Physical Sciences and Mathematics Commons^™

Dg Algebra Techniques For Tor Algebras And Edge Ideals, Desiree Martin

Dissertations - ALL

This thesis is comprised of two projects. The first is individual work where I use semifree Gamma-extensions to show, for an ideal I with infinite projective dimension over a Noetherian local ring R, there exists a splitting morphism from a Tor algebra Tor(R/I,R/I) to the exterior algebra of the R/I-free summands of the conormal module. In particular, when the conormal module is free over R/I, we see that the exterior algebra of the conormal module splits completely from Tor(R/I,R/I) as algebras. For the second project my collaborators, Hugh Geller and Henry Potts-Rubin, and I completely classify all trees and cycle …

On Compact Quasi-Einstein Metrics Of Constant Scalar Curvature, Eric Morgan Cochran

Dissertations - ALL

This thesis concerns a generalization of Einstein manifolds called quasi-Einstein manifolds. These manifolds are a triple $(M,g,X)$ where $(M,g)$ is a Riemannian manifold, and $X$ is a smooth vector field on $M$. Quasi-Einstein manifolds are of interest in general relativity, where a special class of quasi-Einstein manifolds are known as near horizon geometries. They are also related to Ricci solitons, which are self-similar solutions of the Ricci flow. In the first set of results in this thesis, we study the existence of Killing fields on compact quasi-Einstein manifolds. In particular, we prove an equivalence between compact quasi-Einstein manifolds of constant …

A Study Of The Links Between Denudation, Lithology, And Tectonics In The Tropical Andes, Helbert Garcia-Delgado

Dissertations - ALL

Landscape evolution in the tropical Northern Andes is governed by complex interactions between tectonic deformation, climatic shifts, and bedrock lithology. Standard geomorphic models often struggle to capture the full spectrum of these processes, particularly in active orogens where topographic steady state is frequently challenged by variable sediment dynamics and deep weathering. Understanding how these factors dictate landscape responses over different timescales is critical for interpreting the relationship between landscape evolution and surface processes of tropical mountain belts. This dissertation utilizes a combination of cosmogenic nuclide dating, numerical modeling, and subsurface borehole analysis to examine the structural, climatic, and lithological controls …

Development Of Dual-Stimuli Responsive Polymer-Coated Gold Nanoparticles And Their Surface Engineering Via Polyelectrolyte Layer-By-Layer Assembly, Buddhini Chathurangi Nugaduwa Vithanage

Dissertations - ALL

The modification of nanoparticles with combinations of low critical solution temperature (LCST) polymers and polyelectrolyte (PE) layers is studied. Three n-isopropylacrylamide-co-acrylamide polymers were synthesized in which charges could be varied from neutral, to negative or positive by way of incorporating poly acrylic acid (pAAc) or poly 4-vinylpyridene (p4VP) units. Polymerization centered around a disulfide initiator, which when reduced produced two polymer chains and a convenient linkage to gold NPs (NPs). The resulting LCST-NPs conjugates possessed sharp phase changes at critical temperatures (TC), while the incorporation of pAAc or p4VP allowed for tuneable charges and pH sensitivity. Studies with 1H-NMR and …

Quasiparticle Poisoning Of Superconducting Fluxonium Qubits, Kesavan Manivannan

Dissertations - ALL

Superconducting qubits based on Josephson junctions have emerged as a leading hardware platform in the quest to realize large-scale quantum computers. However, qubit decoherence remains a major hurdle on the path toward fault-tolerant quantum computing. In particular, excess quasiparticle (QP) excitations constitute a significant source of dissipation in superconducting quantum devices. The empirically observed QP density in these systems is orders of magnitude larger than that predicted by Bardeen-Cooper-Schrieffer (BCS) theory. Moreover, QP poisoning due to high-energy particle impacts can cause correlated errors that simultaneously affect multiple qubits, thereby impeding quantum error correction. Although QP-induced decoherence has been extensively studied …

Mapping The Rigid Landscapes Of Disordered Networks And Active Solids, Tyler Hain

Dissertations - ALL

Biological systems are able to exhibit remarkable and exotic mechanical properties by tuning their microscopic internal degrees of freedom in order to accomplish global functions. One of the most interesting mechanical behaviors of some such materials is the ability to transition between stiff solid-like states and soft fluid-like states in order to initiate specific flow patterns or tune their mechanical response. Not only this, but they are able to selectively cross this transition while also being optimized for other functions. In this dissertation I explore numerical and analytical methods for mapping the landscapes of states on the edge of rigidity …

