Physical Sciences and Mathematics Commons^™

Design, Fabrication, And Characterization Of Advanced High-Power Single-Mode 9xxnm Semiconductor Lasers, Xiaolei Zhao

All Dissertations

This thesis presents the comprehensive design, fabrication, and demonstration of advanced high-power, high-efficiency single-mode semiconductor lasers operating at a wavelength of 9xxnm. We begin with the design of the laser epitaxial structure, serving as the cornerstone for achieving high-power high-efficiency lasers. Our methodology integrates a semi-analytical calculation model, which accounts for Longitudinal Spatial Hole Burning (LSHB) and Two-Photon Absorption (TPA) effects, facilitating a thorough exploration of how design parameters influence output power and conversion efficiency. This approach offers an effective and time-efficient epitaxial structure optimization strategy compared to conventional full 3D simulation models.

Subsequently, we demonstrate high-power, high-efficiency ridge waveguide …

Robust And Trustworthy Deep Learning: Attacks, Defenses And Designs, Bingyin Zhao

All Dissertations

Deep neural networks (DNNs) have achieved unprecedented success in many fields. However, robustness and trustworthiness have become emerging concerns since DNNs are vulnerable to various attacks and susceptible to data distributional shifts. Attacks such as data poisoning and out-of-distribution scenarios such as natural corruption significantly undermine the performance and robustness of DNNs in model training and inference and impose uncertainty and insecurity on the deployment in real-world applications. Thus, it is crucial to investigate threats and challenges against deep neural networks, develop corresponding countermeasures, and dig into design tactics to secure their safety and reliability. The works investigated in this …

Applications Of Conic Programming Reformulations, Sarah Kelly

All Dissertations

In general, convex programs have nicer properties than nonconvex programs. Notably, in a convex program, every locally optimal solution is also globally optimal. For this reason, there is interest in finding convex reformulations of nonconvex programs. These reformulation often come in the form of a conic program. For example, nonconvex quadratically-constrained quadratic programs (QCQPs) are often relaxed to semidefinite programs (SDPs) and then tightened with valid inequalities. This dissertation gives a few different problems of interest and shows how conic reformulations can be usefully applied.

In one chapter, we consider two variants of the trust-region subproblem. For each of these …

Development Of Chiral Lewis Base Catalysts For Chlorosilane-Mediated Asymmetric C-C Bond Formations, Changgong Xu

Theses and Dissertations

The chiral hydrazine is a crucial structural motif that serves as pivotal structural elements in numerous natural products and biologically significant molecules. We are particularly interested in the catalytic asymmetric reduction of hydrazones, as well as the catalytic asymmetric propargylation and allenylation of hydrazones, because they provide direct pathways to these enantio-enriched chiral building blocks. In this work, we will explore the potential of two different categories of chiral Lewis base catalysts in the said transformations.

Developed by another student in our group, axial-chiral 3,3’-triazolyl biisoquinoline N,N’-dioxides derived catalysts are tested and demonstrated its capability in activating various hydrazone …

A Post-Quantum Mercurial Signature Scheme, Madison Mabe

All Theses

This paper introduces the first post-quantum mercurial signature scheme. We also discuss how this can be used to construct a credential scheme, as well as some practical applications for the constructions.

Assessing Equitable Distribution Of The Urban Tree Canopy At The Neighborhood Scale In Greenville, South Carolina., April Riehm

All Theses

We are living in an era that necessitates adaptation and resilience. The Earth is warming. Our climate has changed (EPA, 2016). Our planet is also rapidly urbanizing. It is predicted that 68% of people will live in cities by 2050. The City of Greenville is a rapidly growing city in South Carolina that has been losing its tree canopy to development(City of Greenville, 2023). The Urban Tree Canopy (UTC) is a community asset that provides many quality-of-life benefits including improved air quality, stormwater management, carbon sequestration, mental and physical well-being, increased mobility and access, aesthetics, a reduction in energy costs, …

