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Articles 6121 - 6150 of 6353
Full-Text Articles in Physical Sciences and Mathematics
Examining The Accuracy Of The Normal Approximation To The Poisson Random Variable, Wesley Jacob Rich
Examining The Accuracy Of The Normal Approximation To The Poisson Random Variable, Wesley Jacob Rich
Master's Theses and Doctoral Dissertations
Because the Poisson distribution is discrete, it is sometimes useful to use the continuous normal distribution as an approximation. In doing so, determining the accuracy of the approximation is important. Some issues of interest include: knowing how the error depends on the Poisson parameter, knowing when the approximation overestimates or underestimates the distribution, bounding the magnitude of the error, and determining if the approximation can be improved. This paper addresses these issues by examining how two types of absolute error measurements are affected by variations in the Poisson parameter; changes in the relative error are also examined. Generally, the error …
Dynamic Adaptation Of Joint Transmission Power And Contention Window In Vanet, Danda B. Rawat, Gongjun Yan, Dimitrie C. Popescu, Michele C. Weigle, Stephan Olariu
Dynamic Adaptation Of Joint Transmission Power And Contention Window In Vanet, Danda B. Rawat, Gongjun Yan, Dimitrie C. Popescu, Michele C. Weigle, Stephan Olariu
Electrical & Computer Engineering Faculty Publications
In this paper, we propose an algorithm for joint adaptation of transmission power and contention window to improve the performance of vehicular network in a cross layer approach. The high mobility of vehicles in vehicular communication results in the change in topology of the Vehicular Ad-hoc Network (VANET) dynamically, and the communication link between two vehicles might remain active only for short duration of time. In order for VANET to make a connection for long time and to mitigate adverse effects due to high and fixed transmission power, the proposed algorithm adapts transmission power dynamically based on estimated local traffic …
Seasonal Adaptation Of Vegetation Color In Satellite Images For Flight Simulations, Yuzhong Shen, Jiang Li, Vamsi Mantena, Srinivas Jakkula
Seasonal Adaptation Of Vegetation Color In Satellite Images For Flight Simulations, Yuzhong Shen, Jiang Li, Vamsi Mantena, Srinivas Jakkula
Electrical & Computer Engineering Faculty Publications
Automatic vegetation identification plays an important role in many applications including remote sensing and high performance flight simulations. This paper proposes a novel method that identifies vegetative areas in satellite images and then alters vegetation color to simulate seasonal changes based on training image pairs. The proposed method first generates a vegetation map for pixels corresponding to vegetative areas, using ISODATA clustering and vegetation classification. The ISODATA algorithm determines the number of clusters automatically. We then apply morphological operations to the clustered images to smooth the boundaries between clusters and to fill holes inside clusters. Six features are then computed …
Iterative Methods For Computing Eigenvalues And Exponentials Of Large Matrices, Ping Zhang
Iterative Methods For Computing Eigenvalues And Exponentials Of Large Matrices, Ping Zhang
University of Kentucky Doctoral Dissertations
In this dissertation, we study iterative methods for computing eigenvalues and exponentials of large matrices. These types of computational problems arise in a large number of applications, including mathematical models in economics, physical and biological processes. Although numerical methods for computing eigenvalues and matrix exponentials have been well studied in the literature, there is a lack of analysis in inexact iterative methods for eigenvalue computation and certain variants of the Krylov subspace methods for approximating the matrix exponentials. In this work, we proposed an inexact inverse subspace iteration method that generalizes the inexact inverse iteration for computing multiple and clustered …
Direct Products And The Intersection Map Of Certain Classes Of Finite Groups, Julia Chifman
Direct Products And The Intersection Map Of Certain Classes Of Finite Groups, Julia Chifman
University of Kentucky Doctoral Dissertations
