Physical Sciences and Mathematics Commons^™

Validation Of The Thermal Work Limit (Twl) Against Known Heat Stress Exposures, Danielle L. Kapanowski

USF Tampa Graduate Theses and Dissertations

Workers are exposed to stressful thermal work environments in multiple industries every day. Methods for assessing heat stress often struggle to balance productivity without compromising the health of the workers. The Thermal Work Limit (TWL) is a method that has been adopted in areas outside of the United States as a viable method for heat assessment that combines health with productivity. TWL recommends a maximum metabolic rate for a given set of environmental conditions, clothing ensemble and acclimatization state. The purpose of this paper was to evaluate the validity of the TWL against a set of heat stress data known …

Remote Estimation Of Surface Water PCo2 In The Gulf Of Mexico, Shuangling Chen

USF Tampa Graduate Theses and Dissertations

Surface ocean partial pressure of CO₂ (pCO₂) is a critical parameter in the quantification of air-sea CO₂ flux, which further plays an important role in quantifying the global carbon budget and understanding ocean acidification. The demand for a clearer understanding of how, and how fast, the ocean is changing due to atmospheric CO₂ absorption, requires accurate and synoptic estimation of surface pCO₂.

Surface ocean pCO₂ is mainly controlled by four oceanic processes – thermodynamics, ocean mixing, biological activities, and air-sea CO₂ exchange. Surface ocean pCO_{2 …}

Ice And Guano Deposits In El Malpais Lava Tubes: Potential Paleoclimate Archives For The Southwest United States, Dylan S. Parmenter

USF Tampa Graduate Theses and Dissertations

Three ice cores and one guano core were obtained from lava tubes in El Malpais National Monument, New Mexico, in the Southwest United States. A large hiatus in the Bat Cave guano record, resulting from mining activities in the early 1900's, left us with only ~50 years of data (from AD 1955-2006) to use in analysis. 13C values in guano (-18 to -11.6‰) primarily fall within the range of C4 plants, and likely indicate a tendency of Tadarida brasiliensis to feed on insects over grasslands to the North or South of the park. Variations in 13C values for this period …

Morphodynamics Of Shell Key And Mullet Key Barrier Islands: Their Origin And Development, Zachary J. Westfall

USF Tampa Graduate Theses and Dissertations

Shell Key and Mullet Key are two sandy barrier islands on the West Central Florida coast near the mouth of Tampa Bay. These islands are part of an interconnected barrier-inlet system that includes Pass-a-Grille (PAG) and Bunces Pass. Shell Key is a relatively new island about 40-years of age that formed in between the two inlets of Bunces Pass and PAG. Mullet Key is an island to the south of Shell Key situated between Bunces Pass and the main Tampa Bay channel that has demonstrated large scale upward shoaling events. Using numerical modeling, the wave and tidal conditions at the …

An Investigation Of Habitat Suitability Factors And Their Interactions For Predicting Gopher Tortoise Habitat, Abigail V. Lavallin

USF Tampa Graduate Theses and Dissertations

This thesis evaluates the interaction between four habitat factors vital to the gopher tortoise in Florida. Federally and state listed as threatened throughout its entire range, the gopher tortoise is vital to protect, not only for itself individually but its burrows provide an essential habitat to over 300 species making it a key stone species within its environment. Historic habitat modeling methods are reviewed for the gopher tortoise to highlight the gap on this topic. This research expanded on the methods utilized by Baskaran et al. (2006) evaluating the soil, landcover, percentage of canopy cover and the depth to water …

Recovery Of Nutrients From Anaerobically Digested Enhanced Biological Phosphorus Removal (Ebpr) Sludge Through Struvite Precipitation, Maraida Balaguer-Barbosa

USF Tampa Graduate Theses and Dissertations

Water resources in Florida have been severely degraded by eutrophic conditions, resulting toxic algae blooms, which negatively affect health and tourism. Eutrophication, or excessive amount of phosphorus (P) and nitrogen (N) in water, overstimulates the production of aquatic plants, depletes dissolved oxygen, and deteriorates the aquatic environment. However, phosphorus is a non-renewable resource essential for all living organisms. In fact, more than half of the total demand for P globally is to supply the food industry, which has concerningly accelerated the depletion rates of phosphate reserves.

