Physical Sciences and Mathematics Commons^™

Structure-Function Relationships In Poly(3-Hexylthiophene)S Formed Via Manipulation Of Oxidative Coupling Routes, Warren James Solfiell

LSU Doctoral Dissertations

This investigation focused on the analytical characterization of poly(3-hexylthiophene), a heterocyclic conducting polymer system, with an overall objective of elucidating the effects that the experimental conditions during chemical oxidation using iron(III) chloride as an oxidant impart on the structure of the resulting polymers. Poly(3-alkylthiophene)s are extensively studied materials due to their high electrical conductivities and unique optical properties that make them extremely valuable for use in contemporary technological applications and devices. Specifically, the aim of this research was to determine the dependence of structural characteristics, such as endgroups, molecular weights, and regioregularities, on the solvent employed for the reaction and …

Some Classes Of Graphs That Are Nearly Cycle-Free, Lisa Warshauer

LSU Doctoral Dissertations

A graph is almost series-parallel if there is some edge that one can add to the graph and then contract out to leave a series-parallel graph, that is, a graph with no K₄-minor. In this dissertation, we find the full list of excluded minors for the class of graphs that are almost series-parallel. We also obtain the corresponding result for the class of graphs such that uncontracting an edge and then deleting the uncontracted edge produces a series-parallel graph.

A notable feature of a 3-connected almost series-parallel graph is that it has two vertices whose removal leaves a …

Marketing Forest-Based Ecotourism In Sri Lanka: Predicting The Ecotourism Behavior And Defining The Market Segment Through A Behavioral Approach, Polwattage K. Perera

LSU Doctoral Dissertations

Tourism industry is one of the main drivers of the global economy and plays a key role in regional development. As negative environmental and socio-cultural impacts of mass tourism became apparent, the appeal of alternative forms of tourism, especially ecotourism, continued to gain a broad recognition. As a result, ecotourism became one of the fastest growing sectors in global tourism during the past decade. Being a fast-developing country with ample natural resources, Sri Lanka can benefit from adopting and promoting ecotourism. At present, Sri Lanka’s ecotourism resources remain largely under-utilized. With rising demand, ecotourism operators are under pressure to meet …

Twisted Frobenius-Schur Indicators For Hopf Algebras, Maria Vega

LSU Doctoral Dissertations

The classical Frobenius--Schur indicators for finite groups are character sums defined for any representation and any integer $m\ge 2$. In the familiar case $m=2$, the Frobenius--Schur indicator partitions the irreducible representations over the complex numbers into real, complex, and quaternionic representations. In recent years, several generalizations of these invariants have been introduced. Bump and Ginzburg in 2004, building on earlier work of Mackey from 1958, have defined versions of these indicators which are twisted by an automorphism of the group. In another direction, Linchenko and Montgomery in 2000 defined Frobenius--Schur indicators for finite dimensional semisimple Hopf algebras. In this dissertation, …

A New Theory Of Stochastic Integration, Anuwat Sae-Tang

LSU Doctoral Dissertations

In this dissertation, we focus mainly on the further study of the new stochastic integral introduced by Ayed and Kuo in 2008. Several properties of this new stochastic integral are obtained. We first introduce the concept of near-martingale for non-adapted stochastic processes. This concept is a generalization of the martingale property for adapted stochastic processes in the It\^o theory. We prove a special case of It\^o isometry for the stochastic integral of certain instantly independent processes. We obtain some formulas for expressing a new stochastic integral in terms of It\^o integrals and Riemann integrals. Several generalized versions of It\^o's formula …

Fully Integrated Microsystem For Bacterial Genotyping, Hui-Wen Chen

LSU Doctoral Dissertations

Methods for bacterial detection and identification has garnered renewed interest in recent years due to the infections they may cause and the antimicrobial resistances they can develop, the potential for bioterrorism threats and possible contamination of food/water supplies. Therefore, the rapid, specific and accurate detection of pathogens is crucial for the prevention of pathogen-related disease outbreaks and facilitating disease management as well as the containment of suspected contaminated food and/or water supplies. In this dissertation an integrated modular-based microfluidic system composed of a fluidic cartridge and a control instrument has been developed for bacterial pathogen detection. The integrated system can …