The main goal of this work is to examine classes of finite groups in which normality, permutability and Sylow-permutability are transitive relations. These classes of groups are called T , PT and PST , respectively. The main focus is on direct products of T , PT and PST groups and the behavior of a collection of cyclic normal, permutable and Sylow-permutable subgroups under the intersection map. In general, a direct product of finitely many groups from one of these classes does not belong to the same class, unless the orders of the direct factors are relatively prime. Examples suggest that …
Electronic And Structural Properties Of Molybdenum Thin Films As Determined By Real Time Spectroscopic Ellipsometry, J. D. Walker, H. Khatri, V. Ranjan, Jian Li, R. W. Collins, S. Marsillac
Electronic And Structural Properties Of Molybdenum Thin Films As Determined By Real Time Spectroscopic Ellipsometry, J. D. Walker, H. Khatri, V. Ranjan, Jian Li, R. W. Collins, S. Marsillac
Electrical & Computer Engineering Faculty Publications
Walker, J.D., Khatri, H., Ranjan, V., Li, J., Collins, R.W., & Marsillac, S. (2009). Electronic and structural properties of molybdenum thin films as determined by real-time spectroscopic ellipsometry. Applied Physics Letters, 94(14). doi: 10.1063/1.3117222
Superfluid Turbulence From Quantum Kelvin Wave To Classical Kolmogorov Cascades, Jeffrey Yepez, George Vahala, Linda L. Vahala, Min Soe
Superfluid Turbulence From Quantum Kelvin Wave To Classical Kolmogorov Cascades, Jeffrey Yepez, George Vahala, Linda L. Vahala, Min Soe
Electrical & Computer Engineering Faculty Publications
The main topological feature of a superfluid is a quantum vortex with an identifiable inner and outer radius. A novel unitary quantum lattice gas algorithm is used to simulate quantum turbulence of a Bose-Einstein condensate superfluid described by the Gross-Pitaevskii equation on grids up to 57603. For the first time, an accurate power-law scaling for the quantum Kelvin wave cascade is determined: k-3. The incompressible kinetic energy spectrum exhibits very distinct power-law spectra in 3 ranges of k space: a classical Kolmogorov k-(5/3) spectrum at scales greater than the outer radius of individual quantum vortex …
Supporting Protocols For Structuring And Intelligent Information Dissemination In Vehicular Ad Hoc Networks, Filip Cuckov
Supporting Protocols For Structuring And Intelligent Information Dissemination In Vehicular Ad Hoc Networks, Filip Cuckov
Electrical & Computer Engineering Theses & Dissertations
The goal of this dissertation is the presentation of supporting protocols for structuring and intelligent data dissemination in vehicular ad hoc networks (VANETs). The protocols are intended to first introduce a structure in VANETs, and thus promote the spatial reuse of network resources. Segmenting a flat VANET in multiple cluster structures allows for more efficient use of the available bandwidth, which can effectively increase the capacity of the network. The cluster structures can also improve the scalability of the underlying communication protocols. The structuring and maintenance of the network introduces additional overhead. The aim is to provide a mechanism for …
The Generalized Burnside And Representation Rings, Eric B. Kahn
The Generalized Burnside And Representation Rings, Eric B. Kahn
University of Kentucky Doctoral Dissertations
Making use of linear and homological algebra techniques we study the linearization map between the generalized Burnside and rational representation rings of a group G. For groups G and H, the generalized Burnside ring is the Grothendieck construction of the semiring of G × H-sets with a free H-action. The generalized representation ring is the Grothendieck construction of the semiring of rational G×H-modules that are free as rational H-modules. The canonical map between these two rings mapping the isomorphism class of a G-set X to the class of its permutation module …
Alterations Of Zinc Transporters In Alzheimer's Disease, Ganna Lyubartseva
Alterations Of Zinc Transporters In Alzheimer's Disease, Ganna Lyubartseva
University of Kentucky Doctoral Dissertations
Alzheimer’s disease (AD), one of the major causes of disability and mortality in Western societies, is a progressive age-related neurodegenerative disorder. Increasing evidence suggests the etiology of AD may involve disruptions of zinc (Zn) homeostasis. We hypothesize that disruption of Zn homeostasis leads to alterations of Zn transporter (ZnT) proteins, resulting in increased production of neurotoxic amyloid beta (Aβ) peptide in AD brain. To address this hypothesis we carried out the following studies.
