Physical Sciences and Mathematics Commons^™

Save Water Drink Wine: Challenges Of Implementing The Ethnography Of The Temecula Valley Wine Industry Into Food-Energy-Water Nexus Decision-Making, Zaida E. Darley

USF Tampa Graduate Theses and Dissertations

This study demonstrates the interrelationships of people, food, energy, and water associated with Temecula Valley’s wine industry and reveals contradictions and biases in how people view these resources, which ultimately shape management and policies. The FEW (Food, Energy, and Water) Nexus is an approach increasingly used by policy- and decision-makers to understand the interrelationship of several resources. However, a FEW Nexus approach often lacks in social aspects that influence environmentally and economically sustainable outcomes, especially in the wine and wine tourism industry. When quantitative and qualitative data are available, the other challenge is which assessment to use. Two assessments often …

A Novel Magnetic Respiratory Sensor For Human Healthcare, Kee Young Hwang

USF Tampa Graduate Theses and Dissertations

Breathing is vital to life. Therefore, the real-time monitoring of a patient’s breathing pattern is crucial to respiratory rehabilitation therapies such as magnetic resonance exams for respiratory-triggered imaging, chronic pulmonary disease treatment, and synchronized functional electrical stimulation. While numerous respiratory devices have been developed, they are often in direct contact with a patient, which can yield inaccurate or limited data. In this study, we developed a novel, non-invasive, and contactless magnetic sensing platform that can precisely monitor a patient’s breathing, movement, or sleep patterns, thus providing efficient monitoring at a clinic or home. A magneto-LC resonance (MLCR) sensor converts the …

Laser-Induced Modifications In Two-Dimensional Materials, Tariq Afaneh

USF Tampa Graduate Theses and Dissertations

Atomically thin two-dimensional (2D) materials have attracted a growing interest in the lastdecade from the fundamental point of view as well as their potential applications in functional devices. Due to their high surface-to-volume ratio, the physical properties of 2D materials are very sensitive to the environmental factor such as surrounding media and illumination conditions (e.g. light-mater interaction). In the first part of this dissertation I will present recent advances in developing laser-assisted methods to tune the physical properties of 2D transition metal dichalcogenides (TMDs). We demonstrate laser-assisted chemical modification ultrathin TMDs, locally replacing selenium by sulfur atoms. The photo-conversion process …

On Some Problems On Polynomial Interpolation In Several Variables, Brian Jon Tuesink

USF Tampa Graduate Theses and Dissertations

Polynomial approximation is a long studied process, with a history dating back to the 1700s, At which time Lagrange, Newton and Taylor developed their famed approximation methods. At that time, it was discovered that every Taylor projection (projector) is the pointwise limit of Lagrange projections. This leaves open a rather large and intriguing question, What happens in several variables?

To this end we define a linear idempotent operator to be an ideal projector whenever its kernel is an ideal. No matter the number of variables, Taylor projections and Lagrange projections are always ideal projectors, and it is well known that …

The Development Of Aapeptides, Lulu Wei

USF Tampa Graduate Theses and Dissertations

Non-natural peptide mimics are referred to as peptidomimetics, which contains unnatural backbones that mimic the primary peptide structure. There are a large number of peptidomimetics that have been developed including α-peptides, β-peptides, peptoids, arylamide oligomers, cationic polymers, and other peptidomimetics in the last decades. Compared to conventional peptides, these peptidomimetics have many advantages such as resistance to proteolysis, improved bioavailability, and reduced immunogenicity. However, the development of peptidomimetics is still far below the expectation due to the limitation of the availability of backbones. It is an urgent need to generate a new diverse library for novel drug discovery, design antimicrobial …

Analytical Methods And Critical Analyses Supporting Thermodynamically Consistent Characterizations Of The Marine Co2 System, Jonathan D. Sharp

USF Tampa Graduate Theses and Dissertations

Chemical equilibria describing the unique behavior of gaseous and ionic forms of dissolved carbon dioxide (CO₂) in seawater comprise what is known as the marine CO₂ (or carbonate) system. Observations of the marine CO₂ system with high degrees of accuracy, reproducibility, spatial coverage, and temporal resolution are critical for evaluating natural cycles of carbon within the Earth system, as well as chemical and biological responses to anthropogenic CO₂ emissions.