Kinetics And Mechanisms Of Release By Redox-Active Liposomes In Drug Delivery, Jerimiah Forsythe

LSU Doctoral Dissertations

Liposomes have had a long and fruitful application of drug delivery devices in the treatment of select tumors and cancer types. Third-generation liposomes possess endogenous triggering methods that hold the ability for site-specific unloading of liposomal contents, thus providing necessary temporal and spatial control over contents release that can be tuned to match the drug efficacy for decreased side effects during treatment. Of these new endogenous triggers, redox-active liposomes that can be triggered to unload contents via two-electron reduction by enzymes or chemical means have demonstrated promise for the encapsulation and delivery of cargo. The research project undertaken involved the …

Application Of Scanning Probe Microscopy For New Physical Measurements And Studies Of Surface Chemical Reactions Of Materials At The Molecular Level, Stephanie Loletha Daniels

LSU Doctoral Dissertations

Scanning probe microscopy (SPM) provides unique capabilities for surface visualization and measurements that reach atomic and molecular dimensions. My research focus is directed toward applying and developing new measurements for analytical and surface chemistry with SPM. Two distinct goals based on studies with atomic force microscopy (AFM) will be described within this dissertation. The primary goal was to develop and apply a new AFM imaging mode for ultrasensitive measurements of the superparamagnetic properties of proteins. Magnetic sample modulation (MSM)-AFM, has capabilities to investigate and map the magnetic response of nanomaterials with unprecedented spatial resolution. The second goal was to apply …

Characterization And Prototyping Of The Rotating Modulator Hard X-Ray/Gamma-Ray Telescope, Brent Budden

LSU Doctoral Dissertations

A hard x-ray/gamma-ray telescope with high sensitivity and wide field of view would be capable of performing an all-sky census of black holes over a wide range of obscuration and accretion rates. As an example, NASA's Black Hole Finder Probe mission was designed to provide a 5-sigma flux sensitivity in a 1-year observation of ~0.02 mCrab in the 10 - 150 keV energy range and 0.5 mCrab in the 150 - 600 keV energy range with 3 - 5 minutes of arc angular resolution. These are significantly higher sensitivity and resolution goals than those of current instruments. The design focus …

On Greenberg's Question: An Algebraic And Computational Approach, David H. Chapman

LSU Doctoral Dissertations

Greenberg asked whether arithmetically equivalent number fields share the same Iwasawa invariants. In this dissertation it is shown that the problem naturally breaks up into four cases, depending on properties of Galois groups. This analysis is then used to give a positive answer to Greenberg’s question in some nontrivial examples.

Spatial Ecology Of Adult Spotted Seatrout, Cynoscion Nebulosus, In Louisiana Coastal Waters, Jody Lynn Callihan

LSU Doctoral Dissertations

Spotted seatrout, Cynoscion nebulosus, are common in estuaries and coastal waters of the south Atlantic and Gulf of Mexico and are of considerable recreational and economic importance. Still, the spatial ecology of this species is under-studied and poorly resolved, especially in Louisiana waters. To address this important knowledge gap, I examined the movements, distribution, and habitat use of adult spotted seatrout in coastal Louisiana primarily using high-resolution acoustic telemetry and secondarily, conventional tagging (mark-recapture) data. At the largest spatial scale investigated, I found that adults exhibited a high degree of estuarine fidelity and rarely undertook large-scale movements in excess of …

Cognitive Radio Network With A Distributed Control Channel And Quality-Of-Service Solution, Urban Terrell Wiggins

LSU Doctoral Dissertations

The proliferation of wireless access and applications to the Internet and the advent of a myriad of highly evolved portable communication devices; creates the need for an efficiently utilized radio spectrum. This is paramount in the licensed and unlicensed radio frequency bands, that spawn an exponential growth in Dynamic Spectrum Access (DSA) research, Cognitive Radio (CR) and Cognitive Radio Networks (CRN) research. DSA research has given way to the paradigm shift toward CR with its dynamic changes in transmission schemas. This paradigm shift from a fixed and centralized frequency spectrum environment has morphed into a dynamic and decentralized one. CR …

Integrated Modular Microfluidic System For Forensic Alu Dna Typing, Samuel Kimani Njoroge