1. We characterized alterations of ZnT-1, ZnT-4 and ZnT-6 in the brain of preclinical AD (PCAD) subjects, who show no overt clinical manifestations of AD but demonstrate …
Paleogeographic Reconstructuion Of The St. Lawrence Promontory, Western Newfoundland, John Stefan Allen
Paleogeographic Reconstructuion Of The St. Lawrence Promontory, Western Newfoundland, John Stefan Allen
University of Kentucky Doctoral Dissertations
Neoproterozoic-Early Cambrian continental rifting related to the breakup of the supercontinent Rodinia framed the continental margin of eastern Laurentia and the departing cratons around the opening Iapetus Ocean. The result of continental extension was the production of a zig-zag set of promontories and embayments on the eastern Laurentian margin defined by northeast-trending rift segments offset by northwesttrending transform faults.
The St. Lawrence promontory defines the Laurentian margin in western Newfoundland. There, Neoproterozoic-Carboniferous clastic, volcanic, and carbonate successions record protracted continental rifting and passive-margin thermal subsidence followed by destruction of the margin during the early, middle, and late Paleozoic Appalachian orogenic …
Aspects Of The Geometry Of Metrical Connections, Matthew J. Wells
Aspects Of The Geometry Of Metrical Connections, Matthew J. Wells
University of Kentucky Doctoral Dissertations
Differential geometry is about space (a manifold) and a geometric structure on that space. In Riemann’s lecture (see [17]), he stated that “Thus arises the problem, to discover the matters of fact from which the measure-relations of space may be determined...”. It is key then to understand how manifolds differ from one another geometrically. The results of this dissertation concern how the geometry of a manifold changes when we alter metrical connections. We investigate how diverse geodesics are in different metrical connections. From this, we investigate a new class of metrical connections which are dependent on the class of smooth …
Imide-Functionalized Conjugated Polymers: Synthesis, Structure-Property And Device Studies, Xugang Guo
Imide-Functionalized Conjugated Polymers: Synthesis, Structure-Property And Device Studies, Xugang Guo
University of Kentucky Doctoral Dissertations
Organic semiconductors are widely studied as potential active components for consumer electronics due largely to their easily tuned properties and the promise of lower-cost solution-based processing technology. Imide-functionalized organic small molecule compounds have been one of the more important and studied organic semiconductors. However, very few imide-functionalized conjugated polymers have been reported in the literature. The body of this dissertation focuses on the synthesis, structure-property and device studies of imide-functionalized conjugated polymers. Reasons for choosing arylene imides as polymer building blocks include: a) they impart low-lying LUMOs to polymers, allowing band-gap engineering through choice of comonomers with variable electron-donating ability; …
Bedrock Mapping Of The Winchendon (1:25,000) Quadrangle (Ma-Nh): Evidence For Discontinous Deformation Along The Bronson Hill-Central Maine Boundary Zone, Timothy M. O'Brien
Bedrock Mapping Of The Winchendon (1:25,000) Quadrangle (Ma-Nh): Evidence For Discontinous Deformation Along The Bronson Hill-Central Maine Boundary Zone, Timothy M. O'Brien
University of Kentucky Master's Theses
Bedrock geology of the Winchendon quadrangle is divided into two zones based on structures and lithology. The eastern zone consists of tightly folded Silurian Rangeley and Paxton metasediments and pegmatites. Planar, NNE-SSW striking, W dipping foliations are characterized by alternating phyllosilicate-rich and leucosome layers. Fold axes of tight to isoclinal upright and recumbent folding are parallel to SSW-NNE shallowly plunging sillimanite, quartz and muscovite lineations. In the western zone Rangeley schists were intruded by Devonian Hardwick and Coys Hill and Fitzwilliam plutons. Planar NNE-SSW striking foliations dip shallowly to steeply west. Fold axes of tight-to-isoclinal asymmetric to recumbent folds plunge …
Variation In C/P Ratios In Devonian-Mississippian Marine Shales: Testing The Productivity-Anoxia Feedback Model, Brian T. Scott
