfolding and higher speeds with the interior point algorithm on the original non-convex problem for data with less than 10,000 points. The second problem is a multi-objective dose optimization for intensity modulated …

Comparison Of Conventional And Bayesian Analysis For The Ultrasonic Characterization Of Cancellous Bone, Amber Groopman

Arts & Sciences Graduate Student Theses and Dissertations

This dissertation investigates the physics underlying the propagation of ultrasonic waves in cancellous bone. Although quantitative ultrasound has the potential to evaluate bone quality even better than the current gold standard X-ray based modality, its clinical utility has been hampered by the incomplete understanding of the mechanisms governing the interaction between ultrasound and bone. Therefore, studies that extend the understanding of the fundamental physics of the relationship between ultrasound and trabecular bone tissue may result in improved clinical capabilities.Ultrasonic measurements were carried out on excised human calcaneal specimens in order to study the effects of overlapping fast and slow compressional …

Uncertainty Relation For Mutual Information, James Schneeloch, Curtis J. Broadbent, John C. Howell

Mathematics, Physics, and Computer Science Faculty Articles and Research

We postulate the existence of a universal uncertainty relation between the quantum and classical mutual informations between pairs of quantum systems. Specifically, we propose that the sum of the classical mutual information, determined by two mutually unbiased pairs of observables, never exceeds the quantum mutual information. We call this the complementary-quantum correlation (CQC) relation and prove its validity for pure states, for states with one maximally mixed subsystem, and for all states when one measurement is minimally disturbing. We provide results of a Monte Carlo simulation suggesting that the CQC relation is generally valid. Importantly, we also show that the …

Spectral Evolution Of Energetic Neutral Atom Emissions At The Heliospheric Poles As Measured By Ibex During Its First Three Yeras, M. Dayeh, F. Allegrini, R. Demajistre, M. I. Desai, R. W. Ebert, S. A. Fuselier, Paul H. Janzen, G. Livadiotis, D. J. Mccomas, Daniel B. Reisenfeld, N. A. Schwadron, M. Siewert

Physics and Astronomy Faculty Publications

The Interstellar Boundary Explorer (IBEX) mission continues to measure energetic neutral atom (ENA) emissions produced by charge exchange between solar wind (SW) protons and interstellar neutrals at the edge of our heliosphere. Using the first 3 yr of IBEX-Hi ENA measurements (2009-2011), we examined the spectral evolution of ~0.5-6 keV ENAs at the polar regions (above 60°). We found the following: (1) pixels with a characteristic "ankle" spectra (lower spectral index at higher energies) increase by ~5% in 2010 and ~10% in 2011 compared to 2009. (2) The averaged spectral index in 2011 is smaller than that of 2009. (3) …

Comparative Population Genetics And Evolutionary History Of Two Commonly Misidentified Billfishes Of Management And Conservation Concern, Andrea M. Bernard, Mahmood S. Shivji, Eric Prince, Fabio H.V. Hazin, Freddy Arocha, Andres Domingo, Kevin A. Feldheim

Marine & Environmental Sciences Faculty Articles

Background:  Misidentifications between exploited species may lead to inaccuracies in population assessments, with potentially irreversible conservation ramifications if overexploitation of either species is occurring. A notable showcase is provided by the realization that the roundscale spearfish (Tetrapturus georgii), a recently validated species, has been historically misidentified as the morphologically very similar and severely overfished white marlin (Kajikia albida) (IUCN listing: Vulnerable). In effect, no information exists on the population status and evolutionary history of the enigmatic roundscale spearfish, a large, highly vagile and broadly distributed pelagic species. We provide the first population genetic evaluation of the …

Privacy-Preserving And Outsourced Multi-User K-Means Clustering, Bharath Samanthula, Fang-Yu Rao, Elisa Bertino, Xun Yi, Dangxi Liu