One component of the CO₂ system is the carbonate ion (CO²−₃), a dissolved ion that is produced when carbonic acid (H …

Multimodal Data Fusion And Attack Detection In Recommender Systems, Mehmet Aktukmak

USF Tampa Graduate Theses and Dissertations

The commercial platforms that use recommender systems can collect relevant information to produce useful recommendations to the platform users. However, these sources usually contain missing values, imbalanced and heterogeneous data, and noisy observations. Such characteristics render the process of exploiting the information nontrivial, as one should carefully address them during the data fusion process. In addition to the degenerative characteristics, some entries can be fake, i.e., they can be the outcomes of malicious intents to manipulate the system. These entries should be eliminated before incorporation to any recommendation task. Detecting such malicious attacks quickly and accurately and then mitigating them …

Unifying Security Policy Enforcement: Theory And Practice, Shamaria Engram

USF Tampa Graduate Theses and Dissertations

Security policies stipulate restrictions on the behaviors of systems to prevent themfrom behaving in harmful ways. One way to ensure that systems satisfy the constraints of a security policy is through the use of security enforcement mechanisms. To understand the fundamental limitations of such mechanisms, formal methods are employed to prove properties and reason about their behaviors. The particular formalism employed, however, typically depends on the time at which a mechanism operates.

Mechanisms operating before a program's execution are static mechanisms, and mechanisms operating during a program's execution are dynamic mechanisms. Static mechanisms are fundamentally limited in the types of …

Multifunctional Metal-Organic Frameworks (Mofs) For Applications In Sustainability, Gaurav Verma

USF Tampa Graduate Theses and Dissertations

Climate change, affordable and clean energy, and responsible consumption and production are some of the important goals to be achieved for sustainable development. The current technologies used to address these challenges are energy and resource intensive. Furthermore, there are various limitations related to cost, storage, scalability and safety.Adsorbent materials are seen as a promising alternative remediation system due to their low energy consumption and minimal chemical waste production. However, most of the traditional adsorbents, such as activated carbon and zeolites lack the structural tunability to have long-term effectiveness and their use is limited. As discussed in Chapter 1, metal organic-frameworks …

Digital Identity: A Human-Centered Risk Awareness Study, Toufic N. Chebib

USF Tampa Graduate Theses and Dissertations

Cybersecurity threats and compromises have been at the epicenter of media attention; their risk and effect on people’s digital identity is something not to be taken lightly. Though cyber threats have affected a great number of people in all age groups, this study focuses on 55 to 75-year-olds, as this age group is close to retirement or already retired. Therefore, a notable compromise impacting their digital identity can have a major impact on their life.

To help guide this study, the following research question was formulated, “What are the risk perceptions of individuals, between the ages of 55 and 75 …

Sustainable Non-Noble Metal Based Catalysts For High Performance Oxygen Electrocatalysis, Swetha Ramani

USF Tampa Graduate Theses and Dissertations

Current energy crisis has dramatically shifted the focus of technological advancements towards clean and renewable forms of energy. Continued dependence and utilization of fossil fuels has created global awareness on harmful greenhouse gas emissions and climate change. A need for sustainable technology has gained a lot of significance in the recent years. This has led to the development of devices and technologies that rely on environmentally friendly electrochemical conversion and storage of energy. One such advancement that generates electrical energy from chemical reactions is known as fuel cell technology. While fuel cells have demonstrated potential in replacing the conventional technologies …

The Use Of Spanish Moss As A Biological Indicator To Examine Relationships Between Metal Air Pollution, Vegetation Cover, And Environmental Equity In Tampa, Florida, Yousif Abdullah

USF Tampa Graduate Theses and Dissertations

Studies of inequality in exposure to less common air pollutants, like metals, are often limited by the costs of high spatial resolution measurements. Spanish moss (Tillandsia usneoides) is a promising bioindicator for measuring air pollution due to its lower cost, enabling capture of time-average environmental concentrations at high spatial resolution. This study had three major aims. First, I aimed to use Spanish moss as a bioindicator to characterize ambient concentrations of selected metals (Ti, Cr, Mn, Co, Ni, Cd, Hg, Pb, As, and Sb) in Tampa, Florida. My second goal was to determine the impact of vegetation cover on metals …

The Efficiency And Accuracy Of Yolo For Neonate Face Detection In The Clinical Setting, Jacqueline Hausmann

USF Tampa Graduate Theses and Dissertations

There are many face detection classification models available for download and use in the modern technological world. Based in the field of deep neural networks, these off-the-shelf solutions are generally inadequate to solve real world challenges. This work presents how current approaches biased towards detecting adult human faces must be modified in order to better accommodate face detection of the neonate in a NICU setting.

