Physical Sciences and Mathematics Commons^™

Experimental Investigation Of The Physical Properties Of Irmsnn (M = 1, 3 And N = 2, 4, 7), Smita Speer

LSU Doctoral Dissertations

Exploration of transition metal stannides, formed from a combination of transition metals (T) and Sn, has resulted in the discovery a variety of materials with interesting physical properties, which is in part due to the complexity of interactions that can occur between the T-d orbitals and Sn-p orbitals. There have been observations of (extremely) large magnetoresistance [1-4], topological flat and nearly flat bands [5-7], superconducting behavior in 2D and 3D systems [5, 8-11], ultrahigh carrier mobility [12-13], and more attributed to d-p orbital mixing in such systems. This dissertation will address the effects of T-Sn interactions …

Characterization Of Electrophoretic Deposited Zinc Oxide Nanopartices For The Fabrication Of Next-Generation Nanoscale Electronic Applications, Fawwaz Abduh A. Hazzazi

LSU Doctoral Dissertations

Several reports state that it is crucial to analyze nanoscale semiconductor materials and devices with potential benefits to meet the need for next-generation nanoelectronics, bio, and nanosensors. The progress in the electronics field is as significant now, with modern technology constantly evolving and a greater focus on more efficient robust optoelectronic applications. This dissertation focuses on the study and examination of the practicality of Electrophoretic Deposition (EPD) of zinc oxide (ZnO) nanoparticles (NPs) for use in semiconductor applications.

The feasibility of several synthesized electrolytes, with and without surfactants and APTES surface functionalization, is discussed. The primary objective of this study …

Surpassing The Standard Quantum Limit Using An Optical Spring, Torrey Cullen

LSU Doctoral Dissertations

In 1916, Albert Einstein predicted the existence of gravitational waves based on his new theory of general relativity. He predicted an accelerating mass with a non-zero quadrupole moment would emit energy in the form of gravitational waves. Often referred to as ripples in space-time, gravitational waves are extremely small by the time reach Earth, potentially having traveled hundreds of megaparsecs. It is common for these ripples in space-time to stretch and squeeze matter 1000 times smaller than the width of a proton.
Laser interferometer observatories were first built in the 1990s in the US and Europe, and as sensitivity improvements …

Breeding Ecology Of Mottled Ducks In Southwestern Louisiana, Elizabeth Sophia Bonczek

LSU Doctoral Dissertations

Mottled ducks are a resident species found in the southern United States that rely on coastal marsh and associated habitat to fulfill the needs of the entirety of their annual cycle. Population monitoring has revealed declines in western Gulf Coast (WGC) mottled ducks since 2008. Mottled duck populations are influenced by survival and recruitment, and changes in these factors may contribute to population declines. The overarching goal of this project was to identify the mechanisms potentially limiting WGC mottled ducks.

I captured adult female mottled ducks during molt on Rockefeller Wildlife Refuge and adjacent lands in southwestern Louisiana from 2017–2019. …

Optimizing The Performance Of Parallel And Concurrent Applications Based On Asynchronous Many-Task Runtimes, Weile Wei

LSU Doctoral Dissertations

Nowadays, High-performance Computing (HPC) scientific applications often face per- formance challenges when running on heterogeneous supercomputers, so do scalability, portability, and efficiency issues. For years, supercomputer architectures have been rapidly changing and becoming more complex, and this challenge will become even more com- plicated as we enter the exascale era, where computers will exceed one quintillion cal- culations per second. Software adaption and optimization are needed to address these challenges. Asynchronous many-task (AMT) systems show promise against the exascale challenge as they combine advantages of multi-core architectures with light-weight threads, asynchronous executions, smart scheduling, and portability across diverse architectures.

