Physical Sciences and Mathematics Commons^™

The Gavel And The Camera: Environmental Law And Photojournalism's Relationship To Appalachian Identity, Emily S. Patton

Honors Theses

Both the federal government and photojournalism have played a substantial role in the “othering” of Appalachia while simultaneously attempting to save it. Examining both institutions demonstrates the exploitative processes that alter the perception of rural communities and their surrounding environment. Stacey Kranitz’s archival exhibit, As It Was Give(n) To Me, internalizes this precarious role of the camera in a region heavily journalized. By inhabiting the area for years, establishing close relationships, and researching the documented history of Appalachia, Kranitz’s work becomes her livelihood in the dissolution of profession vs. personal. She is critical of past projects whose objective portrayal of …

Sedimentary Conditions At A Tidal Creek That Exhibits Seasonal Pelagic-Benthic Variations, Jack B. Corbin

Honors Theses

Tidal creeks in the Grand Strand of South Carolina are small but numerous connectors between land and ocean. One of these creeks, White Point Swash, exhibits a seasonal switch between planktonic and benthic photosynthesizers. As plankton become less abundant in fall, benthic macroalgae bloom, aided by lower water levels due to fall-winter dredging of the main channel, until late Spring. This study builds on previous findings and examines sedimentary conditions at this site further. Sedimentary chlorophyll a (in microphytobenthos) and pore water nutrient concentrations are confirmed to be higher than water-column concentrations. Sedimentary nutrient fluxes to the sediment-water interface, calculated …

Guardians Of The Data: Government Use Of Ai And Iot In The Digital Age, Jannat Saeed

Honors Theses

The exponential growth of technology, epitomized by Moore's Law – “the observation that the number of transistors on an integrated circuit will double every two years”– has propelled the swift evolution of Artificial Intelligence (AI) and Internet of Things (IoT) technologies. This phenomenon has revolutionized various facets of daily life, from smart home devices to autonomous vehicles, reshaping how individuals interact with the world around them. However, as governments worldwide increasingly harness these innovations to monitor and collect personal data, profound privacy concerns have arisen among the general populace. Despite the ubiquity of AI and IoT in modern society, formal …

Side Channel Detection Of Pc Rootkits Using Nonlinear Phase Space, Rebecca Clark

Honors Theses

Cyberattacks are increasing in size and scope yearly, and the most effective and common means of attack is through malicious software executed on target devices of interest. Malware threats vary widely in terms of behavior and impact and, thus, effective methods of detection are constantly being sought from the academic research community to offset both volume and complexity. Rootkits are malware that represent a highly feared threat because they can change operating system integrity and alter otherwise normally functioning software. Although normal methods of detection that are based on signatures of known malware code are the standard line of defense, …

Modeling Vibration Stiffness: An Analytical Extension Of Hertzian Theory For Angular Contact Bearings With A Thin Viscoelastic Coating, Davis R. Burton

Honors Theses

This thesis considers the novel angular contact rolling-element bearings proposed by NASA’s Glenn Research Center, which are coated with a thin solid lubricant that exhibits viscoelastic behavior. Current analytical models for the dynamic stiffness matrix of angular contact bearings, critical for vibration analysis, lack the ability to model the effects of a solid coating, as well as the time dependencies inherent in viscoelastic theory. The author first presents an overview of the stiffness matrix derivation, followed by a treatment of the underlying Hertzian contact theory. An analytical extension of this theory is proposed which accounts for a thin elastic layer …

Screening Full-Sib And Half-Sib Families Of Chestnut Seedlings For Resistance To Cryphonectria Parasitica Using A Small Stem Assay And A Leaf-Disc Assay, Uma Plambeck

Honors Theses

Cryphonectria parasitica is the ascomycete fungus species that causes chestnut blight disease. Symptoms of chestnut blight include bark cankers and eventually the death of American chestnut, Castanea dentata. However, not all Castanea species are equally affected by the disease, and some Asian species appear highly resistant. The OALDS and SSA in this study aim to assist in screening for resistance to C. parasitica within a year. We investigated the effect of C. parasitica on three North American species, one European species, four East Asian species of Castanea, and nine full-sib families of TACF backcross hybrids. Our study used both a …

