Physical Sciences and Mathematics Commons^™

Elucidating The Electronic Structure Of Multiple Bonded Systems: Synthesis And Characterization Of Bimetallic Tungsten And Ruthenium Complexes, Karen Ventura

Open Access Theses & Dissertations

The following study is presented in two sections. In the first section variable-temperature magnetic and structural data of two pairs of diruthenium isomers (having an idealized D4h symmetry), one pair having axial ligands and the formula Ru2(DArF)4Cl (where DArF is the anion of a diarylformamidine isomer, and Ar = p-anisyl or m-anisyl) and the other one being essentially identical but devoid of axial ligands and having the formula [Ru2(DArF)4]BF4, show that the axial ligands have a significant effect on the electronic structure of the diruthenium core. Variable-temperature crystallographic and magnetic data as well as density functional theory (DFT) calculations unequivocally …

Evaluation Of Small Molecules On The Excitatory Amino Acid Transporter 3 (Eaat3) For The Treatment Of Ocd, Emmanuel Zubia

Open Access Theses & Dissertations

We seek to discover new drug candidates for the excitatory amino acid transporter 3 (EAAT3) for the treatment of Obsessive Compulsive Disorder (OCD). We hypothesize that decreasing the glutamatergic transmission via EAAT3 intervention will create an amelioration of the symptoms of OCD. For this we have prepared in-silico binding calculations to identify a better compound that can stimulate EAAT3 and decrease glutamatergic transmission. This research will help us further understand and elucidate the role of glutamate in the neural mechanisms of this illness, which to date remain inconclusive. Those areas of study are significant because, until now, there is no …

Optimization Schemes For The Inversion Of Bouguer Gravity Anomalies, Azucena Zamora

Open Access Theses & Dissertations

Data sets obtained from measurable physical properties of the Earth structure have helped advance the understanding of its tectonic and structural processes and constitute key elements for resource prospecting. 2-Dimensional (2-D) and 3-D models obtained from the inversion of geophysical data sets are widely used to represent the structural composition of the Earth based on physical properties such as density, seismic wave velocities, magnetic susceptibility, conductivity, and resistivity. The inversion of each one of these data sets provides structural models whose consistency depends on the data collection process, methodology, and overall assumptions made in their individual mathematical processes. Although sampling …

Sequence Stratigraphy And Depositional Environment Of The Cambro-Ordovician Bliss Sandstone, Franklin Mountains Of El Paso, Texas, Drew Adam Chenoweth

Open Access Theses & Dissertations

The Bliss Formation formed along the Southwestern continental shelf of

Laurentia during the Late Cambrian and records the craton]wide Cambrian

transgression previously described by Sloss. This study divides the Bliss into five facies associations which were used to determine the depositional environments: 1) The Basal Transgressive Lag (BTL) was interpreted to be a high energy fluvial deposit the top of which has been reworked and winnowed during transgression. 2) The Lower Cyclic Sandstones and Silty Sandstones (LCSS) were interpreted to be be tidal delta or tidal estuary deposits composed of delta deposits, slackwater deposits, and tidal dunes within tidal channels. …

A Case Study Of Accelerator Performance, Esthela Gallardo

Open Access Theses & Dissertations

In recent years the designs of High Performance Computing (HPC) clusters have become more complex. This is due to the emergence of new processing elements, in particular Graphics Processing Units (GPUs) and other many-core processors that can be combined with multi-core processors to enhance application performance. The design of a cluster includes processing elements that meet the needs of the applications that will run on the system. Unfortunately, it has become increasingly difficult to compare the performance of novel many-core processing elements due to the differences in their architectures. This work describes an attempt to develop a methodology for comparing …

Role Of Small Molecules In Rescuing Protein Folding Under Oxidative Stress, Mahmoud Fawzi Megahed Helal Khalil

Open Access Theses & Dissertations

Increased levels of nitrosative stress intracellularly within the endoplasmic reticulum is a key factor involvled in the pathogenesis of both Parkinson's (PD) and Alzheimer's (AD) diseases. Previous in-vitro studies in our lab showed that increased levels of nitrosative stress lead to aggregation of misfolded proteins and formation of Lewy Bodies, the main biomarker of PD and AD diseases. Although this was mainly through nitrosylation of Protein Disulfide Isomerase (PDI), the chief endoplasmic reticulum (ER) resident oxidoreductase chaperone responsible for maturation of disulfide-bond-containing proteins, we demonstrate in this project that increased levels of nitrosative stress has an additional direct effect on …

Towards Analytical Techniques For Optimizing Knowledge Acquisition, Processing, Propagation, And Use In Cyberinfrastructure, Leonardo Octavio Lerma

Open Access Theses & Dissertations

For many decades, there has been a continuous progress in science and engineering applications.

