Physical Sciences and Mathematics Commons^™

Exploring The Potential Of Nutrient Retention And Recycling With Wetlaculture Systems In Ohio With Physical And Landscape Models, Bingbing Jiang

USF Tampa Graduate Theses and Dissertations

Significant expansion of agricultural land use has been widely recognized for leading to global and regional negative environmental impacts, especially increased eutrophication of surface water systems for the last half-century. The landscape-scale environmental problem of overloading nutrients to lakes and streams by excessive fertilizer use and increased human-caused N-fixation is in urgent need of a sustainable landscape-scale solution. Wetlands have long been considered as an effective way to remove nutrients from surface water. However, the influence of regional seasonality and hydrologic conditions on agricultural runoff treatment wetlands still needs more investigation. A new approach, “wetlaculture,” has recently described as a …

Do Similar Exposure Groups (Seg) Differ From Air Force Base To Air Force Base? A Combat Arms Training And Maintenance (Catm) Noise Exposure Comparison Of Moody Afb And Macdill Afb., Miriam F. Escobar

USF Tampa Graduate Theses and Dissertations

Noise is a common hazard for the military. The Department of Defense has set an Occupational Exposure Limit for noise at 85 dBA. The Air Force manages exposures using similar exposure groups (SEGs) which are formed at each Air Force Base. The purpose of this study was to compare the noise levels in SEGs in two Air Force bases across distance and time, and to review the effectiveness of the Air Force Hearing Conservation Program over distance and time. The SEGs chosen were Combat Arms Training and Maintenance (CATM) at Moody Air Force Base and MacDill Air Force Base because …

Reimagining Bottom-Up Participatory Climate Change Adaptation In The Philippines, Emily Clark Nabong

USF Tampa Graduate Theses and Dissertations

While climate change trends indicate the progression towards more widespread and severe impacts across the world, current consequences of society’s climate inaction are already being felt by many vulnerable populations. Low-lying and coastal areas are particularly at risk from climate-related hazards such as sea level rise and increased intensity storms. In order to protect residents, countries and regional governments have begun to plan and implement adaptation strategies to minimize the impact of future climate change related disasters.

This thesis explores the current status of bottom-up participatory climate change adaptation planning in the Philippines and offers new insights into making this …

Identification Of Patterns And Disruptions In Ambient Sensor Data From Private Homes, Yan Wang

USF Tampa Graduate Theses and Dissertations

The world’s population is rapidly aging and the increasing demand for home and health care services from this aging population brings unprecedented challenges to the economy and society. Ambient-assisted smart homes, residences equipped with ambient sensors to monitor the resident’s daily activities in a continuous and unobtrusive way, present great potential to manage the growing care service needs of this older population segment, and enable them to age-in-place.

Despite growing research, using ambient sensor data from private homes to monitor daily activities, health and wellness still faces significant challenges. To study ambient sensor data from private homes where annotated data …

Design Of Support Measures For Counting Frequent Patterns In Graphs, Jinghan Meng

USF Tampa Graduate Theses and Dissertations

In recent years, the popularity of graph datasets has grown rapidly. Frequent subgraph mining (FSM) from graphs becomes an important subject in computer science research. In this dissertation, we study single-graph as an effective model to represent information and its related graph mining techniques. In frequent pattern mining in a single-graph setting, there are two main problems: support measure and search scheme. We study the development of support measures, which are basically functions that map a pattern to its frequency count in a database. Our work is based on the hypergraph framework using the concept of occurrence/instance hypergraphs. We present …

Breakthroughs In Obtaining Qm/Mm Free Energies, Phillip S. Hudson

USF Tampa Graduate Theses and Dissertations

The computation of free energy is pivotal to understanding the fundamental nature of chemical phenomena. That is, whether a specific molecular outcome occurs spontaneously or is inherently unfavorable. The need to do this with consistent accuracy begs for the use of quantum mechanical (QM) methods. However, techniques for directly computing free energy differences with QM or mixed QM/MM methods are untenable, as the computational expense is quite exorbitant. At present, the most feasible approach for obtaining QM/MM free energies is employing the so-called indirect cycle, which relies on accurately computing free energy differences between low (e.g., molecular mechanical, MM) and …

