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2003

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Articles 3031 - 3060 of 3354

Full-Text Articles in Physical Sciences and Mathematics

Synthesis, Characterization, And Application Of Water-Soluble Chiral Calix[4]Arene Derivatives In Spectroscopy And Capillary Electrokinetic Chromatography, Kim Hamilton Jan 2003

Synthesis, Characterization, And Application Of Water-Soluble Chiral Calix[4]Arene Derivatives In Spectroscopy And Capillary Electrokinetic Chromatography, Kim Hamilton

LSU Doctoral Dissertations

This dissertation is an account of the synthesis, characterization, and application of novel water-soluble chiral calixarenes in spectroscopy and capillary electrophoresis. It is divided into four sections. The first part describes the synthesis and nuclear magnetic resonance (NMR) characterization of four p-t-butylcalix[4]arenes bearing L-amino acid moieties on their lower rims (CX4-AA). The structure and conformation of the derivatives have been determined using one- and two-dimensional NMR techniques. Proton and carbon-13 spectra show that the derivatives are tetra-substituted and adopt a cone conformation. The preparation and characterization of silica-bonded calixarene stationary phases for capillary electrochromatography is also reported in Chapter 2. …

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Angle-Resolved Photoemission Study And Neutron Diffraction Measurements On Lasb2, Alice Acatrinei Jan 2003

Angle-Resolved Photoemission Study And Neutron Diffraction Measurements On Lasb2, Alice Acatrinei

LSU Doctoral Dissertations

LaSb2 has recently been found to have unusual magnetoresistive properties despite the fact that neither La nor Sb are magnetic. The resistance is anisotropic, and at high magnetic fields presents an anomaly that might be a result of a charge density transition. The magnetoresistance is anisotropic and linear, and the resistivity presents high relative changes when a magnetic field is applied. Discovered in 1954, LaSb2, as the rest of the light rare-earth diantimonides, was poorly studied. The anisotropic magnetic properties reported in 1998 by Bud'ko, Canfield and their collaborators make the series very interesting. A description of …

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Design, Synthesis, And Applications Of Bio-Derived Crosslinking Monomers For Molecular Imprinting, Martha Sibrian-Vazquez Jan 2003

Design, Synthesis, And Applications Of Bio-Derived Crosslinking Monomers For Molecular Imprinting, Martha Sibrian-Vazquez

LSU Doctoral Dissertations

Most of the research in the field of molecular imprinting has been focused on the development of new functional monomers, in order to improve the molecular recognition properties afforded by these materials. The role of the crosslinking monomer has often been overlooked, since it is considered an inert component that only provides a scaffold to support the binding sites. However, the crosslinking monomer represents a high percent (80-90%) of the composition of molecularly imprinted polymers (MIPs), which can have a large influence on the MIPs properties. This research addresses the design, synthesis, and applications of new crosslinking monomers for molecular …

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Machine Learning Techniques For Efficient Query Processing In Kowledge Base Systems, Kevin Paul Grant Jan 2003

Machine Learning Techniques For Efficient Query Processing In Kowledge Base Systems, Kevin Paul Grant

LSU Doctoral Dissertations

In this dissertation we propose a new technique for efficient query processing in knowledge base systems. Query processing in knowledge base systems poses strong computational challenges because of the presence of combinatorial explosion. This arises because at any point during query processing there may be too many subqueries available for further exploration. Overcoming this difficulty requires effective mechanisms for choosing from among these subqueries good subqueries for further processing. Inspired by existing works on stochastic logic programs, compositional modeling and probabilistic heuristic estimates we create a new, nondeterministic method to accomplish the task of subquery selection for query processing. Specifically, …

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Black Willow (Salix Nigra) Use In Phytoremediation Techniques To Remove The Herbicide Bentazon From Shallow Groundwater, Robert Mark Conger Jan 2003

Black Willow (Salix Nigra) Use In Phytoremediation Techniques To Remove The Herbicide Bentazon From Shallow Groundwater, Robert Mark Conger

LSU Doctoral Dissertations

Wetland environments have been impacted by the activities of man over the past several hundred years in North America. Industrialization into wetland areas has brought with it anthropogenic compounds that have been released into soils and groundwater. The use of phytoremediation to detoxify soil and groundwater began in the mid 1990's and has become a popular remediation technology. In 1994, a feasibility study for using phytoremediation in such an industrialized wetland area was conducted at a petrochemical facility at BASF Corporation, located about 20 kilometers south of Baton Rouge, Louisiana in Ascension Parish. The test site consisted of low level …