LSU Doctoral Dissertations

Driven by the numerous applications of genome-related research, fully integrated microfluidic systems have been developed that have advanced the capabilities of molecular and, in particular, genetic analyses. A brief overview on integrated microfluidic systems for DNA analysis is given in Chapter 1 followed by a report on micro-capillary electrophoresis (µCE) of Alu elements with laser-induced fluorescence (LIF) detection, in which the monomorphic Alu insertions on the X and Y chromosomes were utilized to detect male DNA in large female DNA background (Y: X = 1:19) without cell sorting prior to the determination. The polymorphic Alu loci with known restricted geographical …

Quality Of Service Based Data-Aware Scheduling, Archit Kulshrestha

LSU Doctoral Dissertations

Distributed supercomputers have been widely used for solving complex computational problems and modeling complex phenomena such as black holes, the environment, supply-chain economics, etc. In this work we analyze the use of these distributed supercomputers for time sensitive data-driven applications. We present the scheduling challenges involved in running deadline sensitive applications on shared distributed supercomputers running large parallel jobs and introduce a ``data-aware'' scheduling paradigm that overcomes these challenges by making use of Quality of Service classes for running applications on shared resources. We evaluate the new data-aware scheduling paradigm using an event-driven hurricane simulation framework which attempts to run …

Aquatic Macroinvertebrate And Nekton Community Structure In A Chenier Marsh Ecosystem: Implications For Whooping Crane Prey Availability, Sung-Ryong Kang

LSU Doctoral Dissertations

A suitable foraging habitat model based on prey density, biomass, and energy values in varying hydrologic conditions can provide an objective quantifiable method to assess habitat conditions for the Whooping Crane (Grus americana). Nekton and macroinvertebrates are considered the important prey sources in Whooping Crane's diet at different times. This study focuses on the understanding of habitat relationships of nekton and macroinvertebrate assemblage in the Chenier Plain to provide a foundation for the development for foraging suitability models for the reintroduced Whooping Crane. In this dissertation, in a laboratory study I experimentally examined the effect of salinity on …

Semiconducting Polymers And Block Copolymers Prepared By Chain-Growth Living Polymerization, Jinwoo Choi

LSU Doctoral Dissertations

Organic semiconducting polymers are the unique materials that considered a basis for the next generation of electronic and optoelectronic applications. However, high device performance of semiconducting polymers strongly depends on their molecular structure and nanoscale organization. Therefore, it is an essential task to develop robust and versatile synthetic approaches to build such well-defined semiconducting polymer materials. This Ph.D. study aimed at design of state-of-the-art synthetic approaches towards organic semiconducting polymers via chain-growth living polymerization as well as development of polymer architectures which can self-organize into supramolecular nanoassemblies or allow external control of the polymer’s properties. First, we prepared a series …

Influences Of Landscape Characteristics On The Nesting Ecology Of Female Wild Turkeys And Behavior Of Raccoons, Michael E. Byrne

LSU Doctoral Dissertations

Nest predation is the principle source of reproductive failure in many bird species. Understanding nest predation requires knowledge of interactions between landscape characteristics, and the ecology and behavior of birds and local nest predators. I studied nesting ecology and multi-scale habitat selection of female wild turkeys and the habitat selection and searching behaviors of raccoons, an important nest predator, in a bottomland hardwood forest in Louisiana. My objective was to evaluate the relationships between habitat, wild turkey nest site selection, and raccoon foraging behavior. I used first-passage time (FPT) analysis on nightly foraging tracks of raccoons during the turkey nesting …

Extreme Scale Parallel Nbody Algorithm With Event Driven Constraint Based Execution Model, Chirag Dekate

LSU Doctoral Dissertations

Traditional scientific applications such as Computational Fluid Dynamics, Partial Differential Equations based numerical methods (like Finite Difference Methods, Finite Element Methods) achieve sufficient efficiency on state of the art high performance computing systems and have been widely studied / implemented using conventional programming models. For emerging application domains such as Graph applications scalability and efficiency is significantly constrained by the conventional systems and their supporting programming models. Furthermore technology trends like multicore, manycore, heterogeneous system architectures are introducing new challenges and possibilities. Emerging technologies are requiring a rethinking of approaches to more effectively expose the underlying parallelism to the applications …

