Physical Sciences and Mathematics Commons^™

Studies On The Anti-Corrosion Behavior Of Corrosion Inhibitor To The Ship Building Steel In Moist Air, Yong-Tao Zhao, Jian-Hua Wu, Jia Wang

Journal of Electrochemistry

The anti corrosion behavior of 907A steel, which were covered with thin inibitor layers in moist air, were simulated, The electrochemical measurements, including EIS method and the coulostatic method, were used to atmospheric corrosion monitor (ACM) under thin inhibitor layers to study the mechanism of rust preventiion. the results shown that the mechanism of inhibiting corrosion was different from the steel immersed in inhibitor solutin, the anodic reaction process under thin inhibitor layers had the advantage over that of cathodic for blocking the speed of corrosion. At the later stage of soaking, the blend feature due to the electrochemical process …

The Investigation Of Prepare Condition For Micropores Membranes From Poly(Vinylidene Fluoride), Xu-Mei Ren, Feng Wu, Ying Bai, Hang-Jun Li, Xue-Jie Huang

Journal of Electrochemistry

The micropores membranes from Poly (vinylidene fluoride) were prepared by the phase inversion process. The effects of the casting solution composition, exposure time prior to coagulation and temperature of the coagulation bath on properties of prepared membranes were investigated. For all prepared membranes an asymmetric structure, sometimes without a dense skin layer, was observed.

An Investigation Of Structural Properties Of Li-Al-Mixed Doped Spinels Materials Li 1+XAlYMn Z-YO4, Zi-Shan Zheng, Zi-Long Tang, Zhong-Tai Zhang, Wan-Ci Sheng

Journal of Electrochemistry

Al and Li elements were co-doped into host spinel lithium manganese oxide by a simple and economical preparation technology. There was an investigation of the influence of doped Al contents on the initial capacity and cycling performance of the materials. The investigation of the XRD patterns, the analysis of the SEM micrographs and the determination of IR spectroscopy showed that the particles of dopant materials are fine, narrowly distributed and well crystallized, and the bonds Mn-O are stronger than these of undoped materials. The resulted materials have a high initial capacity of 119 mAh/g and good cycling characterization. The capacity …

Studies On The Properties Of The Anodic Films Formed On Lead- Lanthanum And Lead-Samarium Alloys In Sulfuric Acid Solution, Hou-Tian Liu, Chun-Xuao Yang, Hai-Heng Liang, Jiong Yang, Wei-Fang Zhou

Journal of Electrochemistry

AC voltammetry, linear sweep voltammetry, and cyclic voltammetry were applied to study the anodic corrosion of Pb, Pb-1.0 at% La and Pb-1.0 at% Sm electrodes in 4.5 mol·dm^-3 H₂SO₄ solution (25 ℃). The experiment results show that samarium can inhibit the anodic corrosion of lead and decrease the impedance of anodic Pb(Ⅱ) film. Lanthanum can also decrease the impedance of the anodic Pb(Ⅱ)film, but the effect is smaller.

Analyses On Spm Images And Theoretical Investigations On Oxygen Vacancy Concentration Of Light-Induced Nanostructured Titania Super Hydrophilic Films, Ren-Jie Zeng, Zhong-Hua Lin, Zhi-Min Fang

Journal of Electrochemistry

A typical nanostructured titania super hydrophilic film was chosen for general char2 acterization employing a Scanning Probe Microscope (SPM) and an electrochemical measurement system. Following from the principles of the solid state chemistry and nanomechanics, intensive theoretical. analyses on the SPM images, the oxygen vacancy concentration sand the mechanism of the super hydrophilicity were made; further illuminationsona reactionequation of titania defect formation, a tentative universal surface physical mode for the wet-ability, a concept, amphiphobic-ity, and surface design were carried out after the author’ sprevious introduction and proposal in the end of 1999.

The Research Of Organic Electrolyte Solutions For Li-Ion Batteries, Quang-Chao Zhuang, Shan Wu, Wen-Yuan Liu, Zhao-Da Lu

Journal of Electrochemistry

The characteristics of organic electrolyte solutions and its influences on the ion conductivity are summarized. The chemistry and electrochemistry of organic electrolyte solutions and characteristics of ordinary organic solvents are introduced. Progresses in studies of organic electrolyte solutions such as electrolyte salts, organic solvents, additives in recent years are reviewed, current situation of the studies of organic electrolyte solutions were also discussed.