In many wastewater treatment plants (WWTPs), the enhanced biological phosphorus removal (EBPR) approach has …

Access To Safe Water Supply: Management Of Catchment For The Protection Of Source Water In Ghana, Michael K. Eduful

USF Tampa Graduate Theses and Dissertations

This study investigates provisions made within institutional and regulatory frameworks of water resources management to enhance multi-stakeholder relationships and the challenges of maintaining those relationships, and implications of water resources management for rural communities in the Densu River basin, Ghana. The primary objectives of this study were four fold, these are to: i) review the existing regulatory framework and how it promotes or hinders multi-stakeholder relationships within the catchment area; ii) examine multi-stakeholder relationships to identify challenges in promoting effective collaboration in water resources management; iii) explore the impacts of catchment management on the livelihoods of rural communities; and iv) …

Emotion Recognition Using Deep Convolutional Neural Network With Large Scale Physiological Data, Astha Sharma

USF Tampa Graduate Theses and Dissertations

Classification of emotions plays a very important role in affective computing and has real-world applications in fields as diverse as entertainment, medical, defense, retail, and education. These applications include video games, virtual reality, pain recognition, lie detection, classification of Autistic Spectrum Disorder (ASD), analysis of stress levels, and determining attention levels. This vast range of applications motivated us to study automatic emotion recognition which can be done by using facial expression, speech, and physiological data.

A person’s physiological signals such are heart rate, and blood pressure are deeply linked with their emotional states and can be used to identify a …

Drone Movement Control Using Gesture Recognition From Wearable Devices, Venkata Sireesha Dadi

USF Tampa Graduate Theses and Dissertations

Gesture Recognition is a new and upcoming trend that is being widely used in wearable devices and mobile handheld devices. The sensors like Accelerometer, Gyroscope, Heart rate monitor, Barometer and Ambient Light are mostly being included within the device to detect the static or continuous motion, rotational velocity, heartbeat rate of the user, pressure and light conditions for the device respectively. Implementing algorithms to capture the readings of these sensors and implementing them in a necessary way allows a user to use the wearable devices for a wide variety of applications. One such application is controlling Drone that takes user …

Groups Generated By Automata Arising From Transformations Of The Boundaries Of Rooted Trees, Elsayed Ahmed

USF Tampa Graduate Theses and Dissertations

In this dissertation we study groups of automorphisms of rooted trees arising from the transformations of the boundaries of these trees. The boundary of every regular rooted tree can be endowed with various algebraic structures. The transformations of these algebraic structures under certain conditions induce endomorphisms or automorphisms of the tree itself that can be described using the language of Mealy automata. This connection can be used to study boundarytransformations using the propertiesof the induced endomorphisms, or vice versa.

We concentrate on two ways to interpret the boundary of the rooted d-regular tree. In the first approach discussed in detail …

Application Of Image Recognition Technology To Foraminiferal Assemblage Analyses, Christian Helmut Gfatter

USF Tampa Graduate Theses and Dissertations

Analyses of foraminiferal assemblages involve time consuming microscopic assessment of sediment samples. Image recognition software, which systematically matches features within sample images against an image library, is widely used in contexts ranging from law enforcement to medical research. At present, scientific applications such as identification of specimens in plankton samples utilize flow through systems in which samples are suspended in liquid and pass through a beam of light where the images are captured using transmitted light. Identification of foraminifers generally utilizes reflected light, because most shells are relatively opaque.

My goal was to design and test a protocol to directly …

Development Of Bioactive Peptidomimetics, Fengyu She

USF Tampa Graduate Theses and Dissertations

Peptidomimetics are synthetic foldamers that expected more resistant to proteolytic degradation and enormous chemodiversity when compared with peptides. To date, the functional peptidomimetics such as β-peptides, peptoids, oligoureas, etc have been developed in many science fields. In order to explore the unnatural foldameric architectures, it’s necessary to discover the novel frameworks and molecular scaffolds. γ-AApeptides were reported to be a new class of peptidomimetics that showed its potential applications in drug discovery and chemical biology. However, a wide function and property of γ-AApeptides need to be further explored. To expand the potential application of γ-AApeptides in biochemistry, I have been …