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Splitter Theorems For 3- And 4-Regular Graphs, Jinko Kanno Jan 2003

Splitter Theorems For 3- And 4-Regular Graphs, Jinko Kanno

LSU Doctoral Dissertations

Let g be a class of graphs and ≤ be a graph containment relation. A splitter theorem for g under ≤ is a result that claims the existence of a set O of graph operations such that if G and H are in g and H≤G with G≠H, then there is a decreasing sequence of graphs from G to H, say G=G0≥G1≥G2...Gt=H, all intermediate graphs are in g, and each Gi can be obtained from Gi-1 by applying a single …

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Solid-Phase Dna Sequencing Reactions Performed In Micro-Capillary Reactors And Solid-Phase Reversible Immobilization In Microfluidic Chips For Purification Of Dye-Labeled Dna Sequencing Fragments, Yichuan Xu Jan 2003

Solid-Phase Dna Sequencing Reactions Performed In Micro-Capillary Reactors And Solid-Phase Reversible Immobilization In Microfluidic Chips For Purification Of Dye-Labeled Dna Sequencing Fragments, Yichuan Xu

LSU Doctoral Dissertations

The research presented in this dissertation involves micro-capillary reactors for solid phase DNA sequencing, the identification of dye terminator sequencing fragments with time-resolved methods, and purification of dye-labeled DNA fragments using solid- phase reversible immobilization in microfluidic chips. Solid-phase micro-reactors have been prepared for DNA sequencing applications using slab gel electrophoresis. A PCR product was immobilized to the interior wall of a fused-silica capillary tube via a biotin-streptavidin linkage. Solid-phase sequencing was carried out in micro-capillary reactors using a four-lane, single color dye primer chemistry strategy. The read length was found to be 589 bases. The complementary DNA fragments generated …

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Book Embeddings Of Graphs, Robin Leigh Blankenship Jan 2003

Book Embeddings Of Graphs, Robin Leigh Blankenship

LSU Doctoral Dissertations

We use a structural theorem of Robertson and Seymour to show that for every minor-closed class of graphs, other than the class of all graphs, there is a number k such that every member of the class can be embedded in a book with k pages. Book embeddings of graphs with relation to surfaces, vertex extensions, clique-sums and r-rings are combined into a single book embedding of a graph in the minor-closed class. The effects of subdividing a complete graph and a complete bipartite graph with respect to book thickness are studied. We prove that if n ≥ 3, …

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Control Of Transport Dynamics In Overlay Networks, Qishi Wu Jan 2003

Control Of Transport Dynamics In Overlay Networks, Qishi Wu

LSU Doctoral Dissertations

Transport control is an important factor in the performance of Internet protocols, particularly in the next generation network applications involving computational steering, interactive visualization, instrument control, and transfer of large data sets. The widely deployed Transport Control Protocol is inadequate for these tasks due to its performance drawbacks. The purpose of this dissertation is to conduct a rigorous analytical study on the design and performance of transport protocols, and systematically develop a new class of protocols to overcome the limitations of current methods. Various sources of randomness exist in network performance measurements due to the stochastic nature of network traffic. …

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The Effect On Water Quality Of Riverine Input Into Coastal Wetlands, Robert Raymond Lane Jan 2003

The Effect On Water Quality Of Riverine Input Into Coastal Wetlands, Robert Raymond Lane

LSU Doctoral Dissertations

This dissertation focuses on impact on water quality of two freshwater diversions, the Bonnet Carre Spillway and the Caernarvon freshwater diversion, as well as the Atchafalaya River Estuarine Complex. As water passed through the Bonnet Carre Spillway, there were reductions in total suspended sediment concentrations of 82-83%, in nitrite+nitrate of 28-42%, in total nitrogen (TN) of 26-30%, and in total phosphorus (TP) of 50-59%. The Si:N ratio generally increased and the N:P ratio decreased from the river to the plume edge in Lake Pontchartrain. At the Caernarvon diversion, there were reductions in concentrations of dissolved inorganic Si, N, and P …

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Analyzing The Impact Of Changing Software Requirements: A Traceability-Based Methodology, James Steven O'Neal Jan 2003

Analyzing The Impact Of Changing Software Requirements: A Traceability-Based Methodology, James Steven O'Neal

