Physical Sciences and Mathematics Commons^™

Structural And Geochronologic History Of Southern Alaskan Blueschists, Erik M. Day

Open Access Theses & Dissertations

Detrital zircon data are presented from the Liberty Creek blueschist in the central Chugach Mountains which indicate two distinct periods of the preservation of blueschist facies metamorphism along the southern Alaskan margin. A maximum depositional age of ~136 Ma demonstrates that the Liberty Creek schist was deposited long after the Jurassic cooling ages (196-185 Ma; Lopez-Carmona et al., 2011) recorded in western Alaskan blueschist bodies, revealing two blueschist preservation events. This Early Cretaceous depositional age also indicates that there have been major reorganizations within this subduction complex because the Potter Creek assemblage, directly south of the Liberty Creek schist, is …

Spingolipid Metabolism In A Reptillian Protozoan, Entamoeba Invadens, Duran Dogan Debons

Open Access Theses & Dissertations

Entamoeba invadens (hereinafter E. invadens) is an anaerobic parasitic protozoan that can be found in water and soil. Although the host organisms for this parasite are snakes, lizards, and other reptile species, the parasite is morphologically identical to Entamoeba histolytica, a causative agent of human amebiasis. Entamoeba inavdens exists in two morphological forms--(1) a replicative trophozoite, and (2) a relatively dormant cyst. While the transformation of cyst to trophozoites (called "excystation") takes place in the stomach, the differentiation of trophozoites to cyst (known as "encystation"), occurs in the small intestine. Unlike the cyst, a trophozoite is unable to survive …

Depositional And Sequence Stratigraphic Framework Of An Exposed Neoproterozoic Suprasalt Minibasin At Patawarta Diapir, Flinders Ranges, South Australia, Cora Evelyn Gannaway

Open Access Theses & Dissertations

Outcrops of mixed carbonate/siliciclastic strata comprise the Neoproterozoic (Marinoan) Wilpena Group at Patawarta diapir in the Flinders Ranges, South Australia. Patawarta diapir is a ramping allochthonous salt sheet flanked by suprasalt and subsalt minibasin strata. The stratal and structural attributes of the coeval minibasin fills afford a unique perspective on lateral and vertical salt migration and the impacts of salt-modified bathymetry in shallow marine depositional environments. This study documents the depositional and diagenetic facies, stratal thickness trends, and structural style and stratal geometries of the suprasalt minibasin fill and correlates it to the previously studied subsalt minibasin fill. The goal …

Uptake Of Copper And Cerium By Alfalfa, Lettuce And Cucumber Exposed To Nceo2 And Ncuo Through The Foliage Or The Roots: Impacts On Food Quality, Physiological And Agronomical Parameters, Jie Hong

Open Access Theses & Dissertations

Nanotechnology is increasingly attracting attention not only for its variety of applications in modern life, but for the potential negative effects that nanomaterials (NMs) can cause in the environment and human health. Studies have shown varied effects of engineered nanoparticles (ENPs) on plants; however, most of these studies focused on the interaction of NPs with plants at root level. The increasing production and use of NPs have also increased the atmospheric amounts of NPs, which could be taken up by plants through their leaves. Cucumbers (Cucumis sativus L.) are broad leaf plants commonly grown both commercially and in home vegetable …

Equations Of State In A Strongly Interacting Relativistic System, Jason Paul Keith

Open Access Theses & Dissertations

It has long been understood that the ground state of a superdense quark system, a Fermi liquid of weakly interacting quarks, is unstable with respect to the formation of diquark condensates. This nonperturbative phenomenon is essentially equivalent to the Cooper in-stability of conventional BCS superconductivity. As the quark pairs have nonzero color charge, this kind of superconductivity breaks the SU(3) color gauge symmetry, thus the phe-nomenon is called color superconductivity. However, not much is known about the behavior of quark systems at moderate densities between the formation of baryons and asymptotic freedom. Strong theoretical and experimental evidence suggests that there …

Synthesis And Characterization Of Platinum(Ii) Complexes Of Electron Donor And Acceptor Ligands, Namrata Khanal

