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High-Temperature And “Exotic” Minerals From The Cioclovina Cave, Romania: A Review, Bogdan P. Onac, Herta S. Effenberger, Radu C. Breban Feb 2008

High-Temperature And “Exotic” Minerals From The Cioclovina Cave, Romania: A Review, Bogdan P. Onac, Herta S. Effenberger, Radu C. Breban

Studia UBB Geologia

This paper reports on the identification of four rare minerals in the phosphate deposit in Cioclovina Cave, Romania. Berlinite, AlPO4 and hydroxylellestadite, Ca5[(Si,P,S)O4]3(OH,F,Cl) are minerals that can form only at high temperatures, and would not be expected in a sedimentary environment. In this study we review the characteristics of berlinite and hydroxylellestadite from a heated sedimentary sequence in Cioclovina Cave (Romania) and refine their structure from single-crystal X-ray data. Two other minerals, churchite-(Y), YPO4⋅2H2O and foggite, CaAl(PO4)(OH)2⋅H2O are, for the first time, described from a cave environment. The minerals were documented by means of single-crystal X-ray investigations, X-ray powder diffraction, …