LSU Doctoral Dissertations

Software undergoes change at all stages of the software development process. Changing requirements represent risks to the success and completion of a project. It is critical for project management to determine the impact of requirement changes in order to control the change process. We present a requirements traceability based impact analysis methodology to predictively evaluate requirement changes for software development projects. Trace-based Impact Analysis Methodology (TIAM) is a methodology utilizing the trace information, along with attributes of the work products and traces, to define a requirement change impact metric for determining the severity of a requirement change. We define the …

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Level Of Essentialness Of A Node In Flowcharts And Its Application To Program Testing, Osman Kandara Jan 2003

Level Of Essentialness Of A Node In Flowcharts And Its Application To Program Testing, Osman Kandara

LSU Doctoral Dissertations

Program testing is important to develop bug free software. A common form of program testing involves selecting test cases which execute (cover) a given set W of statements in the program. In regression testing, W typically forms a small subset of the program. It is often possible to find an alternate small set W so that execution of W' implies execution of W. We develop concepts and algorithms for finding W' as small as possible with the condition that the statements in W' are "close" to those in W in terms of program structure. These concepts generalize the notion of …

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Gravitational Radiation Detectability Of Supernova 1987a'S Remnant Fully Matched Filter For Double Resonant Gravitational Detector, Giovanni Santostasi Jan 2003

Gravitational Radiation Detectability Of Supernova 1987a'S Remnant Fully Matched Filter For Double Resonant Gravitational Detector, Giovanni Santostasi

LSU Doctoral Dissertations

Part I There is some observational evidence of the presence of a pulsating light source in the remnant of the supernova (SN) 1987A [1]. This source is considered to be a rotating neutron star. Fourier analysis of the light intensity of this source reveals a main narrow frequency peak and side bands that are understood as a modulation of the main sinusoidal signal. A particular model of the neutron star invokes a precessing object to explain the modulation. From the Fourier spectrum of the source and changes in the frequency value, we can determine important parameters of the spinning neutron …

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The Kauffman Bracket Skein Module Of The Quaternionic Manifold, John Michael Harris Jan 2003

The Kauffman Bracket Skein Module Of The Quaternionic Manifold, John Michael Harris

LSU Doctoral Dissertations

In this work, we study the structure of the Kauffman bracket skein module of the quaternionic manifold over the field of rational functions. We begin with a brief survey of manifolds whose Kauffman bracket skein modules are known, and proceed in Chapter 2 by recalling the facts from Temperley-Lieb recoupling theory that we use in the proofs. In Chapter 3, using recoupling theory and with Mathematica's assistance, we index an infinite presentation of the skein module, and conjecture that it is five-dimensional. In Chapter 4, using a new set of relations, we prove that the skein module is indeed spanned …

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Toward A Global Microscopic Theory For Nuclear Structure: Mean Field Plus Random Phase Approximation Vs. Shell Model, Ionel Stetcu Jan 2003

Toward A Global Microscopic Theory For Nuclear Structure: Mean Field Plus Random Phase Approximation Vs. Shell Model, Ionel Stetcu

LSU Doctoral Dissertations

Our understanding of nuclear structure is built upon mean-field theories such as Hartree-Fock and time-dependent Hartree-Fock. The small-amplitude limit of the latter is the random phase approximation (RPA), which is widely used to model giant resonances in nuclei. Despite this popularity, RPA has been mostly validated against toy models; tests against complex models are scarce in the literature. We perform a thorough test of the RPA against full 0hw shell model (SM) calculations, including in our investigation binding energies, scalar ground-state observables, for which we develop a new method, and transition strengths. We allow deformed Hartree-Fock solutions and compare results …

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Parallel Molecular Dynamics Simulations Of Dynamics Of Oxidation And Reactive Wetting In Metal/Ceramic Systems, Gurcan Aral Jan 2003

Parallel Molecular Dynamics Simulations Of Dynamics Of Oxidation And Reactive Wetting In Metal/Ceramic Systems, Gurcan Aral

LSU Doctoral Dissertations

Oxidation of a flat aluminum (111) surface and the reactive wetting of the aluminum (Al) droplet on a flat alumina (α-Al2O3) surface are investigated by using parallel molecular-dynamics simulations with dynamic charge transfer among atoms on a microscopic length scale. The interatomic potential, based on the formalism of Streitz and Mintmire, allows atoms to vary their charges dynamically between anions and cations, when atoms move and their local environment is altered. We investigate the oxidation thickness as a function of time and the oxygen density which is 10-40 times that of the normal state (1 atm …