The Impacts Of Wind On Coastal Trees, Julian Halil

All Theses

Trees in hurricane-prone areas are exposed to severe winds and flooding. We studied the physiological and structural responses of forested wetland trees in relation to wind stress. We evaluated the windfirmness of two forested wetland tree species. Baldcypress was chosen because of high survival in post-hurricane studies. In contrast, laurel oak co-occurs with baldcypress yet resists hurricane-force winds poorly. In a static winching study, we quantified the critical turning moment (Mcrit) required to topple both species. Mcrit increased with trunk diameter at breast height (DBH) and crown size. Baldcypress and laurel oak demonstrated similar Mcrit, but regression models indicate baldcypress …

Redesign Of X-Ray Irradiator To Expand Research Of Low-Dose X-Ray Radiation, Lauren Ulbrich

All Theses

The effects of high-dose radiation are well-documented, and are understood to be harmful to the human body. On the other hand, the effects of low-dose radiation are much less understood. There is debate over whether or not there are negative, positive, or no effects at all from low-dose radiation. One of the reasons why these effects are not well known is because there aren't as many studies done on this type of radiation. It is a lot harder to classify the effects of radiation at low doses due to many external factors. However, the Clemson Medical Physics lab has been …

Photobiomodulation Of Bovine Oocytes During Maturation Increases Atp Content And Enhances Subsequent Embryonic Development, Kendall Richey

All Theses

Bovine in-vitro production(IVP) of embryos is a growing field for producing offspring with desirable genetics in the cattle industries. While IVP is effective, oocyte cytoplasmic maturation is compromised, and bovine oocytes matured in-vitro have reduced metabolic activity than those matured in-vivo. Mitochondria are the central unit of oocyte metabolism, producing ATP through OXPHOS. Photobiomodulation is a light treatment reported to improve metabolic activity. In five experiments, we measured the effects of photobiomodulation treatment with red LED at 16-(L-16) and 20 h(L-20) of bovine oocyte in-vitro maturation on subsequent embryonic development, mitochondrial activity and nuclear progression. Bovine COCs were aspirated …

Using Strainmeters To Characterize Enhanced Geothermal Systems, Clem Laffaille

All Theses

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Using Ion Mobility Mass Spectrometry In Conjuction With Derivatization Methods To Enhance The Separation Of Different Steroid Isomers, Shadrack Lucas

All Theses

One of the major problems facing analytical chemistry challenge is the isomers separation, due to their closely related molecular structures and physicochemical properties. Therefore, in this thesis, we have performed the separation of steroid isomers through the use of ion mobility mass spectrometry, using various chemical approaches. Ion mobility is an effective high-resolution separation techniques that utilizes the mobility of ions in the gas-phase environment. A useful tool for isomeric analysis due to the ability to separate different isomeric classes of steroids according to their varied collision cross-sections, which is achieved by taking advantage of differences in ion mobility.

Moreover, …

Models Of Functional Redundancy In Ecological Communities, Sandra Annie Tsiorintsoa

All Dissertations

Functional redundancy is the number of taxa that perform a given function within a given community. In most systems, high levels of functional redundancy are important, because they contribute to ecosystem stability. However, we currently have very little understanding of why functional redundancy varies among communities. One possible factor that could affect functional redundancy is environmental complexity. Many studies show that simplified ecosystems harbor communities with lower taxon diversity. What is less clear is if this simplicity and lower taxon diversity also affects functional redundancy. To answer this question, we use metacommunity models to explore the connection between environmental complexity …

Engineering Multifunctional Silicon Nanostructures From Biorenewable Cellulose Nanocrystals, Nancy Chen

All Dissertations

The imperative search for alternative materials to address the pressing demand for advance energy storage is underscored by the escalating environmental predicaments. Lithium-ion batteries (LIBs) with graphite anodes have become the benchmark in energy storage; however, they are approaching a saturation point in terms of energy density. Silicon emerges as a promising contender to supplant graphite, owing to its profuse availability, cost-effectiveness, and impressive specific capacity of 4200 mAh g^-1. By integrating silicon anodes, LIBs stand to undergo a radical transformation, markedly diminishing in weight and size, thus heralding a novel wave of compact, lightweight energy storage systems. …

