Physical Sciences and Mathematics Commons^™

Exfoliated Poly(Methyl Methacrylate) And Polystyrene/ Nanocomposites Occur When The Clay Cation Contains A Vinyl Monomer, Shengpei Su, Charles A. Wilkie

Chemistry Faculty Research and Publications

The bulk polymerization of methyl methacrylate and styrene in the presence of an organically modified clay containing a vinyl group that can be involved in the polymerization produces exfoliated nanocomposites. These nanocomposites have been characterized by X-ray diffraction, transmission electron microscopy, thermogravimetric analysis, mechanical properties, and cone calorimetry. The onset temperature of thermal degradation increases with the mechanical properties. The peak heat release rate is significantly reduced for nanocomposites containing 3 or 5% clay. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1124–1135, 2003

Massively Parallel Molecular Dynamics Simulations Of Crack-Front Dynamics And Morphology In Amorphous Nanostructured Silica, Cindy Lynn Rountree

LSU Doctoral Dissertations

Atomistic aspects of dynamic fracture in amorphous and nanostructured silica are herein studied via Molecular dynamics (MD) simulations, ranging from a million to 113 million atom system. The MD simulations were performed on massivelly parallel computers using highly efficient multi-resolution algorithms. Crack propagation in these systems is accompanied by nucleation and growth of nanometer scale cavities up to 20 nm ahead of the crack front. Cavities coalesce and merge with the advancing crack to cause mechanical failure. Recent AFM studies in silica glasses confirm this scenario of fracture [1]. The morphology of the fracture surfaces is studied by calculating the …

The Extinction Properties Of Reddened Galactic Ob Sightlines, Lynne Angela Valencic

LSU Doctoral Dissertations

A solid understanding of dust grains and their extinction properties is needed to better remove the effects of extinction from data and to comprehend the nature of the processes which modify grains. This requires a large sample of Galactic sightlines, extending far beyond the solar neighborhood, sampling not only a large volume of space but also a wide variety of environments. To fulfill this requirement, a database of sightlines toward 426 young, reddened stars was constructed using extinction curves based on IUE spectra. The curves were fit and the Fitzpatrick-Massa (FM) parameters were found. FM parameters allow for a quantitative …

Table Of Contents

Journal of the South Carolina Academy of Science

No abstract provided.

Histological Effect Of Ascocotyle Tenuicollis (Digenea: Heterophyidae) Metacercarial Infection On The Heart Of Fundulus Heteroclitus (Teleostei: Cyprinodontidae), Toni Hicks, Edna Steele

Journal of the South Carolina Academy of Science

No abstract provided.

2002 & 2003 Annual Meeting Extended Abstracts

Journal of the South Carolina Academy of Science

No abstract provided.

Some Notes On Multiplicative Congruential Random Number Generators With Mersenne Prime Modulus 261-1., James Harris

Journal of the South Carolina Academy of Science

No abstract provided.

Scas Officers And Council Members 2003 - 2004

Journal of the South Carolina Academy of Science

No abstract provided.

Parallel Software For Processing Hydrographic Data, Dr. M.J. Miller, Geary Layne, Dave Fabre, Dr. Krzysztof Sarnowski

Hydrographic Science Research Center

The Naval Research Laboratory’s Code 7440 Production Enhancement Team at the Stennis Space Center has been tasked to develop ways to speedup hydrographic data processing at the Naval Oceanographic Office [Depn02]. This paper presents the final development of a parallelized version of the Pfm_loader application customized to run on a Beowulf cluster.

This paper specifically covers software development efforts in early FY02 [Sarn02 ]. In a series of algorithms, called Schemes D, E, and F, a parallel algorithm previously implemented in Scheme C (see Figure 1) has been integrated with an improved version NAVO’s of the Pure File Magic (PFM) …

Analysis Of Multibeam Crosschecks Using Automated Methods, Susan Sebastian, Dave Wells

Hydrographic Science Research Center

The widespread use of multibeam sonar systems has brought to the forefront many developments to handle the tremendous amounts of data collected. One of the valuable quality assurance tools available for hydrographic data is that of analyzing depths where two tracklines cross. In contrast to the single-beam echosounding case, where crossing tracks result in single overlapping footprints, multibeam sonar crossing tracks involve the analysis of a multitude of redundant data points. The earliest (pre-GPS) multibeam crossing track analysis tools were used to improve georeferencing, shifting tracks to achieve spatial correlation at all intersections. Now, with georeferencing handled by GPS and …