Cyber Center Publications

Many techniques for privacy-preserving data mining (PPDM) have been investigated over the past decade. Often, the entities involved in the data mining process are end-users or organizations with limited computing and storage resources. As a result, such entities may want to refrain from participating in the PPDM process. To overcome this issue and to take many other benefits of cloud computing, outsourcing PPDM tasks to the cloud environment has recently gained special attention. We consider the scenario where n entities outsource their databases (in encrypted format) to the cloud and ask the cloud to perform the clustering task on their …

Structural Studies And Reactions Of Rhenium And Rhenium-Gold Metal Carbonyl Complexes, Yuen Onn Wong

Theses and Dissertations

The six-membered heavy atom heterocycles [Re2(CO)8(μ-H)(μ-SbPh2)]2, 2.1 and Pd[Re2(CO)8(μ-H)(μ-SbPh2)]2, 2.3, have been prepared by the palladium-catalyzed ring-opening cyclo-dimerization of the three-membered heterocycle Re2(CO)8(μ-H)(μ-SbPh2). The palladium atom that lies in the center of the heterocycle 2.3 was removed to yield 2.1. The palladium removal was found to be partially reversible leading to an unusual example of host-guest behavior. A related dipalladium complex Pd2Re4(μ-Ph)(CO)16(μ4-SbPh)(μ3-SbPh2)(μ-H)2, 2.2, was also formed in these reactions of palladium with Re2(CO)8(μ-H)(μ-SbPh2). Thermolysis of 2.1 at 85 °C yielded Re3(CO)12(μ-SbPh2)(μ-H)2, 2.4 (2.9% yield), Re3(CO)12(μ-SbPh2)2(μ-H), 2.5 (25.1% yield), and Re3(CO)13(μ-SbPh)(μ-H), 2.6 (14.6% yield). The electronic structure of 2.1 and 2.3 …

A Periodic Matrix Population Model For Monarch Butterflies, Emily Hunt

Senior Honors Projects, 2010-2019

The migration pattern of the monarch butterfly (Danaus plexippus) consists of a sequence of generations of butterflies that originate in Michoacan, Mexico each spring, travel as far north as Southern Canada, and ultimately return to the original location in Mexico the following fall. We use periodic population matrices to model the life cycle of the eastern monarch butterfly and find that, under this model, this migration is not currently at risk. We extend the model to address the three primary obstacles for the long-term survival of this migratory pattern: deforestation in Mexico, increased extreme weather patterns, and milkweed degradation.

Examining The Effectiveness Of Ecotourism As A Funding Source For Protected Area Management In Guyana, Jordan S. Flagel

Masters Theses, 2010-2019

Protected areas in tropical rainforests serve many important ecosystem services, including carbon sequestration. These areas are often in need of donor or grant funding to operate as governments in tropical forested countries are not always able to provide adequate funds for protection. This paper focuses on the Iwokrama International Center for Rainforest Conservation and Development in the South American country of Guyana, which has had funding issues since the global economic crisis of 2008 and an accompanying shift in donor country financial priorities. Increasing the amount of sustainable ecotourism in the Iwokrama reserve was identified as a potential source for …

Policy Context Of The Endemic Flora Of The Maltese Islands In A Changing Taxonomic Landscape, Clara Agius

Masters Theses, 2010-2019

The degradation of the environment since the Industrial Revolution has been a turning point for legislation, leading to many countries, including EU states, to create legislations that conserve the environment. These legislations are based on scientific facts. This can create a divide between policy and science, as science and scientific methods are constantly changing, while policy has to keep up. Scientific facts of yesterday, may not necessarily be the same as today. This divide between science and policy may have implications on the designation of Protected Areas. One of the criteria of a Protected Area is the protection of an …

Synthesis And Characterization Of Polymer (Sulfonated Poly-Ether-Ether-Ketone) Based Nanocomposite (H-Boron Nitride) Membrane For Hydrogen Storage, Naresh Muthu, S. Rajashabala, R. Kannan

