Physical Sciences and Mathematics Commons^™

Simplified Methodology For Designing Parabolic Trough Solar Power Plants, Ricardo Vasquez Padilla

USF Tampa Graduate Theses and Dissertations

The performance of parabolic trough based solar power plants over the last 25 years has proven that this technology is an excellent alternative for the commercial power industry. Compared to conventional power plants, parabolic trough solar power plants produce significantly lower levels of carbon dioxide, although additional research is required to bring the cost of concentrator solar plants to a competitive level. The cost reduction is focused on three areas: thermodynamic efficiency improvements by research and development, scaling up of the unit size, and mass production of the equipment. The optimum design, performance simulation and cost analysis of the parabolic …

Probing Molecules In Confined Space, Carissa Marie Vetromile

USF Tampa Graduate Theses and Dissertations

Despite the plethora of information regarding cellular crowding and its importance on modulating protein function the effects of confinement on biological molecules are often overlooked when investigating their physiological function. Recently however, the encapsulation of biomolecules in solid state matrices (NafionTM, sol-gels, zirconium phosphate,etc.) has increased in importance as a method for examining protein conformation and dynamics in confined space as well as novel applications in biotechnology. Biotechnological applications include, but are not limited to, bioremediation, biosensors, biocatalysts, etc. In order to better utilize solid state materials as substrates for biological molecules an understanding of the effects of encapsulation on …

Modeling Direct Runoff Hydrographs With The Surge Function, Denis Voytenko

USF Tampa Graduate Theses and Dissertations

A surge function is a mathematical function of the form f(x)=ax^pe^-bx. We simplify the surge function by holding p constant at 1 and investigate the simplified form as a potential model to represent the full peak of a stream discharge hydrograph. The previously studied Weibull and gamma distributions are included for comparison. We develop an analysis algorithm which produces the best-fit parameters for every peak for each model function, and we process the data with a MATLAB script that uses spectral analysis to filter year-long, 15-minute, stream-discharge data sets. The filtering is necessary to locate the …

Assessment Of Fertility Potential In Bottlenose Dolphins (Tursiops Truncatus): An Elisa-Based Biomarker Analysis, Leslie Schwierzke Wade

USF Tampa Graduate Theses and Dissertations

As apex predators in coastal systems, bottlenose dolphins (Tursiops truncatus) are susceptible to persistent organic pollutant (POP) accumulation and retention over time, which has prompted continued interest in understanding the extent to which contaminant body burdens or other stressors are sufficient to cause adverse sublethal effects on energetic fitness, immune function, or reproduction. Increasing our knowledge of reproductive endocrinology in bottlenose dolphins may provide insight into changes in reproductive rates, thereby expanding the capacity to assess conservation status. This study used the Enzyme-Linked ImmunoSorbent Assay (ELISA) technique to examine peptide fertility hormones [inhibin A, inhibin B and anti-Müllerian …

Dynamics Of Stony Coral Assemblages On Patch Reefs Of The Upper Florida Reef Tract, Including Biscayne National Park, Amy Wallace

USF Tampa Graduate Theses and Dissertations

The patch reefs located in Biscayne National Park (BNP) are some of the most northern reefs of the Florida reef system. The focus of my study is seven patch reefs that were first surveyed annually between 1977 and 1981, revealing 8% - 28% cover by scleractinian corals. An assessment of BNP patch reefs completed in 2000 reported that coral cover had decreased to approximately 0.4% - 10%. The once dominant species in the Florida reef tract, Acropora palmata and A. cervicornis, have rapidly declined over time and were not found in any transects during the 2000 survey.

This study is …

Statistical Models For Environmental And Health Sciences, Yong Xu

USF Tampa Graduate Theses and Dissertations

Statistical analysis and modeling are useful for understanding the behavior of different phenomena. In this study we will focus on two areas of applications: Global warming and cancer research. Global Warming is one of the major environmental challenge people face nowadays and cancer is one of the major health problem that people need to solve.