Open Access Theses & Dissertations

Pt(II) complexes of N,N-diphenylpyridineamine or 4-diphenylphosphino derivatized triphenylamine as novel electron donors and alkynyl derivatized benzothiadiazole as electron acceptors were synthesized. All the complexes were characterized by 1H and 13C nuclear magnetic resonance spectroscopy, electronspray ionization mass spectrometry, infrared spectroscopy, and 31P nuclear magnetic resonance spectroscopy for the complexes of 4-diphenylphosphino derivatives. The electronic properties studied using UV/vis spectroscopy exhibit ᴫ-ᴫ* transition, metal to ligand charge transfer, and optical highest occupied molecular orbital-lowest unoccupied molecular orbital bandgaps from 2.62-2.65 eV. The electrochemical study performed using cyclic voltammetry have shown the highest occupied molecular orbital-lowest unoccupied molecular orbital bandgaps from 2.70-2.74 …

Application Of Stir Bar Sorptive Extraction Thermal Desorption Gas Chromatography Mass Spectrometry For The Study Of Water Accommodated Fractions Of Fossil Fuels And Biodiesel, Ricardo Mccreary

Open Access Theses & Dissertations

Even though measures are taken to decrease accidental release of crude oil and refined fuels into the aquatic environment, continued demand of such fuels--particularly in the transportation sector--pose a continued threat to the aquatic environment throughout their handling, processing, and consumption. Even though measures can be taken to remove the visible layers of fuel in water, it has been shown that constituents of these fuels--that partition into water--can have adverse health effects on the aquatic organisms at low concentrations that are not necessarily predictable through the study of the actual fuel's original composition. Consequently, this renders the need for an …

Light Scattering From Aerosol Particles In The El Paso Del Norte Region / The Effect Of Humidity, Richard Medina Calderon

Open Access Theses & Dissertations

Atmospheric aerosols play an important role in climate forcing, through scattering and absorption of the incoming solar radiation. The extinction of light by the presence of atmospheric aerosols was studied using two first-principle models, and corresponding computer codes. In the first model the extinction of light from irregularly shaped aerosol particles was analyzed. In the second model it was assumed that the irregularly shaped aerosol particles were covered by a film of water, and the hygroscopicity and the extinction of light by the aerosols was analyzed. These models were then applied to the Paso del Norte region and their light …

Structural Investigation Of The Molecular Chaperonin Tf55 From Thermophilic Archaeon Sulfolobus Solfataricus, Sanjay Kumar Molugu

Open Access Theses & Dissertations

Chaperonins are ubiquitous multi-subunit macromolecules that mediate the folding and assembly of certain proteins that cannot fold properly in vivo. The Archaea bacterium Sulfolobus solfataricus encodes for three chaperonin complexes formed from three different, but closely related subunits named alpha,betaand Gamma. These subunits form a homo-18mer composed of all beta subunits at temperatures ranging between 80oC-85oC, a hetero-16mer composed of alpha and beta subunits at temperatures ranging between 70oC-75oC and a hetero 18mer composed of alpha, beta and gamma subunits at temperatures of 60oC. Structures exist for the chaperonin TF55 all-beta complex and for the TF55 alpha-beta complex but not …

Geochemical Studies Of Backfill Aggregates, Lake Sediment Cores And The Hueco Bolson Aquifer, Anita Thapalia

Open Access Theses & Dissertations

This Dissertation comprises of three different researches that focuses on the application of geochemistry from aggregates, lake sediment cores and Hueco Bolson Aquifer. Each study is independent and presented in the publication format. The first chapter is already published and the second chapter is in revision phase. Overall, three studies measure the large scale (field) as well as bench scale (lab) water-rock interactions influenced by the climatic and anthropogenic factors spans from the field of environmental geology to civil engineering.

The first chapter of this Dissertation addresses the chemical evaluation of coarse aggregates from six different quarries in Texas. The …

Biofuel Feedstock Optimization Considering Different Land Cover Scenarios And Watershed Impacts, Rodney Wayne Vance

Open Access Theses & Dissertations

With an increased demand for renewable energy production, especially the conversion of biomass to biofuels, perennial grasses are gaining interest as a renewable source of biofuel feedstocks. Identifying the trade-offs between bioenergy crop cultivation and nutrient runoff, erosion, and water requirements will be important as the demand for these crops continues to grow. The primary objective of this study is develop an integrated optimal control model that estimates the potential effects on water quality and demand and soil erosion from cultivating switchgrass and other perennial grasses instead of conventional crops at the watershed scale. The Soil and Water Assessment Tool …

A Visualization And Simulation Tool That Will Generate Effective Patrolling Strategies To Protect The U.S. Borders From Illegal Intrusion Using Game Theoretic Methods And Models, Eric Gutierrez