A Fundamental Investigation Into Low Thermal Conductivity P-Type Chalcogenides And Skutterudites With Potential Thermoelectric Applications, Dean Hobbis

USF Tampa Graduate Theses and Dissertations

Sustainable and renewable energy is an incredibly important area in today’s society and investigation into avenues to improve this wide ranging technology are underway in many different fields. Thermoelectric devices possess the ability for the direct solid-state interconversion of heat and electrical power, which not only allows for sustainable refrigeration but also waste heat recovery. One current restriction on the efficiency of thermoelectric devices is the disparity in thermoelectric performance of p-type and n-type materials. Furthermore, a key physical attribute shared by the majority of high performing thermoelectric materials is low thermal conductivity. Thus in this thesis three separate p-type …

Assessing The Impacts Of Ghana’S Oil And Gas Industry On Ecosystem Services And Smallholder Livelihoods, Michael Acheampong

USF Tampa Graduate Theses and Dissertations

Ghana discovered oil and gas within its shores in commercial quantities in the year, 2007. This discovery was hailed as a potential turn around for the country’s economic destiny. While this optimism may have been well-founded, there has been a relative lack of appreciation of the potential adverse implications of the industry on traditional smallholder livelihoods, and the critical ecosystems that form their basis. In many countries, discovery of natural resources results in negative environmental and social outcomes, due to the loss of local livelihoods and environmental degradation. Deterioration of local livelihoods occurs through several biophysical pathways, both simple and …

Germania-Based Sol-Gel Coatings And Core-Shell Particles In Chromatographic Separations, Chengliang Jiang

USF Tampa Graduate Theses and Dissertations

Chapter one reviewed the development of sol-gel stationary phase for gas chromatograph (GC). Inorganic sol-gel precursor creates the substrate support for stationary phase bind to silica surface through the condensation of silanol groups, the rough surface with enhanced surface area enlarger the capacity of the sol-gel stationary phase, the porosity of sol-gel structure decreases the mass transferring coefficient, the term C in Van Deemter equation, which makes sol-gel stationary phase thicker coating up to 1 um but keeps the high resolution for gas chromatography. Chemical bound stationary phase significantly improve GC column with better thermal stability and solvent stability. Partial …

Using Ecosystem-Based Modeling To Describe An Oil Spill And Assess The Long-Term Effects, Lindsey N. Dornberger

USF Tampa Graduate Theses and Dissertations

The goal of the research conducted in this dissertation was to define and test methods to incorporate oil spill effects into an ecosystem-based assessment model. It was instigated by the Deepwater Horizon oil spill, an unprecedented oil spill in the United States for both depth and volume, with unknown implications for the health of the region. Using an ecosystem-based assessment model like Atlantis, with integrated oil spill dynamics, was the ideal candidate to predict long-term impacts such as decreased abundance or population recovery time. However no previous methodology existed for doing so in any ecosystem-based assessment model. Therefore, first I …

Validating The Accuracy Of Neatwork, A Rural Gravity Fed Water Distribution System Design Program, Using Field Data In The Comarca Ngöbe-Bugle, Panama, Maria Briones

USF Tampa Graduate Theses and Dissertations

Despite the sustainable development goals to increase access to improved water there are still 884 million people in the world without access to an improved water source (WHO, 2017). One method to improve access to water in rural, mountainous areas, is through construction of gravity fed water distribution systems. These systems should be designed based upon fundamental principles of hydraulics. One method of doing so in a time efficient manner with minimal engineering knowledge is to utilize a downloadable computer program such as Neatwork, which aids in design of rural, gravity fed water distribution systems and has been used by …

Application Of The Fusion Model For Cognitive Diagnostic Assessment With Non-Diagnostic Algebra-Geometry Readiness Test Data, Robert H. Fay

USF Tampa Graduate Theses and Dissertations

This study retrofitted a Diagnostic Classification Model (DCM) known as the Fusion model onto non-diagnostic test data from of the University of Chicago School Mathematics Project (UCSMP) Algebra and Geometry Readiness test post-test used with Transition Mathematics (Third Edition, Field-Trial Version). The test contained 24 multiple-choice middle school math items, and was originally given to 95 advanced 6th grade and 293 7th grade students. The use of these test answers for this study was an attempt to show that by using cognitive diagnostic analysis techniques on test items not constructed for that purpose, highly predictable multidimensional cognitive attribute profiles for …