New Progress Of Intrinsic Conducting Polymers' Application, Wan Chen, Cheng-Hao Liang, Yang Xie

Journal of Electrochemistry

As a kind of functional polymer, the intrinsic conducting polymer has the special chemical, electrochemical and optical properties. So it has wide application such as batteries, electromagnetic wave shielding, electroluminescent etc. Recent development and the problems of the intrinsic conducting polymers' application were briefly reviewed in this paper.

Thermal Effects On The Measurement Of Photocurrent At Anodic Films On Silver Electrode, Yuan Gu, Zhi-Yu Jiang

Journal of Electrochemistry

The influence of heat on the photocurrent of Ag electrde in alkaline solution was investigated by measuring photocurrent, photothermal signal and thermal current under the irraiation of laser beams with the wavelengths of 488 nm and 532 nm. It was found the photocurrent atthe Ag₂O film was influenced by the temperature change at the electrode surface under the irradiation of light. During the electrochemical transfer between Ag, Ag₂O and AgO in the anodic filmthe surface temperature changed obviously due to the different absprptance of the surface subrstances.It was suggested by comparing the voltammograms, photocurrent curves and …

Study Of Hydrogen Diffusion Behavior In Hydrogen Storage Alloy Mlni3.75Co0.65Mn0.4Al0.2 With Potential Step Method, Xian-Xia Yuan, Nai-Xin Xu

Journal of Electrochemistry

Potential step method was employed to study the hydrogen diffusion behavior in hydrogen storage alloy MlNi_3.75 Co_0.65Mn_0.4Al_0.2 with various depth of discharge (DOD) at ambient temperature and with 50% DOD at various temperatures. It was found that hydrogen diffusion cofficient in the hydrogen storage alloy increaes with the increase in DOD at ambient temperature. and for the alloy with 50% DOD, the hydrogen diffusion coefficient increases with the increase in temperature and the activation energy for hydrogen diffusion in the alloy is 19.87 kJ/mol.

Study Of Electrochemistry Of Aloe-Emodin And Determination Of It With 1.5th Order Derivative Anodic Stripping Voltammetry, Xin-Hua Lin, Li-Ying Huang, Wei Chen, Hong-Bin Luo, Bin Qiu, Chun-Yan Li

Journal of Electrochemistry

In 0.1 mol/L, HAc solution (pH=2.89), the voltammetric behaviours of aloeemodin at a glassy carbon electode has been studied, One pair of current peak of the voltammogram maybe attributed to a quasireversible two-electron transfer of aloeemodin molecules at the glassy carbon electrode. A new method, the derivative anodic stripping voltammetry, for aloeemodin de-termination is described. The adsorptive potential of aioeemodin is -0. 80 V (vs. SCE) , while itsstripping potential is -0.38 V (vs. SCE). The peak current is propotionat to the concentration ofaloeemodin over the range of 2.0 x10⁷~8.0 x10⁶ mol/L. The method is simple, rapid …

On Some Optimal Tests In Finite Mixtures: Constructions And Applications., Chandranath Pal Dr.

Doctoral Theses

Mixtures of distributions are now-a-days playing very important roles in both theoretical and applied statistics. There is an abundance of real-life situations where mixture distributions are being extensively used for modelling data and drawing inference. Several books and monographs on mixtures have so far been published, e.g., Everitt and Hand (1981), Titterington et al. (1985), McLachlan and Basford (1988), McLachlan (1997) etc., which cover a wide area on different aspects of mixture distributions and their applications. The book by Titterington et al. (1985, pp. 16-21), in particular, contains a comprehensive list of references on direct applications of finite mixtures in …

Research Progress On Proton Exchange Membranes Of Fuel Cells, Jing-Rong Yu, Dan-Min Xing, Fu-Qiang Liu, Jian-Guo Liu, Bao-Lian Yi

Journal of Electrochemistry

The proton exchange membrane fuel cells (PEMFC) use proton exchange membranes(PEM) as their electrolytes. The performance of the PEMFC is strongly dependent on the characteristics of the PEM. In this paper, the requirements of the PEM utilized in the PEMFC were analyzed. The per-fluorinated, partially fluorinated and non-fluorinated PEM were introduced respectively. The structures, preparation, properties of the various types of PEM and their applications in the PEMFC were also discussed in detail.