Characterizing Capacitance Of Josephson Junctions For Quantum Devices, Bradley Gordon Cole

Dissertations - ALL

The field of quantum computing is growing at a rapid rate with the promise of dramatic improvements in the ability to solve critical computational problems. A leading approach for implementing fault-tolerant quantum computers is based on superconducting circuits containing Josephson junctions to form qubits. These qubits have many attractive qualities, but predicting the device performance requires detailed knowledge of the junction properties. Thus, precise characterization is crucial for realizing different qubit designs. The coherence of superconducting qubits is limited by several sources in the circuit en- vironment. Building a quantum computer requires effort to reduce gate errors caused by decoherence. …

Quasi-Einstein Metrics And Homogeneous Conformally Einstein Manifolds, Nazia Valiyakath

Dissertations - ALL

This thesis investigates a classic question in Riemannian geometry: What is the best metric to put on a Riemannian manifold? It combines two projects that explore different aspects of this question. The first project studies nilpotent and unimodular solvable Lie groups that admit m-quasi-Einstein metrics (M,g,X) with X a left-invariant vector field, which we call totally left-invariant quasi-Einstein metrics. We give a complete classification of nilpotent Lie groups admitting such metrics, showing that this occurs if and only if the group is isomorphic to Heisenberg Lie group. For unimodular solvable Lie groups S, we prove that the existence of a …

The Role Of Gender And Salient Social Identities In Producing Vulnerability And Maladptation To Flooding In Koraso, Berekum, Ghana, Kingsley Damoah Oppong

Geography ETDs

This paper highlights how social identities like polygamy, illiteracy, and ethnicity hinder rural women farmers in Ghana from adapting to climate change. It advocates for an intersectional approach to address these challenges, moving beyond simplistic gender binaries. Using qualitative interviews (n=49) in a flood-prone village in Berekum, Ghana, the study reveals how these identities intersect with gender roles and colonial legacies, exacerbating vulnerability. It bridges Black feminist thought with climate change, an underexplored area, offering insights into climate change and environmental studies, as well as Black feminist scholarship. This research urges a reevaluation of how we understand climate change in …

Incorporating Sustainable Strategies And Practices Into The City Improvements Plan Of Madisonville, Kentucky To Better Suit It For The Changing World, Cade R. Howell

Honors College Theses

This project aims to make the case for city improvements in Madisonville, Kentucky by using successful strategies implemented by other cities across the region. These strategies include sidewalk improvements, the installation of roundabouts and parking garages, increased walkability and beautification, and a restructuring of the types of cars predominantly used in the area. The strategies would be implemented from least expensive to most expensive, and in a way that gets the communities involved as much as possible. By using these strategies, Madisonville can better prepare itself for a more sustainable future.

Increasing Photocatalytic Activity Of Tio₂ Nanocrystals With Cobalt Dopants And Nio Heterojunctions, Lara A. Haack

Honors Thesis

Carbon emissions and fossil fuel usage has increased dramatically in recent decades, and the need for renewable energy has grown with it. Photocatalytic processes on titanium dioxide (TiO₂) nanocrystals may be used for solar energy driven production of fuel/oxidizer pairs. Many different methods have been developed to increase the effectiveness of TiO₂ in photocatalysis, including dye sensitization, quantum dot sensitization, doping with metals and non-metals, and the surface attachment of cocatalyst materials. Impurity dopants are not susceptible to photo-bleaching or degradation and judicious selection of cocatalyst materials can lead to robust all-inorganic heteronanocrystal photocatalysts: whereas, the use of molecular dye …

Determining Cave Presence And Diet Variation Of The Ozark Big-Eared Bat (Corynorhinus Townsendii Ingens) From Guano Dna, Lark E. Sybrant

ATU Theses and Dissertations 2021 - Present

The Ozark big-eared bat (Corynorhinus townsendii ingens; OBEB) is federally endangered in Arkansas, where it persists in a few small, geographically restricted populations within the Ozark National Forest. Although the region contains many caves that appear suitable for OBEB, expanded survey efforts are needed to locate additional roost sites for monitoring and protection. Effective conservation also requires a clear understanding of their distribution and diet. Traditional cave surveys can be disruptive and often miss cryptic species, and earlier diet studies based on manually sorting prey remains provided only coarse taxonomic resolution and overlooked soft‑bodied insects. To address these …