Service Provisioning And Security Design In Software Defined Networks, Mohamed Rahouti

USF Tampa Graduate Theses and Dissertations

Information and Communications Technology (ICT) infrastructures and systems are being widely deployed to support a broad range of users and application scenarios. A key trend here is the emergence of many different "smart" technology paradigms along with an increasingly diverse array of networked sensors, e.g., for smart homes and buildings, intelligent transportation and autonomous systems, emergency response, remote health monitoring and telehealth, etc. As billions of these devices come online, ICT networks are being tasked with transferring increasing volumes of data to support intelligent real-time decision making and management. Indeed, many applications and services will have very stringent Quality of …

Climate Change And Liberation In Latin America, Ernesto O. Hernández

USF Tampa Graduate Theses and Dissertations

The purpose of this dissertation is to propose the liberation movements in Latin America as alternative philosophical frameworks to the crisis of climate change. These movements have provided the grounds to identify inequities and injustices and have practiced ethical methodologies to overcome them. Additionally, the movements seek to represent and reflect the value of non-traditional philosophical agents in Latin America. The work focuses on four major Latin American ecological liberation movements; theology, philosophy, pedagogy, and feminism. Eco-Theology advances the role of Religion as the practice of Religação, reexamination, and resetting our relationship with nature by reconnecting with it. Eco-Philosophy of …

Growth And Characterization Of 2d Layered Materials, Algene Fryer Ii

USF Tampa Graduate Theses and Dissertations

2D layered materials are becoming an important area of research due to their exceptional electrical and optical properties. Specifically, 2D layered monochalcogenides are known for their high carrier motilities, whereas layered metal halides have been shown to have noteworthy photoresponsivity. Despite the assortment of 2D layered materials, the search for reliable and scalable synthesis methods is still a challenge in this family of materials. Often a certain growth technique will compromise a desirable trait needed for further fabrication, such as the quality of the crystal or its coverage on a substrate. In this study, two growth techniques that incorporate changeable …

Keyless Anti-Jamming Communication Via Randomized Dsss, Ahmad Alagil

USF Tampa Graduate Theses and Dissertations

Nowadays, wireless networking is ubiquitous. In wireless communication systems, multiple nodes exchange data during the transmission time. Due to the natural use of the communication channel, it is crucial to protect the physical layer to make wireless channels between nodes more reliable. Jamming attacks consider one of the most significant threats on wireless communication. Spread spectrum techniques have been widely used to mitigate the effects of the jammer. Traditional anti-jamming approaches like Frequency Hopping Spread Spectrum (FHSS) and Direct Sequence Spread Spectrum (DSSS) require a sender and a receiver to share a secret key prior to their communication. If this …

Artificial Intelligence Towards The Wireless Channel Modeling Communications In 5g, Saud Mobark Aldossari

USF Tampa Graduate Theses and Dissertations

Channel prediction is a mathematical predicting of the natural propagation of the signal that helps the receiver to approximate the affected signal, which plays an important role in highly mobile or dynamic channels. The standard wireless communication channel modeling can be facilitated by either deterministic or stochastic channel methodologies. The deterministic approach is based on the electromagnetic theories and every single object in that environment has to be known in that propagation space and an example of this method is ray tracing. While the stochastic modeling method is based on measurements that involve statistical distributions of the channel parameters and …

Post-Overlay Flexible Pavement Performance Modeling And Its Application In Sustainable Asphalt Overlay Policy Making, Chunfu Xin

USF Tampa Graduate Theses and Dissertations

Highway pavement is a critical component of the highway transportation infrastructure. After the construction of a pavement system, pavement condition will deteriorate over time due to a combination effect of material aging, traffic loading, and environmental impact. To restore the pavement performance and to reduce its adverse effects on public users and environment, asphalt overlay activities are conducted frequently during the service life of a pavement. As a key component that bridges the overlay policies with future pavement performance, economic cost and environmental impact, the forecast accuracy of post-overlay pavement performance model is extremely important. However, most of previous studies …

New Synthetic Methodology Using Base-Assisted Diazonium Salts Activation And Gold Redox Catalysis, Abiola Azeez Jimoh

USF Tampa Graduate Theses and Dissertations

Over the past two decades, homogeneous Au(I) catalysis has been a valuable synthetic tool for activating a series of unsaturated carbon-carbon bonds towards nucleophilic attack. Despite this progress, Au(I/III) redox chemistry has not been well explored. This is largely due to the challenges associated with the high oxidation potential of gold. Hence, the need for an efficient and safe method for Au oxidation.