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Biomechanical Reconstruction Of The Appendicular Skeleton In Three North American Jurassic Sauropods, Ray Wilhite Jan 2003

Biomechanical Reconstruction Of The Appendicular Skeleton In Three North American Jurassic Sauropods, Ray Wilhite

LSU Doctoral Dissertations

Forelimb and hindlimb articulation, reconstructed musculature, and function were examined in Apatosaurus, Diplodocus, and Camarasaurus. A technique was developed using a Microscribe three-dimensional digitizer to capture external morphological data for skeletal reconstruction and determination of taxonomically useful features. The appendicular musculature of Alligator mississippiensis was dissected to determine form, function, origin, and insertion of muscles to aid in reconstruction of sauropod musculature. Contrary to the literature, M. caudofemoralis longus was found to originate primarily from the lateral surfaces of the proximal chevrons instead of the bodies and transverse processes of the caudals, demonstrating that chevron morphology is indicative of the …

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Molecular-Dynamics Simulations Of Self-Assembled Monolayers (Sam) On Parallel Computers, Satyavani Vemparala Jan 2003

Molecular-Dynamics Simulations Of Self-Assembled Monolayers (Sam) On Parallel Computers, Satyavani Vemparala

LSU Doctoral Dissertations

The purpose of this dissertation is to investigate the properties of self-assembled monolayers, particularly alkanethiols and Poly (ethylene glycol) terminated alkanethiols. These simulations are based on realistic interatomic potentials and require scalable and portable multiresolution algorithms implemented on parallel computers. Large-scale molecular dynamics simulations of self-assembled alkanethiol monolayer systems have been carried out using an all-atom model involving a million atoms to investigate their structural properties as a function of temperature, lattice spacing and molecular chain-length. Results show that the alkanethiol chains tilt from the surface normal by a collective angle of 25o along next-nearest neighbor direction at 300K. At …

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A Comparison Of Life Histories And Ecological Aspects Among Snappers (Pisces: Lutjanidae), Fernando Martinez-Andrade Jan 2003

A Comparison Of Life Histories And Ecological Aspects Among Snappers (Pisces: Lutjanidae), Fernando Martinez-Andrade

LSU Doctoral Dissertations

An extensive search for data on life-history and ecological variables was conducted for a representative number of the species within the family Lutjanidae. After creating different databases and standardizing all data, these variables were examined in statistical, correlation and graphic analyses. Additionally, a series of Principal Component Analyses were used to examine patterns among variables. Life-history variables included age at length zero, asymptotic length, maximum length, longevity, asymptotic weight, length at maturity, age at maturity, reproductive life span, growth rate and mortality rate. Ecological variables included latitudinal and vertical distribution, habitat selection (represented by substrate type), and spawning seasons. The …

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Controls On Middle To Late Ordovician Synorogenic Deposition In The Southeastern Corner Of Laurentia, German Bayona Jan 2003

Controls On Middle To Late Ordovician Synorogenic Deposition In The Southeastern Corner Of Laurentia, German Bayona

University of Kentucky Doctoral Dissertations

Middle and Upper Ordovician strata in the southernmost Appalachians document initial collision along the southeastern margin of Laurentia during the Blountian orogeny, an early phase of the Taconic orogeny. Coeval drowning and exposure of different parts of the former platform and variations in stratal architecture have been attributed to tectonic and depositional loading along the collisional margin. Stratigraphic correlations, using a bentonite-graptoliteconodont time framework, a palinspastic map, and a map of subsurface basement structures, suggest that basement-fault reactivation, flexural subsidence, and eustasy variously controlled uplift, subsidence, and deposition at different sites within the peripheral foreland basin. This dissertation documents how …

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Nanocomposites Based On Poly (Ε-Caprolactone) (Pcl)/Clay Hybrid: Polystyrene, High Impact Polystyrene, Abs, Polypropylene And Polyethylene, Xiaoxia Zheng, Charles A. Wilkie Jan 2003

Nanocomposites Based On Poly (Ε-Caprolactone) (Pcl)/Clay Hybrid: Polystyrene, High Impact Polystyrene, Abs, Polypropylene And Polyethylene, Xiaoxia Zheng, Charles A. Wilkie

Chemistry Faculty Research and Publications

Nanocomposites of polystyrene, high impact polystyrene, acrylonitrile–butadiene–styrene terploymer, polypropylene and polyethylene have been prepared using an organically-modified clay that contains polycaprolactone—PCL-modified clay. Depending upon the mode of preparation of the PCL-modified clay, all three types of nanocomposites, immiscible, intercalated and exfoliated, may be produced. The materials have been characterized by X-ray diffraction, transmission electron microscopy, cone calorimetry, thermogravimetric analysis, and the evaluation of mechanical properties.