Distribution, Habitat, And Fish Assemblages Associated With The Rocky Shiner In Arkansas, Savannah L. Wise

ATU Theses and Dissertations 2021 - Present

The Rocky Shiner (Notropis suttkusi) is a minnow species endemic to the Red River and its tributaries in southern Arkansas and Oklahoma. This species is petitioned for listing under the Endangered Species Act and is a species of greatest conservation need (SGCN) in Arkansas. However, there is little information for the species’ distribution, habitat use, and ecological niche, especially within the Arkansas portion of its range. Because of this data gap, my study provides an updated description of its distribution and habitat associations using conditional occupancy modeling and explores patterns of species co-occurrence within the community. I sampled …

Development Of Water-Soluble Nanofibrous Poly(Vinyl Alcohol) Collectors For Bioaerosol Sampling And Environmental Surface Microbial Detection, Kevin Crown

Theses & Dissertations

Environmental surveillance for pathogenic microorganisms requires sampling technologies capable of efficiently collecting biological particles from air and surfaces for downstream detection.  Current environmental sampling materials, such as fibrous aerosol filters and surface sampling swabs, are designed to capture particles effectively but often retain a portion of the collected material during extraction.  Incomplete recovery reduces the sensitivity of microbiological and molecular detection, particularly in situations where microbiological concentrations are low, such as in environmental monitoring and clearance sampling following biological contamination events.  This dissertation describes the development and evaluation of water-soluble nanofibrous sampling materials designed to improve microbial recovery while maintaining …

Replication And Extension Of Kras-Associated Gene Expression Signatures In Lung Adenocarcinoma: A Cox Proportional Hazards Analysis Of Mutation Status, Gene Expression, Multi-Gene Mutation Count, And Ras De Novo Signature, Camryn Berry

Theses & Dissertations

This study evaluates the robustness and reproducibility of a previously published analysis of lung adenocarcinoma gene expression data (Schabath et al.), which examined KRAS-associated biology in relation to co-occurring STK11 and TP53 mutations. The original study used Kaplan-Meier (KM) survival analysis and gene expression signatures to assess associations between driver mutations, tumor suppressor mutations, and patient outcomes. The aim of this work is to replicate these analyses and evaluate consistency across independent datasets (Wilkerson and Selamat), with extension using Cox proportional hazards (PH) models. Two hypotheses are evaluated: (1) that the number of mutated genes increases the hazard of death, …

The Influence Of Fermentation Duration And Secondary Fermentation Conditions On The Bioactive Compound Profile Of Kombucha, Jordan Vereen

Honors Theses

Kombucha is a fermented sweet tea produced using a symbiotic culture of bacteria and yeast (SCOBY) and has gained widespread popularity due to its proposed health benefits. Kombucha has been studied to understand these advantages in cardiovascular support, improved metabolism, increased antioxidant effects, enhanced antimicrobial properties, and even potentially slowing the progression of certain diseases. Despite its increasing popularity, the way in which the specific bioactive compounds responsible for these effects and the fermentation conditions that influence their production remain unclear. The present study, conducted in collaboration with Dr. Budner, focuses on quantifying bioactive compounds in kombucha to better understand …

The Legacy Of Lead: Lead Exposure's Harmful Effects And Its Concentration In Poc Communities, Layla Sophronia Barber

Student Theses 2015-Present

This thesis examines the disproportionate burden of lead exposure carried by low income, POC communities. The systemic nature of this problem is a symptom of a longstanding legacy of environmental injustice in the United States. Decades of federal neglect are reflected in the higher statistics of lead exposure and poisoning in predominantly black communities. While it is understood that lead exposure poses a serious threat to physical health and early cognitive development, there is a discouraging lack of urgency to remove the toxin from non-wealthy communities. The material covered by this thesis aims to identify and correct the discriminatory social …

The Prospect Of F.E.W. Resources: How Food, Energy, And Waste Management Workforce Programs Address Global Equity And Sustainability, Quincy P. Biddle

Student Theses 2015-Present

As a global society, the issues affecting a specific city or country are no longer isolated; instead, they impact other places in myriad ways. Over the past few decades, environmental degradation and economic inequality, both within and between countries, have caused shortages of necessities like food and water, inadequate access to safe energy sources, and increased pollution, impacting people’s prosperity and the well-being of the planet. It is of global interest to remediate these issues for the betterment and progress of society, and thus, an approach to addressing these complications collectively and comprehensively is of utmost importance. This paper investigates …