The Influence Of Synthesis Conditions On The Electrochemical Properties Of Spinel Limn2O4, Jun-Feng Xu, Zhi-Yu Jiang

Journal of Electrochemistry

The electrochemical properties of spine LiMn₂O₄ synthesized via a solid state reaction were investigated. Electrolysis MnO₂(EMD), Li₂CO₃ ,LiOH and LiNO₃ were used as the initial materials. It was found that the electrochemical properties of LiMn₂O₄ were strongly influenced by the synthesis conditions. The LiMn₂O₄ sample sprepared via the reactionof EMD and LiNO₃ showed the best properties for a lithiumion intercalation reaction. The procedure includes two steps:pretreatment at 280 ℃ for 6 hours to initiate the permeation of melting LiNO₃ into the microporesof EMD …

Adsorption And Oxidation Of Methanol On Pt And Sb, S Modified Pt Electrodes Using Cyclic Voltammetry And Eqcm, Guo-Liang Chen, Sheng-Pei Chen, Heng Lin, Xing-Hong Zheng, Shi-Gang Sun

Journal of Electrochemistry

The processes of adsorption and oxidation of methanol on Pt, Pt/Sb ad and Pt/S ad electrodes were studied by using cyclic voltammetry and electrochemical quartz crystal microbalance (EQCM). The results demonstrated that the oxidation of methanol depends strongly on oxidation states of electrode surface. Sb adatoms on Pt surface can adsorb oxygen at relatively low potentials, and exhibit catalytic effects for methanol oxidation. In contrast to Pt electrodes, the oxidation peak potential of methanol in this case negatively shifted to about 130 mV. In a contrary, the oxidation of S_ad atoms consumes oxygen species of Pt electrode surface. As …

Study On Electrochemical Behavior Of Copper In Nh3 ·H2O Solution Medium Including K3[Fe(Cn)6] During Cmp, Yue-Hua Hu, Han-Wei He, Ke-Long Huang

Journal of Electrochemistry

Influence of medium pH value and passivator concentrations on the copper passivation and CMP process were studied by electrochemical measurement technologies, relations of the film thickness and tightness with polishing process and polishing rates were investigated. Electrochemical variables influencing polishing process and rates were found out. Electochemical mechanism of polishing processes were explained by corrosion potential and corrosion current density. A recipe of K₃[Fe(CN)₆] as passivator and nano sized γ-Al₂O₃ as abrasives in medium of NH₃·H₂O solution was confirmed reasonable. It is shown that the conditions of polishing process …

Study On The Anticorrosion Of Ld-2 Compound Inhibitor On Reinforcing Steel In Seawater, Rong-Gui Du, Zhou-Cheng Wang, Ruo-Shuang Huang, Rong-Gang Hu, Bing Zhao, Jian-Guang Tan, Chang-Jian Lin

Journal of Electrochemistry

The effect of LD-2 compound inhibitor developed in our laboratory on its anticorrosion action on the reinforcing steel in concrete immersed in seawater was shown in this paper. The corrosion behavior of the reinforcing steel in seawater was studied using electrochemical techniquesand immersion tests. The polarization curve of the reinforcing steel immersed in seawater showedthe free corrosion potential of the steel increased by 0. 220 V (vs. SCE), and the corrosion current decreased by two orders of magnitude by adding 25 g⋅L^-1 compound inhibitor to the seawater. The potentiodynamic anodic polarization curve of reinforcing steel in the seawater with …

Reflection Of A Long-Period Gravity Wave Observed In The Nightglow Over Arecibo On May 8–9, 1989?, Michael P. Hickey Ph.D.

Publications

During the Arecibo Initiative for Dynamics of the Atmosphere (AIDA) campaign in 1989 a characteristic of gravity wave perturbations observed in mesopause region airglow emissions was that airglow brightness fluctuations and airglow-derived temperature fluctuations often occurred either in phase or in antiphase. This stimulated the development of a theory suggesting that such in-phase fluctuations were most probably the result of strong reflections occurring in the mesosphere and lower thermosphere region. Recent examination of a particular wave event and application of simple WKB-type theory has appeared to support this hypothesis. Here we use a full-wave model and a WKB-type model, each …

Tachyonic Instability And Dynamics Of Spontaneous Symmetry Breaking, Gary Felder, Lev Kofman, Andrei Linde