Short-Term Shoreline And Volume Changes For The Beaches South Of Sebastian Inlet, Fl From August 21, 2000 Tonovember 23, 2002, Donald Evan Cresitello

Theses and Dissertations

This research examines the short-term mean high water (MHW) shoreline and sand volume changes for 4.3-miles of coastline in Northern Indian River County, Florida. Eighteen surveys covering 47 profile lines surveyed from the dune to wading depth were performed from 8/21/00 to 11/23/02. Wind, wave, and water level data were used to determine the effects of individual storm events. The primary objective was to analyze the profile line changes for the study region. Shoreline and sand volume changes were computed and compared to the proximity to Sebastian Inlet, the location and width of the nearshore reef, and the differing directions …

Phosphorus Contamination And Storage In Bottom Sediments Of The James River Arm Of Table Rock Lake, Southwest Missouri, Marc R. Owen

Graduate Theses/Dissertations

Eutrophic conditions in the upper James River Arm (JRA) of Table Rock Lake have been linked to phosphorus (P) inputs by wastewater treatment facilities and increasing urban development in the upper James River Basin (3,770 km2). Since the majority of P in aquatic environments is bound to sediments, bottom sediment can function as both a source and sink of P in lake systems. This study evaluates the spatial distribution, physical and chemical characteristics, and storage of sediment-P in the active layer ( < 5cm) of bottom sediments in the JRA. The JRA makes up about 20% of Table Rock Lake’s surface area, contributes about 30% of the inflow, and has the poorest water quality of the entire lake. For this study, grab samples were collected in the main arm and tributary coves at the deepest part of the lake and at several shallow sites along the main arm. Concentrations increase in a down-lake direction in the main arm ranging from 5 to >2000 ppm P. However, water-column P concentrations show a decrease down-lake, indicating that sedimentation is removing P from …

Us Nuclear Security Cooperation With Russia And Transparency, David W. Hafemeister

Physics

This chapter reviews the efforts of Russia and the United States to conclude agreements on the control or reduction of their inventories of nuclear warheads and military fissile materials. While some of the negotiations attempted to codify arms limitation and reduction measures, others were aimed at constraining the spread of fissile materials and technologies to the non-nuclear weapon states (NNWS). A number of the negotiations had elements of both arms control and non-proliferation.

Most of the monitoring provisions contained in nuclear agreements between Russia and the USA are in the category of transparency measures—those that give confidence that a …

Approaches To The Synthesis Of Novel Triptycene Dendrimers And Hyperbranched Poly(Phenylene Sulfides) And Poly(Phenylene Sulfones), Alfredo Mellace

Seton Hall University Dissertations and Theses (ETDs)

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The Local-Time Variation Of The Quiet Plasmasphere: Geosynchronous Observations And Kinetic Theory, Mark Anthony Reynolds, G. Ganguli, Y-J Su, M.F. Thomsen

Publications

The quiet-time structure of the plasmaspheric density was investigated using observations of the Los Alamos geosynchronous satellites, and these observations were compared with theoretical predictions of the quasi-static localtime variation by a kinetic model. It was found that the coupling to the ionosphere (via the local-time variation of the exobase) played a key role in determining the density structure at 6.6 RE. The kinetic model predicts that most of the local-time variation at geosynchronous orbit is due to the variation of the exobase parameters. During quiet times, when the convection electric field is dominated by the corotation field, the effects …

Fact Sheet, Yale Office Of Institutional Research

Fact Sheets

No abstract provided.

The Variability Of Currents In The Yucatan Channel: Analysis Of Results From A Numerical Ocean Model, Tal Ezer, Lie-Yauw Oey, Hyun-Chul Lee, Wilton Sturges

CCPO Publications

The flow through the Yucatan Channel and into the Gulf of Mexico is a major component of the Gulf Stream and the subtropical gyre circulation. Surprisingly, however, little is known about the forcing and physical parameters that effect the current structures in the Channel. This paper attempts to improve our understanding of the flow through the Channel with a detailed analysis of the currents obtained from a primitive-equation model that includes the Gulf and the entire Caribbean Sea and forced by 6-hourly wind from ECMWF. The analysis includes two parts: First, the overall statistics of the model results, including the …

Observations Of Cross Channel Structure Of Flow In An Energetic Tidal Channel, Mario Caceres, Arnoldo Valle-Levinson, Larry P. Atkinson