Herein, a base-assisted diazonium salt activation has been used to facilitate Au redox reactions under mild reaction conditions. This oxidative coupling method afforded functional isoxazolines with good to excellent yields, while the alternative photoactivation method provided trace …

Composition Of Atomic-Obligation Security Policies, Danielle Ferguson

USF Tampa Graduate Theses and Dissertations

There has been significant work to date on policy-specification languages that allow specification of arbitrary obligations, but there continues to exist open challenges in the composition of these arbitrary obligations, especially when obligations can be complex (i.e. consist more than one action). There are currently no solutions that allow complete and automatic resolution of conflicts between policies and other policies' obligations or that allow policies to react to the complex obligations of other policies. In particular, there is minimal work that considers the benefits and challenges of allowing complex obligations that operate in an atomic fashion, that is that execute …

Models Of Secure Software Enforcement And Development, Hernan M. Palombo

USF Tampa Graduate Theses and Dissertations

Computer Security has been a pressing issue that affects our society in multiple ways. Although a plethora of security solutions have been proposed and implemented throughout the years, security continues to be a problem for at least two important reasons, (1) implementations of runtime enforcement mechanisms have not been modeled rigorously and thus may not be enforcing the policies that are expected to enforce, and (2) there are conflicting tensions in the software development process that hinder the implementation and maintenance of secure software. To investigate these issues, this dissertation is divided into two parts.

The first part of this …

Complexities Of Data, Tasks And Workflows In Health It Management, Gaurav Jetley

USF Tampa Graduate Theses and Dissertations

This dissertation focuses on three key aspects in health IT management: (1) Complexities in the collection of health data in electronic health record (EHR) systems and the use of EHR data in research, (2) Complexities of collaboration between physicians and AI for improving healthcare delivery, and (3) Complexities of workflows and collaborations between healthcare organization (HCO) staff during the delivery of care. The first dissertation essay (Chapter 1) examines the key data quality issues that arise in recorded health information in EHR systems, provides quality thresholds that the data needs to meet for mitigating errors and increasing reproducibility of downstream …

Developing Agent-Based Models To Study Financial Markets, Saurav Chakraborty

USF Tampa Graduate Theses and Dissertations

This dissertation presents research that employs agent-based modelling to provide a framework to support simulation as a complement to traditional economic models for policy evaluation. It consists of three studies. The first study employs cluster analysis to capture the different types of banks and the associated business models that define their decision-making. The results from study one will help us get an understanding of how different banks behave and provide an insight into their lending practices. Hence, it would be very helpful in evaluating and analyzing the impact of future policies. Study two develops a fine-grained interbank lending model based …

Functional Object-Oriented Network: A Knowledge Representation For Service Robotics, David Andrés Paulius Ramos

USF Tampa Graduate Theses and Dissertations

In this dissertation, we discuss our work behind the development of the functional object-oriented network (abbreviated as FOON), a graphical knowledge representation for robotic manipulation and understanding of its own actions and (potentially) the intentions of humans in the household. Based on the theory of affordance, this representation captures manipulations and their effects on actions through the coupling of object and motion nodes as fundamental learning units known as functional units. The activities currently represented in FOON are cooking related, but this representation can be extended to other activities that involve manipulation of objects which result in observable changes of …

Polycyclic Aromatic Hydrocarbon Exposure, Hepatic Accumulation, And Associated Health Impacts In Gulf Of Mexico Tilefish (Lopholatilus Chamaeleonticeps), Susan M. Snyder

USF Tampa Graduate Theses and Dissertations

Following the 2010 Deepwater Horizon oil spill, systematic demersal longline surveys were conducted throughout the Gulf of Mexico (GoM) continental shelf to evaluate polycyclic aromatic hydrocarbon (PAH) exposure, hepatic accumulation, and health indices in demersal fishes. Tilefish (Lopholatilus chamaeleonticeps) were chosen as a target species due to high vulnerability to environmental disturbance, commercial importance, Gulf-wide distribution, and documented high exposure to PAHs post-Deepwater Horizon. Over 200 Tilefish were sampled in the north central GoM at repeat stations from 2012 to 2017, and from the northwest GoM, southwest GoM, Bay of Campeche, and Yucatán Shelf over years 2015 and 2016. Tilefish …