Variation In C/P Ratios In Devonian-Mississippian Marine Shales: Testing The Productivity-Anoxia Feedback Model, Brian T. Scott
University of Kentucky Master's Theses
Carbon/phosphorus ratios for late Devonian-early Mississippian marine black shales along a transect from the Illinois Basin, across the Cumberland Saddle, and into the Appalachian Basin were evaluated to assess the role of productivity in organic carbon accumulation. Phosphorus is a key limiting nutrient for biological productivity in marine environments and may be regenerated preferentially relative to organic carbon, the amount of regeneration possibly being related to bottom-water anoxia. A positive feed-back mechanism (more specifically, productivity-anoxia feedback or PAF) has been proposed between water-column anoxia, high benthic regeneration of phosphorus, and marine productivity. This regeneration of phosphorus under anoxic conditions and …
Use Of Surface Geophysical Techniques To Locate A Karst Conduit In The Cane Run - Royal Spring Basin, Kentucky, Ganesh N. Tripathi
Use Of Surface Geophysical Techniques To Locate A Karst Conduit In The Cane Run - Royal Spring Basin, Kentucky, Ganesh N. Tripathi
University of Kentucky Master's Theses
Groundwater flow in karst terrains is difficult to map because it can be concentrated through conduits that do not necessarily coincide with the surface features. We applied electrical resistivity (ER) and self-potential (SP) techniques at three sites to locate an inferred trunk conduit feeding a major spring in the Inner Bluegrass region of Kentucky. Royal Spring is the primary water supply for the city of Georgetown; the upper part of its basin coincides with the Cane Run watershed. ER and SP profiles were perpendicular to the inferred trunk conduit orientation. ER profiles (972 m total length) were measured using a …
Structural Geology Of The Transylvania Fault Zone In Bedford County, Pennsylvania, Elizabeth Lauren Dodson
Structural Geology Of The Transylvania Fault Zone In Bedford County, Pennsylvania, Elizabeth Lauren Dodson
University of Kentucky Master's Theses
Transverse zones cross strike of thrust-belt structures as large-scale alignments of cross-strike structures. The Transylvania fault zone is a set of discontinuous right-lateral transverse faults striking at about 270º across Appalachian thrust-belt structures along 40º N latitude in Pennsylvania. Near Everett, Pennsylvania, the Breezewood fault terminates with the Ashcom thrust fault. The Everett Gap fault terminates westward with the Hartley thrust fault. Farther west, the Bedford fault extends westward to terminate against the Wills Mountain thrust fault. The rocks, deformed during the Alleghanian orogeny, are semi-independently deformed on opposite sides of the transverse fault, indicating fault movement during folding and …
Risk Indexes For Draft Ccl3 Chemicals, J. Alan Roberson, Matthew Lueders, Craig Adams, Jeffrey S. Rosen
Risk Indexes For Draft Ccl3 Chemicals, J. Alan Roberson, Matthew Lueders, Craig Adams, Jeffrey S. Rosen
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
To supplement the processes used for developing the draft third Contaminant Candidate List (CCL3) and better inform decisions made by the US Environmental Protection Agency on future CCLs, the authors offer an evaluation tool for efficiently synthesizing, visualizing, and organizing data for effective comparisons among contaminants. Graphical presentations of health effects-occurrence indexes were developed for more than 300 chemical contaminants, including those on the draft CCL3. a risk indexes framework was then used to elucidate the extent of available data, the data quality, and the underlying uncertainties for occurrence and toxicity. Choosing the appropriate contaminant for regulation is a complex …
Regional Characterisation Of Hard-Bottom Nursery Habitat For Juvenile Caribbean Spiny Lobster (Panulirus Argus) Using Rapid Assessment Techniques, Rodney D. Bertelsen, Mark J. Butler Iv, William F. Herrnkind, John H. Hunt
Regional Characterisation Of Hard-Bottom Nursery Habitat For Juvenile Caribbean Spiny Lobster (Panulirus Argus) Using Rapid Assessment Techniques, Rodney D. Bertelsen, Mark J. Butler Iv, William F. Herrnkind, John H. Hunt
Biological Sciences Faculty Publications