CCPO Publications

[1] Measurements of velocity and density profiles were made to describe the transverse structure of flow in Chacao Channel, Southern Chile (41.75 degreesS), where typical tidal velocities are similar to4 m/s. Current profiles were obtained with a 307.2 kHz Acoustic Doppler Current Profiler (ADCP) over 25 repetitions of a cross-channel transect during one semidiurnal tidal cycle. The 2.2 km long transect ran northeast/southwest across the channel. A northern channel (120 m deep) and a southern channel (85 m deep) were separated by Remolinos Rock, a pinnacle that rises to 20 m depth at similar to0.7 km from the southern side. …

Flow Induced By Upwelling Winds In An Equatorward Facing Bay: Gulf Of Arauco, Chile, Arnoldo Valle-Levinson, Larry P. Atkinson, Dante Figueroa, Leonardo Castro

CCPO Publications

[1] Shipborne observations of hydrographic and flow velocity profiles were combined with wind velocity measurements to describe the characteristics of the wind-induced flow in an equatorward facing bay of central Chile in South America. The measurements, which were taken from two transects and one anchor station, were made during late austral spring, between 4 and 10 December 2000. Most observations concentrated on Boca Grande, a transect that crossed the deep, northern ( equatorward) entrance to the bay. The other transect crossed the smaller and shallower, westward entrance to the bay, Boca Chica. The anchor station was located inside the bay, …

Academic Fleet Renewal- Two Years Later, Larry Atkinson

CCPO Publications

(First paragraph) In November 2000, I wrote a Soapbox article on fleet renewal for Sea Technology. It is a little unsettling to see how slowly ideas move towards implementation. Nevertheless, we are making progress. In this editorial I will note a bit of that progress and try to guess where we will be in two more years.

Reversing Circulation Patterns In A Tropical Estuary, Arnoldo Valle-Levinson, Kathryn T. Bosley

CCPO Publications

A combination of current velocity and water density measurements was used to characterize the basic patterns of water exchange in the Gulf of Fonseca, a tropical estuary on the Pacific Ocean side of Central America. The measurements were obtained during spring and neap tides in March ( dry season) and June ( wet season) of 2001 and consisted of profiles of current velocity and density along four transects. From mid-March to mid-April a time series of hourly surface current velocity maps was also obtained with a high-frequency radar system of two antennas. The sampling transects and the radar coverage concentrated …

Intergalactic Globular Clusters, Michael J. West, Ted Von Hippel, Patrick Cote, Henry C. Ferguson, Michael D. Gregg, Andres Jordan, Ronald O. Marzke, Nial R. Tanvir

Publications

We confirm and extend our previous detection of a popula- tion of intergalactic globular clusters in Abell 1185, and report the first discovery of an intergalactic globular cluster in the nearby Virgo cluster of galaxies. The numbers, colors and luminosities of these objects can place constraints on their origin, which in turn may yield new insights to the evolution of galaxies in dense environments.

Measurement Of The Stochasticity Of Low-Latitude Geomagnetic Temporal Variations, Mark Anthony Reynolds, James A. Wanliss

Publications

Ground magnetometer measurements of total magnetic field strength from 6 stations at low latitudes were analyzed using power spectrum and Hurst range scaling techniques. The Hurst exponents for most of these time-series were near 0.5, which indicates stochasticity, with the highest latitude stations exhibiting some persistence with Hurst exponents greater than 0.6. Although no definite correlations are evident, the relative increase of the Hurst exponent with latitude suggests the possibility that the underlying dynamics of the magnetosphere change with latitude. This result may help quantify the dynamics of the inner magnetosphere itself without the direct presence of the solar wind …

Simulation Of Dynamic Electrochemical Processes, John Cassidy

Articles

This work is designed to introduce electrochemists in a tutorial manner to the basics of modeling of electrochemical systems based primarily on diffusion equations. There is an introduction to analytical and numerical methods with examples taken from typical electrochemical experiments. The Laplace transform is used to derive the Cottrell equation and chronopotentiometry. The response of an electrode to a Gaussian concentration profile is detailed. Laplace’s equation is solved for a simple cell to determine the potential distribution. Discrete methods are employed to calculate the current time behavior following a potential step using the explicit finite difference method. Cyclic voltammetry is …

Molecular Mass And Dynamics In Pma-D₃ In The Glass Transition Region, Burak Metin, Frank D. Blum