A large part of this progress comes from the new knowledge that researchers acquire, propagate, and use. This new knowledge has revolutionized many aspects of our life, from driving to communications to shopping.

Somewhat surprisingly, there is one area of human activity which is the least impacted by the modern technological progress: the very processes of acquiring, processing, and propagating information. When we decide where to place sensors, which algorithm to use for processing the data – we rely mostly on our own intuition and on …

Synthesis Of Benzofused-P-Indolequinones From 1,4-Naphthoquinone And Selective N-Debenzylation By Dess-Martin Periodinane, Quang Huynh Luu

Open Access Theses & Dissertations

p-Indolequinones are important heterocycles since they display interesting bioactivities such as anticancer activities as well as the ability to trigger drug release in drug targeting research. Additionally, they are also useful in precursors for the synThesis of bioactive compounds. Over decades, many methodologies have been investigated for the synThesis of p-indolequinones. Among those, cyclization of quinones plays an important role in convenient synThesis of these compounds. However, the great majority of these methods only describe quinones as electrophiles in cyclization. In our research, we found an intramolecular nucleophilic attack of quinone to an in-situ generated carbonyl group and developed a …

Does Low-Level Arsenic Exposure Predict Blood Pressure In Children?, Tania Angelica Mayorga

Open Access Theses & Dissertations

Background & Significance: Inorganic arsenic is a heavy metal naturally found in soil and human exposure to this heavy metal causes adverse effects. Exposure risks are particularly high in developing children. Arsenic is mainly found in bedrock. It is also a by-product of smelting, it is used in cement production, and historically is has been found in crop pesticides. Among other ill-effects, arsenic exposure in humans can cause respiratory diseases, peripheral neuropathy and liver fibrosis. In particular arsenic has been shown in many studies to be a contributing factor in the risk for hypertension in adults however no studies have …

High Performance Computing In Air Quality Models An Their Applications, Roberto A. Perea

Open Access Theses & Dissertations

High Performance Computing has become an important tool for many applications and services in the areas of Air Quality research. One important aspect is the use of computational technology in simulation and modeling of complex Air Quality models which makes it affordable in terms of data analysis, processing and speed. For this Dissertation, three projects using Air quality models were developed using high performance computing.

For the first project, ozone concentrations for the Paso del Norte Region are simulated using air quality models and compared against experimental data. For the second project, the Development of models and optimization of codes …

Processing And Property Evaluation Of Tungsten-Based Mixed Oxides For Photovoltaics And Optoelectronics, Mirella Vargas

Open Access Theses & Dissertations

Tungsten Oxide (WO3) films and low-dimensional structures have proven to be promising candidates in the fields of photonics and electronics. WO3 is a well-established n-type semiconductor characterized by unique electrochromic behavior, an ideal optical band gap that permits transparency over a wide spectral range, and high chemical integrity. The plethora of diverse properties endow WO3 to be highly effective in applications related to electrochromism, gas sensing, and deriving economical energy. Compared to the bulk films, a materials system involving WO3 and a related species (elements or metal oxides) offer the opportunity to tailor the electrochromic response, and an overall enhancement …

Comparison Of Blood Lead Levels Between Children In An Urban Setting And Children In A Rural Setting, Juan Manuel Alvarez

Open Access Theses & Dissertations

Environmental heavy metal exposure is a public health problem that is of great concern because it is highly toxic for children. The urban setting in downtown El Paso is historically known to be contaminated through various sources of contamination of heavy metals. The goal of this study was to compare whether children in a historically contaminated urban downtown area had significantly increased levels of lead exposure as compared to children in a demographically similar rural area approximately 20 miles north of the urban center, while controlling for gender and age. Cadmium and mercury were also measured for comparison purposes. It …

Associativity Forcing Commutativity In Left Nil Rings, Md Al Masum Bhuiyan

Open Access Theses & Dissertations

Our study in this thesis is concentrated on the AFC groups (Associativity Forces Commutativity) and observing the ring structure there. We are looking for abelian groups yielding ring structures (K) where associativity forces commutativity. We call them K-AFC groups.