Shallow, hard-bottom habitat constitutes approximately 30% of the coastal waters of south Florida, United States, yet it is a chronically understudied feature of the marine seascape in this region. In this study, we characterised the general biogeographic and structural features of shallow benthic hard-bottom communities in the Florida Keys, and related those to the abundance of juvenile Caribbean spiny lobster (Panulirus argus), the target of one of Florida's most economically valuable fisheries. We used rapid assessment techniques to survey more than 100 hard-bottom sites in the Florida Keys to estimate the percentage bottom coverage of vegetation (seagrass and …
Phytoplankton Blooms: Their Occurence And Composition Within Virginia's Tidal Tributaries, Harold G. Marshall, Todd A. Egerton
Phytoplankton Blooms: Their Occurence And Composition Within Virginia's Tidal Tributaries, Harold G. Marshall, Todd A. Egerton
Biological Sciences Faculty Publications
Sporadic algal bloom development within a 10 year monitoring program in Virginia tidal tributaries of Chesapeake Bay is reviewed. These blooms were common events, characteristically producing a color signature to the surface water, typically short lived, occurring mainly from spring into autumn throughout different salinity regions of these rivers, and were produced primarily by dinoflagellates. The abundance threshold levels that would identify bloom status from a non-bloom presence were species specific, varied with the taxon's cell size, and ranged from ca. 10 to 10(4) cells mL(-1). Among the most consistent sporadic bloom producers were the dinoflagellates Akashiwo sanguinea, Cochlodinium …
Patterns Of Larval Atlantic Croaker Ingress Into Chesapeake Bay, Usa, Jason J. Schaffler, Christian S. Reiss, Cynthia M. Jones
Patterns Of Larval Atlantic Croaker Ingress Into Chesapeake Bay, Usa, Jason J. Schaffler, Christian S. Reiss, Cynthia M. Jones
OES Faculty Publications
We compared ingress patterns of Atlantic croaker Micropogonias undulatus larvae into Chesapeake Bay, USA, with published ingress patterns through barrier island inlets, the accepted model for larval fish ingress. This model asserts that larvae ingress on night flood tides at the flooddominated side of the inlet and at all depths. At the Chesapeake Bay mouth and in the adjacent coastal waters, we compared the distribution of abundance, size, age, and growth rates of croaker prior to ingress, In contrast to the barrier island inlet model, croaker larvae were more abundant at depth than closer to the surface regardless of location. …
Synergistic Effects Of Iron And Temperature On Antarctic Phytoplankton And Microzooplankton Assemblages, J. M. Rose, Y. Feng, G. R. Ditullio, R. B. Dunbar, C. E. Hare, P. A. Lee, M. Lohan, M. Long, W. O. Smith Jr., B. Sohst, S. Tozzi, Y. Zhang, D. A. Hutchins
Synergistic Effects Of Iron And Temperature On Antarctic Phytoplankton And Microzooplankton Assemblages, J. M. Rose, Y. Feng, G. R. Ditullio, R. B. Dunbar, C. E. Hare, P. A. Lee, M. Lohan, M. Long, W. O. Smith Jr., B. Sohst, S. Tozzi, Y. Zhang, D. A. Hutchins
OES Faculty Publications
Iron availability and temperature are important limiting factors for the biota in many areas of the world ocean, and both have been predicted to change in future climate scenarios. However, the impacts of combined changes in these two key factors on microbial trophic dynamics and nutrient cycling are unknown. We examined the relative effects of iron addition (+1 nM) and increased temperature (+4° C) on plankton assemblages of the Ross Sea, Antarctica, a region characterized by annual algal blooms and an active microbial community. Increased iron and temperature individually had consistently significant but relatively minor positive effects on total phytoplankton …
Cirene Air-Sea Interactions In The Seychelles-Chagos Thermocline Ridge Region, J. Vialard, J. P. Duvel, M. J. Mcphaden, P. Bouruet-Aubertot, B. Ward, E. Key, D. Bourras, R. Weller, P. Minnett, A. Weil
Cirene Air-Sea Interactions In The Seychelles-Chagos Thermocline Ridge Region, J. Vialard, J. P. Duvel, M. J. Mcphaden, P. Bouruet-Aubertot, B. Ward, E. Key, D. Bourras, R. Weller, P. Minnett, A. Weil
OES Faculty Publications
A field experiment in the southwestern Indian Ocean provides new insights into ocean-atmosphere interactions in a key climatic region.