Chemistry and Biochemistry Faculty Publications

The development of light weight and compact hydrogen storage materials is still prerequisite to fuel-cell technology to be fully competitive. The present experimental study reports the hydrogen storage capability of sulfonated poly-ether-ether-ketone (SPEEK)-hexagonal boron nitride (h-BN) (SPEEK-h-BN) nanocomposite membranes. The nanocomposite membranes are prepared by considering various amount of h-BN (0, 1, 3 and 5 wt. %) by phase inversion technique. The degree of sulfonation of the PEEK (SPEEK) is found to be 65% by Proton Nuclear Magnetic Resonance (¹H NMR) spectroscopy. Hydrogen adsorption studies have been carried out using a Seiverts-like hydrogenation setup. The membranes are characterized …

Colloidal And Biological Properties Of Triscationic Amphiphiles With One Or Two Tails, John N. Marafino

Masters Theses, 2010-2019

The decline in the development of novel antimicrobials, combined with the misusage and over prescription of antibiotics, has contributed to the increasing prevalence of antimicrobial-resistant infections. Thus development of effective novel disinfectants could reduce the transmission of pathogens and decrease the risk of infection by antibiotic resistant organisms. The antimicrobial activity of amphiphiles, compounds with hydrophobic and hydrophilic regions, was first reported in 1935, and has influenced the synthesis of amphiphiles with variations in structure. In this study, three series of amphiphiles were synthesized by two subsequent Menshutkin reactions. Each amphiphile contains one or two hydrocarbon tails ranging from 8 …

Performance Quantification Of Extensive Green Roof Substrate Blend: Expanded Shale And Biochar, James Sheats

Masters Theses, 2010-2019

Urban stormwater management practices often involve the redirection of runoff to local waterbodies. As such, the quality of runoff directly affects the condition of these receiving waters. Green roofs offer many benefits to the urban environment including attractive aesthetics, thermal insulation for buildings and stormwater runoff reduction. Unfortunately, in order to promote the spread of vegetation, fertilization is often practiced that can lead to elevated nutrient concentrations in runoff and, ultimately, nearby streams, rivers and bays. Different amounts of biochar, pyrolyzed biomass, were added to model green roof trays to test for the ability of this charcoal-like substance to prevent …

An Analysis Of U.S./Canadian Fisheries Policy In Regards To Pacific Salmon And The Preservation Of Indigeneity In The Pacific Northwest, Michael James Lockwood

Masters Theses, 2010-2019

For more than 160 years, the Pacific salmon has been an important resource for the United States and Canada. However, it has been overexploited. Proper management of the species is essential not only for maintaining healthy populations but also maintaining the interests of diverse stakeholders. One set of stakeholders consists of the indigenous peoples of North America because the Pacific salmon are crucial to their food, social, and ceremonial traditions.

This thesis explores the impacts of Canadian and U.S. public policies on the cultural integrity of native peoples in the Pacific Northwest, specifically as those peoples rely on wild Pacific …

Polyculture Bioremediation: An Analysis Of Potential Nitrogen Assimilation And Removal By Mya Arenaria, Gracilaria Tikvahiae And Ulva Lactuca Harvests In The Corsica River, Md, Kathleen Hemeon

Masters Theses, 2010-2019

An analysis of nitrogen bioremediation in a tidal tributary of the Chesapeake Bay by the use of a hypothetical bivalve and macroalgae polyculture covering 1%, 3% and 5% of the Corsica River bottom area. This study was performed to illustrate the role ecosystem services play in managing diffuse watershed pollution, particularly nitrogen, resulting in water quality and living resource degradation. Excess concentrations of nitrogen in the Corsica River estuary lead to seasonal eutrophication and subsequent hypoxic events. Mya arenaria L. and Gracilaria tikvahiae (McLachlan, 1979) were chosen for this theoretical study due to their high assimilative capacities for nitrogen and …