We consider that the only conditions put on a ring multiplication are the distributive laws over the additive group addition. After [1], We say that an abelian group (G, +) is an AFC-group if (i) there exists a nonassociative and noncommutative ring (G, +, ˙) and (ii) all associative rings (G, +, ˙) are commutative.

We call a ring left-nil if …

Salt And Mineral Recovery From High Salinity Waters, Osvaldo Alejandro Broesicke

Open Access Theses & Dissertations

Natural salt springs in the Salt Fork Basin in Crosby County, Texas, result in the natural salt pollution of the Brazos River, rendering it unusable for most potable purposes. Previous research indicates that by intercepting the source of the pollution, water quality of the Brazos River can be greatly improved. This paper investigates and assesses two strategies for salt and mineral recovery using natural brine collected from the Salt Fork Basin, the first of which is presented in a separate work.

The research described in this paper evaluates the potential of a desulfation, soda-caustic softening, acidification/decarbonation, and evaporation process to …

Investigation Of The Natural Degradation Of Selected Endocrine Disrupting Compounds In Wastewater, Toni Carrick

Open Access Theses & Dissertations

Endocrine disrupting compounds (EDCs) are a class of compounds that are of concern for their potentially adverse effects on fish, wildlife, and humans. They can cause developmental and reproductive anomalies at concentrations in the low ppb to ppt levels. Studies have shown the primary route of exposure of EDCs within the environment is through the discharge of effluent wastewater. Removal efficiencies of wastewater treatment plants have been studied extensively, however, in rural or developing areas, which often lack secondary or tertiary wastewater treatment, little is known about the stability of these compounds and the rate at which they degrade in …

Study Of A Directly Heated Oxy-Fuel Supercritical Power Generation System, A S M Arifur Rahim Chowdhury

Open Access Theses & Dissertations

The Directly heated supercritical oxy-fuel gas turbines have the potential to become an important addition to current power generation systems. They provide a higher thermal efficiency and more effective carbon capture techniques than existing gas turbines. Due to the higher density of the working fluids, the turbomachinery size in these systems can be reduced significantly; this will facilitate to minimize the operational cost. To achieve supercritical working fluid at the turbine inlet combustion needs to be conducted under enormous amounts of pressure; these values are is about 10 times those found in the present gas turbines. Additionally, existing material operational …

Characterization Of Kendex® 0834 (Heavy Resins) & Kendex® 0897 (Light Resins), Victor Correa

Open Access Theses & Dissertations

Characterization of crude oil and some of its refined products has always been a challenge in the refining industry. This is mainly due to the high molecular complexity of crude oil. In this research, Heavy and Light Resins extracted from Penn Grade crude oil were analyzed with a wide variety of techniques, ranging from X-Ray Diffraction, Electron Microscopy, Fourier Transformed Infrared, C-13 Nuclear Magnetic Resonance, and chromatographic methods. An asphaltene extraction protocol was performed on both products. Only the Heavy Resin sample yielded a low amount of asphaltene. Results show that both Resins have a high degree of carbon branching, …

An Assessment Of The Role Of Roads In Population Demography And Genetic Structuring In Two Species Of Lizards In The Northern Chihuahuan Desert, Kevin Floyd

Open Access Theses & Dissertations

Roads can fragment habitat and increase mortality rates of wildlife, potentially reducing population sizes and gene flow, which in turn can reduce genetic diversity through genetic drift. Although negative road impacts have been found in a variety of taxa, not all species are impacted. For instance, species that move less and rarely encounter roads and those that avoid the roads are predicted to not be negatively affected. Yet tests of these predictions are uncommon, especially for reptiles and particularly lizards. Side-blotched lizards (Uta stansburiana) are small sit-and-wait predators, while the larger marbled whiptails (Aspidoscelis marmorata) are active foragers. Their responses …