Early Neoproterozoic Origin Of The Metazoan Clade Recorded In Carbonate Rock Texture: Reply, Fritz Neuweiler, Elizabeth C. Turner, David J. Burdige
Early Neoproterozoic Origin Of The Metazoan Clade Recorded In Carbonate Rock Texture: Reply, Fritz Neuweiler, Elizabeth C. Turner, David J. Burdige
OES Faculty Publications
We (Neuweiler et al., 2009) used scanning electron microscopic, fluorescence spectroscopic, fluorescence microscopic, and thin-section analytical work from modern, Cretaceous, Silurian, and early Neoproterozoic reefal material to make a geological case for an early Neoproterozoic origin of animals. In a modern analogue for ancient petrographic textures, degradative calcification of the extracellular collagenous matrix (ECM) of a modern siliceous sponge can be directly observed (Neuweiler et al., 2007).
Thin Layer Formation During Runaway Stratification In The Tidally Dynamic San Francisco Estuary, Alexander B. Bochdansky, Stephen M. Bollens
Thin Layer Formation During Runaway Stratification In The Tidally Dynamic San Francisco Estuary, Alexander B. Bochdansky, Stephen M. Bollens
OES Faculty Publications
During the course of a year, we repeatedly collected high-resolution vertical fluorometer data timed to coincide with a specific state during the tidal cycle. The time (end of the ebb during neap tide) and the location (a deep channel half-way between the Golden Gate and the point of tidally averaged bottom salinity of 2 psu) were chosen with the goal to observe runaway stratification. We consistently found at least one pronounced chlorophyll peak in the water column; however, the vertical location of these peaks varied within three types including surface, bottom and subsurface maxima. Our results showed that heterogeneity of …
A Robust, Multisite Holocene History Of Drift Ice Off Northern Iceland: Implications For North Atlantic Climate, John T. Andrews, Dennis A. Darby, Dennis Eberle, Anne E. Jennings, Matthias Moros, Astrid Ogilvie
A Robust, Multisite Holocene History Of Drift Ice Off Northern Iceland: Implications For North Atlantic Climate, John T. Andrews, Dennis A. Darby, Dennis Eberle, Anne E. Jennings, Matthias Moros, Astrid Ogilvie
OES Faculty Publications
An important indicator of Holocene climate change is provided by evidence for variations in the extent of drift ice. A proxy for drift ice in Iceland waters is provided by the presence of quartz. Quantitative xray diffraction analysis of the < 2 mm sediment fraction was undertaken on 16 cores from around Iceland. The quartz weight (wt.)% estimates from each core were integrated into 250-yr intervals between −0.05 and 11.7 cal. ka BP. Median quartz wt.% varied between 0.2 and 3.4 and maximum values ranged between 2.8 and 11.8 wt.%. High values were attained in the early Holocene and minimum values were reached 6–7 cal. ka BP. Quartz wt.% then rose steadily during the late Holocene. Our data exhibit no correlation with counts on haematite-stained quartz (HSQ) grains from VM129-191 west of Ireland casting doubt on the ice-transport origin. A pilot study on the provenance of Fe oxide grains in two cores that cover the last 1.3 and 6.1 cal. ka BP indicated a large fraction of the grains between 1 and 6 cal. ka BP were from either Icelandic or presently unsampled sources. However, there was a dramatic increase in Canadian and Russian sources from the Arctic Ocean ~1 cal. ka BP. These data may indicate the beginning of an Arctic Oscillation-like climate mode.