To The Torus And Beyond: An X-Ray Study Of Agn Tori Morphology, Andrealuna Pizzetti

All Dissertations

Active Galactic Nuclei (AGN) are among the Universe's most energetic and powerful objects, fueled by an accreting supermassive black hole (SMBH) at the host galaxy's center, surrounded by a toroidal structure of dusty gas. Ultraviolet photons arising from the accretion disk get up-scattered to X-rays via inverse Compton scattering by hot electrons close to the accretion disk. Being produced in the very center of the AGN, X-ray photons are powerful messengers that probe the physics of the accretion system and the matter in the surroundings. The torus, formerly considered homogeneous, appears to be a more complex structure of clouds with …

Selected Topics On Sequential Designs For Decision Making, Caroline Kerfonta

All Dissertations

This dissertation is comprised of three parts. The first proposes a sequential approach to determine the experimental setting with the minimum variance (Kerfonta et al., 2024). Two acquisition functions are developed to assist developing the approach. Theoretical results along with a case study using data from crystallization experiments is conducted to show the ability of the proposed method to correctly select the experiment with the minimum variance. The second and third parts propose adaptations to the Bayesian optimization algorithm using transformed additive Gaussian processes (TAG) as the surrogate model. The goal of using the TAG framework is to decompose the …

The Human Side Of Adaptive Autonomy: Design Considerations For Adaptive Autonomous Teammates, Allyson Hauptman

All Dissertations

Ground-breaking advances in artificial intelligence (AI) have led to the possibility of AI agents operating not just as useful tools for teams, but also as full-fledged team members with unique, interdependent roles. This possibility is fueled by the human desire to create more and more autonomous systems that possess computational powers beyond human capability and the promise of increasing the productivity and efficiency of human teams dramatically. Yet, for all the promise and potential of these human-AI teams, the inclusion of AI teammates presents several challenges and concerns for both teaming and human-centered AI.

An important part of teaming is …

Oscillations Of Capillary Surfaces With Volume And Edge Effects, Dingqian Ding

All Dissertations

Capillary surfaces are defined by an interface endowed with surface tension that is partially supported by a solid substrate and are susceptible to oscillations reflecting a balance between fluid inertia and the restorative force of surface tension. The wave dynamics strongly depend upon volume change within the domain and edge effects through the boundary conditions applied at the contact-line formed at the liquid-gas-solid interface, while the spatial wave structure conforms to the geometry of the capillary surface. This dissertation develops mathematical models to address these effects for several canonical capillary surfaces, which are organized into two parts that are focused …

Numerical Simulation Of Laser Induced Elastic Waves In Response To Short And Ultrashort Laser Pulses., Alireza Zarei

All Dissertations

In an era of intensified market competition, the demand for cost-effective, high-quality, high-performance, and reliable products continues to rise. Meeting this demand necessitates the mass production of premium products through the integration of cutting-edge technologies and advanced materials while ensuring their integrity and safety. In this context, Nondestructive Testing (NDT) techniques emerge as indispensable tools for guaranteeing the integrity, reliability, and safety of products across diverse industries.

Various NDT techniques, including ultrasonic testing, computed tomography, thermography, and acoustic emissions, have long served as cornerstones for inspecting materials and structures. Among these, ultrasonic testing stands out as the most prevalent method, …

Efficient Fully Bayesian Approaches To Brain Activity Mapping With Complex-Valued Fmri Data: Analysis Of Real And Imaginary Components In A Cartesian Model And Extension To Magnitude And Phase In A Polar Model, Zhengxin Wang

All Dissertations

Functional magnetic resonance imaging (fMRI) plays a crucial role in neuroimaging, enabling the exploration of brain activity through complex-valued signals. Traditional fMRI analyses have largely focused on magnitude information, often overlooking the potential insights offered by phase data, and therefore, lead to underutilization of available data and flawed statistical assumptions. This dissertation proposes two efficient, fully Bayesian approaches for the analysis of complex-valued functional magnetic resonance imaging (cv-fMRI) time series.