Trace Element Behavior During Coal Combustion: Insights From Cadmium And Zinc Isotope Analysis, Fotios Fouskas

Open Access Theses & Dissertations

Due to its low cost and abundance, coal has been pervasively used in recent decades to meet large energy demands worldwide. Coal combustion provides the dominant electrical source in the U.S and produces over 100 million tons of coal combustion products (CCPs) per year domestically. The disposal/beneficial use of CCPs has the potential to release toxic trace elements, including cadmium (Cd) and zinc (Zn), into the environment. High temperature combustion of coal changes both physical states and chemical properties of Cd and Zn compounds in CCPs. Related processes such as evaporation and condensation, can lead to mass-dependent fractionation of Cd …

Effect Of Plastic Deformation Anisotropies On Shock-Induced Phase Transitions In Metallic Single Crystals, Punam Ghimire

Open Access Theses & Dissertations

Most metals and alloys undergo plastic deformation at shear stresses and/or pressures in the Kbars regime. On the other hand, typical pressure-induced structural transitions, take place at much higher pressures, in the tens of GPa range. Surprisingly, there has not been to date, a systematic study on the role plastic deformation plays on the dynamics of defect-mediated phase transformations. The main purpose of this work was to investigate via atomistic simulations, the contribution of pre-existing defect densities on the kinetics of structural transformations under dynamic loading. We have carried out molecular dynamics simulations - including large-scale non-equilibrium molecular dynamics (NEMD), …

The Meteorological Conditions Affecting The Propagation Of Respiratory Diseases, Rosette Maria Gonzalez

Open Access Theses & Dissertations

Valley Fever, also known as Coccidioidomycosis, is endemic of the US Southwest. In 2012 this disease was the second most-reported disease in Arizona, according to the New Yorker January 2014 edition. The Paso Del Norte Region (PdN) is a semi-arid region with significant agricultural acreage and Valley Fever is known to be a threat in this region. It is our goal in this Thesis work to apply an existing PBL Height Program (e.g., Liu, et.al.) to the Paso Del Norte Region (PdN) to study the effect it has in the transmission of Valley Fever. Obtaining the PBLH as it evolves …

Physical Engagement As A Way To Increase Emotional Rapport In Interactions With Embodied Conversational Agents, Ivan Gris Sepulveda

Open Access Theses & Dissertations

One of the major goals in research on embodied conversational agents (ECAs) is to increase the believability and perceived trustworthiness of agents. To improve the efficacy of the interaction between humans and ECAs, I focus on the development of rapport, which is a complex and extensive behavioral state of affinity, synchronicity, coordination and mutual understanding that is difficult to model, measure and interpret. I present our AGENT Framework and our ECA, Adriana, which is capable of speech recognition and gesture recognition over long periods of time. Our current system provides up to 60 minutes of human-ECA interaction in a jungle-survival …

Multi-Expert Multi-Criteria Decision Making, Joel Henderson

Open Access Theses & Dissertations

Expert analysis and decisions are highly valued assets in a wide variety of fields, from social services to grant funding committees. However, the use of experts can be prohibitive due to either lack of availability or cost. As such, it is desirable to be able to replicate such decisions. However, there are many obstacles that impede an accurate simulation of expert decisions. For example, despite looking at the same information, two experts may disagree on the decisions. In addition, a single expert may make inconsistent decisions across similar scenarios.

In this work, we focus on multi-criteria decision making and in …

High Temperature Helical Tubular Receiver For Concentrating Solar Power System, Nazmul Hossain

Open Access Theses & Dissertations

In the field of conventional cleaner power generation technology, concentrating solar power systems have introduced remarkable opportunity. In a solar power tower, solar energy concentrated by the heliostats at a single point produces very high temperature. Falling solid particles or heat transfer fluid passing through that high temperature region absorbs heat to generate electricity. Increasing the residence time will result in more heat gain and increase efficiency. A novel design of solar receiver for both fluid and solid particle is approached in this paper which can increase residence time resulting in higher temperature gain in one cycle compared to conventional …

