Physical Sciences and Mathematics Commons^™

Crystal Engineering Of Functional Metal-Organic Material Platforms For Gas Storage And Separation Applications, Sameh Khamis Elsaidi

USF Tampa Graduate Theses and Dissertations

Metal-organic materials (MOMs) represent a unique class of porous materials that captured a great scientific interest in various fields such as chemical engineering, physics and materials science. They are typically assembled from metal ions or metal clusters connected by multifunctional organic ligands. They represent a wide range of families of materials that varied from 0D to 3D networks: the discrete (0D) structures exemplified by metal-organic polyhedra (MOPs), cubes and nanoballs while the polymeric 1D, 2D and 3D structures exemplified by coordination polymers (CPs). Indeed, the porous 3D structures include metal-organic frameworks (MOFs), porous coordination polymers (PCPs) and porous coordination networks …

Characterization Of The Depositional Environment Of Phreatic Overgrowths On Speleothems In The Littoral Caves Of Mallorca (Spain): A Physical, Geochemical, And Stable Isotopic Study, Liana Marie Boop

USF Tampa Graduate Theses and Dissertations

Phreatic overgrowths on speleothems (POS) are one of many sea-level proxies available to Quaternary geologists in Mallorca; these carbonate encrustations form at the air-water interface in cave passages flooded with brackish water. POS are ideal for reconstruction of western Mediterranean sea level because they are widespread in Mallorca's caves, can be precisely dated by U-series methods, constrain sea-level stands to sub-meter elevation, and are well preserved and accessible in the subterranean environment.

This research investigates the POS depositional environment, which is relatively understudied compared to the other proxies used for sea-level reconstructions. This disparity has led to assumptions on many …

Managing Regional Water Resources Amidst Rapid Urbanization In Southwest Florida: A Case Study, Nicole Owusua Caesar

USF Tampa Graduate Theses and Dissertations

Experts and organizations involved in freshwater resources management have emphasized the importance of long-term urban resource planning and management that considers the tight coupling which exists between human - nature - technology systems. The resistance of contemporary urban growth efforts to consider resource carrying capacities and ecosystem requirements has led to costly unintended consequences including the deterioration of natural capital and their associated ecosystem services, and the degradation of water resource flows. As these problems continue to worsen, resource experts have called for the development of a new water resource management paradigm inclusive of various sustainability criteria.

Historically water-rich Florida …

Opuntia Ficus-Indica Mucilage Potential To Remove Nuclear Active Contaminants From Water Based On A Surrogate Approach, Jose Adan Leon

USF Tampa Graduate Theses and Dissertations

Potable water is a necessity and unfortunately, it can be contaminated in many different ways. This paper specifically addresses the case scenario when, water has been contaminated by radionuclides. The mucilage of Opuntia ficus-indica (OFI), has been proven to be a great flocculating agent, turbidity reducer, crude oil dispersant and an environmentally friendly substance as an absorbent of water contaminants. In this work, the OFI mucilage was investigate to evaluate its capacity to separate radioactive ions from water. The surrogate approach is modeled based on water studies performed by Willi A. Brand, who proved that radioactive isotopes behave similar to …

Connecting Institutional Discourses And Everyday Understandings Of Climate Change: Viewpoints From A Suburban Neighborhood In Tampa, Florida, Christopher Metzger

USF Tampa Graduate Theses and Dissertations

Despite a general consensus regarding anthropogenic global climate change across the international scientific community, many of the major greenhouse gas producers in the world, especially the United States, are hesitant to implement strict emissions regulations. According to some prominent atmospheric scientists, such as James Hansen and Michael Mann, if industrialized countries continue to produce carbon emissions at current rates, an irreversible planetary tipping point of raising temperatures 2°C above pre-industrial levels could be reached in less than 40 years. Societies have a wealth of information from the natural sciences to understand the climate problem and currently possess the technological means …

Statistical Modeling And Prediction Of Hiv/Aids Prognosis: Bayesian Analyses Of Nonlinear Dynamic Mixtures, Xiaosun Lu

USF Tampa Graduate Theses and Dissertations

Statistical analyses and modeling have contributed greatly to our understanding of the pathogenesis of HIV-1 infection; they also provide guidance for the treatment of AIDS patients and evaluation of antiretroviral (ARV) therapies. Various statistical methods, nonlinear mixed-effects models in particular, have been applied to model the CD4 and viral load trajectories. A common assumption in these methods is all patients come from a homogeneous population following one mean trajectories. This assumption unfortunately obscures important characteristic difference between subgroups of patients whose response to treatment and whose disease trajectories are biologically different. It also may lack the robustness against population heterogeneity …