Stories Of The Proterozoic Earth: Paleoproterozoic Chuanlinggou Arcitarchs And Neoproterozoic ¹⁷O-Depleted Barite, Yongbo Peng

LSU Doctoral Dissertations

This dissertation consists of two independent topics, both critical to understanding Earth history during the Proterozoic Eon. (1) Paleoproterozoic Chuanlinggou Acritarchs: The eukaryotic affinity of acritarchs from the Chuanlinggou Formation has been questioned because of lack of indisputable morphological evidence. In this study, Chuanlinggou acritarchs were examined by jointly using optical microscopy, scanning electron microscopy, and transmission electron microscopy. In most cases, an ovoidal group of acritarchs represents a half-vesicle following a complete longitudinal rupture, which is a morphological model different from a whole envelope with medial splits, as proposed by earlier studies. This ovoidal group displays a bipolar morphology, …

Sensor-Based Autonomous Pipeline Monitoring Robotic System, Jong-Hoon Kim

LSU Doctoral Dissertations

The field of robotics applications continues to advance. This dissertation addresses the computational challenges of robotic applications and translations of actions using sensors. One of the most challenging fields for robotics applications is pipeline-based applications which have become an indispensable part of life. Proactive monitoring and frequent inspections are critical in maintaining pipeline health. However, these tasks are highly expensive using traditional maintenance systems, knowing that pipeline systems can be largely deployed in an inaccessible and hazardous environment. Thus, we propose a novel cost effective, scalable, customizable, and autonomous sensor-based robotic system, called SPRAM System (Sensor-based Autonomous Pipeline Monitoring Robotic …

Exotic Ground States: A Study In The Structural Effects On Frustration And Dimensionality, Melissa C. Menard

LSU Doctoral Dissertations

Structural disorder and dimensionality play central roles in the characterization of structure and properties of crystalline materials. Although structural disorder is commonly considered an undesirable quality, structural disorder may be desirable when searching for new materials with exotic properties. Disorder can be used as a tunable parameter when considering atomic sizes, coordination preferences, and electronegativity differences can be varied by substituting elements into a given structure. Dimensionality can be viewed as another adjustable parameter when searching for new materials presenting unique challenges when characterizing new materials. One way to tune dimensionality is by chemical doping to affect coupling between layers/chains. …

Fragmentation Sensitivity And Its Consequences On Demography And Host-Ectoparasite Dynamics In Amazonian Birds, Erik I. Johnson

LSU Doctoral Dissertations

The Amazon rainforest is experiencing rapid deforestation due to ranching, agriculture, and urban development, which often leads to remnant patches serving as refugia for forest organisms. By mist-netting passerines in 11 forest fragments (1-, 10-, and 100-ha patches) and nearby continuous forest at the Biological Dynamics of Forest Fragmentation Project near Manaus, Brazil, I conducted a series of studies to identify mechanisms that drive population changes in fragmented landscapes. First, I examined the age structure of bird populations from six ecological guilds in fragments and continuous forest. Immatures are the dispersing age group in birds, and their relative abundance in …

Synthesis, Biological And Photophysical Studies Of Novel Compounds For Cancer Therapy, Edith Khavwajira Amuhaya

LSU Doctoral Dissertations

Cancer remains the second most common cause of death in the United States. It is therefore imperative that a lot of effort be put into finding a cure for this dreadful disease that shows no discrimination, and virtually anybody is at risk of developing the disease. Chapter 1 introduces basic facts about cancer and the available treatments, including PDT and BNCT. Our focus will be on these two bimodal therapies, which form the basis of my research work, which involves the synthesis of potential sensitizers to be used either in PDT or BNCT or both. In Chapter 2, I discuss …

Next Generation Multi-Scale Quantum Simulations For Strongly Correlated Materials, Shuxiang Yang

LSU Doctoral Dissertations

This thesis represents our effort to develop the next generation multi-scale quantum simulation methods suitable for strongly-correlated materials, where complicated phase-diagrams prevail, suggesting complicated underlying physics. We first give a detailed description of the parquet formalism. With its help, different approximate methods can be unified and a hierarchy of approximate methods with different accuracies and computational complexity can thus be designed. Next, we present a numerical solution of the parquet approximation. Results on the Hubbard model are compared to those obtained from Determinant Quantum Monte Carlo (DQMC), FLuctuation EXchange (FLEX), and self-consistent second-order approximation methods. The comparison shows a satisfactory …