For Global Warming, we are interest to do research on two major contributable variables: Carbon dioxide (CO2) and atmosphere temperature. We will model carbon dioxide in the atmosphere data with a system of differential equations. We will develop a differential equation for each of six …

Sex And The Seas: Gene Transfer Agents, Elizabeth Young

USF Tampa Graduate Theses and Dissertations

Gene Transfer Agents (GTAs) are phage-like pthesiss that are produced by many alpha proteobacteria in late stationary growth phase and are capable of transferring chromosomal genes (termed "constitutive transduction"). Examination of alpha proteobacterial genomic sequences indicated widespread occurrence of GTA-like elements. The goal of this study was to investigate gene transfer potential of GTAs of marine alpha proteobacteria in culture as well as in natural marine environments. Another goal was to determine the potential of bacterial symbionts from zooxanthellae and coral to genetically transfer beneficial properties between symbionts. Ruegeria mobilis (ID 45A6) was isolated from cultures of the coral endosymbiotic …

An Examination Of The Impacts Of Urbanization On Green Space Access And Water Resources: A Developed And Developing World Perspective, Heather E. Wright Wendel

USF Tampa Graduate Theses and Dissertations

This dissertation addresses the impact of urbanization and land use change on the availability and accessibility of two urban amenities that are often inequitably distributed: green space and water features. Diverse methodologies were utilized in order to gain a better understanding of the role of these amenities in improving urban quality of life and integrated water management. Using an interdisciplinary approach, this research provides a unique perspective within both a developed and developing world context by evaluating aspects of urbanization to emphasize more sustainable and integrated approaches to development.

A preliminary analysis highlights potential drivers of green space revitalization in …

Alternative Statistical Methods For Analyzing Geological Phenomena: Bridging The Gap Between Scientific Disciplines, Joseph Frank Van Gaalen

USF Tampa Graduate Theses and Dissertations

When we consider the nature of the scientific community in conjunction with a sense of typical economic circumstances we find that there are two distinct paths for development. One path involves hypothesis testing and evolution of strategies that are linked with iterations in equipment advances. A second, more complicated scenario, can involve external influences whether economic, political, or otherwise, such as the government closure of NASA's space program in 2011 which will no doubt influence research in associated fields. The following chapters are an account of examples of two statistical techniques and the importance of both on the two relatively …

A Comparison Of Ecological Conditions And Relationships In An Altered Wetland And An Unaltered Wetland, Mark Kiyoshi Hurst

USF Tampa Graduate Theses and Dissertations

The purpose of the study is to identify and quantify the hydrologic and ecologic differences between two adjacent sections of Colt Creek; one section unaltered and one section altered by clearing and drainage. These differences were measured by monitoring water levels, groundcover vegetation in each of the two areas, and monitoring numbers and species of birds utilizing the two areas. Surface water levels were measured in three locations: in the historic Colt Creek flow way, in the ditch draining the creek, and in an adjacent wetland strand. In addition, a shallow monitor well in the creek was used to measure …

Growth And Characterization Of Thermoelectric Ba8Ga16Ge30 Type-I Clathrate Thin-Films Deposited By Pulsed Dual-Laser Ablation, Robert Harry Hyde

USF Tampa Graduate Theses and Dissertations

The on-going interest in thermoelectric (TE) materials, in the form of bulk and films, motivates investigation of materials that exhibit low thermal conductivity and good electrical conductivity. Such materials are phonon-glass electron-crystals (PGEC), and the multi-component type-I clathrate Ba₈Ga₁₆Ge₃₀ is in this category. This work reports the first investigation of Ba₈Ga₁₆Ge₃₀ films grown by pulsed laser deposition (PLD).

This dissertation details the in-situ growth of polycrystalline type-I clathrate Ba₈Ga₁₆Ge₃₀ thin-films by pulsed laser ablation. Films deposited using conventional laser ablation produced films that contained a …

Combining Natural Language Processing And Statistical Text Mining: A Study Of Specialized Versus Common Languages, Jay Jarman

USF Tampa Graduate Theses and Dissertations

This dissertation focuses on developing and evaluating hybrid approaches for analyzing free-form text in the medical domain. This research draws on natural language processing (NLP) techniques that are used to parse and extract concepts based on a controlled vocabulary. Once important concepts are extracted, additional machine learning algorithms, such as association rule mining and decision tree induction, are used to discover classification rules for specific targets. This multi-stage pipeline approach is contrasted with traditional statistical text mining (STM) methods based on term counts and term-by-document frequencies. The aim is to create effective text analytic processes by adapting and combining individual …

Minimal And Symmetric Global Partition Polynomials For Reproducing Kernel Elements, Mario Jesus Juha