YOLO is a powerful object detection algorithm. Due to optimizations such as Cross mini-batch Normalization, Modified Spatial Attention Modules, Modified Path Aggregation Networks, Self-Adversarial Training, Mosaic Data Augmentation, DropBox Regularization, Multi-Input Weighted Residual Connections and …

Assessment And Integration Of Socioeconomic And Demographic Factors In The Implementation Of Integrated Water Resources Management In The Lake Chad Basin, Nodjidoumde Mbaigoto

USF Tampa Graduate Theses and Dissertations

Most developing countries have responded to the 2002 World Summit on Sustainable Development (WSSD) call to implement Integrated Water Resources Management (IWRM) in their national water policy to reach water sustainability and socioeconomic welfare. Despite the Lake Chad Basin Commission's adoption of the IWRM principles, the basin experiences a massive humanitarian crisis driven by the lake's shrinkage, the water shortage for food production, the rapid population growth, and the terrorist attacks perpetrated by Boko Haram. This study sought to assess the socioeconomic and demographic status of people living upstream of Lake Chad in order to understand the challenges associated with …

The Quantification Of Heavy Metals In Infant Formulas Offered By The Florida Wic Program, Naya Martin

USF Tampa Graduate Theses and Dissertations

Many infants rely on the WIC program to provide their main source of sustenance in theform of infant formula. In 2016, about 86% of the eligible infant population participated in this program. Infants in Florida account for about 30% of participation in the Southeast. For this reason, it is necessary to ensure that the formulas offered by this program provide the best opportunity for an optimal health outcome.

Exposure to heavy metals can have detrimental effects on the development of infants and children. Arsenic, lead, and cadmium specifically have been commonly found in certain types of infant formulas. Significant exposures …

Control Of A Human Arm Robotic Unit Using Augmented Reality And Optimized Kinematics, Carlo Canezo

USF Tampa Graduate Theses and Dissertations

There are more than 350000 amputees in the US who suffer loss of functionality in their daily living activities, and roughly 100000 of them are upper arm amputees. Many of these amputees use prostheses to compensate part of their lost arm function, including power prostheses. Research on 6-7 degree of freedom powered prostheses is still relatively new, and most commercially available powered prostheses are typically limited to 1 to 3 degrees of freedom. Due to the myriad of possible options for various powered protheses from different manufacturers, each configuration is governed by a distinct control scheme typically specific to the …

Humanistic Climate Philosophy: Erich Fromm Revisited, Nicholas Dovellos

USF Tampa Graduate Theses and Dissertations

Given the current juncture in history, humanity is faced with the herculean task of adapting to a tumultuous present and a gimmer future. Should climate projections be accurate, there is little time to waste. This work makes the claim that we are not only in a political gridlock but also in an academic one. Researching climate philosophy from its inception, the concluding view is that no major progress, outside of a standardized descriptive analysis, has been achieved. Thus, the work evaluates an array of climate philosophers e.g. Stephen Gardiner, James Garvey, Peter Singer, Walter Sinnott-Armstrong, etc., with specific emphasis on …

Using Geospatial Data To Predict The Locations Of Groundwater Discharge To Salmon-Bearing Streams, Alaska, Mary Gerlach

USF Tampa Graduate Theses and Dissertations

Identification and protection of groundwater resources are considerations of increasing interest as climate shifts but can be challenging to accomplish in remote areas. To that end, a series of GIS techniques and weight of evidence approach were applied to determine the feasibility of remotely identifying likely areas of ground discharge. Through the confluence of topographic analyses and a novel geologic dataset, these techniques were found to consistently identify areas characterized by either shallow subsurface or aquifer-fed groundwater discharge or evidence of ephemeral surficial water features. Two distinct GIS techniques to build spatial proxies of the effects of topography and geology …