In …

Bloch Spectra For High Contrast Elastic Media, Jayasinghage Ruchira Nirmali Perera

LSU Doctoral Dissertations

The primary goal of this dissertation is to develop analytic representation formulas and power series to describe the band structure inside periodic elastic crystals made from high contrast inclusions. We use source free modes associated with structural spectra to represent the solution operator of the Lame' system inside phononic crystals. Then we obtain convergent power series for the Bloch wave spectrum using the representation formulas. An explicit bound on the convergence radius is given through the structural spectra of the inclusion array and the Dirichlet spectra of the inclusions. Sufficient conditions for the separation of spectral branches of the dispersion …

From Equal-Mass To Extreme-Mass-Ratio Binary Inspirals: Simulation Tools For Next Generation Gravitational Wave Detectors, Samuel Douglas Cupp

LSU Doctoral Dissertations

Current numerical codes can successfully evolve similar-mass binary black holes systems, and these numerical waveforms contributed to the success of the LIGO Collaboration's detection of gravitational waves. LIGO requires high resolution numerical waveforms for detection and parameter estimation of the source. Great effort was expended over several decades to produce the numerical methods used today. However, future detectors will require further improvements to numerical techniques to take full advantage of their detection capabilities. For example, the Laser Interferometer Space Antenna (LISA) will require higher resolution simulations of similar-mass-ratio systems than LIGO. LISA will also be able to detect extreme-mass-ratio inspiral …

Dynamics Of Polymer Melts And Polymer Nanocomposites Studied By Broadband Dielectric Spectroscopy, Mengchun Wu

LSU Doctoral Dissertations

Materials based on polymers and polymeric nanocomposites have properties advantageous for many applications. In many cases, the physical behavior is connected to molecular motion. Polymers are macromolecules in which both fast local motions and slower chain relaxations may contribute to the material properties. Answering fundamental questions on the molecular dynamics is challenging, because of the existence of many different processes and the strong temperature dependence of the processes. An investigation covering a broad window over many orders of magnitude in the time scale is needed. Hence, dielectric spectroscopy is an appropriate tool to enhance fundamental understanding. This dissertation pays special …

Ligers Interferometric Survey Of M Dwarf Diameters, Tyler Gregory Ellis

LSU Doctoral Dissertations

In this dissertation, I present the largest single collection of M dwarf stellar radii in over a decade and contextualize these measurements with the systematic model discrepancies. The measurements of stellar angular diameters are also important in the quantification of the properties of exoplanets. In order to estimate the property of the exoplanet, it is first necessary to quantify the properties of the planet's host star. Using the survey results complemented with previous direct observations of the angular diameters of low mass stars, I develop updated updated surface brightness relationships. These relationships allow predictions of angular diameters using easy to …

New Chemoselective Dehydration And Cyclization Strategies Enabled By Triphosgene, Moshood Oreofeoluwa Ganiu

LSU Doctoral Dissertations

Since Friedrich Wöhler’s synthesis of urea in 1828, the techniques of organic synthesis have developed and advanced greatly. This advancement has facilitated the discovery of new organic synthetic methods, and enabled access to a more expansive chemical space. The purpose of this dissertation is to present the development of new organic synthetic reactions that were uncovered through previous discoveries. Additionally, the main theme of this work relies on exploiting the versatility of triphosgene in organic synthesis. To this end, the developed chemistries rely on the ability of triphosgene to serve as an activating agent, and a chloride source.

Chapter 1 …

Efficient Low Dimensional Representation Of Vector Gaussian Distributions, Md Mahmudul Hasan

LSU Doctoral Dissertations

This dissertation seeks to find optimal graphical tree model for low dimensional representation of vector Gaussian distributions. For a special case we assumed that the population co-variance matrix $\Sigma_x$ has an additional latent graphical constraint, namely, a latent star topology. We have found the Constrained Minimum Determinant Factor Analysis (CMDFA) and Constrained Minimum Trace Factor Analysis (CMTFA) decompositions of this special $\Sigma_x$ in connection with the operational meanings of the respective solutions. Characterizing the CMDFA solution of special $\Sigma_x$, according to the second interpretation of Wyner's common information, is equivalent to solving the source coding problem of finding the minimum …

New Synthetic Reactions Enabled By Protected Oxyallyl And Amidoallyl Cations, Binod Nepal

LSU Doctoral Dissertations

This dissertation entails design and development of two new synthetic methodologies made possible through the generation of cationic species, namely oxyallyl and amidoallyl cations. Chapter 1 involves literature survey on generation and trapping of oxyallyl cations. Mostly known for cycloaddition reactions with these elusive species, the most recent approach of direct nucleophilic capture of oxyallyl cations are discussed. Apt design of substrates and reaction conditions by Kartika Group to access a-electrophilic carbon towards the synthesis of a variety of value-added compounds, i.e., 1,4- and 1,6-dicarbonyls, carbazoles, densely substituted pyrroles and furans are elaborated.