Secondhand Or Second-Class? Environmental Injustice In Global Textile Waste Trade, Wendy S. Escalante

Student Theses 2015-Present

This paper addresses the issue of textile waste dumping, specifically how secondhand clothing exports from the Global North create environmental, social, and public health burdens in the Global South. The study focuses on case studies in Chile’s Atacama Desert, where shipments of used clothing overwhelm local waste infrastructures and worsen patterns of environmental injustice. Chapter 1 describes the global flows of textile waste, including trade volumes, landfill accumulation, and the impacts of discarded clothing on ecosystem services such as clean water, fertile soils, and breathable air, alongside health risks from microplastic pollution, toxic runoff, and respiratory hazards from textile fires. …

Solid Waste Management In Greater Khartoum City, Sudan, Roba Mahmoud

Student Theses 2015-Present

This study investigates the rising solid waste management (SWM) dilemma in Greater Khartoum City (GKC), a critical environmental and public health issue caused by fast urbanization and inadequate infrastructure, with historical linkages to Sudan's colonial and postcolonial growth. Chapter 1 describes the current problem using quantitative and qualitative data, demonstrating that GKC produces approximately 3,340 tons of waste each day, with 56% organic matter, 8% plastics, and 16% paper. Collection efficiency remains severely poor, at 31.5%. Informal recyclers known as Nakasha or Barkata collect approximately 7% of total waste, supporting roughly 3,900 people, whereas filthy open dumps and unsorted medical …

Stridevision: Automated Detection Of Running Form Deviations From 2d Pose Estimation And Machine Learning, Paulina Eguibar Ortega

Honors Theses

Running gait analysis plays a critical role in injury prevention and performance optimization, however, existing approaches often rely on specialized laboratory equipment or wearable sensors with limited interpretability. Recent advances in computer vision, particularly 2D human pose estimation, enable markerless motion analysis from standard video. However, progress remains constrained by the lack of publicly available datasets designed for running form analysis.

In this work, we introduce a preliminary dataset and benchmark for stride-level running gait analysis. The dataset consists of 73 treadmill running videos from 15 participants with varying experience levels, annotated with over 4,600 stride-level labels across multiple biomechanical …

Identifying The Cultural Significance Behind Local Study Sites Used By Marine Scientists, Mackenzie Anonick

Honors Theses

This project brings awareness to the cultural significance of places that scientists (specifically marine scientists associated with CCU) study and do field work at. It is important to be respectful of places you work in and understand what environment and land you are working with. It is also important to know your privilege when working in areas of less privilege. For example, CCU students travel to Bucksport on field trips, and the majority of them are not aware of the fact that Bucksport is a largely Black and lower income town that has extreme flooding issues that impact the residents …

Teacher Shortages In Arkansas Rural School Districts: Employed Teacher’S Perceptions Of The Impact On Their Effectiveness, Carloss Guess

ATU Theses and Dissertations 2021 - Present

ABSTRACT

TEACHER SHORTAGES IN ARKANSAS RURAL SCHOOL DISTRICTS: EMPLOYED TEACHERS’ PERCEPTIONS OF THE IMPACT

ON THEIR EFFECTIVENESS

Carloss Guess

Teacher shortages in rural school districts remain a persistent challenge that affects instructional quality, teacher workload, and professional sustainability. The purpose of this qualitative phenomenological study was to explore how teachers in rural Arkansas perceive the impact of staffing shortages on their instructional roles, workload, and professional well-being. Data were collected through semi-structured interviews with 10 K–12 teachers representing elementary, middle, and high schools and across varying career stages. Interview transcripts were analyzed using an inductive qualitative approach and the constant …

Debriefing In Emergency Departments And Intensive Care Units To Combat Compassion Fatigue, Madison N. Chiolino

ATU Theses and Dissertations 2021 - Present

Compassion fatigue can be associated with nurses working in increased stressful environments such as the Intensive Care Unit (ICU) and Emergency Room (ER).  There is a gap in healthcare facilities, where structured interventions like debriefing tools are not implemented to address compassion fatigue. The purpose of this study was to determine if implementing a debriefing tool in areas where nurses are placed in high stress scenarios such as the intensive care unit and emergency department can aid in combating compassion fatigue. A piloted quantitative pre-and post-survey intervention design was used. Data was collected using the ProQOL 5 and PEARLS debriefing …