Chiral Phosphoric Acids And Alkaline Earth Metal Phosphates Chemistry, Tao Liang

USF Tampa Graduate Theses and Dissertations

Asymmetric synthesis and catalysis is one of the leading research areas in chemistry society, for its versatility and efficiency in obtaining chiral molecules that found the vast majority in natural active compounds and synthetic drugs. Developing asymmetric catalytic methodology is at the frontier in both industrial and academic research laboratories. Enantioselective organocatalysis has emerged as a powerful synthetic tool that is complementary to metal-catalyzed transformations. The development of chiral phosphoric acid and metal phosphate as catalysts has been a breakthrough in recent years. Chiral phosphoric acids have been shown to be powerful catalysts in many organic transformations. Moreover, chiral metal …

Assessing The Environmental Justice Implications Of Flood Hazards In Miami, Florida, Marilyn Christina Montgomery

USF Tampa Graduate Theses and Dissertations

While environmental justice (EJ) research in the U.S. has traditionally focused on inequities in the distribution of technological hazards, the disproportionate impacts of Hurricane Katrina on racial minorities and socioeconomically disadvantaged households have prompted researchers to investigate the EJ implications of natural hazards such as flooding. Recent EJ research has also emphasized the need to examine social inequities in access to environmental amenities. Unlike technological hazards such as air pollution and toxic waste sites, areas exposed to natural hazards such as hurricanes and floods have indivisible amenities associated with them. Coastal property owners are exposed to flood hazards, but also …

Interpolating Beach Profile Data Using Linear And Non-Linear Functions, Lance Calloway Croft

USF Tampa Graduate Theses and Dissertations

ABSTRACT

Beach and nearshore surveys are conducted in a variety of ways, the most commonly used being the level-and-transit method; because it is inexpensive, time conducive and highly accurate. Specifically, beach surveys are conducted to better understand cross-shore, long-shore sediment transport processes, as well as to quantify volume changes, which are used to evaluate beach performance. In this study, a section of the beach on Sand Key, FL was surveyed using rod-and-transit. In addition to the commonly used linear data analysis, a non-linear analysis was conducted using NURBS (Non-Uniform Rational B-Splines).

Survey data was collected within a short time window …

Timing Of Svalbard/Barents Sea Ice Sheet Decay During The Last Glacial Termination, Tasha Snow

USF Tampa Graduate Theses and Dissertations

The Arctic and North Atlantic underwent significant climactic changes since the Last Glacial Maximum (25,000 years before present (1950 AD); ka BP), but offsets in the timing of events between the two regions are poorly constrained due to age model uncertainties that arise from changing radiocarbon reservoir ages. Here, we use a relatively high-resolution, multi-proxy stable isotope and sedimentologic dataset from Eastern Fram Strait (ODP Leg 162 Site 986) marine sediments to constrain the timing of Svalbard/Barents Sea Ice Sheet decay and infer deglacial reservoir ages over the last 30 ka. We use magnetic susceptibility, inorganic and organic carbon, foraminiferal …

Organic Fluids And Passive Cooling In A Supercritical Rankine Cycle For Power Generation From Low Grade Heat Sources, Rachana Vidhi

USF Tampa Graduate Theses and Dissertations

Low grade heat sources have a large amount of thermal energy content. Due to low temperature, the conventional power generation technologies result in lower efficiency and hence cannot be used. In order to efficiently generate power, alternate methods need to be used. In this study, a supercritical organic Rankine cycle was used for heat source temperatures varying from 125°C to 200°C. Organic refrigerants with zero ozone depletion potential and their mixtures were selected as working fluid for this study while the cooling water temperature was changed from 10-25°C. Operating pressure of the cycle has been optimized for each fluid at …

Recursive Methods In Number Theory, Combinatorial Graph Theory, And Probability, Jonathan Burns

USF Tampa Graduate Theses and Dissertations

Recursion is a fundamental tool of mathematics used to define, construct, and analyze mathematical objects. This work employs induction, sieving, inversion, and other recursive methods to solve a variety of problems in the areas of algebraic number theory, topological and combinatorial graph theory, and analytic probability and statistics. A common theme of recursively defined functions, weighted sums, and cross-referencing sequences arises in all three contexts, and supplemented by sieving methods, generating functions, asymptotics, and heuristic algorithms.