Wind Farm Optimization Using Evolutionary Algorithms, Carlos Marco Ituarte-Villarreal

Open Access Theses & Dissertations

In recent years, the wind power industry has focused its efforts on solving the Wind Farm Layout Optimization (WFLO) problem. Wind resource assessment is a pivotal step in optimizing the wind-farm design and siting and, in determining whether a project is economically feasible or not. In the present work, three (3) different optimization methods are proposed for the solution of the WFLO: (i) A modified Viral System Algorithm applied to the optimization of the proper location of the components in a wind-farm to maximize the energy output given a stated wind environment of the site. The optimization problem is formulated …

Japanese Computational Lexicon: A Computational Dictionary Of Japanese Verb Forms, Mayumi Kobayashi

Open Access Theses & Dissertations

This paper presents two main topics: a linguistic analysis of Japanese morphological lexicon focused on verb conjugation and a computational analysis of Japanese verb conjugation in Prolog programming. Prolog is one of the computer programming languages and is used to solve a problem logically with a number of statements called "clauses," which are defining various relationships of the entities. With respect to the linguistic aspect, this paper discusses Japanese verb formation, its conjugation patterns, twelve basic forms of Japanese verbs, and a Japanese morphophonemic process called “音便 (onbin)” by investigating 304 regular verbs and 2 irregular verbs. Among the several …

Transition Metal Carbide (Tmc) Novel Materials For Novel Catalytic Applications, Svetlana Lagoykina

Open Access Theses & Dissertations

Transition metal carbides (TMC) constitute a diverse class of materials and traditionally have many technological applications. TMC became a subject of extensive research since 1973, when their platinum -like properties were discovered. They demonstrated high catalytical activity and selectivity in a variety of chemical reaction and have potential for some novel catalytic application.

This research is an effort to design new high effective, selective and stable bimetal or alkali promoted TMC catalyst. After extensive theoretical research a wide range of TMC, including bimetal and alkali promoted carbides, were synthesized by different methods. All solids were characterized by XRD and microscopy. …

On The Path To Multi-Electron Redox Chemistry With Bimetallic Systems, Nathalie Metta

Open Access Theses & Dissertations

The following study is presented in two sections, in the first, a novel digold (II) complex with semi-bridging chlorides supported by two bulky formamidinates was synthesized for the purpose of studying late-transition metal multi-electron redox chemistry. Electrochemical analysis shows one non-reversible reduction. Although the electrochemistry of this complex is restricted, the compound shows interesting electronic properties. The crystal structure reveals a geometry distortion of the Au2ï?­-Cl2 core. The coupling of an unoccupied orbital and an occupied orbital through a vibrational mode, causes a distortion in the geometry of the molecule lowering the D2h symmetry to C2h. This is an example …

When Can The Primitive Element Be Written As A Sum Of Two Algebraic Elements Adjoined To The Field Of The Rational Numbers, Mohamad Moussa

Open Access Theses & Dissertations

Given a field F and elements \alpha and \beta not in F, then F(\alpha, \beta) is the smallest field containing \alpha,\beta, and F. A simple extension is a field extension which is generated by the adjunction of a single element. The Primitive Element Theorem says that if F is a field of characteristic 0, and \alpha and \beta are algebraic over F, then there is an element \gamma in F(\alpha ,\beta ) such that

F(\alpha ; \beta ) = F(\gamma). When can we say that \gamma=\alpha+\beta? We will introduce some situations where \gamma=\alpha+\beta is true and some when this is …

Latina/O High School Students' Standpoint On Environmental Justice In A Border Community: A Phenomenological Study, Cynthia Christina Ontiveros

Open Access Theses & Dissertations

This qualitative research is a transcendental phenomenology seeking to understand Latin@ high school students’ perceptions and standpoints as they participated lessons that addressed border environmental justice issues in an underrepresented, marginalized community. Seven students from Borderland High School, enrolled in a senior level course, Environmental Science, participated in the study which focused on their experiences in an environmental justice air quality thematic unit built around the complex issues surrounding a local refinery, American Smelting and Refining Company (ASARCO). The study analyzed the meaning students made and their standpoints regarding the impact of the factory and its one-hundred year history polluting …