Human Activity Recognition Based On Transfer Learning, Jinyong Pang

USF Tampa Graduate Theses and Dissertations

Human activity recognition (HAR) based on time series data is the problem of classifying various patterns. Its widely applications in health care owns huge commercial benefit. With the increasing spread of smart devices, people have strong desires of customizing services or product adaptive to their features. Deep learning models could handle HAR tasks with a satisfied result. However, training a deep learning model has to consume lots of time and computation resource. Consequently, developing a HAR system effectively becomes a challenging task. In this study, we develop a solid HAR system using Convolutional Neural Network based on transfer learning, which …

Hamiltonian Structures And Riemann-Hilbert Problems Of Integrable Systems, Xiang Gu

USF Tampa Graduate Theses and Dissertations

We begin this dissertation by presenting a brief introduction to the theory of solitons and integrability (plus some classical methods applied in this field) in Chapter 1, mainly using the Korteweg-de Vries equation as a typical model. At the end of this Chapter a mathematical framework of notations and terminologies is established for the whole dissertation.

In Chapter 2, we first introduce two specific matrix spectral problems (with 3 potentials) associated with matrix Lie algebras $\mbox{sl}(2;\mathbb{R})$ and $\mbox{so}(3;\mathbb{R})$, respectively; and then we engender two soliton hierarchies. The computation and analysis of their Hamiltonian structures based on the trace identity affirms …

Automatic Multimodal Assessment Of Neonatal Pain, Ghada Zamzmi

USF Tampa Graduate Theses and Dissertations

For several decades, pediatricians used to believe that neonates do not feel pain. The American Academy of Pediatrics (AAP) recognized neonates' sense of pain in 1987. Since then, there have been many studies reporting a strong association between repeated pain exposure (under-treatment) and alterations in brain structure and function. This association has led to the increased use of anesthetic medications. However, recent studies found that the excessive use of analgesic medications (over-treatment) can cause many side effects. The current standard for assessing neonatal pain is discontinuous and suffers from inter-observer variations, which can lead to over- or under-treatment. Therefore, it …

Generalizations Of Quandles And Their Cohomologies, Matthew J. Green

USF Tampa Graduate Theses and Dissertations

Quandles are distributive algebraic structures originally introduced independently by David Joyce and Sergei Matveev in 1979, motivated by the study of knots. In this dissertation, we discuss a number of generalizations of the notion of quandles. In the first part of this dissertation we discuss biquandles, in the context of augmented biquandles, a representation of biquandles in terms of actions of a set by an augmentation group. Using this representation we are able to develop a homology and cohomology theory for these structures.

We then introduce an n-ary generalization of the notion of quandles. We discuss a number of properties …

Evaluation Of Trace-Metal And Isotopic Records As Techniques For Tracking Lifetime Movement Patterns In Fishes, Jennifer E. Granneman

USF Tampa Graduate Theses and Dissertations

The focus of this work was on the use of otolith microchemistry and fish eye lens chemical profiles to measure fish movement and provided indirect support for the use of otolith microchemistry to examine exposure to crude oil. Chapter 1 provides an introduction to the applications of otolith microchemistry and eye lens isotopic profiles. In the second chapter, which examined associations between metal exposure and lesion formation in fishes collected after the Deepwater Horizon (DWH) oil spill, I did not observe any change in oil-associated metal concentrations in otoliths coinciding with the timing of the DWH oil spill. This suggests …

Spatial And Temporal Distributions Of Pelagic Sargassum In The Intra-Americas Sea And Atlantic Ocean, Mengqiu Wang

USF Tampa Graduate Theses and Dissertations

Pelagic Sargassum is one type of marine macroalgae that is known to be abundant in the Gulf of Mexico and Sargasso Sea. It is also known to serve as a critical habitat for many marine animals. In the past few years, large amounts of Sargassum have been reported in the Tropical Atlantic and Caribbean Sea (CS), causing significant environmental and economic problems. The goal of this study is to improve the understanding of Sargassum distributions, quantity, transport pathways, and bloom mechanisms in the CS and Tropic Atlantic through combining a variety of techniques including satellite remote sensing, field and laboratory …