Chapter 2 focuses on our discovery of …

Tuning Properties Of Topological Insulators: An Ab-Initio Approach, Karunya Shailesh Shirali

LSU Doctoral Dissertations

This thesis develops a first-principles based approach to explore the tuning of topological properties of the tetradymite topological insulators. We begin by setting up a framework to systematically obtain the bulk and surface properties of topological insulators, treating the structural and electronic properties on an equal footing. We determine a consistent method for including the van der Waals interactions, which are responsible for the weak coupling between sets of atomic layers in this family of layered materials, which is important in obtaining accurate structural properties. We obtain close agreement with experimental values for both the bulk and surface states.

To …

Anticipating Stochastic Integrals And Related Linear Stochastic Differential Equations, Sudip Sinha

LSU Doctoral Dissertations

Itô’s stochastic calculus revolutionized the field of stochastic analysis and has found numerous applications in a wide variety of disciplines. Itô’s theory, even though quite general, cannot handle anticipating stochastic processes as integrands. There have been considerable efforts within the mathematical community to extend Itô’s calculus to account for anticipation. The Ayed–Kuo integral — introduced in 2008 — is one of the most recent developments. It is arguably the most accessible among the theories extending Itô’s calculus — relying solely on probabilistic methods. In this dissertation, we look at the recent advances in this area, highlighting our contributions. First, we …

Seismic Inversion And Modeling For Improving Earthquake Hazard Assessment, Rasheed Ajala

LSU Doctoral Dissertations

The substantial research and the uncertain timeline to achieve deterministic earthquake prediction make the ground-shaking estimation of realistic earthquake scenarios a helpful approach in seismic hazard assessment. The accuracy of these computations depends on having structural subsurface models with good representations of sedimentary basins, fault zones, and crustal heterogeneity. We develop higher resolution seismic models for the Coachella Valley in Southern California and Indo-Burma. These areas have rising populations, expanding infrastructure, and highly anticipated disruptive earthquakes. We utilize data from recent seismic deployments and newly developed seismic imaging algorithms and the techniques of travel time tomography, wave propagation simulation, and …

Synthesis, Characterization, And Photo-Reactivity Studies On Mo(Vi) Dioxo Complexes For C-H Activation And O-Atom Transfer, Saeed Fosshat

LSU Doctoral Dissertations

Metal oxos are important intermediates in various chemical transformations that include electron transfer, proton-coupled electron transfer (PCET) and and O-atom transfer. Various extent of π-bonding from the oxo ligands to the central metal causes changes in nucleophilicity and overall reactivity of these species. Several factors can influence the electronic structure of the M=O bonds such as central metal oxidation state, geometry, ancillary ligands and spin state of the metal. A general strategy to increase the reactivity of metal oxos is to use electron rich metal centers that are less oxophilic. As a result of this, extensive amount of research has …

Practical Considerations And Applications For Autonomous Robot Swarms, Rory Alan Hector

LSU Doctoral Dissertations

In recent years, the study of autonomous entities such as unmanned vehicles has begun to revolutionize both military and civilian devices. One important research focus of autonomous entities has been coordination problems for autonomous robot swarms. Traditionally, robot models are used for algorithms that account for the minimum specifications needed to operate the swarm. However, these theoretical models also gloss over important practical details. Some of these details, such as time, have been considered before (as epochs of execution). In this dissertation, we examine these details in the context of several problems and introduce new performance measures to capture practical …

Performing Memory Forensics For Object Recovery From Android Application Memory, Sneha Sudhakaran

LSU Doctoral Dissertations

The analysis of application-specific behavior has become an increasingly important technique in cyber forensics and incident response. The ability to determine the precise actions taken by a user can be the difference between a successful analysis and one that fails to meet its goals. The precise actions includes URLs visited, files downloaded, messages sent and received, images viewed, and data accessed. Evidence extraction from application memory at runtime is an effective solution to successfully extract valuable objects allocated by each application, and it is evident that there is a need for more Android forensics analysis tools that support recovering evidence …