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In Situ Reactive Blending To Prepare Polystyrene-Clay And Polypropylene-Clay Nanocomposites, Dongyan Wang, Charles A. Wilkie Jan 2003

In Situ Reactive Blending To Prepare Polystyrene-Clay And Polypropylene-Clay Nanocomposites, Dongyan Wang, Charles A. Wilkie

Chemistry Faculty Research and Publications

Nanocomposites of polystyrene and polypropylene with organically-modified clay may be prepared by melt blending in a Brabender mixer the clay and the polymer. The presence of maleic anhydride increases the likelihood of nanocomposite formation for polystyrene but is less important for polypropylene. The materials that result are immiscible materials, in that the clay is not uniformly distributed throughout the polymer matrix, but there is polymer inserted between the clay layers. The results from cone calorimetry suggest that nanocomposite formation has occurred, since there is a significant reduction in the peak heat release rate.

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A Stibonium-Modified Clay And Its Polystyrene Nanocomposite, Dongyan Wang, Charles A. Wilkie Jan 2003

A Stibonium-Modified Clay And Its Polystyrene Nanocomposite, Dongyan Wang, Charles A. Wilkie

Chemistry Faculty Research and Publications

Triphenylhexadecylstibonium trifluoromethylsulfonate has been prepared and ion-exchanged with sodium montmorillonite to obtain a new organically-modified clay. The clay has higher thermal stability than an ammonium clay; only a portion of the alkyl chain is lost during degradation and all of the antimony is retained. This clay has been used to prepare a polystyrene nanocomposite in which the clay is not uniformly distributed throughout the polymer. Nonetheless the polymer does insert into the clay layers and the d-spacing of the clay expands from 2.0 to 3.0 nm. The enhanced thermal stability of this system may mean that it could be …

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Molecular Recognition Of No/No+ Via Multicenter (Charge-Transfer) Binding To Bridged Diarene Donors. Effect Of Structure On The Optical Transitions And Complexation Thermodynamics, Sergiy V. Rosokha, Sergey V. Lindeman, Rajendra Rathore, Jay K. Kochi Jan 2003

Molecular Recognition Of No/No+ Via Multicenter (Charge-Transfer) Binding To Bridged Diarene Donors. Effect Of Structure On The Optical Transitions And Complexation Thermodynamics, Sergiy V. Rosokha, Sergey V. Lindeman, Rajendra Rathore, Jay K. Kochi

Chemistry Faculty Research and Publications

Bridged diarenes form very strong [1:1] complexes with nitrosonium/nitric oxide in which the NO moiety is optimally sandwiched in the cleft between a pair of cofacial aromatic rings which act as a molecular “Venus flytrap”. The spectral features of these associates are generally similar to those for [1:1] and [2:1] nitrosonium complexes with mononuclear alkyl-substituted benzenes, and they are appropriately described within the LCAO molecular-orbital methodology and the Mulliken (charge-transfer) formulation of donor/acceptor electronic transitions. The thermodynamics study indicates that the efficient binding is determined by (i) the close matching of the donor/acceptor redox potentials and (ii) the ability of …

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Design And Synthesis Of Constrained Dipeptide Units For Use As Β-Sheet Promoters, Umut Oguz Jan 2003

Design And Synthesis Of Constrained Dipeptide Units For Use As Β-Sheet Promoters, Umut Oguz

LSU Doctoral Dissertations

The study of factors promoting beta-sheet formation has recently gained interest due to the suspected involvement of beta-sheets in brain degenerative diseases such as Alzheimer's disease (AD), Creutzfeldt-Jacob disease (CJD) and bovine spongiform encephalopathy. Understanding beta-sheet formation and the factors that stabilize beta-sheet structure may serve as a basis for future drug design. The extended structure of a beta-sheet can be stabilized by constrained amino acid analogs that are pre-organized to adopt the extended conformation. In this dissertation using innovative synthetic organic chemistry methods, two dipeptide units are designed and synthesized that are constrained to form the extended conformation and …