Chapter 2 introduces the model, referred to as CV-sSGLMM, using the real and imaginary components of cv-fMRI data and sparse spatial generalized linear mixed model prior. This model extends the …

Experimental Analyses Of Emission Lines In The Uv/Vis/Nir Range For Astrophysically-Important Elements: From The Iron Group To R-Process Elements, Brynna Neff

All Dissertations

Analysis of astrophysical phenomena requires an understanding of the electronic

structure and transition probabilities of the elements present in that environment,

yet there are still many charge states of heavy elements whose electronic

structures and spectroscopic properties are not yet well understood. To address this,

we investigated the spectroscopic properties of three different elements through an

analysis of spectra collected from three different experimental apparatuses.

In order to better understand the spectroscopic properties of Ni I and II, we

analyzed spectra collected from the Compact Toroidal Hybrid (CTH) apparatus at

Auburn University. In this experiment, a nickel sample was inserted …

Carbon "Quantum" Dots: Structures, Properties, And Issues, Weixiong Liang

All Dissertations

Carbon dots (CDots) are small carbon nanoparticles (CNPs) with effective surface passivation. The effective passivation has been achieved by the surface functionalization of pre-existing CNPs with organic molecules, mostly molecules containing primary or secondary amine moieties. In the studies highlighted in this dissertation, CNPs were functionalized by selected organic molecules, including especially the use of radical addition reactions, to generate CDots with strong absorption and bright fluorescence emissions. A good demonstration of the approach was the N-ethylcarbazole (NEC) radical addition to CNPs under microwave irradiation. Spectroscopy and microscopy methods were employed to characterize the resulting NEC-CDots, and the results …

On Cheeger Constants Of Knots, Robert Lattimer

Electronic Theses, Projects, and Dissertations

In this thesis, we will look at finding bounds for the Cheeger constant of links. We will do this by analyzing an infinite family of links call two-bridge fully augmented links. In order to find a bound on the Cheeger constant, we will look for the Cheeger constant of the link’s crushtacean. We will use that Cheeger constant to give us insight on a good cut for the link itself, and use that cut to obtain a bound. This method gives us a constructive way to find an upper bound on the Cheeger constant of a two-bridge fully augmented link. …

In-Between Frame Generation For 2d Animation Using Generative Adversarial Networks, Francisco Arriaga Pazos

Open Access Theses & Dissertations

Traditional 2D animation remains a largely manual process where each frame in a video is hand-drawn, as no robust algorithmic solutions exist to assist in this process. This project introduces a system that generates intermediate frames in an uncolored 2D animated video sequence using Generative Adversarial Networks (GAN), a deep learning approach widely used for tasks within the creative realm. We treat the task as a frame interpolation problem, and show that adding a GAN dynamic to a system significantly improves the perceptual fidelity of the generated images, as measured by perceptual oriented metrics that aim to capture human judgment …

Dispersal And Population Structure Of Euchlanis Chihuahuaensis Via Anemochory In The Chihuahuan Desert, Tristan Chavez-Poeschel

Open Access Theses & Dissertations

Desert ecosystems present challenges for aquatic organisms as habitats are fragmented, both in space and time; however, diapausing stages of rotifers can travel hundreds of kilometers during wind events. I used the rotifer Euchlanis chihuahuaensis as a model species to investigate the influence of wind dispersal on gene flow and population genetics in Chihuahuan Desert populations. I hypothesized that anemochory facilitates gene flow from source populations in the Northern Chihuahuan Desert in Mexico and the western United States to habitats in the Trans-Pecos region via delineated wind corridors. To test this hypothesis, the genetic diversity of populations from both inside …