Do You Know The Pangolin?: Analyzing Biodiversity Awareness And Attitudes, Ariel "Jazz" Holcomb

Honors Theses

Understanding the impact education has on environmental knowledge and values is critical for knowing how we can promote pro-environmental awareness and attitudes. Thus, this study investigated how environmental education level influences awareness and attitudes on environmental issues, specifically the Biodiversity Crisis. Through a survey primarily utilizing Likert scale statements, the researcher evaluated the differences in knowledge and care levels between classes taking an introductory environmental science course, one class of environmental science majors and one for non-majors. One focus point of the course is the world’s most trafficked mammal, the pangolin, so this species was used as a focus species …

Synthesis And Characterization Of Silver(I) And Manganese(Ii) Complexes With Thione Imidazoles, Shannon Keyser, Audrey Lawrence, Jaime M. Murphy Ph.D.

Honors Theses

Coordination polymers are chemical complexes with versatile applications such as catalysts, electrical conduc-tors, non-linear optics, magnetics, chemical sensing, and molecular storage. The polymers are comprised of a repeating series of metal-ligand complexes, which form various structures in varying ratios depending on the metal and ligand used. Certain metal-ligand combinations have shown particular promise as potentially being polymers or, if not polymers, possessing other useful features such as electromagnetic conductivity. Complexes were synthesized using silver(I) and manganese(II) with the ligands methimazole, 2-mercaptoimidazole, and thiocarbanilide with counterions of either chloride or nitrate. These com-plexes were characterized using elemental analysis, infrared spectroscopy, and …

An Analysis Of Pollution In Liverpool, Uk, Luke W. Lawson

Honors Theses

Within this experiment the different levels of pollution in areas around Liverpool were tested. These areas were Stanley Park, Lunt Meadows, and Woolton Road. At Stanley Park one of two transects had a geochemical analysis as well as magnetic measurements run to investigate source attribution within the urban environment resulting in data showing high variability in soil properties among the transect. With data supporting evidence of diamagnetic, paramagnetic, and ferromagnetic properties in soil along the same transect. At Lunt Meadows, through the use of XRF for soil samples and nitrate and phosphate testing for water samples, it was found that …

Exploration Of Sulfonamides And Benzothiazoles As Peptide-Based Cleavable Linkers, Abigail Dalton

Honors Theses

Cleavable linkers have demonstrated great potential in various applications of medicinal organic chemistry, such as in modern therapeutic development. Linkers are stable compounds that cleave in specific conditions to release molecular cargo. We have developed cleavable linkers based on nucleophilic aromatic substitution reactions on sulfonamide and benzothiazole substrates in small molecule and in peptide studies. Sulfonamides, commonly with an electron-withdrawing group, reacted in high conversion of starting material to the sulfide product in small molecule studies, but was unable to successfully cleave the sulfonamide linker on peptide in mild conditions. Next, a benzothiazole sulfone substrate was analyzed and optimized in …

Self-Quenching Of Carbon Monoxide In The Presence Of Noble Gases, Madeline V. Hinkle

Honors Theses

Precise rate coefficients for the vibrational relaxation pathways of CO(v)-CO in the presence of Ar and Kr have been determined through the work of this thesis. This work was motivated by the need to find a more cost-effective alternative to using xenon as a bath gas, which has increased significantly in price in the past few years. Similar experiments within this lab at Bucknell have been conducted in the past using argon, which can be used in the same manner as xenon but comes at a much lower price, but the experiments yielded inferior results compared to those using xenon. …

Echolocation On Manifolds, Kerong Wang

Honors Theses

We consider the question asked by Wyman and Xi [WX23]: ``Can you hear your location on a manifold?” In other words, can you locate a unique point x on a manifold, up to symmetry, if you know the Laplacian eigenvalues and eigenfunctions of the manifold? In [WX23], Wyman and Xi showed that echolocation holds on one- and two-dimensional rectangles with Dirichlet boundary conditions using the pointwise Weyl counting function. They also showed echolocation holds on ellipsoids using Gaussian curvature.