Impacts Of Organic Matter On Laser Particle-Size Analysis Of Marsh Sediments, Alexander Powell

Honors Theses

Grain size analysis (GSA) is widely used in sedimentology and paleoenvironmental reconstruction; however, its utility can be constrained by the presence of organic matter. This study assesses the impact of organic matter through the analysis and comparison of untreated and hydrogen peroxide-treated samples. Organic-rich samples from the Thousand Acre marsh in Georgetown, SC, were subjected to three treatments: untreated, standard, and enhanced. Grain size distribution was measured for each of these treatments using a CILAS 1190 laser diffraction particle analyzer, and organic matter was quantified by loss-on-ignition (LOI). Results show that untreated samples are significantly coarser than treated samples, demonstrating …

Nutrilog: Design And Development Of A Full-Stack Web Application For Holistic Health Tracking, Jaromir J. Saloni

Honors Theses

NutriLog is a web-based fitness and nutrition tracking application designed to help users record, organize, and interpret personal health data in one centralized platform. Many existing applications focus primarily on either nutrition tracking or exercise performance, which can make it difficult for users to understand how food intake and physical activity interact. NutriLog addresses this gap by combining food logging, exercise logging, calorie adjustment, nutrition summaries, and historical tracking into a single dashboard-based interface.

The application was developed using React and TypeScript for the frontend and Supabase for authentication, database storage, and user-specific data management. Nutrition data is supported through …

The One-Shot Ceiling: Comparing Rag And Fine-Tuning Architectures For Ai-Assisted Math Mentoring, Michael J. Cummins

Computer Science Honors Papers

Providing individualized feedback to math students is a resource-intensive bottleneck in STEM education. We present Mentir-AI, a tool designed to elevate teacher capacity by generating high-quality mathematical feedback using the Mathforum's "Problem of the Week" archive. By analyzing a corpus of nearly one million interactions, we compare the efficacy of Retrieval-Augmented Generation (RAG) and Fine-Tuning (FT) architectures. This study details the development of an automated grading pipeline, the evolution of a multi-component system prompt, and the implementation of an automated mentor grading system in AI-led evaluation. While Fine-Tuning demonstrates superior instructional judgement, our results identify persistent failure modes in mathematical …

Synthesis Of A Halogenated Glyoxime For Cobalt Deposition Suppression, Liam S. Allen

Honors Theses

Dr. Qiang Huang at the University of Alabama is a chemical engineering professor and works on the electrodeposition of metals to create circuitry. During this process suppressive molecules may be added to control help the process. This project focuses on synthesizing an alpha-halogenated glyoxime to test whether the compound is a more effective suppressant in comparison to regular glyoximes. More specifically the target chemical is called bromo-dimethylglyoxime which is created in a two-stage reaction. The starting material, diacetyl monoxime, is brominated at the alpha carbon position. The product of this reaction, officially called bromodimethylglyoxalmonoxime, is then reacted with hydroxylammonium chloride …

How Ai Governance Differs Between Regime Type, Jackson T. Guillou

Honors Theses

This thesis will examine how artificial intelligence (AI) regulation and development differ across political regime types, arguing that governance outcomes are fundamentally shaped by institutional political structures. This thesis will draw on comparative frameworks analyzing democratic and authoritarian systems. This thesis will also include case studies of the European Union, the United States of America, China, and Russia. The study finds that democratic regimes tend to emphasize transparency, accountability, and rights-based regulation of AI. This often results in slow regulation of AI, but it is more ethically legitimate and constrained. In contrast, authoritarian regimes prioritize centralized control, strategic coordination, and …

The Role Of Peat Matrix Structure In The Accumulation, Storage, And Release Of Biogenic Gases From A Variety Of Peat Soils Across A Latitudinal Gradient, Md Rajeun Islam

Electronic Theses and Dissertations 2020 - Present

Peatlands store about a third of the global soil carbon pool and are among the most important natural sources of biogenic greenhouse gases, including methane (CH₄) and carbon dioxide (CO₂). While biogenic gas production in peatlands has been studied extensively over the last few decades, the physical controls that regulate how these gases accumulate within the soil matrix and their influence on gas dynamics as they get released to the atmosphere still remain uncertain. Most studies investigating biogenic gas dynamics in peatlands have inferred in-situ gas distribution either exclusively from measurements of gas flux releases, or …