Physical Sciences and Mathematics Commons^™

Excited State Processes In Radical Elaborated Platinum Donor-Acceptor Complexes, Sangita Paudel

Chemistry and Chemical Biology ETDs

Organo-transition metal complexes are being widely studied to understand their photophysical properties for their wide range of applications as efficient emitters in organic light emitting diodes (OLEDs), light emitting electrochemical cells (LEECs), etc. Cyclometalated organo-transition metal complexes such as cyclometalated square planar platinum(II) complexes are becoming suitable candidates for such applications because of their highly efficient luminescence. Understanding the excited properties of such complexes is useful in designing highly efficient and color tunable phosphors with desired excited state lifetimes. We aim to explore the influence of radical substituents on electronic structure, luminescence quantum efficiencies, and excited state lifetimes by synthesizing …

Volumetric Imaging Using The Pupil-Matched Remote Focusing Technique In Light-Sheet Microscopy, Sayed Hassan Dibaji Foroushani

Optical Science and Engineering ETDs

ABSTRACT

The dissertation explores innovative techniques in light sheet microscopy, a pivotal tool in biomedical imaging, to enhance its speed, resolution, and efficiency in capturing dynamic biological processes. Light sheet microscopy allows for quick 3D imaging of biological specimens ranging from cells to organs with high spatiotemporal resolution, large field-of-view, and minimal damage, making it vital for in vivo imaging.

The first project introduces a novel optical concept designed to optimize Axially Swept Light Sheet Microscopy (ASLM). This technique is crucial for imaging specimens ranging from live cells to chemically cleared organs due to its versatility across different immersion media. …

Smart Applications And Resource Management In Internet Of Things, Zeinab Akhavan

Computer Science ETDs

Internet of Things (IoT) technologies are currently the principal solutions driving smart cities. These new technologies such as Cyber Physical Systems, 5G and data analytic have emerged to address various cities' infrastructure issues ranging from transportation and energy management to healthcare systems. An IoT setting primarily consists of a wide range of users and devices as a massive network interacting with different layers of the city infrastructure resulting in generating sheer volume of data to enable smart city services. The goal of smart city services is to create value for the entire ecosystem, whether this is health, education, transportation, energy, …

Computational Study Of The Effect Of Geometry On Molecular Interactions, Sarika Kumar

Computer Science ETDs

The specificity and predictability of DNA make it an excellent programmable material and have allowed bio-programmers to build sophisticated molecular circuits. These molecular devices should be precise, correct, and function as intended. In order to implement these circuits, the challenge is to build a robust, reliable, and scalable logic circuit with ideally minimum unwanted signal release. Performing experiments are expensive and time-consuming, so modeling and analyzing these bio-molecular systems become crucial in designing molecular circuits. This dissertation aimed to develop algorithms and build computational tools for automated analysis of molecular circuits that incorporate the molecular geometry of nanostructures. Molecular circuits …

Radio Insights Into Gamma-Ray Mysteries, Seth M. Bruzewski

Physics & Astronomy ETDs

In the time since its launch, the \textit{Fermi Gamma-Ray Space Telescope} has provided new and unparalleled views of the $\gamma$-ray sky, dramatically increasing our understanding of sources of high-energy radiation. During that same time, however, its ``unassociated'' sources have provided a consistent mystery: approximately one third of the modern gamma-ray sky remains completely unaccounted for in other electromagnetic regimes. While some of the fainter sources simply pose challenges in achieving the necessary signal-to-noise ratio, others are well constrained and have resisted traditional investigations for years, and in some cases, for over a decade. Radio astronomy has traditionally been the best …

Modeling Lithographic Quantum Dots And Donors For Quantum Computation And Simulation, Mitchell Ian Brickson

Physics & Astronomy ETDs

Our first focus is on few-hole quantum dots in germanium. We use discontinous Galerkin methods to discretize and solve the equations of a highly detailed k·p model that describes these systems, enabling a better understanding of experimental magnetospectroscopy results. We confirm the expected anisotropy of single-hole g-factors and describe mechanisms by which different orbital states have different g-factors. Building on this, we show that the g-factors in Ge holes are suciently sensitive to details of the device electrostatics that magnetospectroscopy data can be used to make a prediction of the underlying confinement potential. The second focus is on designing quantum …

Roadside Lidar Data Processing For Intelligent Transportation System, Md Parvez Mollah