In this thesis, we provide full details for Wyman and Xi's proof for one- and two-dimensional rectangles and we show that …

The Precedence-Constrained Quadratic Knapsack Problem, Changkun Guan

Honors Theses

This thesis investigates the previously unstudied Precedence-Constrained Quadratic Knapsack Problem (PC-QKP), an NP-hard nonlinear combinatorial optimization problem. The PC-QKP is a variation of the traditional Knapsack Problem (KP) that introduces several additional complexities. By developing custom exact and approximate solution methods, and testing these on a wide range of carefully structured PC-QKP problem instances, we seek to identify and understand patterns that make some cases easier or harder to solve than others. The findings aim to help develop better strategies for solving this and similar problems in the future.

Modeling The Opioid Crisis In Virginia: A Differential Equations Model Assessing The Impact Of Medication-Assisted Treatment On The Addicted Population, Maniha Zehra Akram

Honors Theses

The opioid epidemic is prevalent in countless communities throughout the United States and has yet to be mitigated. Treatments for OUD (opioid use disorder) include Medication-Assisted Treatment (MAT) and treatment without medication (non-MAT), with the former being judged as more effective in terms of lower relapse rates, death rates, and criminal activity (U.S. Food & Drug Administration, 2023; SAMHSA, 2024). Motivated by the promising research on MAT, this paper models the relationship

between the treatment and addicted populations using a system of ordinary differential equations. In addition to producing closed-form equilibrium solutions, the model leads to the conclusion that expanding …

Sigma Hole Trends Across D-Block Metal Halides, Nam Huy Pham

Honors Theses

he effects of d-block metals on halogen bonding and other sigma hole interactions is currently understudied. We identify and document the trend of MFnI compounds serving as halogen bond donors across the d-block for M = groups 3 to 12 metals. Compounds were investigated using density functional theory and electrostatic potential (ESP) values at the I center have been examined to compare sigma hole strengths. d-block metal halides are found to be relatively weak compared to their p-block counterparts in inducing sigma holes, with only few exceptions. An interesting phenomenon involving the MXI compounds (X = F, Cl, Br, I) …

The Impact Of U.S. News And World Report College Rankings On Prospective Students’ Decisions And Enrollment Outcomes, Camilla Schneider

Honors Theses

The following paper further expands on previous research using more recent data which is important given changes in the last decade. This paper will answer the question: How do U.S. News and World Report college rankings impact college application and enrollment decisions for prospective students within American public and private colleges and universities? Application decisions refer to the choice to apply to a school while enrollment decisions refer to the choice to attend a school after being accepted. This paper analyzes Integrated Postsecondary Education Data System (IPEDs) admissions/applicant, fall enrollment, and financial data alongside historical USNWR rankings lists to investigate …

The Effect Of Solvent Identity And Hydride-Donor On The Reduction Of Co2 Into Useful Fuels, Abigail Mcentire

Honors Theses

One possible strategy for decreasing CO2 emissions is through electrocatalytic reduction reactions to convert the CO2 back into combustible fuels , such as methane or methanol. However, it can be challenging to control the reaction to select one of these useful fuels as opposed to carbon monoxide or formate. Our strategy is to investigate a specific hydride donor and solvent combinations for which the reaction favors conversion to methanol. It was found that in acetonitrile , several hydride donors were capable of selective reduction of CO2 to the methanol oxidation state.