In the area of number theory, this work generalizes the sieve of Eratosthenes to a sequence of polynomial values called polynomial-value sieving. In the …

Determining What Factors Affect Peoples' Perceptions Of The Use Of Reclaimed Water As A Source For Potable Water: A Study Within Hillsborough County, Florida, Susana Rebecca Alvarado Tricoche

USF Tampa Graduate Theses and Dissertations

In response to water supply depletion challenges, countries such as Australia, the United States, and Namibia have implemented technologies that treat wastewater up to the standards permissible to use for irrigation, toilet flushing, and even drinking water. However, many of these countries have been unable to successfully implement some of their ambitious reclaimed water reuse projects due to negative public perceptions of recycling wastewater. The focus of this study was to understand which factors in risk perception theory are the most influential in shaping community perceptions of reclaimed water reuse as a future source of drinking water within Hillsborough County. …

An Evaluation Of Florida Gulf Coast University's Residence Life Staff Member's Hurricane Preparedness, Erin Floto

USF Tampa Graduate Theses and Dissertations

Florida Gulf Coast University (FGCU) is located along the coast of the Gulf of Mexico in southern Florida, in an area vulnerable to hurricane strikes. At FGCU, The Office of Housing and Residence Life (OHRL) is responsible for three locations on- and off-campus where students reside in apartment or suite-style housing. Due to the large number of students with varying backgrounds, the OHRL staff members have become essential personnel during severe weather events that may cause safety concerns for the residents living in OHRL housing locations. This study's purpose is to assess the Residence Life staff on their level of …

Synthesis Of [1,2,4]-Triazines As Kinase Inhibitors And Of Novel Fluorine Capture Reagents For Pet Probes, Fenger Zhou

USF Tampa Graduate Theses and Dissertations

ABSTRACT

Anaplastic lymphoma kinase (ALK) is a tyrosine kinase receptor, which plays a pivotal part in the development of the central nervous system. Aberrant expression of full-length ALK occurs in neuroblastoma and chromosomal translocation or inversion of the ALK gene can generate novel fusion-ALK proteins that possess constitutive kinase activity and contribute to oncogenic processes. One of the well-studied fusion proteins is nucleophosmin (NPM-ALK), which draws a lot of attention for medicinal chemists to design small molecules as kinase inhibitors for this target. In this dissertation, [1, 2, 4]-Dihydrotriazine dimers as competitors of the lead compound NVP-TAE684 targeting NPM-ALK have …

Use Of System Dynamics Modeling To Explicate The Theory-Of-Change Of A Social Marketing Innovation, Brian J. Biroscak

USF Tampa Graduate Theses and Dissertations

Community coalitions are an important part of the public health milieu and thus subject to many of the same external pressures as public health organizations--including changes in required strategic orientation. Many funding agencies have shifted their funding agenda from program development to policy change. Thus, the Florida Prevention Research Center created the Community-Based Prevention Marketing for Policy Development framework to teach community coalitions how to apply social marketing to policy change. The dissertation research reported here was designed to explicate the framework's theory-of-change. The research question was: "What are the linkages and connections between CBPM inputs, activities, immediate outcomes, intermediate …

A Multi-Proxy Approach To Understanding Abrupt Climate Change And Laurentide Ice Sheet Melting History Based On Gulf Of Mexico Sediments, Clare Carlisle Williams

USF Tampa Graduate Theses and Dissertations

During the last deglaciation (ca. 24-10 ka thousand years ago (ka)), the North American Laurentide Ice Sheet (LIS) was a major source of meltwater to the Arctic Ocean, North Atlantic Ocean, and the Gulf of Mexico (GOM), and it is hypothesized that meltwater routing played an important role in regulating Late Quaternary millennial-scale climate variability, via its influence on Atlantic Meridional Overturning Circulation (AMOC). For example, the meltwater routing hypothesis predicts that a rerouting of meltwater from the GOM to the North Atlantic and/or Arctic Oceans resulted in a decrease of North Atlantic Deep Water (NADW) formation and subsequent cooling …

Stochastic Modeling And Analysis Of Energy Commodity Spot Price Processes, Olusegun Michael Otunuga

USF Tampa Graduate Theses and Dissertations

Supply and demand in the World oil market are balanced through responses to price movement with considerable complexity in the evolution of underlying supply-demand

expectation process. In order to be able to understand the price balancing process, it is important to know the economic forces and the behavior of energy commodity spot price processes. The relationship between the different energy sources and its utility together with uncertainty also play a role in many important energy issues.