Fields Brook Superfund Site: Race, Class, And Environmental Justice In A Blasted Landscape, Richard C. Bargielski

USF Tampa Graduate Theses and Dissertations

In 1980, the United States Congress passed the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA). This federal law provided the U.S. Environmental Protection Agency (EPA) with the legal tools necessary to pursue polluters who had improperly stored or disposed hazardous wastes. Since its passage, more than a thousand sites have been added to the National Priorities List (NPL), but only a fraction have been cleaned up. Proponents of neoliberalism argue that aggressive environmental policies such as CERCLA harm workers by making it impossible for businesses to operate profitably. This coincides with a drop of nearly 50% in the U.S. …

Large Thecosome Pteropods Of The Northern Gulf Of Mexico: Species Abundance, Spatial And Vertical Distribution With A Temporal Comparison Of Shell Thickness, Sarah M. Shedler

USF Tampa Graduate Theses and Dissertations

Large thecosome pteropods have a significant role in the pelagic ecosystem of the northern Gulf of Mexico (GoM). This research analyzed species abundances, vertical and horizontal distributions, and trends in shell thickness between 2011 and 2015. Pteropod samples were collected following the 2010 Deepwater Horizon oil spill by two midwater sampling programs: the Offshore Nekton Sampling and Analysis Program (ONSAP, 2011) and the Deep Pelagic Nekton Dynamics of the Gulf of Mexico (DEEPEND, 2015). All samples were collected using a 10-m2 Multiple Opening/Closing Net and Environmental Sensing System (MOC10) midwater trawl, with 3-mm mesh size. This gear sampled five discrete …

Spatiotemporal Changes Of Microbial Community Assemblages And Functions In The Subsurface, Madison C. Davis

USF Tampa Graduate Theses and Dissertations

The subsurface hosts diverse microbial community assemblages and functions. These communities play an important role in biogeochemical cycling and groundwater purification. Many physicochemical factors affect microbial communities and can cause short-term or long-term perturbations. Subsurface microbes are susceptible to anthropogenic changes in the environment, which can be caused by nutrient inputs or municipal groundwater extraction. Despite the importance of the subsurface microbiome, these microbial communities are poorly characterized. This dissertation describes the characterization of spatiotemporal drivers of subsurface microbial communities through a variety of techniques that include eDNA analyses, bioinformatics, hydrochemical analyses, stable isotope geochemistry, and multivariate statistics. Three coastal …

Laser-Induced Breakdown Spectroscopy For Elemental Analysis In Bioarchaeology And Forensic Anthropology, Kelsi N. Kuehn

USF Tampa Graduate Theses and Dissertations

Within bioarchaeology and forensic anthropology, the current processes of differentiating between individual human skeletal remains are imprecise, costly, and inefficient. A novel analytical technique within anthropology, laser-induced breakdown spectroscopy (LIBS) can aid in the identification of human remains using rapid laser ablation occurring at the micro-scale, making the technique virtually non-destructive to the sample. Considering this, LIBS could offer a superior method for materials discrimination and human identification. This research sought to examine whether LIBS can be used to obtain elemental signatures within bones to distinguish individuals from one another in a rapid, non-destructive manner. Seven human skeletal donors and …

Analyzing The Retention Of Knowledge Among General Chemistry Students, James T. Kingsepp

USF Tampa Graduate Theses and Dissertations

General chemistry is a survey course meant to form a foundation for students’ to build upon as they progress into chemistry sub-disciplines. The effectiveness of this foundation rests heavily on students’ abilities to retain or relearn concepts from the course. This study seeks to investigate the utility of a measure of general chemistry students’ knowledge retention across the time period of one semester. This approach was enacted in five different courses of either first or second semester general chemistry. The results showed that one-quarter to one-half of students exhibited a high rate of retention across the semester. A smaller group, …

Testing The Efficacy Of Recompression Tools To Reduce The Discard Mortality Of Reef Fishes In The Gulf Of Mexico, Oscar E. Ayala