Computer Science ETDs

Roadside LiDAR (Light Detection and Ranging) sensors are recently being explored for Intelligent Transportation System aiming at safer and faster traffic management and vehicular operations. However, massive data volume, occlusion, and limited viewing angles are significant obstacles to the widespread use of roadside LiDARs. In this dissertation, we address three major challenges to enable applications of Intelligent Transportation System through roadside LiDAR data: (i) real-time transmission of the massive point-cloud data from the roadside LiDAR devices to the cloud using 5G network, (ii) mitigating sensor occlusion problem to increase coverage and detect events occurred in occluded regions of a sensor, …

Environmental Fate Of Sulfur In Sulphur Creek, Valles Caldera, Nm: Implications For Metal Transport And Water Quality, Daniel Lavery

Earth and Planetary Sciences ETDs

The 1.2 Ma Valles Caldera in north-central New Mexico hosts a young igneous volcanic hydrothermal system after the model proposed in Goff and Janik (2000). The Sulphur Springs area within Valles Caldera is an acid-sulfate area typical of this model, discharging acidic waters (pH 1.5-3) formed by oxidation of magmatic H₂S at the surface. We report on samples obtained from springs and streams collected between October 2021 and May 2023 in the Sulphur Creek and Alamo watersheds. Sulphur Creek receives input from Sulphur Springs and exhibits low pH (2-4) and high concentrations of Al (≤110 mg/L), Fe (≤60 …

Dryland Vegetation Mapping Using High Spatial-Temporal Resolution Satellite Imagery In New Mexico: A Comparison Of Phenological Time-Series Transformation Methods, Pratistha Sharma

Geography ETDs

New Mexico's drylands are undergoing notable vegetation changes due to rising aridity, higher temperatures, and shifts in precipitation with changing climate. Mapping drylands through remote sensing is challenging compared to mesic systems due to the irregular patterns of rainfall-driven phenology and weaker vegetation absorption signals. This study aims to enhance vegetation mapping in New Mexico, utilizing a high-resolution, frequently revisited PlanetScope dataset with multispectral capabilities, specifically chosen for its suitability for time-series analysis. The challenge with high spatial and temporal data lies in the overwhelming volume, leading to issues like the curse of dimensionality, overfitting, data redundancy, collinearity, and visualization …

Ai Assisted Workflows For Computational Electromagnetics And Antenna Design, Oameed Noakoasteen

Electrical and Computer Engineering ETDs

These days large volumes of data can be recorded and manipulated with relative ease. If valuable information can be extracted from them, these vast amounts of data can be a rich resource not just for the digital economy but also for scientific discovery and development of technology. When it comes to deriving valuable information from data, Machine Learning (ML) emerges as the key solution. To unlock the potential benefits of ML to science and technology, extensive research is needed to explore what algorithms are suitable and how they can be applied.

To shine light on various ways that ML can …

Domain Specific Feature Representation Learning For Diverse Temporal Data, Farhan Asif Chowdhury

Computer Science ETDs

Humans can leverage domain context to recognize novel patterns and categories based on limited known examples. In contrast, computational learning methods are not adept at exploiting context and require sufficient labeled examples to achieve similar accuracy. Many temporal data domain, for example, seismic signals and oil mining sensor data, requires domain expert annotation, which is both costly and time-consuming. The dependency on training data limits the applicability of machine learning algorithms for domains with limited labeled data. This dissertation aims to address this gap by developing temporal mining algorithms that exploit domain context to learn discriminative feature representation from limited …

Understanding The Nature Of Pulsars And Characterizing Propagation Effects Using Pulsar Timing, Pratik Kumar

Physics & Astronomy ETDs

Pulsars are highly magnetized stellar remnants, among the densest known objects, and primarily produce radio emission in the form of lighthouse beams sweeping across the line of sight as a regular train of pulses. Apart from providing tests for matter in high-density regimes, general relativity, and plasma emission; perhaps the most notable characteristic is their applicability as precise astronomical clocks to measure various effects. Pulsar Timing Arrays (PTAs) are galactic scale detectors analogous to ground-based detectors of Gravitational Waves (GWs) like LIGO, with the aim of detecting low-frequency nano-Hz GWs from coalescing binary supermassive black holes. PTAs consist of a …