USF Tampa Graduate Theses and Dissertations

The Reproducing Kernel Element Method is a numerical technique that combines finite element and meshless methods to construct shape functions of arbitrary order and continuity, yet retains the Kronecker-δ property. Central to constructing these shape functions is the construction of global partition polynomials on an element. This dissertation shows that asymmetric interpolations may arise due to such things as changes in the local to global node numbering and that may adversely affect the interpolation capability of the method. This issue arises due to the use in previous formulations of incomplete polynomials that are subsequently non-affine invariant. This dissertation lays out …

Biodegradation Of Bisphenol-A And 17b-Estradiol In Soil Mesocosms Under Alternating Aerobic/Anoxic/Anaerobic Conditions, Won-Seok Kim

USF Tampa Graduate Theses and Dissertations

Soil-aquifer treatment (SAT) has been proposed as a method for reusing treated municipal wastewater. SAT is characterized by alternating cycles of aerobic and anaerobic conditions in the subsurface, in response to alternating cycles of flooding and drainage of a surface impoundment. It is not yet known how these alternating redox conditions affect the removal of potentially harmful endocrine-disrupting compounds (EDCs) from treated effluent.

The overall objective of my doctoral research is to determine the fate of EDCs in alternating aerobic/anoxic/anaerobic conditions under simulated SAT conditions. To assess the fate of EDCs in simulated SAT conditions, I first had to develop …

Gender Differences In Lung Cancer Treatment And Survival, Margaret Anne Kowski

USF Tampa Graduate Theses and Dissertations

The objectives of this research were to test treatment and survival differences between women and men with lung cancer as there is minimal investigation in the literature. Three research questions were developed with statistical testing for gender differences based on similar cancer type, stage, treatment assignment and survival. Data for 44,863 primary lung cancer cases were collected from eight U.S. state-based cancer registries to investigate the research questions. The lung cancer incidence data included the morphological cell-types of adenocarcinoma (AC); squamous cell carcinoma (SCC); large cell carcinoma (LCC) and small cell carcinoma (SCC). Stage, grade, treatment type, as well as, …

High-Resolution Event Stratigraphy Of Mm-Scale Laminated Sediments From Coastal Salt Ponds: St. John, Us Virgin Islands, Rebekka Amie Larson

USF Tampa Graduate Theses and Dissertations

A multi-proxy approach is utilized on mm- to cm-scale laminated sediment records in coastal salt ponds on St. John, U.S. Virgin Islands to characterize the sediments, identify their sources and depositional processes/events (heavy rainfall, tropical cyclones, tsunamis). Historical records are combined with high-resolution geochronology (short-lived radioisotopes, ²¹⁰Pb, ¹³⁷Cs, ⁷Be) and scanning elemental techniques (XRF and LA-ICP-MS) to link depositional events to how they are manifested in the sedimentary record. Volcanic rocks are the terrigenous sediment source and the sedimentary signature of terrigenous sediment in the geologic record consists of higher amounts of Al, Fe, Ti, Co, and …

Assessment Of The Dependence Of Ventilation Image Calculation From 4d-Ct On Deformation And Ventilation Algorithms, Kujtim Latifi

USF Tampa Graduate Theses and Dissertations

Ventilation imaging using 4D-CT is a convenient and cost effective functional imaging methodology which might be of value in radiotherapy treatment planning to spare functional lung volumes. To calculate ventilation imaging from 4D-CT we must use deformable image registration (DIR). This study validates the DIR methods and investigates the dependence of calculated ventilation on DIR methods and ventilation algorithms.

The first hypothesis is if ventilation algorithms are robust then they will be insensitive to the precise DIR used provided the DIR is accurate. The second hypothesis is that the change in Houndsfield Unit (HU) method is less dependent on the …

Usf's Coverage Of Women's Athletics: A Census Of The Usf Athletics Home Web Page, Laura Ann Lebeau

USF Tampa Graduate Theses and Dissertations

This study examines the coverage of women’s athletics at USF provided through photographic representations on the university’s Athletics Internet home web page during the 2009–2010 academic year. Findings from this census of five areas that comprise the USF Athletics Internet home web page revealed that, consistent with recent research on coverage of female athletes and women’s athletics on university web pages, women, compared to men, were underrepresented in the majority of the five areas of the home page analyzed. The difference in the number of overall total photographs of women and men was not that large—48% and 52%, respectively, not …