A New Perspective On A Polynomial Time Knot Polynomial, Robert John Quarles

LSU Doctoral Dissertations

In this work we consider the Z1(K) polynomial time knot polynomial defined and
described by Dror Bar-Natan and Roland van der Veen in their 2018 paper ”A polynomial time knot polynomial”. We first look at some of the basic properties of Z1(K), and develop an invariant of diagrams Ψm(D) related to this polynomial. We use this invariant as a model to prove how Z1(K) acts under the connected sum operation. We then discuss the effect of mirroring the knot on Z1(K), and described a geometric interpretation of some of the building blocks of the invariant. We then use these to …

General Stochastic Calculus And Applications, Pujan Shrestha

LSU Doctoral Dissertations

In 1942, K. Itô published his pioneering paper on stochastic integration with respect to Brownian motion. This work led to the framework for Itô calculus. Note that, Itô calculus is limited in working with knowledge from the future. There have been many generalizations of the stochastic integral in being able to do so. In 2008, W. Ayed and H.-H. Kuo introduced a new stochastic integral by splitting the integrand into the adaptive part and the counterpart called instantly independent. In this doctoral work, we conduct deeper research into the Ayed–Kuo stochastic integral and corresponding anticipating stochastic calculus.

We provide a …

Advanced Communication And Sensing Protocols Using Twisted Light And Engineered Quantum Statistics, Michelle L. Lollie

LSU Doctoral Dissertations

Advanced performance of modern technology at a fundamental physical level is driving new innovations in communication, sensing capability, and information processing. Key to this improvement is the ability to harness the power of physical phenomena at the quantum mechanical level, where light and light-matter interactions produce technological advancement not realizable by classical means. Theoretical investigation into quantum computing, sensing capability beyond classical limits, and quantum information has prompted experimental work to bring state-of-the-art quantum systems to the forefront for commercial use. This dissertation contributes to the latter portion of the work. A set of preliminaries is included highlighting pertinent physical …

Characterizations Of Certain Classes Of Graphs And Matroids, Jagdeep Singh

LSU Doctoral Dissertations

``If a theorem about graphs can be expressed in terms of edges and cycles only, it probably exemplifies a more general theorem about matroids." Most of my work draws inspiration from this assertion, made by Tutte in 1979.

In 2004, Ehrenfeucht, Harju and Rozenberg proved that all graphs can be constructed from complete graphs via a sequence of the operations of complementation, switching edges and non-edges at a vertex, and local complementation. In Chapter 2, we consider the binary matroid analogue of each of these graph operations. We prove that the analogue of the result of Ehrenfeucht et. al. does …

Unavoidable Structures In Large And Infinite Graphs, Sarah Allred

LSU Doctoral Dissertations

In this work, we present results on the unavoidable structures in large connected and large 2-connected graphs. For the relation of induced subgraphs, Ramsey proved that for every positive integer r, every sufficiently large graph contains as an induced subgraph either K_r or K_r. It is well known that, for every positive integer r, every sufficiently large connected graph contains an induced subgraph isomorphic to one of K_r, K_1,r, and P_r. We prove an analogous result for 2-connected graphs. Similarly, for infinite graphs, every infinite connected graph contains an induced subgraph …

New Aspects Of Optical Coherence And Their Potential For Quantum Technologies, Nathaniel Robert Miller

LSU Doctoral Dissertations

Currently, optical technology impacts most of our lives, from light used in scientific measurement to the fiber optic cables that makeup the backbone of the internet. However, as our current optical infrastructure grows, we discover that these technologies are not limitless. Astronomers find themselves unable resolve stars that are too close to one another. Meanwhile, the internet is always under threat as our computer technology improves and more complex ways to break encryption emerge, threatening our personal information and infrastructure. However, our current optical technology functions on classical principles, and can be easily improved by incorporating our knowledge of quantum …

Competitive Sorption And Transport Of Heavy Metals In Soil And Mn Oxide-Coated Sand, Joshua Tyler Padilla