Improving Human-Automation Collaboration In Motion Planning, Torin J. Adamson

Computer Science ETDs

Human-automation collaboration is becoming a part of everyday life as AI helps us drive, make decisions, and solve a variety of other tasks. However, safe and effective collaboration systems depend on factors in trust, communication, and more. Existing studies to explore these are typically carried out in laboratory settings, providing robust data under tight environmental control. However, human behavior evolves over time, driven by external factors that cannot be fully captured in single participation sessions. These factors form the "human context", contextualizing the behavioral data for a more complete understanding. In this thesis, video game adaptations upon conventional subject studies …

Hydrochemistry Of An Alpine Karst System, Northern New Mexico: Las Huertas, Kambray A. Townsend

Earth and Planetary Sciences ETDs

Las Huertas in the Sandia Mountains relies on snowmelt, monsoonal recharge, and groundwater inputs. Our hypothesis, the proportion of groundwater contribution varied spatially and temporally, was assessed by observing travertine and multiple geochemical tracers to differentiate water balance components. We report 26 samples from 13 locations (sampled between 2021-2023). Major ion and isotopic analysis indicated Las Huertas headsprings vary spatially. Capulin Spring has higher salinity; major ions suggest recharged waters are a mix of CaCO3-rich and sulfate-chloride-containing water. The proportion of groundwater to spring discharge is a mix of winter and summer precipitation. Travertine supersaturation is seasonal, with variations downstream, …

Syntheses And Characterization Of Photoactive Ruthenium And Iron Polypyridyl Complexes, Rajani Thapa Magar

Chemistry and Chemical Biology ETDs

Within this dissertation, two distinct classes of metal complexes have been discussed that bear significance in the field of solar energy conversion, photo redox catalysis and memory devices. The first class of the metal complexes is a series of photochromic Ruthenium polypyridyl N-heterocyclic carbene tethered sulfoxide complexes that are reported to undergo unusually slow isomerization from S-bonded to O-bonded and unusually fast thermal reversion from O-bonded to S-bonded configuration. The role of NHC in the excited state dynamics of these complexes have been discussed in detail in Chapter 3.

For the first time in two decades, structural information of the …

Applications Of Observational Seismology: Insights Into Volcanic And Near Surface Processes, Justin T. Wilgus

Earth and Planetary Sciences ETDs

The field of observational seismology has made tremendous progress in the past two decades. This progress has been multi-faceted in form, but significant contributions emanated from 1) increases in both the quality and the quantity of seismic data 2) advances in computational power 3) advances in algorithmic capability, including machine learning. In this dissertation I report on three distinctly different seismic applications made possible by the aforementioned progress and discuss the insights these applications have provided in understanding volcanic and near surface processes of the Earth.

In the first chapter titled, “Shear Velocity Evidence of Upper Crustal Magma Storage Beneath …

The Impacts Of Transfer Learning For Ungulate Recognition At Sevilleta National Wildlife Refuge, Michael Gurule

Geography ETDs

As camera traps have grown in popularity, their utilization has expanded to numerous fields, including wildlife research, conservation, and ecological studies. The information gathered using this equipment gives researchers a precise and comprehensive understanding about the activities of animals in their natural environments. For this type of data to be useful, camera trap images must be labeled so that the species in the images can be classified and counted. This has typically been done by teams of researchers and volunteers, and it can be said that the process is at best time-consuming. With recent developments in deep learning, the process …

Testing The Niche Center Hypothesis In The Fossil Record Of Atlantic Bivalves, Rhiannon Z. Nolan

Earth and Planetary Sciences ETDs

Paleoecological analyses of six shallow marine bivalves were conducted to test the Abundant Center Hypothesis using data from the fossil record of the Pleistocene through modern day. This hypothesis predicts the highest abundance of a species is at the center of the geographic or environmental range, decreasing toward the edges. In geographic space, distances to a centerline within a geographic range were variably correlated with population abundances, and some species displayed a sharp drop-off in abundance as distance increased. In environmental space, bivalve species showed moderate correlations between abundance and centrality when measured using cumulative data across the last 2.8 …

Seismic Shadow Zone Investigation In The Upper Magma Reservoir Of The Yellowstone Caldera, Sarah Nolt-Caraway