The qualitative and quantitative behavior of energy commodities in which the trend in price of one commodity coincides with the trend in price of …

A Multi-Period Mixed Integer Linear Programming Model For Desalination And Electricity Co-Generation In Kuwait, Nael Abdulhameed Alqattan

USF Tampa Graduate Theses and Dissertations

Water is the root of life and the engine that drives agriculture, industry, economy and services. The demand for water often necessitates desalination, particularly in arid coastal environments where there are several desalination technologies in use today such as Multi-Effect Distillation (MED) and Reverse Osmosis (RO). The key utility requirement for technologies such as desalination and population in general include energy in one form or another. Therefore, desalination and co-generation are often integrated. Another key utility is electricity which is generated from either renewable or non-renewable sources. The demands for water and electricity change over time and are subject to …

Evolution And Equilibration Of Artificial Morphologic Perturbations In The Form Of Nearshore Berm Nourishments Along The Florida Gulf Coast, Katherine Emily Brutsché

USF Tampa Graduate Theses and Dissertations

Inlets and channels are dredged often to maintain navigation safety. It is beneficial to reintroduce the dredged material back into the littoral system, in the form of beach or nearshore nourishments. Nourishment in the nearshore is becoming an increasingly utilized method, particularly for dredged material that contains more fine sediment than the native beach. This research examines the morphologic evolution of two different nearshore nourishments. A nearshore berm was constructed at Fort Myers Beach, Florida using mixed-sized sediment dredged from a nearby channel. The nearshore berm was placed in water depths between 1.2 and 2.4 m with the berm crest …

Synthesis, Characterization And Mechanistic Studies Of Biomolecules@Mesomofs, Yao Chen

USF Tampa Graduate Theses and Dissertations

Encapsulation of biomolecules is of great interest to research advances related to biology, physiology, immunology, and biochemistry, as well as industrial and biomedical applications such as drug delivery, biocatalysis, biofuel, food and cosmetics. Encapsulation provides functional characteristics that are not fulfilled by free biomolecules and stabilizes the fragile biomolecules. In terms of biocatalysis, solid support can often enhance the stability of enzymes, as well as facilitate separation and recovery for reuse while maintaining activity and selectivity. Various kinds of materials have been used for encapsulation of biomolecules, among which, porous materials are an important group. Metal-organic frameworks (MOFs) have attracted …

Topological Data Analysis Of Properties Of Four-Regular Rigid Vertex Graphs, Grant Mcneil Conine

USF Tampa Graduate Theses and Dissertations

Homologous DNA recombination and rearrangement has been modeled with a class of four-regular rigid vertex graphs called assembly graphs which can also be represented by double occurrence words. Various invariants have been suggested for these graphs, some based on the structure of the graphs, and some biologically motivated.

In this thesis we use a novel method of data analysis based on a technique known as partial-clustering analysis and an algorithm known as Mapper to examine the relationships between these invariants. We introduce some of the basic machinery of topological data analysis, including the construction of simplicial complexes on a data …

Can The Usa National Weather Service Heat Index Substitute For Wet Bulb Globe Temperature For Heat Stress Exposure Assessment?, Ivory Iheanacho

USF Tampa Graduate Theses and Dissertations

Heat stress occurs when the body cannot adequately cool itself due to the combined contributions of metabolic heat, environmental factors and clothing. Heat stress found in the workplace puts employees at risk of developing heat-related illnesses, disorders and could be fatal. The wet bulb globe temperature (WBGT) index is the current method used to assess environmental contributions to heat stress in an occupational setting. The purpose of this thesis was to explore whether the National Weather Service's Heat Index (HI) could substitute for the WBGT Index during occupational heat stress exposure assessment. The possibility of using the HI for heat …

Environment, Rights, And Waste In Bolivia: Addressing Water And Sanitation Processes For Improved Infrastructure, Maryann R. Cairns

USF Tampa Graduate Theses and Dissertations

Water and sanitation (WatSan) development projects impact both natural systems and societal structures where they are placed. A complex process of development, including inter-governmental policies, aid agencies, personal relationships, and community politics enhance and constrain the efficacy of these projects. This study presents the many ways in which the WatSan development process has unintended and unexpected returns for certain community groups. Using a political ecology framework, I look at power structures, perceived and projected environmental impacts, multiple stakeholders, and individual discourses to critique how the right to water and sanitation is implemented in a specific community context. This project advances …