Investigating Changes In Surface Water Chemistry Across The Llano Uplift And The Balcones Fault Zone In Central Texas Using Strontium And Uranium Isotopes, Hao Tuan Pham

Open Access Theses & Dissertations

The landscape of central Texas is shaped by over one billion years of Earth's history. An array of lithology lies within central Texas along with two large geological structures. The Llano Uplift, characterized by Proterozoic metamorphic and igneous rocks dating back to 1.37 billion years ago, is encircled by Paleozoic and Mesozoic sedimentary rocks. To the southeast of the Llano Uplift lies the Balcones Fault Zone (BFZ), an extensional structural system of mostly normal faults that delineates the transition between Paleozoic-Mesozoic sedimentary rocks and Cenozoic sedimentary cover, which are influential to the regional hydrogeology. This study investigates the hydrogeological dynamics …

Side Channel Detection Of Pc Rootkits Using Nonlinear Phase Space, Rebecca Clark

Honors Theses

Cyberattacks are increasing in size and scope yearly, and the most effective and common means of attack is through malicious software executed on target devices of interest. Malware threats vary widely in terms of behavior and impact and, thus, effective methods of detection are constantly being sought from the academic research community to offset both volume and complexity. Rootkits are malware that represent a highly feared threat because they can change operating system integrity and alter otherwise normally functioning software. Although normal methods of detection that are based on signatures of known malware code are the standard line of defense, …

Monero: Powering Anonymous Digital Currency Transactions, Jake Braddy

Theses/Capstones/Creative Projects

Cryptocurrencies rely on a distributed public ledger (record of transactions) in order to perform their intended functions. However, the public’s ability to audit the network is both its greatest strength and greatest weakness: Anyone can see what address sent currency, and to whom the currency was sent. If cryptocurrency is ever going to take some of the responsibility of fiat currency, then there needs to be a certain level of confidentiality. Thus far, Monero has come out on top as the preferred currency for embodying the ideas of privacy and confidentiality. Through numerous cryptographic procedures, Monero is able to obfuscate …

Resource Scarcity Caused By Environmental Changes: Driving Factor In Terrorism Attacks In Afghanistan, Pakistan, Syria, Amaris Bustamante

Open Access Theses & Dissertations

Climate change, resource scarcity, and terrorist attacks are ever-growing crises that disproportionately impact different states. They are crises that can impact the stability and resilience of humanity in the following decades if they are not addressed and mitigated. This study addresses the impact of resource scarcity caused by climate change that can then serve as a driving force in terrorist attacks in climate-sensitive and conflict-prone states. The objective of this mixed-methods study is to identify the correlation between climate changes that lead to resource scarcity such as rainfall and surface temperatures with terrorist attacks when taking into consideration other demographic, …

Water Sufficiency For Organismal Function In Dryland Critical Zones, Lindsey Dacey

Open Access Theses & Dissertations

Water availability is crucial for organismal survival and growth in dryland environments, affecting both ecological interactions and carbon dynamics. The goal of this thesis is to develop soil water release curves (SWRCs) that link soil water potentials (Ψ) to soil water content (θ). Using the SWRCs, temporal soil water sufficiency curves are developed, which quantify the amount of time that dryland critical zones have enough water to sustain the physiology of organisms. These curves allow for effectively indicating water availability across different species, coverage types, and soil conditions, enhancing our understanding of water dynamics in drylands and contributing important parameters …

Analysis Of Additively Manufactured Inconel 718 Combustion Behavior In Promoted Oxygen Environments, Dominic George Dieguez

Open Access Theses & Dissertations

Promoted combustion testing is a vital tool for engineers to establish the combustion and flammability characteristics of materials (metallic or otherwise) in oxygen enriched environments. Historically, much of the established data for metallic promoted combustion has been with regards to materials in their cast and wrought forms. However, with the emergence of additive manufacturing as a preferred method of fabrication, the need exists to evaluate how metals in that form behave. Recent testing has demonstrated that even if a metal or alloy is nominally the same with regards to chemistry, flammability between samples in the wrought form can differ significantly …