LSU Doctoral Dissertations

This study investigated the competitive sorption of Ni, Pb, and Zn as well as synergistic interactions between Ni and phosphate (P) in soils and Mn oxide-coated sand. During stirred-flow experiments, the sorption of heavy metal cations by Olivier soil was mutually reduced when applied simultaneously. When applied consecutively, the cation of higher affinity was able to displace the cation of lower affinity from the soil surface, however, no evidence for the reverse case was observed. A novel general exchange kinetics model was able to correctly describe such displacement. Competition between Ni and Zn mutually increased mobility in Olivier and Windsor …

A Numerical Investigation Of Flood And Sediment Dynamics Over The Coastal Watersheds During Hurricane Events, Dongxiao Yin

LSU Doctoral Dissertations

Landfalling tropical cyclones can cause catastrophic floods and sediment disturbance over the coastal watersheds. This study aims to unravel the contribution of different processes to hurricane-induced flooding, to assess the uncertainties in flood modelling and forecasting, and to advance the techniques in sediment simulation over coastal watersheds during hurricanes.

First, I examined the hydrometeorology and hydrology of Hurricane Florence (2018) induced inland flooding. My results suggest that the slow motion in combination with the “L-shaped” path was the most distinctive feature of the hurricane that incurred catastrophic and widespread rainfall and flooding over the Cape Fear River Basin (CFRB).

Second, …

Are Long-Period Exoplants Around Cool Stars More Common Than We Thought?, Emily Jane Safron

LSU Doctoral Dissertations

The Kepler mission has been the catalyst for discovery of nearly 5,000 confirmed and candidate exoplanets. The majority of these candidates orbit Sun-like stars, and have orbital periods comparable to or shorter than that of the Earth, due to the selection bias inherent in the transit method and the limitations of automated transit search algorithms. We aim to develop a richer understanding of the population of exoplanets around the lowest-mass stars, the M spectral type. We are particularly interested in exoplanets with long orbital periods, which are difficult or impossible to find using standard transit search algorithms. In our study, …

Performance Analysis And Improvement For Scalable And Distributed Applications Based On Asynchronous Many-Task Systems, Nanmiao Wu

LSU Doctoral Dissertations

As the complexity of recent and future large-scale data and exascale systems architectures grows, so do productivity, portability, software scalability, and efficient utilization of system resources challenges presented to both industry and the research community. Software solutions and applications are expected to scale in performance on such complex systems. Asynchronous many-task (AMT) systems, taking advantage of multi-core architectures with light-weight threads, asynchronous executions, and smart scheduling, are showing promise in addressing these challenges.

In this research, we implement several scalable and distributed applications based on HPX, an exemplar AMT runtime system. First, a distributed HPX implementation for a parameterized benchmark …

Synthesis Of Thiol-Acrylate Hydrogels For 3d Cell Culture And Microfluidic Applications, Anowar Hossain Khan

LSU Doctoral Dissertations

Globally cell culture is an $18.98 billion industry as of 2020, with an 11.6 percent annual growth rate. Drug discovery has an estimated worth of $69.8 billion in 2020 and is predicted to grow to $110.4 billion by 2025. Three-dimensional (3D) cell culture of cancer cells is one of the rapidly growing felids since it better recapitulates in vivo conditions compared to two-dimensional (2D) models. However, it is challenging to grow 3D tumor spheroids outside the body, and some of the existing technology can generate these spheroids outside the human body but poorly mimic in vivo tumor models. Therefore, there …

The Spectra Of Hydrogen-Deficient Carbon Stars: The Effects Of Evolution And Nucleosynthesis, Courtney Lauren Crawford

LSU Doctoral Dissertations

The rare class of stars known as the Hydrogen-deficient Carbon (HdC) stars includes the R Coronae Borealis (RCB) variables and the non-variable Dustless HdC (dLHdC) stars. These stars are believed to be formed via the merger of two white dwarf (WD) stars. They are known to exhibit many spectral peculiarities, such as partial helium burning products, enhancement of s-processed material and severe hydrogen-deficiency. In this work I explore many facets of HdC evolution. I begin by creating 18 HdC models in the stellar evolution code Modules for Experiments in Stellar Astrophysics (MESA) by merging two WD progenitors and evolving the …