The Effect Of Habitat Change On Nutrient Removal In The Atchafalaya River Basin, Louisiana, Amy E. Scaroni

LSU Doctoral Dissertations

The Mississippi and Atchafalaya rivers are the major sources of freshwater and nutrients to the Gulf of Mexico. Increased nutrient loads from these rivers exacerbate eutrophication in coastal receiving waters and contribute to the large area of hypoxia that develops seasonally in the Gulf. Levees along the Mississippi River have reduced contact between the river and the historic floodplain; this limits the ability of floodplain wetlands to naturally mitigate excess nutrients. However, the Atchafalaya River diverges from the Mississippi 217 km from the Gulf and enters a large river floodplain with a widely spaced levee system. This enhances the ability …

Oceanic Light Absorption Properties: Assessment And Characterization In The Southeastern Bering Sea Using Field And Satellite Observations, Puneeta Suresh Naik

LSU Doctoral Dissertations

In recent decades the Bering Sea has been subjected to large climatic variability with cascading consequences on its productive marine ecosystem. Long-term as well as short-term monitoring is essential if we are to maintain its capability to supply the resources on which the national and local economy depend. Remote sensing together with in-situ and laboratory measurements of physical, biological and optical properties have considerable potential for monitoring and measuring the effects of climate-driven changes on this ecosystem. A major shortcoming to obtain accurate estimates of optically active components (such as colored dissolved organic matter, non-algal particulate matter, and phytoplankton) from …

Two-Particle Level Diagrammatic Approaches For Strongly Correlated Systems, Herbert Fotso

LSU Doctoral Dissertations

This thesis presents the development of new numerical methods for the treatment of strongly correlated electron systems based on self-consistent approaches at both the one and the two-particle level such as the parquet formalism. The parquet formalism was solved for the first time on a two-dimensional cluster. When the fully irreducible vertex is approximated by the bare vertex, we obtain the parquet approximation. Its validity was investigated by comparing results that it produces to those of other conserving approximations such as the FLuctuation EXchange (FLEX) approximation or the Second Order Perturbation Theory (SOPT). We found that it provides a significant …

Variability In Red Snapper Otolith Microchemistry Among Gulf Of Mexico Regions, Michelle Zapp Sluis

LSU Doctoral Dissertations

Red snapper, Lutjanus campechanus, has been an economically important reef fish in the Gulf of Mexico (Gulf) for over 150 years and is currently overfished. Catch statistics and demographic differences have lead to the population being categorized into eastern and western substocks divided by the Mississippi River, but data is recombined to set a Gulf-wide annual catch limit. The two objectives of this study were to apply otolith nursery chemical signatures to estimate red snapper mixing dynamics in the western Gulf, and to determine if signatures based upon trace metals associated with oil and gas platforms could discriminate between region …

Capturing Elements In Matroid Minors, Deborah Chun

LSU Doctoral Dissertations

In this dissertation, we begin with an introduction to a matroid as the natural generalization of independence arising in three different fields of mathematics. In the first chapter, we develop graph theory and matroid theory terminology necessary to the topic of this dissertation. In Chapter 2 and Chapter 3, we prove two main results. A result of Ding, Oporowski, Oxley, and Vertigan reveals that a large 3-connected matroid M has unavoidable structure. For every n exceeding two, there is an integer f(n) so that if |E(M)| exceeds f(n), then M has a minor isomorphic to the rank-n wheel or whirl, …

Testing And Improving The Luminosity Relations For Gamma-Ray Bursts, Andrew Collazzi

LSU Doctoral Dissertations

Gamma Ray Bursts (GRBs) have several luminosity relations where a measurable property of a burst light curve or spectrum is correlated with the burst luminosity. These luminosity relations are calibrated for the fraction of bursts with spectroscopic redshifts and hence the known luminosities. GRBs have thus become known as a type of "standard candle"; where standard candle is meant in the usual sense that their luminosities can be derived from measurable properties of the bursts. GRBs can therefore be used for the same cosmology applications as Type Ia supernovae, including the construction of the Hubble Diagram and measuring massive star …