Earth and Planetary Sciences ETDs

This study investigates whether the Yellowstone Caldera has enough melt to mute S-waves, creating a seismic shadow zone. Using a dense nodal deployment of ~650 stations, 7-9 earthquakes during the nodal deployment, and 21 broadband stations with 3,000-4,000 events per station; amplitude and noise maps, seismograms, and automatic phase picks probabilities from a deep learning model were analyzed to assess the potential role of melt, crustal attenuation, and noise in affecting body waves, particularly S-phases. The results are inconclusive, with unclear evidence whether observed amplitude decay is normal signal decay due to distance, noise-related, melt, or from scattering and intrinsic …

Seismic Analysis Of The Upper & Lower Falls Of The Yellowstone River, Loring Schaible

Earth and Planetary Sciences ETDs

Twelve years of concurrent hydrologic and continuous seismic data along with temporary seismic data demonstrate that the Upper and Lower Falls of the Grand Canyon of the Yellowstone River comprise a highly localized source of 0.5-5 Hz seismic energy that overwhelms anthropogenic contributions. In aggregate, seismic amplitude from 2008-2019 is linearly related to discharge with a correlation coefficient of 0.96. Repeated deviations from this linear relationship persist for 1-2 weeks prior to the date that Yellowstone Lake becomes clear of winter ice coverage. Seismic efficiency increases by ~50-250% during this period of ice-breakup, during which lake ice flows into the …

Probabilistic Modeling Of Social Media Networks, Distinguishing Phylogenetic Networks From Trees, And Fairness In Service Queues, Md Rashidul Hasan

Mathematics & Statistics ETDs

In this dissertation, three primary issues are explored. The first subject exposes who-saw-from-whom pathways in post-specific dissemination networks in social media platforms. We describe a network-based approach for temporal, textual, and post-diffusion network inference. The conditional point process method discovers the most probable diffusion network. The tool is capable of meaningful analysis of hundreds of post shares. Inferred diffusion networks demonstrate disparities in information distribution between user groups (confirmed versus unverified, conservative versus liberal) and local communities (political, entrepreneurial, etc.). A promising approach for quantifying post-impact, we observe discrepancies in inferred networks that indicate the disproportionate amount of automated bots. …

Synthesis And Reactivity Of Heteroatom Embedded Cycloalkynes In Spaac, Nickel Catalyzed Alkylarylation Of Alkenes, And Carbofluorination Of Alkynes, Namrata Khanal

Chemistry and Chemical Biology ETDs

Part I covers Chapters 1, 2, and 3

cycloaddition reactions, that is utilized in biorthogonal chemistry. This metal free version The strain promoted azide-alkyne cycloaddition (SPAAC) reaction is one of the popular 1,3-dipolar of click reaction offers advantage over copper catalyzed click reaction. Since it eliminates the use of copper that is toxic to cells, it is considered favorable for biocompatible reaction. Due to the increased reactivity with dipoles without the use of metal catalyst, cycloalkynes, in particular cyclooctynes, have been employed as the biorthogonal reagent in biorthogonal chemical reaction for the study of a biological processes in vivo. The …

Super-Resolution Microscopy With Color Centers In Diamond, Forrest A. Hubert

Optical Science and Engineering ETDs

This dissertation explores the development and application of diamond color centers, specifically the silicon-vacancy (SiV) and nitrogen-vacancy (NV) centers, in super-resolution microscopy and magnetic imaging techniques. It demonstrates the potential of SiV centers as photostable fluorophores in stimulated emission depletion (STED) microscopy, with a resolution of approximately 90 nm. The research also presents a method for nanoscale magnetic microscopy using NV centers by combining charge state depletion (CSD) microscopy with optically detected magnetic resonance (ODMR) to image magnetic fields produced by 30 nm iron-oxide nanoparticles. The individual magnetic feature width reaches ~100 nm while resolving magnetic field patterns from nanoparticles …

Application Of Quantum Mechanical Techniques To Optical Waveguide Structures, Stuart Ward

Physics & Astronomy ETDs

The focus of this dissertation is on the application of supersymmetric quantum mechanics to the problem of microbending in optical waveguides and on the analysis of soliton decay due solely to quantum mechanical effects.