Road-Based Landscape Metrics For Quantifying Habitat Fragmentation, Rebecca Whitehead Loraamm

USF Tampa Graduate Theses and Dissertations

Landscape metrics measure the composition and configuration of habitats within landscapes; often the goal is to measure fragmentation. While a variety of existing metrics characterize the connectivity and contiguity of habitat patches, most do not explicitly consider the fragmenting effects of roads in their formulations. This research develops a set of new landscape metrics that explicitly quantify how roads disconnect and break apart habitat patches. This research introduces the following four metrics to consider the fragmenting effects of transportation networks: (1) Number of Connected Patches, a measure of connectivity; (2) Euclidean Nearest Neighbor-Roads, a measure of proximity; (3) Road Density, …

A Study Of Complex Systems: From Magnetic To Biological, Douglas Carroll Lovelady

USF Tampa Graduate Theses and Dissertations

This work is a study of complex many-body systems with non-trivial interactions. Many such systems can be described with models that are much simpler than the real thing but which can still give good insight into the behavior of realistic systems. We take a look at two such systems. The first part looks at a model that elucidates the variety of magnetic phases observed in rare-earth heterostructures at low temperatures: the six-state clock model. We use an ANNNI-like model Hamiltonian that has a three dimensional parameter space and yields two-dimensional multiphase regions in this space. A low-temperature expansion of the …

Problems In Classical Potential Theory With Applications To Mathematical Physics, Erik Lundberg

USF Tampa Graduate Theses and Dissertations

In this thesis we are interested in some problems regarding harmonic functions. The topics are divided into three chapters.

Chapter 2 concerns singularities developed by solutions of the Cauchy problem for a holomorphic elliptic equation, especially Laplace's equation. The principal motivation is to locate the singularities of the Schwarz potential. The results have direct applications to Laplacian growth (or the Hele-Shaw problem).

Chapter 3 concerns the Dirichlet problem when the boundary is an algebraic set and the data is a polynomial or a real-analytic function. We pursue some questions related to the Khavinson-Shapiro conjecture. A main topic of interest is …

Underwater Hearing In The Loggerhead Turtle (Caretta Caretta): A Comparison Of Behavioral And Auditory Evoked Potential Audiograms, Kelly Martin

USF Tampa Graduate Theses and Dissertations

Methods for collecting behavioral audiograms are often time consuming and require trained, captive subjects. It is more practical to measure hearing sensitivity using electrophysiological methods, such as auditory evoked potential (AEP) testing, in which electrodes measure action potentials in response to acoustic stimuli. These data can be collected in a matter of hours. However, results should be verified through behavioral testing. Current knowledge of marine turtle auditory abilities is based on a few electrophysiological tests. The purpose of this study was to collect and compare behavioral and auditory evoked potential audiograms in a captive adult loggerhead turtle (Caretta caretta …

Urbanization And Land Surface Temperature In Pinellas County, Florida, Bruce Coffyn Mitchell

USF Tampa Graduate Theses and Dissertations

Since the early 1800's, many studies have recognized increased heat in urban areas, known as the urban heat island (UHI) effect, as one of the results of human modification to the natural landscape. UHI is related to differences in land surface temperature (LST) between rural areas and urban areas where factors of the built environment such as the thermodynamic capacities of materials, structural geometry, and heat generating activities cause increased storage and re-radiation of heat to the atmosphere. This thesis examines the correlation between factors of urbanization and differences in land surface temperature (LST) in the subtropical climate of Pinellas …

Parametric And Bayesian Modeling Of Reliability And Survival Analysis, Carlos A. Molinares

USF Tampa Graduate Theses and Dissertations

The objective of this study is to compare Bayesian and parametric approaches to determine the best for estimating reliability in complex systems. Determining reliability is particularly important in business and medical contexts. As expected, the Bayesian method showed the best results in assessing the reliability of systems.