Physics: Faculty Publications

Spontaneous symmetry breaking usually occurs due to the tachyonic (spinodal) instability of a scalar field near the top of its effective potential at φ=0. Naively, one might expect the field φ to fall from the top of the effective potential and then experience a long stage of oscillations with amplitude O(v) near the minimum of the effective potential at φ=v until it gives its energy to particles produced during these oscillations. However, it was recently found that the tachyonic instability rapidly converts most of the potential energy V(0) into the energy of colliding classical waves of the scalar field. This …

Regional Variations Of Kachina Iconography In Eastern Pueblo Rock Art, Dara Leigh Saville

Geography ETDs

This research addresses the problem of identifying patterns of regional variation in the kachina iconography of the Eastern Pueblo Province. Data produced in this study is also used to reevaluate the Rio Grande Hypothesis, which proposes a Jornada Mogollon origin for Pueblo kachinas. The author examines a sample of kachina images that are present in the rock art of the Rio Grande Valley and Eastern Mountain region of central New Mexico. The sample includes kachinas from the Lyden site on Black Mesa, Frijoles Canyon of Bandelier National Monument, Piedras Marcadas Canyon of Petroglyph National Monument, Cerro Indio at San Acacia, …

Terahertz Gain In A Sige/Si Quantum Staircase Utilizing The Heavy-Hole Inverted Effective Mass, Richard A. Soref, Greg Sun

Physics Faculty Publications

Modeling and design studies show that a strain-balanced Si_1−xGe_x/Si superlattice onSi_1−yGe_y-buffered Si can be engineered to give an inverted effective mass HH2 subband adjacent to HH1, thereby enabling a 77 K edge-emitting electrically pumped p–i–pquantum staircase laser for THz emission at energies below the 37 meV Ge–Ge optical phonon energy. Analysis of hole-phonon scattering, lifetimes, matrix elements, and hole populations indicates that a gain of 450 cm⁻¹ will be feasible at f = 7.3 THz during 1.7 kA/cm² current injection.

Environment-Induced Degradation And Crack-Growth Studies Of Candidate Target Materials: Aaa Task-4 Quarterly (September 1 – November 30, 2001) Report, Ajit K. Roy, Brendan O'Toole

Transmutation Sciences Materials (TRP)

The primary objective of this task is to evaluate the effect of hydrogen on environment-assisted cracking of candidate materials for applications in spallation-neutron-target (SNT) systems such as accelerator production of tritium (APT) and accelerator transmutation of waste (ATW). The materials selected for evaluation and characterization are martensitic stainless steels including HT- 9, EP 823 and 422. The susceptibility to stress corrosion cracking (SCC) and hydrogen embrittlement (HE) of these alloys will be evaluated in environments of interest using tensile specimens under constant load and slow-strain-rate (SSR) conditions. The extent and morphology of cracking of these alloys will further be evaluated …

Development Of A Mechanistic Understanding Of High-Temperature Deformation Of Alloy Ep-823: Task 10, First Quarter Report, Ajit K. Roy, Brendan O'Toole

Transmutation Sciences Materials (TRP)

The objective of this task is to evaluate the elevated temperature tensile properties of Alloy EP-823, a leading target material for accelerator-driven waste transmutation applications. The test material will be thermally treated prior to evaluation of its tensile properties at temperatures relevant to the transmutation applications. The deformation characteristics of tensile specimens, upon completion of testing, will be evaluated by surface analytical techniques including scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The overall results are expected to provide a mechanistic understanding of high-temperature deformation behavior of Alloy EP-823 as a function of heat treatment.

Highlights of Accomplishment

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Fine-Tuning Solution For Hybrid Inflation In Dissipative Chaotic Dynamics, Rudnei O. Ramos

Dartmouth Scholarship

We study the presence of chaotic behavior in phase space in the preinflationary stage of hybrid inflation models. This is closely related to the problem of initial conditions associated with these inflationary types of model. We then show how an expected dissipative dynamics of fields just before the onset of inflation can solve or ease considerably the problem of initial conditions, driving the system naturally toward inflation. The chaotic behavior of the corresponding dynamical system is studied by computation of the fractal dimension of the boundary in phase space separating inflationary from noninflationary trajectories. The fractal dimension for this boundary …

Interactions Of Ultrashort, Ultrahigh Intensity Laser Pulses With Underdense Plasmas, Xiaofang Wang, Wei Yu, Sterling Backus, Margaret Murnane, Henry Kapteyn, Donald P. Umstadter

Donald Umstadter Publications

The interactions of ultraintense laser pulses with underdense plasmas are studied in a new regime in which the longitudinal spatial extent of the pulse duration is close to both the laser focal spot size and the plasma wavelength.