USF Tampa Graduate Theses and Dissertations

In order to enhance the recovery of overfished stocks, fishery managers have implemented increasingly restrictive harvest regulations. However, discarded fish are susceptible to mortality from barotrauma when retrieved from depth. Venting tools are commonly used to enable fish to return to their depth of capture. An alternative method has been developed that involves the rapid descent of fish to their depth of capture to reduce buoyancy. In the Gulf of Mexico, the released portion of Red Snapper (Lutjanus campechanus) and Red Grouper (Epinephelus morio) has exceeded 80% of total catch. I tested the survival of these two economically important species …

Predictive Validity Of Standards-Based And Curriculum-Embedded Assessments For Predicting Readiness At Kindergarten Entry, Elizabeth Ashton Decamilla

USF Tampa Graduate Theses and Dissertations

As with traditional K-12 educational settings, early childhood assessments have been a primary source of information determining whether early educational experiences have promoted children’s readiness to start school in kindergarten. The level of use of Kindergarten Entry Assessments (KEAs) has become more wide-spread to establish levels of school readiness at kindergarten entry.

This quantitative, correlational study of children in schools that have blended Head Start/Voluntary Prekindergarten funded programs examined the predictive relationships between the independent variables (i.e., VPK Assessments and Teaching Strategies GOLD) and the dependent variable of kindergarten readiness, as measured by the Work Sampling System™ (WSS). Additionally, the …

Toward Culturally Relevant Emotion Detection Using Physiological Signals, Khadija Zanna

USF Tampa Graduate Theses and Dissertations

Research shows that emotional distress has a statistically significant impact on a student’s grade point average and intent to drop out of college. Because students of different races have varying college experiences, it is important to understand the emotional experiences of different racial groups to better support students’ needs and academic success. In this work, we explore several physiological responses to ten different emotional stimuli captured from 140 students. We employ unsupervised learning via the Density-Based Spatial Clustering of Applications with Noise (DBSCAN) algorithm and supervised learning via Random Forests and Support Vector machines to analyze clustering partitions and classification …

The Ecology And Conservation Of An Urban Karst Subterranean Estuary, Robert J. Scharping

USF Tampa Graduate Theses and Dissertations

Sulphur Springs is an artesian spring and part of the limestone karst topography of metropolitan Tampa, Florida, USA. Underlying this spring is an extensive cave system that hosts saltwater vents and conspicuous microbial biofilm communities. For decades, water from Sulphur Springs has been extracted and used to supplement public water supply and dry season flows in the Hillsborough River Estuary. This dissertation describes research conducted at Sulphur Springs to determine the impacts of urban land use on the underlying cave and downstream estuary ecosystems, and presents the use of this system as a model to fill certain ecological knowledge gaps. …

The Short-Term Effects Of Different Removal Methods Of Urochloa Maxima, Guinea Grass, On Acoustic Complexity, Connor D. Wagner

USF Tampa Graduate Theses and Dissertations

Invasive exotic species are one of the biggest threats to ecosystems in Florida, and land managers instill numerous methods to try and control them. Mechanical treatment, such as mowing, and chemical treatment, such as foliar spraying with the herbicide glyphosate, are two methods of invasive species removal. While the effectiveness of these management practices has been thoroughly observed and studied, little research has been done on their impacts to the ecological soundscape. The ecological soundscape refers to all biotic and abiotic sounds produced in the environment. Species presence and acoustic complexity was measured before and immediately following a mechanical and …

On The P(X)-Laplace Equation In Carnot Groups, Robert D. Freeman

USF Tampa Graduate Theses and Dissertations

In this thesis, we examine the p(x)-Laplace equation in the context of Carnot groups. The p(x)-Laplace equation is the prototype equation for a class of nonlinear elliptic partial differential equations having so-called nonstandard growth conditions. An important and useful tool in studying these types of equations is viscosity theory. We prove a p()-Poincar´e-type inequality and use it to prove the equivalence of potential theoretic weak solutions and viscosity solutions to the p(x)-Laplace equation. We exploit this equivalence to prove a Rad´o-type removability result for solutions to the p-Laplace equation in the Heisenberg group. Then we extend this result to the …