Offshore Wind Energy In The U.S. Mid-Atlantic Region And The Epa Clean Power Plan Proposed Rule, Kamil E. Armaiz Nolla

Masters Theses, 2010-2019

ABSTRACT

Offshore Wind Energy in the U.S. Mid-Atlantic Region and the EPA Clean Power Plan Proposed Rule

Kamil E. Armaiz Nolla

Carbon dioxide (CO₂) levels in the atmosphere have been experiencing a rapid rise since the start of the Industrial Era. Human activities have been recognized by the scientific community as the main contributors to CO₂ emissions by way of the combustion of fossil fuels such as coal, oil, and natural gas. Scientific consensus about human-induced climate change has been recognized since 1992 by the work of the United Nations Framework Convention on Climate. Since then, …

Thermomechanical Performance Assessment Of Bio-Based Pu Adhesives Derived From Castor Oil, Anand Patel

Electronic Theses & Dissertations

Thermomechanical Performance Assessment of Bio-based PU Adhesives Derived from Castor Oil

An Abstract of the Thesis by

Anand V. Patel

Adhesives play a critical role in binding diverse materials, thereby promoting structural integrity and functional versatility across numerous daily applications. A significant challenge remains in developing polyurethane adhesives that exhibit exceptional bonding strength, as many are derived from petroleum products. To reduce dependence on non-renewable resources and offer sustainable and affordable alternatives, vegetable oils are being utilized to create a range of polyurethane adhesives. These oils are preferred due to their low toxicity, cost-effectiveness, and reduced environmental impact. This research …

Kirkland D.W., 2014 - Role Of Hydrogen Sulfide In The Formation Of Cave And Karst Phenomena In The Guadalupe Mountains And Western Delaware Basin, New Mexico And Texas, Leslie A. Melim

International Journal of Speleology

No abstract provided.

Some Observations On Scientific Epistemology With Applications To Conflict Resolution And Constructive Controversy, Judith Puncochar, Don Faust

Other Presentations

An overview, by Judy and Don (published in 2013 in the BULLETIN OF SYMBOLIC LOGIC):

Explorationism is a perspective wherein all of our knowledge is (so far) less than certain, and naturally would come equipped with a base logic entailing machinery for representing and processing evidential knowledge. One such base logic is Evidence Logic, which strives to deal with the phenomenon of the gradational presence of both confirmatory and refutatory evidence. From this perspective, we will address questions surrounding sociological problem areas that we see as deeply infused with substantial epistemological factors. By defining a framework as any theory, …

Controlling Pm2.5 In Chengdu: Analysis And Recommendations From The China, U.S. And California Experience, Weijia Li

Master's Projects and Capstones

Chengdu, China, is experiencing rapid economic growth and urbanization at a cost of serious air pollution problems. China has developed a series of policies to reduce PM2.5 emissions and to reform energy structure. However, problems exist which may prevent effectively implementation of the PM2.5 policies, include poor PM2.5 monitoring, isolated environmental management, lack of health improvement target, unclear consequence of non-compliance, and unequally distributed PM2.5 management.

This research reviews U.S. PM2.5 emission control technologies related to coal-fired boilers and iron and steel manufacturing industries, which represent major emission sources of Chengdu. Chengdu’s choice of PM2.5 control technology should always consider …

The Future Of Direct Potable Reuse In California: Overcoming Public Acceptance Barriers, Allison Chan

Master's Projects and Capstones

Due to the water shortages, population growth, and competing demands for water in California, the possibility of incorporating direct potable reuse technology in the state’s water supply portfolio is being considered by various water resource providers. This paper focuses on public acceptance challenges that may be encountered. By evaluating best practices employed by six different potable water reuse case studies, recommendations for future direct potable reuse projects are developed. It is recommended that future project proponents plan early and conduct public opinion surveys regarding this type of technology, develop and implement public outreach and education plans that include best practices …