The Effect Of The Expanded Child And Dependent Care Tax Credit On Maternal Labor Supply, Abby Letocha

Honors Theses

Policies that subsidize childcare have many potential economic benefits such as mitigating the high cost of childcare, incentivizing families to have more children, increasing paid childcare participation, and increasing parental labor supply. In this paper, I focus on the effect of childcare subsidies on maternal labor supply through a tax policy expansion. The Child and Dependent Care Tax Credit (CDCTC) is the primary federal childcare subsidy in the United States, and it was temporarily expanded in 2021 under the American Rescue Plan Act. This expansion increased the generosity of the credit and made it fully refundable for the 2021 tax …

Investigation Of Zinc And Iron In Wildflower Honey, Savannah Simpson

Honors Theses

Honey acts as a valuable food source for both animals and humans. When found in contaminated environments, there is an increased likelihood that honey samples will have high metal concentrations. It has been discovered that honey concentrations in metals can be different based on location. This experiment aims to determine the amount of two valuable metals, zinc, and iron, in various honey sources. These metals can be important to the human body because they help boost immunity and allow the body to carry out the functions required for survival. However, if these elements are present in copious quantities, then it …

Development Of An App For The Kalamazoo Nature Center, Ernest Au

Honors Theses

Kalamazoo Nature Center (KNC), which has been recognized by its peers as one of the top nature centers in the country, is home to over 14 miles of hiking trails winding through woods, wetlands, and prairies. There are numerous places/plots in KNC that have an interesting and impressive history besides being home to a variety of animals and hundreds of wildflowers and other plant life. To improve the visitor’s experience at KNC, we will design a software app via the senior capstone project at the department of Computer Science at WMU. As the first step towards establishing a reference model …

Ensuring Non-Repudiation In Long-Distance Constrained Devices, Ethan Blum

Honors Theses

Satellite communication is essential for the exploration and study of space. Satellites allow communications with many devices and systems residing in space and on the surface of celestial bodies from ground stations on Earth. However, with the rise of Ground Station as a Service (GsaaS), the ability to efficiently send action commands to distant satellites must ensure non-repudiation such that an attacker is unable to send malicious commands to distant satellites. Distant satellites are also constrained devices and rely on limited power, meaning security on these devices is minimal. Therefore, this study attempted to propose a novel algorithm to allow …

Stress-Sensing In Flexible Epoxy Adhesives, Christine Rukeyser

Honors Theses

In mechanochemistry, mechanical force causes a chemical change using small molecules, called mechanophores, by covalently connecting them into polymer materials. Stress-sensing mechanophores give a visual signal of mechanical force on the molecular level within a material. To our knowledge, stress-sensing mechanophores have never been incorporated into a commercially available epoxy kit. In this work, the characterization of two 3MTM Scotch-Weld TM Epoxy Adhesive kits: DP100 Plus Clear and DP190 Translucent have been completed through FT-IR Spectroscopy. The addition of the mechanophore spiropyran to the 3M kits will be discussed; as well as preparation and characterization of three dimerized anthracene derivatives. …

The Factors Affecting Fashion Trends Have Changing Over The Years By Different Age Groups & The Evolution Of Media., Omnahqiran Dazz

Honors Theses

Introduction:

Fashion trends undergo continuous evolution, influenced by factors such as age groups and the ever-changing landscape of media. This research delves into the intricate relationship between these elements. Initially driven by a passion for fashion, the project expanded to explore the profound impact of social media evolution over the past 15-20 years.

Objectives: Investigate changing fashion trends across age groups.

Examine the evolution of media.

Analyze the factors affecting current-day fashion trends.

Explore the influence of social media on fashion choices.

This study provides invaluable insights for fashion designers, brands, and retailers, aiding in the development of effective market …

Fostering A Sense Of Wonder: Promoting Experiential Learning Through Outdoor Discoveries On The Coast Of Maine, Joslyn Primicias

Honors Theses

Recent generations of children have been experiencing a decrease in connection to Nature, causing various negative effects on personal development and well-being. Researchers are studying the impact of environmental education programs as a potential resolution to this issue dubbed “nature deficit disorder.” Studies have shown that while citizen science by youth is rapidly expanding, little research addresses conservation science with environmental education. Recognizing this gap, the summer camps at Wells NERR are designed to ensure children’s environmental stewardship as they learn about estuarine ecology alongside environmental issues. This educational study focuses on how environmental education through estuarine activities at summer …