The techniques of supersymmetric quantum mechanics are applied to the equation of motion describing light propagation in an optical waveguide which is undergoing microbending. Based on these supersymmetric techniques, given a particular refractive index profile, one may derive a new refractive index profile which results in less loss due to the microbending -- the particular example of the monomial index profile is analyzed in detail. An …

High-Power Laser Cooling And Temperature-Dependent Fluorescence Studies Of Ytterbium Doped Silica, Brian Topper

Optical Science and Engineering ETDs

Experimental observation of optical refrigeration using ytterbium doped silica glass in recent years has created a new solution for heat mitigation in high-power laser systems, nonlinear fiber experiments, integrated photonics, and precision metrology. Current efforts of different groups focus on compositional optimization, fiber fabrication, and investigating how much silica can be cooled with a laser. At the start of this work, the best effort in laser cooling ytterbium doped silica saw cooling by 6 K from room temperature. This dissertation follows the experimental efforts that culminated in the increase of this initial record by one order of magnitude. Comprehensive spectroscopic …

Near- And Far- Field Optical Response Of Ensembles Of Nanostructures, Lauren Zundel

Physics & Astronomy ETDs

The ability of metallic nanostructures to support collective oscillations of their conduction electrons, known as surface plasmons, makes them attractive candidates for a wide range of applications in areas as diverse as cancer therapy, biosensing, and solar energy harvesting. These applications are especially promising for periodic arrays of nanostructures, which can support collective modes known as lattice resonances, and for nanostructures with extreme aspect ratios that give rise to enhanced light-matter interaction. In this Thesis, we employ a coupled dipole model to theoretically explore the lattice resonances supported by complex arrays of nanoparticles containing multiple nanoparticles per unit cell. We …

Assessing Ecological Relationships Among Late Triassic Vertebrates In Petrified Forest National Park, Alexandra Davis Apgar

Earth and Planetary Sciences ETDs

The complex vertebrate ecosystem of the Late Triassic has not yet been fully understood, largely due to oversimplification of hypothesized trophic hierarchies and limited preservation of direct evidence of faunal interaction. Paleocommunity reconstruction attempts can also fall victim to taphonomic biases, time-averaging inaccuracies, and non-analogue paleoecologies. Utilizing a combination of PAIRS analysis and NMDS ordination, we highlight vertebrate faunal relationships within the Adamanian and Revueltian faunachrons of Petrified Forest National Park, assess the likelihood that these patterns have ecological rather than preservational drivers, and examine how these potential interactions may have been impacted by the Adamanian-Revueltian turnover event. We are …

Photophysical Properties Of Synthetic Oligomeric Phenylene Ethynylene, Hugh F. Fritz Jr.

Chemistry and Chemical Biology ETDs

Oligomeric Phenylene Ethynylenes (OPEs) are a class of synthetically prepared compounds with the basic structure of phenylene rings connected by triple-bonded carbon atoms, also known as an ethyne link. This structure can be modified by incorporating functional groups onto one or more of the phenylene rings. The addition of functional groups, such as sulfoxide or imidazole, may alter the photophysical properties in detectable ways. The photophysical techniques used in this report include fluorescence, spectroscopy in the ultraviolet and visible light range (UVVIS), and photon-based excitation using a photo chamber.

One attractive function of OPEs is their antimicrobial property. Previously published …

Modified Geometries, Clifford Algebras And Graphs: Their Impact On Discreteness, Locality And Symmetr, Roma Sverdlov

Mathematics & Statistics ETDs

In this dissertation I will explore the question whether various entities commonly used in quantum field theory can be “constructed". In particular, can spacetime be “constructed" out of building blocks, and can Berezin integral be “constructed" in terms of Riemann integrals.

As far as “constructing" spacetime out of building blocks, it has been attempted by multiple scientific communities and various models were proposed. But the common downfall is they break the principles of relativity. I will explore the ways of doing so in such a way that principles of relativity are respected. One of my approaches is to replace points …

Methods Of Magneto-Optical Spectroscopy And Analysis For Porphyrins And Polymer Thin-Films, Emigdio E. Turner

Chemistry and Chemical Biology ETDs

This dissertation describes the construction of two high precision magneto-polarimeters for performing Faraday rotation and Magnetic Circular Dichroism (MCD) measurements of polymer thin-films. There is a focus in materials science on the development of thin-film magneto-optically active materials. These materials could allow for the construction of a thin-film optical diode, an important device for next-generation photonic technology. Upon completion of the Faraday rotation spectrometer, two publications were generated from Faraday rotation measurements of novel polymer thin-film materials.

With growing interest by materials scientists in magneto-optically active transition-metal containing materials, an MCD spectrometer was constructed to study these materials. This spectrometer …