Chemistry Faculty Research & Creative Works

The segmental dynamics through the glass transition region, by which the glassy polymer becomes rubbery, are not well understood. Free volume, thermodynamic and kinetic theories have been used to describe the phenomenon behind the glass transition and some of those theories were tested with computer simulations. Different experimental techniques, such as NMR, thermo-mechanical analysis (TMA), differential scanning calorimetry (DSC), dilatometry and dynamic mechanical analysis (DMA) have all been also used to probe this important phenomena. Deuterium (2H) NMR has been a valuable tool for the investigation of the dynamics of macromolecules. Deuteration of macromolecules at specific locations on the chains …

Two Distributed Algorithms For E-Ticket Validation Protocols For Mobile Clients, H. Mohanty, Sanjay Kumar Madria, T. Suman Kumar Reddy, R. K. Ghosh

Computer Science Faculty Research & Creative Works

The e-ticket (electronic ticket) validation problem has relevance in mobile computing environment because of the multiple submission of a ticket that is possible due to intermittent disconnections and mobility of hosts. Here, we propose protocols that are not only sensitive to disconnection but also to location. One of the proposed protocols is the variant of the distributed protocol proposed by Pedone (2000) for Internet users. This shows that a distributed protocol for static network can be restructured for distributed computation in a mobile computing environment. We have also proposed another protocol that uses a hierarchical location database of mobile hosts …

Production Of An E. Coli Toxin Protein; Colicin A In E. Coli Using An Inducible System, İsa Gökçe, Jeremy H. Lakey

Turkish Journal of Chemistry

Colicins are bacterial toxins that kill Escherichia coli and related cells; their mode of action is of interest in protein import and toxicology. Colicins translocate across the E. coli outer membrane and periplasm by interacting with several receptors. This translocation process involves interaction of the colicin with the outer membrane porin OmpF and subsequently with the integral membrane protein TolA. The N-terminal domain of colicin N is involved in the import process. Our aim was to produce a large quantity of colicin A for functional and structural studies. It is a prerequisite to have a correctly folded and stable protein …

Crystal Structure Of Cis-Bis(N,N-Dimethyl-N'-Benzoylthioureato)Palladium(Ii), Göktürk Avşar, Hakan Arslan, Hans-Jurgen Haupt, Nevzat Külcü

Turkish Journal of Chemistry

In this study cis-bis(N,N-dimethyl-N'-benzoylthioureato) palladium(II) is synthesised and the crystal structure is determined by X-ray diffraction methods. It crystallises in the space group P2_{1}/c, with a = 11.943(1) Å, b = 11.713(1) Å, c = 15.345(1) Å, \beta = 93.90(1)°, and D_{calc} = 1.616 g cm^{-1} for Z = 4. The Pd(II) atom is in a four-coordinate geometry consisting of two thiocarbonyl S and two carbonyl O atoms from two ligand groups. The Pd-S and Pd-O bond lengths are 2.2313(6) and 2.0211(16) Å, respectively.

Voltammetric And Flow Injection Amperometric Determination Of Cysteine At A Glassy Carbon Electrode In The Presence Of Copper(Ii) Ions, Zekerya Dursun, İlyas Şahbaz, F. Ni̇l Ertaş, Gürel Ni̇şli̇

Turkish Journal of Chemistry

The voltammetric behaviour of cysteine was investigated in the presence of Cu(II) ions at a rotating glassy carbon electrode (RGCE). Two reduction peaks related to the successive reduction of the cysteine complexes of Cu(II) and Cu(I) ions were observed at --0.30 and --0.60 V vs. SCE respectively. These peaks were increased upon the addition of cysteine into a pH 9.20 borate buffer solution containing 0.1 M KNO_{3} and 1.0 x 10^{-5} M Cu(II) ions. The calibration curve was linear in the concentration range of 5.0 x 10^{-10}- 2.0 x 10^{-8} M for cysteine by utilising the peak current at --0.6 …

Synthesis, Characterization And Biological Applications Of Organotin(Iv) Derivatives Of 2-(2-Fluoro-4-Biphenyl)Propanoic Acid, Sohail Mahmood, Saqib Ali, Moazzam Hussain Bhatti, Mohammad Mazhar, Rashid Iqbal, Khalid Mohammed Khan, Ghulam Mustafa Maharvi

Turkish Journal of Chemistry

A series of organotin(IV) derivatives with the general formula R_{4 - n}SnL_{n} (where n = 1 or 2, R = Me, Et, n-Bu, Ph and L = 2-(2-fluoro-4-biphenyl)propanoate) have been synthesized and characterized by infrared, multinuclear NMR (^{1}H, ^{13}C, ^{119}Sn), ^{119m}Sn Mössbauer spectroscopy and mass spectrometry. Screening tests of these compounds showed that they are highly active against various bacteria and fungi.