In the first study, the Bayesian reliability function under the Higgins-Tsokos loss function using Jeffreys as its prior performs similarly as when the Bayesian reliability function is based on the squared-error loss. In addition, the Higgins-Tsokos loss function was found to be as robust as the squared-error loss function and slightly more efficient. …

Environmental Health In The Latin American And Caribbean Region: Use Of Water Storage Containers, Water Quality, And Community Perception, Erlande Omisca

USF Tampa Graduate Theses and Dissertations

Water quality and availability are important issues in many developing countries where portions of populations still lack access to potable water. Throughout the English-speaking Caribbean and parts of Latin America, households and businesses invest in water supply systems even when they are connected to and pay for water services from a private or state owned provider. Inconsistent supplies of water from the water companies have led many people to invest in storage tanks which, if operated correctly, can provide water throughout the day even when the supply from the main is low or zero. While these individual systems help to …

Evaluating The Effectiveness Of Irrigation Restrictions Within Key Communities In Tampa, Florida, Lin Allen Ozan

USF Tampa Graduate Theses and Dissertations

The City of Tampa, Florida has instituted water restrictions over the past decade that have been primarily aimed at mitigating non-essential usage of water resources by limiting domestic lawn irrigation. The mandatory restrictions are enforced by the issuance of citations to violators, which is intended to promote compliance and deter from subsequent violations. This thesis provides a thorough investigation of historical water restriction with relation to compliance in order to determine which factors might be related to high rates of water usage within key Tampa communities. The objectives are to: (1) develop a GIS data set that can be used …

Sol-Gel Resorcinarene Sorbent For Capillary Microextraction Coupled To Gas Chromatography, Abdullah Awadh Alhendal

USF Tampa Graduate Theses and Dissertations

For the first time, octahydroxyl methylresorcinarene with four hexyl groups on the lower rim was utilized in the in-situ preparation of a silica-based sol-gel organicinorganic hybrid coating for sample preconcentration by capillary microextraction (CME). Tetraethoxysilane (TEOS) was chosen as a sol-gel precursor to create a crosslinked sol-gel network via acid-catalyzed hydrolytic polycondensation reactions. Sol-gel chemistry helped in the in situ preparation of resorcinarene-containing extraction phase in the form of a surface coating. It also provided an effective means to chemically bind the coating to the inner surface of fused silica capillary via condensation of the hydroxyl groups in the sol-gel …

Synthesis And Characterization Of Self-Healing Poly (Carbonate Urethane) Carbon-Nanotube Composites, Roger Wesley Bass

USF Tampa Graduate Theses and Dissertations

Synthesis of high molar mass polycarbonate polyurethanes using a novel polyol is described. The resulting elastomers demonstrate excellent mechanical properties as well as the capability to re-heal after rupture without the addition of additives or imbedded healing agents. The self-healing functionality is shown to greatly improve with the addition of up to 1% single and multi-walled carbon nanotubes. The interface of the carbon nanotubes and self-healing polymer are probed using Raman techniques and provide an insight into how the self-healing actions are improved with the addition of carbon nanotubes.

Synthesis of polycarbonate polyurethanes and carbon nanotube composites using a novel …

Stable Isotope Studies Of Paleoenvironment And Paleoclimate From Afar, Ethiopia, Zelalem K. Bedaso

USF Tampa Graduate Theses and Dissertations

The sedimentary deposits of the Hadar Formation at Dikika and the Mount Galili Formation at Galili preserve a wealth of paleoenvironmental and paleoclimatic records spanning the last 5.29 Ma. Stable carbon and oxygen isotopic compositions of herbivore tooth enamel were analyzed for more than 600 specimens of 15 different taxa from 10 stratigraphic intervals. The application of carbon and oxygen isotopes here aims principally at reconstructing shifts in the relative abundance of C₄ grasses, and its implications for climate indicators including temperature, aridity, and seasonality. The full range of δ¹³C_enamel values throughout the Plio-Pleistocene signifies a …

Initial Ablation Of The Laurentide Ice Sheet Based On Gulf Of Mexico Sediments, Elizabeth A. Brown

USF Tampa Graduate Theses and Dissertations

The objective of this project is to reconstruct a picture of initial Laurentide Ice Sheet retreat at the end of the Last Glacial Maximum (LGM) using geochemical proxies in Gulf of Mexico sediments, and place the reconstruction into global perspective. The project asks two questions. (1) Can a time frame be established for initial retreat of the Laurentide Ice Sheet? (2) If so, how does the timing compare to that of other large ice sheets and mountain glaciers in both hemispheres?

Sediment core MD02-2550 from the anoxic Orca Basin offers excellent preservation and a high sediment accumulation rate. Twelve accelerator …