Optimal Strategies For Grassland Restoration To Increase Spatial Carrying Capacity Of Florida Sandhill Cranes In Pasco County, Florida, Ibrahim Kaya

USF Tampa Graduate Theses and Dissertations

The Florida sandhill crane (Antigone canadensis pratensis) is a non-migratory bird species occurring throughout the Florida peninsula and the Okefenokee Swamp in southeastern Georgia. Human land-altering activities have led to a substantial decline in the amount and condition of suitable habitat, including grasslands, for the species in Florida, thereby decreasing the population size significantly. Grasslands located in close proximity to nesting locations are one of the habitat types on which the population viability of the species depends, as they provide foraging and brooding habitat which is crucial for successful reproduction. The purpose of this study is to propose the most …

Numerical Study Of Gap Distributions In Determinantal Point Process On Low Dimensional Spheres: L-Ensemble Of O(N) Model Type For N = 2 And N = 3, Xiankui Yang

USF Tampa Graduate Theses and Dissertations

Poisson point process is the most well-known point process with many applications. Unlike Poisson point process, which is the random set of non-intersecting points, determinantal point process refers to certain class of point processes where the points tend to interact with each other. The interaction often leads to more uniformly distributed points compared to those in Poisson point process.

In this article, we study the gap distribution of certain class of determinantal point process, L-ensemble of O(n) model type, and compare the distribution with the ones from the other known determinantal point process that appears in random matrices. Our numerical …

Using Tidal Analysis To Examine Lake-Aquifer Connectivity On A Modern Carbonate Platform, Ronald A. Knoll

USF Tampa Graduate Theses and Dissertations

Lake-aquifer connectivity on carbonate platforms is governed by basin morphology which is influenced by diagenetic and depositional processes. Both these processes cause aquifer permeability to vary significantly with scale of measurement (i.e., pore-scale, well-scale, and regional-scale). Because coastal aquifers are well-known to have tidally controlled water level fluctuations, inland lakes may be used to expand the areal measurement of permeability and establish a link between well-scale and regional scale connectivity in the aquifer. To evaluate the impact of lake basin morphology on aquifer connectivity, water level fluctuations were collected at high temporal resolution in the ocean and twenty-four surface water …

A Sustainability Machine: The Incineration-Based Waste Regime In Tampa, Fl, Usa, Kevin P. Martyn

USF Tampa Graduate Theses and Dissertations

Recent history has seen some significant changes in terms of how society thinks about and deals with its wastes. Increasingly troubling indications of the immediacy of ecological concerns, now often described by the Anthropocene concept, have been provocative of a reinvigorated fervor for a sustainability transition. As a result, sustainability has become well-established as both an urgent pursuit and an eminently pliable buzzword. This research describes and explains one key aspect of society’s pursuit of some version of sustainability: our relationship with waste.

The site of this research is Tampa, Florida, a sunbelt city with a unique waste management system. …

Current And Projected Sustainability Of The Water-Energy-Food Nexus In Caribbean Small Island Developing States, Zachary S. Winters

USF Tampa Graduate Theses and Dissertations

Within Latin American and the Caribbean (LAC), small island developing states (SIDS) of the latter are wholly reliant on their natural environments for their tourism-dependent economies yet are experiencing declining environmental health. These effects are exacerbated by Caribbean susceptibility to climate change and growing populations. With limited size, elevation, GDP, and water resources compared to Latin America, the subregion requires management and solutions tailored to the needs of each country. This study examined current and future sustainability of the Caribbean SIDS by assessing the nexus of water-energy-food (WEF) resources at the national level. In addition, the potential for nature-based solutions …

Design, Synthesis Of Axial Chiral Triazole, Jing Wang

USF Tampa Graduate Theses and Dissertations

This thesis contains three parts: 1) The briefly review of chiral P, N-ligands. 2) The summary of triazole as ligands. 3) The attempt of designing, synthesizing the chiral triazole ligands.

In the first part, we have reviewed all the major P, N-ligands in the history, including how they were synthesized and resolved into single enantiomer. We also used some examples to show their utility potential in different reactions.

In the second part, we summarized the triazole ligands which mainly developed by our group including their structures, their potential and utility in different types of chemical reactions.