Peptide Hydrolysis And The Uptake Of Dipeptides By Phytoplankton, Margaret R. Mulholland, Cindy Lee
Peptide Hydrolysis And The Uptake Of Dipeptides By Phytoplankton, Margaret R. Mulholland, Cindy Lee
OES Faculty Publications
Rates of peptide hydrolysis (using the fluorescent substrate, lucifer yellow anhydride-labeled tetra-alanine) and dipeptide uptake (using dually labeled, 15N and 13C, dialanine) were measured in phytoplankton cultures and in natural populations during algal blooms dominated by one or two taxa. During most sampling events, both peptide hydrolysis and dipeptide uptake were greatest in the size fraction containing the dominant phytoplankter, suggesting that phytoplankton contribute substantially to or may even dominate observed extracellular peptide hydrolysis and dipeptide uptake in the environment. These are the first data suggesting that dipeptides may be taken up directly by phytoplankton and this may …
Radical Bonding: Structure And Stability Of Bis(Phenalenyl) Complexes Of Divalent Metals From Across The Periodic Table, Smaranda Craciun, Kelling J. Donald
Radical Bonding: Structure And Stability Of Bis(Phenalenyl) Complexes Of Divalent Metals From Across The Periodic Table, Smaranda Craciun, Kelling J. Donald
Chemistry Faculty Publications
We examine the bonding possibilities of the bis(phenalenyl) MP2 sandwich complexes of the divalent metals M = Be, Mg, Ca, Sr, Ba, Zn, Cd, and Hg, at the B3LYP level of theory. The outcome is an extraordinarily diverse class of low symmetry bis(phenalenyl)metal complexes in which bonding preferences and binding enthalpies differ dramatically. The lowest energy group 2 metal MP2 complexes include an intriguing η1,η3 BeP2 structure, and bent η6,η6 systems for M = Ca, Sr, and Ba. The group 12 bis(phenalenyl) complexes are thermodynamically unstable η1, …
Open Ocean Dms Air/Sea Fluxes Over The Eastern South Pacific Ocean, C. A. Marandino, Warren J. De Bruyn, S. D. Miller, E. S. Saltzman
Open Ocean Dms Air/Sea Fluxes Over The Eastern South Pacific Ocean, C. A. Marandino, Warren J. De Bruyn, S. D. Miller, E. S. Saltzman
Biology, Chemistry, and Environmental Sciences Faculty Articles and Research
Air/sea fluxes of dimethylsulfide (DMS) were measured by eddy correlation over the Eastern South Pacific Ocean during January 2006. The cruise track extended from Manzanillo, Mexico, along 110 degrees W, to Punta Arenas, Chile. Bulk air and surface ocean DMS levels were also measured and gas transfer coefficients (k(DMS)) were computed. Air and seawater DMS measurements were made using chemical ionization mass spectrometry (API-CIMS) and a gas/liquid membrane equilibrator. Mean surface seawater DMS concentrations were 3.8 +/- 2.2 nM and atmospheric mixing ratios were 340 +/- 370 ppt. The air/sea flux of DMS was uniformly out of the ocean, with …
3d Reconstruction Using Multi-View Imaging System, Conglin Huang
3d Reconstruction Using Multi-View Imaging System, Conglin Huang
University of Kentucky Master's Theses
This thesis presents a new system that reconstructs the 3D representation of dental casts. To maintain the integrity of the 3D representation, a standard model is built to cover the blind spots that the camera cannot reach. The standard model is obtained by scanning a real human mouth model with a laser scanner. Then the model is simplified by an algorithm which is based on iterative contraction of vertex pairs. The simplified standard model uses a local parametrization method to obtain the curvature information. The system uses a digital camera and a square tube mirror in front of the camera …