Chemical And Genetic Composition Analysis Of Organic And Nonorganic Tortilla Chips, Aubrey White-Day

Honors Theses

The aim of this study was to explore the chemical and genetic differences between organic and nonorganic tortilla chips using GC-MS and PCR. Twenty chip brands were selected: 10 organic and 10 nonorganic. A survey on shopping preferences was created and distributed to compare results of public opinion to experimental data. It yielded 212 responses. All organic chip brands, and one out of ten nonorganic chip brands, tested negative for GMOs. This study concluded that there are minimal chemical differences based on Jaccard similarity indicies and stark genetic differences between organic and nonorganic tortilla chips. In comparing statistical analyses to …

Photophysical And Photochemical Processes In Small Molecules And Materials For Solar Energy Conversion, Ethan Lambert

Honors Theses

The work covered in this thesis all falls under the theme of photophysical processes after light and matter interact. Those of primary interest are Raman scattering induced vibrations and excited state dynamics probed by transient absorption spectroscopy. Small molecules are studied with Raman spectroscopy and computational chemistry. These studies unearth the shifts in vibrational frequency as a function of charge transfer or receipt and how a quantitative assay of natural orbital populations and delocalization can offer both the nature and magnitude of this charge transfer. Further, a method is presented that builds upon previous work within the academic family tree; …

Structural Integrity And Stability Of Dna In Ionic Liquid And Near-Infrared Indolizine Squaraine Dye, Ember Yeji Suh

Honors Theses

Luminol, the most common presumptive test for blood at a crime scene, has multiple issues, such as false positive results with chemical agents, no luminescence due to “active oxygen” cleaning agents on bloodstains, and inability to penetrate textile materials. A combination of indolizine squaraine dye and ionic liquid (IL), or Dye Enhanced Textile Emission for Crime Tracking (DETECT), have shown potential to address these issues. The purpose of this study was to assess the binding mechanism of CG (1:1) and SO₃SQ dye to HSA and how the mechanism can explain the W214 fluorescence quenching effect and to determine …

Aging An Ancient Maya Population From Actuncan, Belize Using Dental X-Rays, Kaitlyn Nicole Cash

Honors Theses

My goal is to determine an accurate age at death estimation of an ancient Maya population from the archaeological site of Actuncan, Belize. This was done by measuring the lengths of the coronal pulp cavities in the individuals’ teeth. I used X-Ray images to measure the coronal pulp cavities of the teeth and estimated age using multiple regression formulae for premolars, molars, and incisors to make age estimations. The formulae came from two studies, Ikeda et al. (1985) and Drusini (2008), that form the basis of my research. Ikeda et al. (1985) was the first to use this aging method, …

A Study Of Data/Monte Carlo Agreement In Charmed Baryon Decays At Belle Ii, Kaitlyn Thurmond

Honors Theses

The Belle II experiment at the SuperKEKB electron-positron accelerator facility in Tsukuba, Japan has a primary goal of searching for new physics beyond the Standard Model of particle physics. Extremely precise measurements of particle decays will be compared with Standard Model predictions in order to expose the presence of new particles and interactions. These measurements are prepared using simulated samples to avoid potential biases when studying the data. The Belle II collaboration produces two types of simulated samples for this purpose. One is produced with consistent calibration payloads and another with payloads calibrated as a function of data taking. This …

Investigating Reactivity Of Artificial Copper Peptides With Small Molecules, Allyson Bryant

Honors Theses

The design of artificial enzymes has been a topic of significant interest in the field of biochemistry, as they can provide new opportunities for catalytic processes and drug development. De novo protein design has emerged as a promising approach to create such enzymes, and the study of metalloproteins, particularly copper-binding peptides, has become a focus of this research. This thesis investigates the reactivity of a mutated copper-binding peptide, I5A-3SCC, with oxygen and its implications in the development of artificial enzymes.

The parent peptide, 3SCC, was mutated by replacing Isoleucine residues with smaller Alanine side chains, which was hypothesized to enhance …