Machine Learning Methods For Network Intrusion Detection And Intrusion Prevention Systems, Zheni Svetoslavova Stefanova

USF Tampa Graduate Theses and Dissertations

Given the continuing advancement of networking applications and our increased dependence upon software-based systems, there is a pressing need to develop improved security techniques for defending modern information technology (IT) systems from malicious cyber-attacks. Indeed, anyone can be impacted by such activities, including individuals, corporations, and governments. Furthermore, the sustained expansion of the network user base and its associated set of applications is also introducing additional vulnerabilities which can lead to criminal breaches and loss of critical data. As a result, the broader cybersecurity problem area has emerged as a significant concern, with many solution strategies being proposed for both …

Interrogation Of Protein Function With Peptidomimetics, Olapeju Bolarinwa

USF Tampa Graduate Theses and Dissertations

Proteins can be described as the “machineries” responsible for almost all tasks in the levels of organizational complexity in multi-cellular organisms namely: the cells, tissues, organs and systems. Any disorder in the function of a protein at any of these levels could result in disease, and a study of protein function is critical to understanding the pathological features of the disease at the molecular level. A quick glance at these abundantly present proteins reveals two striking features: large diversity of biological function, and the variations in structural complexity, which varies from simple random coils, to turns and helices, and on …

Analytics For Novel Consumer Insights (A Three Essay Dissertation), Utkarsh Shrivastava

USF Tampa Graduate Theses and Dissertations

Both literature and practice have investigated how the vast amount of ever increasing customer information can inform marketing strategy and decision making. However, the customer data is often susceptible to modeling bias and misleading findings due to various factors including sample selection and unobservable variables. The available analytics toolkit has continued to develop but in the age of nearly perfect information, the customer decision making has also evolved. The dissertation addresses some of the challenges in deriving valid and useful consumer insights from customer data in the digital age. The first study addresses the limitations of traditional customer purchase measures …

The Effect Of Processing Conditions On The Energetic Diagram Of Cdte Thin Films Studied By Photoluminescence, Shamara P. Collins

USF Tampa Graduate Theses and Dissertations

The photovoltaic properties of CdTe-based thin films depend on recombination levels formed in the CdTe layer and at the heterojunction. The localized states are resultant of structural defects (metal sublattice, chalcogen sublattice, interstitial), controlled doping, deposition process, and/or post-deposition annealing. The photoluminescence study of CdTe thin films, from both the bulk and heterojunction, can reveal radiative states due to different defects or impurities. Identification of defects allows for potential explanation of their roles and influence on solar cell performance. A thorough understanding of the material properties responsible for solar cell performance is critical in further advancing the efficiency of devices. …

An Interdisciplinary Approach To Understanding Predator-Prey Relationships In A Changing Ocean: From System Design To Education, Ileana M. Freytes-Ortiz

USF Tampa Graduate Theses and Dissertations

Climate change is ecologically and socially complex, deemed the most important issue of our generation. Through this dissertation I have approached climate change research through an interdisciplinary perspective, investigating how this phenomenon will affect marine ecological systems, how we can better develop experimental systems to answer ecological questions, and how we can effectively educate about this issue.

In Chapter 2, I provided accessible alternatives for researching the effects of climate change (elevated temperatures and pCO2) on marine ecosystems. I designed, built, and troubleshooted two accurate and inexpensive climate-controlled experimental systems capable of maintaining target conditions: a temperature-controlled system and an …

Theory And Application Of Geophysical Geodesy For Studying Earth Surface Deformation, Makan A. Karegar

USF Tampa Graduate Theses and Dissertations

An interdisciplinary approach at the interface between geodesy and geophysics has recently resolved several Earth science problems at regional and global scales. I use the term “geophysical geodesy” to distinguish the technical and theoretical aspect of geodesy from geophysical applications of geodetic techniques. Using a wide range of Earth observation data, I study the spatio-temporal characteristics of Earth surface deformation in the United States associated with several geophysical processes, including natural and anthropogenic subsidence and uplift, regional relative sea-level rise, and continental hydrological loading. The theoretical portion of this dissertation applies loading theory and develops a new hybrid method to …