Open Access Theses & Dissertations

In the recent decade, the United States Border Patrol has increased the presence of border security officers at points of entry along the U.S.- Mexico border. In response to this increased presence of border security officials at ports of entries, illegal intruders have rerouted their intrusions in between ports of entry, in harsher terrain areas of the U.S. (e.g., the Arizona desert). The U.S. Border Patrol could benefit from a tool that plans effective border patrolling routes, and helps border security officials to make risk-based decisions for resource allocation. We are currently developing a tool called Genetic Algorithm for a …

Isomerase Activity Of Candida Rugosa Lipase In Conversion Of Racemic Ibuprofen To (S)-Ibuprofen, Saideh Sadat Mortazavi

Open Access Theses & Dissertations

The Candida rugosa lipase-catalyzed Dynamic Kinetic Resolution of racemic ibuprofen methyl ester was optimal at pH 7.6 to produce (S)-ibuprofen in 72 hours. The concentration of various buffers for these reactions ranged from 0.2 to 0.5 M. The commercial lipase was found to be acidic altering the final pH of the reaction mixtures. Dimethylformamide co-solvent maintained the reaction pH better than dimethylsulfoxide, with evidence of the latter functioning as an oxidizing agent. Lower concentrations of ibuprofen methyl ester and higher stirring rates led to faster conversions. The minimal amount of lipase needed was 20 mg/mL buffer. Reaction of (R)-ibuprofen methyl …

Risk Assessment Of Waterborne Cryptosporidium, Victoria Norma Ochoa

Open Access Theses & Dissertations

In an effort to update the risk assessment of waterborne Cryptosporidium an additional and more complete human dose-response dataset of the parasite was used to calculate the risk of infection. The complete data studied contains larger human outcomes than the initial prior risk assessment evaluated by Haas et. al. in 1999. Quantitative analysis of the complete dose-response indicates that it no longer follows the Exponential Model used to estimate the risk for the initial data. The complete dataset appears to provide a better fit with the Beta-Poisson Model and even a dose independent constant risk model, which shows a considerable …

Geophysical Model Of The Cu-Mo Porphyry Ore Deposit At Copper Flat Mine, Hillsboro, Sierra County, New Mexico, Adrian Emmanuel Gutierrez

Open Access Theses & Dissertations

A 3D gravity model of the Copper Flat Mine was performed as part of the exploration of new resources in at the mine. The project is located in the Las Animas Mining District in Sierra County, New Mexico. The mine has been producing ore since 1877 and is currently owned by the New Mexico Copper Corporation, which plans o bringing the closed copper mine back into production with innovation and a sustainable approach to mining development. The Project is located on the Eastern side of the Arizona-Sonora-New Mexico porphyry copper Belt of Cretaceous age. Copper Flat is predominantly a Cretaceous …

Furthering Our Understanding And Assessing The Effectiveness Of Scaling Patterns And Controls Of Land-Atmosphere Carbon Exchange In A Shrubland Of The Chihuahuan Desert With Novel Cyberinfrastructure, Aline Jaimes

Open Access Theses & Dissertations

Over the last century, arid and semiarid regions have undergone intense desertification and in many regions, vegetation has shifted from grassland to shrubland dominated ecosystems. This land cover change has important implications for how desert ecosystems function - especially with regards to land-atmosphere exchange of carbon, water, and energy. Although the extent of desertified landscapes is expected to expand over the next 30 to 40 years, there is a relatively poor understanding of how this state transition will impact ecosystem function and feedbacks to other components of the earth system. Key to addressing this challenge is an improved understanding of …

A Long- And Short-Run Analysis Of Electricity Demand In Ciudad Juarez, Ericka Cecilia Mendez

Open Access Theses & Dissertations

Economic growth and appliance saturation are increasing electricity consumption in Mexico. Annual frequency data from 1990 to 2012 are utilized to develop an error correction framework that sheds light on short- and long-run electricity consumption behavior in Ciudad Juarez, a large Mexican metropolitan economy at the border with the United States. The results for this study reveal that electricity is an inelastic normal good in this market. Moreover, natural gas is found to be a weak complement to electricity. With regards to the customer base in this urban economy, population, employment, and income exercise positive and statistically significant impacts on …

Impact Of Zinc Oxide Nanoparticles On Green Pea Plant & Seed Quality And Effects On Physiological Traits Of Green Peas, Corn, And Zucchini By Silver Nanoparticles, Arnab Mukherjee