In the last part, …

Covalent Organic Frameworks As An Organic Scaffold For Heterogeneous Catalysis Including C-H Activation, Harsh Vardhan

USF Tampa Graduate Theses and Dissertations

Linking small organic molecules into an extended solid usually afford disordered amorphous polymers. The instigation of order into such a material is of profound interest to induce inherent fine control of the overall structure. Covalent organic frameworks (COFs) are new class of porous crystalline material prepared by connecting organic building blocks via strong covalent bonds. The judicious choice of organic monomers can give rise to highly ordered and predictable frameworks with high crystallinity, surface area, and thermal/chemical stability. The role of connecting linkages such as B─O, C─C, C─N extends the principle of fundamental molecular covalent chemistry to the formation of …

Detecting Symptoms Of Chronic Obstructive Pulmonary Disease And Congestive Heart Failure Via Cough And Wheezing Sounds Using Smart-Phones And Machine Learning, Anthony Windmon

USF Tampa Graduate Theses and Dissertations

Chronic Obstructive Pulmonary Disease (COPD) and Congestive Heart Failure (CHF) are progressive disorders, and major health concerns among today’s aging population. COPD causes a large mucus buildup in the lungs, leading to chronic cough and difficulty to breathe. CHF causes fluid buildup in the lower lungs due to the failing heart, causing cough and difficulty to breath. People who are clinically diagnosed with COPD or CHF are expected to regularly monitor their symptoms and follow complex medical recommendations in an effort to prevent exacerbation. In this dissertation, we elaborate upon three different machine learning based techniques that we developed for …

Feature Selection Via Random Subsets Of Uncorrelated Features, Long Kim Dang

USF Tampa Graduate Theses and Dissertations

The role of feature selection is crucial in many applications. A few of these include computational biology, image classification and risk management. In biology, gene expression micro array data sets have been used extensively in many areas of research. These data sets typically suffer from an important problem: the ratio between the number of features over the number of examples is very high. This problem mainly affects prediction accuracy because it is best to collect more labeled examples than features. A correlation based random subspace ensemble feature selector (CCC_RSM) was proposed to handle this problem [5]. In this approach, first …

Establishing Topological Data Analysis: A Comparison Of Visualization Techniques, Tanmay J. Kotha

USF Tampa Graduate Theses and Dissertations

When visualizing data, we would like to convey both the data and the uncertainty associated with it. There are many incentives to do this, ranging from hurricane path projection to geographical surveys. Important decision making tasks rely upon humans perceiving a clear picture of the data and having confidence in their decisions. Topological Data Analysis has the potential to visualize the data as features or hierarchies in ways that are familiar to human intuition, and thus could help us convey the variation associated with uncertainty.

In this thesis, we evaluate four visualization techniques: color maps, isocontours, Reeb graphs, and persistence …

Development Of Ultrasonic-Based Ambient Desorption Ionization Mass Spectrometry, Linxia Song

USF Tampa Graduate Theses and Dissertations

Ambient desorption/ionization techniques (ADI) have drawn significant attention in mass spectrometric instrumentation development. The analyte classes that are successfully studied by any ADI mass spectrometry (MS) method strongly depends on how gas-phase ions are generated. Spray-based techniques may ionize molecules across a wide range of mass-to-charge ratios, but are commonly used for polar analyte, however, suffers from severe matrix effect. Contrastingly, methods employing electric (or laser) plasmas are capable of ionization of polar and nonpolar analytes suffering from less matrix effect, but primarily targeting those with low molecular masses. Thus far, developments of universal ionization methods, which do not depend …

Understanding The Complex Ethical Landscape Of Artificial Intelligence Adoptions, Chrissann R. Ruehle

USF Tampa Graduate Theses and Dissertations

Although Artificial Intelligence (AI) has existed since the 1950’s, it has experienced a series of expansions and declines over the years. Currently, AI is on an upward trajectory and has prompted the fourth industrial revolution as many scientists have noted. Some firms have rapidly embraced this technology and experienced growth while others have been slow to adopt. Naturally, this expansion often has societal impacts. The aim of this study is to explore ethical considerations that arise during the adoption of this technology. This research addressed three questions: 1. How do market and regulatory forces reportedly shape Artificial Intelligence adoptions? 2. …