Laser Acceleration Of Protons From Thin Film Targets, K. Flippo, Sudeep Banerjee, V. Yu. Bychenkov, S. Gu, Anatoly Maksimchuk, G. Mourou, K. Nemoto, Donald P. Umstadter

Donald Umstadter Publications

A collimated beam of fast protons, with energies as high as 10 MeV and total number of 10⁹, confined in a cone angle of 40°±10° has been observed when a 10 TW laser with frequencies either ω₀ (corresponding to 1 μm) or 2ω₀ was focused to an intensity of a few times 10¹⁸ W/cm² on the surface of a thin film target. The protons, which originate from impurities on the front side of the target, are accelerated over a region extending into the target and exit out the backside in a direction normal to …

Status Of The Lilac Experiment, N. Saleh, P. Han, C. Keppel, P. Gueye, V Yanovsky, Donald P. Umstadter

Donald Umstadter Publications

We present the status of the LILAC experiment [1], including results on the propagation of 30-fs duration laser pulses in plasmas of the requisite density, and measurements of the dark current [2]. We also discuss the status of a laser upgrade, an electron beam line and plans for the future.

Three-Dimensional Spectral Classification Of Low-Metallicity Stars Using Artificial Neural Networks, Shawn Snider, Ted Von Hippel, Et Al.

Publications

We explore the application of artificial neural networks (ANNs) for the estimation of atmospheric parameters (T_eff, log g, and [Fe/H]) for Galactic F- and G-type stars. The ANNs are fed with medium-resolution (Δλ ~ 1-2 Å) non-flux-calibrated spectroscopic observations. From a sample of 279 stars with previous high-resolution determinations of metallicity and a set of (external) estimates of temperature and surface gravity, our ANNs are able to predict T_eff with an accuracy of σ(T_eff) = 135-150 K over the range 4250 ≤ T_eff ≤ 6500 K, log g with an accuracy …

Magnetite Morphology And Life On Mars, Peter R. Buseck, Rafal E. Dunin-Borkowski, Bertrand Devouard, Richard B. Frankel, Martha R. Mccartney, Paul A. Midgley, Mihály Pósfai, Mathew Weyland

Physics

Nanocrystals of magnetite (Fe₃O₄) in a meteorite from Mars provide the strongest, albeit controversial, evidence for the former presence of extraterrestrial life. The morphological and size resemblance of the crystals from meteorite ALH84001 to crystals formed by certain terrestrial bacteria has been used in support of the biological origin of the extraterrestrial minerals. By using tomographic and holographic methods in a transmission electron microscope, we show that the three-dimensional shapes of such nanocrystals can be defined, that the detailed morphologies of individual crystals from three bacterial strains differ, and that none uniquely match those reported from …

Charged-Particle Multiplicity Pp̅ Collisions At √S = 1.8 Tev, T. Affolder, Kenneth A. Bloom, Collider Detector At Fermilab Collaboration

Kenneth Bloom Publications

We report on a measurement of the mean charged-particle multiplicity of jets in dijet events with dijet masses in the range 80-630 GeV/c², produced at the Tevatron in pp̅ collisions with √s= 1.8 TeV and recorded by the Collider Detector at Fermilab. The data are fit to perturbative-QCD calculations carried out in the framework of the modified leading log approximation and the hypothesis of local parton-hadron duality. The fit yields values for two parameters in that framework: the ratio of parton multiplicities in gluon and quark jets, r=N^g-jet _partons/N^q-jet _partons =1.7 ± …

Novel Field Sampling Procedure For The Determination Of Methiocarb Residues In Surface Waters From Rice Fields, Thomas M. Primus, Dennis J. Kohler, Mike Avery, Pat Bolich, M.O. Way, John J. Johnston

United States Department of Agriculture Wildlife Services: Staff Publications

Methiocarb was extracted from surface water samples collected at experimental rice field sites in Louisiana and Texas. The sampling system consisted of a single-stage 90-mm Empore extraction disk unit equipped with a battery-powered vacuum pump. After extraction, the C-18 extraction disks were stored in an inert atmosphere at -10 °C and shipped overnight to the laboratory. The disks were extracted with methanol and the extracts analyzed by reversed-phase high-performance liquid chromatography with a methanol/water mobile phase. Methiocarb was detected by ultraviolet absorption at 223 nm and quantified with the use of calibration standards. Recoveries from control surface water samples fortified …