Open Access Theses & Dissertations

The production and use of numerous engineered nanomaterials (ENMs) have increased exponentially over the past decade. Nanoparticles (NPs), ENMs possessing diameter between 1-100 nm, (NPs), are widely used in many applications. Worldwide consumption of NPs has increased their possible release into the environment. This, in turn, has elevated the extent of the potential impacts of NP exposure to living and non-living organisms. This is why the assessment of the impact of NPs on different environmental components, especially on plants, the producer in the food web, has become a very important aspect of nano-ecotoxicology. However, studies focusing on phytotoxicity and effects …

Development Of A Transferable Student Engagement And Knowledge Retention Framework For The Earth Sciences, Sunay Palsole

Open Access Theses & Dissertations

The earth sciences play an important role in engaging students in science and in science, technology, engineering and mathematics (STEM) disciplines, because of the integrative nature of the disciplines. It then becomes important for us to provide an engaging experience for students taking earth science courses, because it serves a dual purpose of possibly increasing new majors in the discipline and helping to create a science literate population.

Given that a majority of students in the larger introductory courses are non-majors, it behooves us to explore alternative engagement techniques and measure their efficacy in student engagement, which in turn can …

Digitally Manufactured Spatially Variant Photonic Crystals, Javier Jair Pazos

Open Access Theses & Dissertations

Metamaterials and photonic crystals are engineered composites that exhibit electromagnetic properties superior to those found in nature. They have been shown to produce novel and useful phenomena that allow extraordinary control over the electromagnetic field. One of these phenomena is self-collimation, an effect observed in photonic crystals in which a beam of light propagates without diffraction and is forced to flow in the direction of the crystal. Self-collimation however, like many of the mechanisms enabled through dispersion engineering, is effective in directions only along the principal axes of the lattice. To this effect, a general purpose synThesis procedure was developed …

Fast Algorithm For Finding Lattice Subspaces In Rn And Its Implementation, Andrew Martin Pownuk

Open Access Theses & Dissertations

There are known necessary and sufficient conditions for a subspace of Rm to be lattice-ordered. Let Y = {y1,…,ym} and yi are rows of the matrix X. A subspace ⟨X⟩, of linear space generated by the set X of n linearly independent positive vectors is lattice-ordered if and only the set X admits a fundamental set of indices I, which means that the subset YI ⊆ Y of vectors indexed by I is linearly independent, and every vector from Y\YI is a nonnegative linear combination of vectors form YI.

In economics it is possible to prove that the minimum-cost insured …

Three Essays On Social/Political Structures And Icts Use, Seungeui Ryu

Open Access Theses & Dissertations

My research identifies how social structures affect the use of the Internet and/or a mobile chat application and how the Internet impacts the political structure of a nation. In my first essay of the 3-essay Dissertation, I am designing three models based on social structure theory that are used to study the Internet and a popular mobile chat application's use by managers in South Korea, with the help of a survey instrument. In my first essay, the contribution is on i) testing a model of manager's personal behavior on Information and Communication Technology (ICT) use at the individual level involving …

Finite Density Qed At Strong Magnetic Field, Paul Lee Springsteen

Open Access Theses & Dissertations

In this Thesis we study the effect of a dense medium on the quantum properties of a relativistic electron-positron plasma under a magnetic field. From the calculation of the photon polarization operator depending on temperature, chemical potential, and the magnetic field; we study how the electric susceptibility of the strongly magnetized plasma is charged with temperature and density. In the same manner we study the dependence of the Debye mass with density. Then we investigated the phenomenon of magnetic catalysis of chiral symmetry breaking for a dense medium. We found that there exist a critical value of the chemical potential …

Homeomorphisms Between Pairs Of Genus Two Handlebodies And Separating Circles In Their Boundaries, Daniel Orlando Vazquez

Open Access Theses & Dissertations

A known result in low-dimensional topology is that every incompressible surface properly embedded in a genus two handlebody is boundary compressible. This result produces a pair consisting of a genus two handlebody and a separating curve in its boundary.