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Design And Synthesis Of Handles For Solid-Phase Peptide Synthesis And Convergent Peptide Synthesis, Jose Giraldes Jan 2003

Design And Synthesis Of Handles For Solid-Phase Peptide Synthesis And Convergent Peptide Synthesis, Jose Giraldes

LSU Doctoral Dissertations

The recent popularity of methods for solid-phase peptide synthesis that use the 9-fluorenylmethyloxycarbonyl (Fmoc) group for Nα-amino protection has created a need for compatible anchoring linkages and handles. In an effort to develop mild new methods for use in solid-phase peptide synthesis (SPPS), a new ferrocene containing linker or “handle”, the 1’1-ferrocenyl carboxaldehyde handle was designed, synthesized, characterized and tested. This linker is analogous to those commercially available and developed by Barany. The ferrocenyl amine linker(FAL) releases C-terminal peptide amides upon acidolysis. Since the FAL handle is acid labile it is compatible with Fmoc and Nα-dithiasuccinoyl …

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Characterization Of Native And Bypass Human Coronary Artery Plaque Deposits From The Same Heart: Investigation Of The Chemical Form Of Calcium In Human Coronary Artery Plaque Deposits, Serigne Thiam Jan 2003

Characterization Of Native And Bypass Human Coronary Artery Plaque Deposits From The Same Heart: Investigation Of The Chemical Form Of Calcium In Human Coronary Artery Plaque Deposits, Serigne Thiam

LSU Doctoral Dissertations

Gradual deposits of lipids, proteins, and calcium on the coronary arterial walls cause atherosclerosis, leading to blockage of the blood flow and possible heart attack. Despite many studies, the mechanism underlying these processes remains unclear. In this research, differences between native and bypass plaque deposits from the same heart were examined. In addition, the crystalline and the amorphous plaques within these native and bypass vessels were characterized. The techniques used to characterize the deposits included inductively coupled plasma mass spectrometry (ICPMS), solid-state nuclear magnetic resonance (NMR), high performance liquid chromatography (HPLC), etc. The results from the ICPMS technique showed that …

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Synchrotron Radiation As A Probe Of Chemical Information Using Novel Experimental Configurations, George Farquar Jan 2003

Synchrotron Radiation As A Probe Of Chemical Information Using Novel Experimental Configurations, George Farquar

LSU Doctoral Dissertations

Determination of chemical information with synchrotron radiation is an area of great scientific interest, and expanding the range of available techniques is the topic of this dissertation. The experimental methods described herein allows for a significant advancement of the availability of subtle chemical information. This dissertation uses ionizing radiation to study three chemical systems. First, the l=3 shape resonance in CO is investigated using a cryogenically cooled gas jet. Shape resonant effects have been studied for many years. Previously, this was accomplished on the vibrational structure of molecules with a limited ability to determine the rotational substructure effects. A dramatic …

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Atomic And Electronic Structure Of Bulk Intermetallic And Heteroepitaxially Grown Surface Alloys, Orhan Kizilkaya Jan 2003

Atomic And Electronic Structure Of Bulk Intermetallic And Heteroepitaxially Grown Surface Alloys, Orhan Kizilkaya

LSU Doctoral Dissertations

It has been well documented that the surfaces of solids may differ from their bulk counterpart. The symmetry that a bulk possesses is broken at the surface. Due to this broken symmetry in the reduced dimension of the surface, the energetic of the surface also differs from the bulk counterpart. Reconstruction, charge redistribution, and surface alloying are phenomena that minimize the surface free energy. Surface properties of scientifically and technologically important bimetallic systems are the main focus of this dissertation. Specifically, surfaces of bulk alloy or heteroepitaxially grown metal-on-metal systems have been investigated primarily with two indispensable surface techniques, scanning …

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Diffusion Of A Rodlike Virus In Complex Solutions, Randall Charles Cush Jan 2003

Diffusion Of A Rodlike Virus In Complex Solutions, Randall Charles Cush

LSU Doctoral Dissertations

Entanglement phenomena in concentrated polymer solutions remain an interesting and challenging problem. It is still unclear how entanglement onset affects polymer chain motion at small distance scales. One way to study such motion is to follow the diffusion of a probe particle while increasing the concentration of the polymer. Many such studies have been done using probes ranging from linear and star polymers to various colloidal particles; however, relatively few studies have used rodlike probes. Rodlike probes are potentially more interesting due to the added information that may be gained by following rotational as well as translational diffusion. The anisotropic …

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