Analysis Of Critical Behavior In Magnetic Materials, Dustin David Belyea

USF Tampa Graduate Theses and Dissertations

This work contains a broad study of a variety of magnetic materials undergoing second order phase transitions. In general this leads to an overall increase in information and analytical methods to further the field of magnetocalorics. Specifically, critical aspects of magnetocaloric materials were compared within systems in relation to structure, stoichiometry, magnetic minority phases and magnetic contaminants. Detailed analyses were developed to quantify techniques which were in the past used mainly in a qualitative way, leading to a more complete understanding of how critical phenomena impacts the magnetocaloric response.

The Use And Effectiveness Of Online Social Media In Volunteer Organizations, Amy J. Connolly

USF Tampa Graduate Theses and Dissertations

Volunteer organizations face two challenges not found in non-volunteer organizations: recruiting and retaining volunteers. While social media use is increasing amongst individuals, its use and effectiveness for volunteer recruitment and retention by volunteer organizations is unknown. The dissertation reports the results of three studies to investigate this important question. Using a mixed-methods approach, it addressed the dual nature of social media and its effectiveness by including volunteer organizations and social media users.

This dissertation found that although volunteer organizations are not using social media effectively, they could virtualize requirements of the recruitment process by focusing on relatable events instead of …

Characterization Of Waste Anesthetic Gas Exposures To Veterinary Workers In The Tampa Bay Area, Kyle Vogel

USF Tampa Graduate Theses and Dissertations

Veterinarians routinely conduct surgical operations on animals while veterinary technicians administer anesthetic gas to sedate the animal prior to an operation. One commonly used anesthetic agent in veterinary clinics is isoflurane. Veterinary workers have the potential to be exposed to this gas during surgical operations. The Occupational Safety and Health Administration (OSHA) does not have a specific Permissible Exposure Limit (PEL) for isoflurane, however The National Institutes for Health (NIH) does advise that workers should not be exposed to isoflurane in concentrations exceeding 2 parts per million (ppm) for an 8 hour Time Weighted Average (TWA).

Animal clinics vary in …

Insights Into The Epitaxial Relationships Between One-Dimensional Nanomaterials And Metal Catalyst Surfaces Using Density Functional Theory Calculations, Debosruti Dutta

USF Tampa Graduate Theses and Dissertations

This dissertation involves the study of epitaxial behavior of one-dimensional nanomaterials like single-walled carbon nanotubes and Indium Arsenide nanowires grown on metallic catalyst surfaces. It has been previously observed in our novel microplasma based CVD growth of SWCNTs on Ni-Fe bimetallic nanoparticles that changes in the metal catalyst composition was accompanied by variations in the average metal-metal bond lengths of the nanoparticle and that in turn, affected nanotube chirality distributions. In this dissertation, we have developed a very simplistic model of the metal catalyst in order to explain the nanotube growth of specific nanotube chiralities on various Ni-Fe catalyst surfaces. …

Development And Assessment Of Self-Explaining Skills In College Chemistry Instruction, Adrian Villalta-Cerdas

USF Tampa Graduate Theses and Dissertations

The prevalent trend in chemistry instruction relies on what has been described as the classroom game. In this model, students take a passive role and the instructor does all the explaining (thinking), and learning is trivialized to knowing the correct answers (memorizing) and being able to produce them when prompted (regurgitating). The generation of explanations is central to scientific and technological development. In the process of figuring out explanations, the generation of inferences relies on the application of skills associated with scientific behaviors (e.g., analytical reasoning and critical thinking). The process of explanation generation causes a deeper analysis and revision …

Diffuse Nutrient Pollution From Residential Catchments, Melissa Rachelle Butcher

USF Tampa Graduate Theses and Dissertations

Nonpoint source nutrient pollution is diffuse pollution lacking discrete origin and conveyance. This thesis synthesizes and critically reviews research on residential nitrogen and phosphorus loss to stormwater runoff and leaching. The evaluation pulls from research covering influential socio-demographic indicators, such as use of lawn maintenance services and homeowner fertilizer practices. The extent to which such social and economic factors may influence the prevalence and fate of diffuse nutrients in stormwater runoff from residential areas has not been adequately established. Understanding the source and influencing factors of diffuse nutrient pollution is important in order to effectively protect surface and groundwater resources. …