We study particular examples of genus two handlebodies and essential simple closed curves which separate their boundaries. The aim of this paper is to give our own construction of separating curves on the boundary of genus two handlebodies and compare them with previously studied pairs. These constructions involve taking 2n arcs on either side of a waist disk of a genus …

Alkali Promoted Molybdenum (Iv) Sulfide Based Catalysts, Development And Characterization For Alcohol Synthesis From Carbon Monoxide And Hydrogen, Belinda Delilah Molina

Open Access Theses & Dissertations

For more than a century transition metal sulfides (TMS) have been the anchor of hydro-processing fuels and upgrading bitumen and coal in refineries worldwide. As oil supplies dwindle and environmental laws become more stringent, there is a greater need for cleaner alternative fuels and/or synthetic fuels. The depletion of oil reserves and a rapidly increasing energy demand worldwide, together with the interest to reduce dependence on foreign oil makes alcohol production for fuels and chemicals via the Fischer Tropsch synthesis (FTS) very attractive. The original Fischer-Tropsch (FT) reaction is the heart of all gas-to-liquid technologies; it creates higher alcohols and …

A Study Of Ti-Doped Wo3 Thin Films Using Comparative Theoretical And Experimental Approach, Aurelio Paez

Open Access Theses & Dissertations

Metal oxides like Tungsten Oxide (WO3) are well documented and characterized in the literature, with uses in darkening windows and mirrors, flat computer displays, solar panel cooling, and sensors (of interest in this study). Ti doping of WO3 is less documented and the focus of this study. Sample thin films of pure WO3 and varyingly Ti doped WO3 were prepared using Radio Frequency magnetron sputtering (RF) (13.56 MHz) to grow thin films on a silicon substrate. This study aims to compare multiple Ti doping percentages in WO3 theoretically and then compare with experimental data taken from thin films of various …

Exploring The Hydrogeologic Controls On Brackish Water And Its Suitability For Use In Hydraulic Fracturing: The Dockum Aquifer, Midland Basin Texas, Francisco Ruben Reyes

Open Access Theses & Dissertations

Water scarcity in arid regions can limit or impede certain hydrocarbon production activities, such as hydraulic fracturing and well drilling. The Midland Basin, a major oil-producing area in semi-arid far west Texas and the eastern sub-basin of the Permian Basin, is already impacted by limited freshwater availability. A typical tight oil well in the Midland Basin requires ~3.8-11.4 x 103 m3 of water per fracture treatment (Nicot et al., 2012). Despite draught conditions and limited resources, data for 2011 indicate freshwater comprises ~70% of the water used in hydraulic fracturing in the Midland basin. Thus, the Midland Basin represents an …

Synthesis And Characterization Of Fluorophores For The Detection Of Lanthanides And Actinides, Robinson I. Roacho

Open Access Theses & Dissertations

A series of fluorophores based in the boron dipyrromethene (BODIPY) family were synthesized and characterized. These fluorophores have the capacity of being introduced to a carbamoyl methyl phosphine oxide (CMPO) lanthanide/actinide extractant. These blue, green and red emission fluorophores show high thermal/moisture stability and high fluorescence efficiencies. The fluorescence intensity seems to be dependent on the restricted rotation about the C(8)-C bond in 8-Ph-BODIPY. By taking advantage of this feature, a hydroxyl- containing BODIPY with high fluorescence intensity was synthesized to be incorporated to a CMPO carboxylic acid via esterification. Unfortunately, we did not observe an optical response upon the …

Platform-Independent Data Locality Analysis To Predict Cache Performance On Abstract Hardware Platforms, Sonish Shrestha

Open Access Theses & Dissertations

This research is part of a co-design project that has the goal of designing hardware systems to match application requirements and efficiently mapping applications to hardware. This thesis is focused on optimizing the platform cache memory hierarchy configuration. To determine application requirements, we characterize the application using platform- independent locality metrics. Next we use locality data and an analytical model to predict cache an application performance of sequential versions of application codes for various cache configurations. After using an analytical model to select a candidate set of cache memory hierarchy configurations, we used architectural simulation to test the selection for …

Evaluation Of Ozone Trends In Southern Doña Ana County, New Mexico Thru Wind Rose Analysis And Use Of Noaa Hysplit Model, Maria Aurelia Sisneros

Open Access Theses & Dissertations

The objective of this study was to determine whether increasing ozone concentrations in 2012 and 2013 at the Santa Teresa air quality monitor in Doña Ana County, New Mexico were due to a local point source impacting this monitor only or part of a regional phenomenon that affects all the monitors within the Paso del Norte Region. In addition, the study focused on identifying local and regional/long-range source areas contributing transport ozone to the study area (southern Doña Ana County).

The study showed that increasing ozone levels were not unique to the Santa Teresa monitor due to the fact that …