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Full-Text Articles in Physical Sciences and Mathematics

Data-Driven Research On Engineering Design Thinking And Behaviors In Computer-Aided Systems Design: Analysis, Modeling, And Prediction, Molla Hafizur Rahman Aug 2022

Data-Driven Research On Engineering Design Thinking And Behaviors In Computer-Aided Systems Design: Analysis, Modeling, And Prediction, Molla Hafizur Rahman

Graduate Theses and Dissertations

Research on design thinking and design decision-making is vital for discovering and utilizing beneficial design patterns, strategies, and heuristics of human designers in solving engineering design problems. It is also essential for the development of new algorithms embedded with human intelligence and can facilitate human-computer interactions. However, modeling design thinking is challenging because it takes place in the designer’s mind, which is intricate, implicit, and tacit. For an in-depth understanding of design thinking, fine-grained design behavioral data are important because they are the critical link in studying the relationship between design thinking, design decisions, design actions, and design performance. Therefore, …


Development Of Deep Shear Wave Velocity Profiles And An Approach To Generate Site Signature Consistent Pseudo Shear Wave Velocity Profiles In The Mississippi Embayment, Ashraf Kamal Himel Aug 2022

Development Of Deep Shear Wave Velocity Profiles And An Approach To Generate Site Signature Consistent Pseudo Shear Wave Velocity Profiles In The Mississippi Embayment, Ashraf Kamal Himel

Graduate Theses and Dissertations

This dissertation details the development of a surface wave method (SWM) technique to generate deep shear wave velocity profiles (VS profiles), applying this technique at 24 sites across the Mississippi embayment and developing an approach to generate pseudo site signature consistent VS profiles from velocity functions and fundamental frequency. In the presented SWM technique, active and passive source surface wave measurements are inverted along with fundamental frequency to develop a site signature consistent VS profile. Multiple transformation methods, including MSPAC, HRFK and FK are used to resolve experimental dispersion data from surface wave measurements. SWM VS profile at the Central …


Societal Sustainability: Projects To Address The Three Dimensions Of A Sustainable Future, Braden K. Bateman Aug 2022

Societal Sustainability: Projects To Address The Three Dimensions Of A Sustainable Future, Braden K. Bateman

Graduate Theses and Dissertations

Sustainability is an important, commonly discussed societal goal regarding assurance of resources for the world to be able to enjoy a prosperous future. Three primary dimensions of sustainability include environmental, economic, and social sustainability, and objectives for various projects can be aimed at any of the three dimensions to pursue societal sustainability. Solar installations, which can be used to pursue environmental and economic sustainability, convert abundant sunlight to electricity, displacing fossil fuel use that contributes harmful greenhouse gases to the atmosphere. The regulatory environment at the state level has a significant impact on the feasibility of solar projects. At present, …


Scheduling, Complexity, And Solution Methods For Space Robot On-Orbit Servicing, Susan E. Sorenson Aug 2022

Scheduling, Complexity, And Solution Methods For Space Robot On-Orbit Servicing, Susan E. Sorenson

Graduate Theses and Dissertations

This research proposes problems, models, and solutions for the scheduling of space robot on-orbit servicing. We present the Multi-Orbit Routing and Scheduling of Refuellable On-Orbit Servicing Space Robots problem which considers on-orbit servicing across multiple orbits with moving tasks and moving refuelling depots. We formulate a mixed integer linear program model to optimize the routing and scheduling of robot servicers to accomplish on-orbit servicing tasks. We develop and demonstrate flexible algorithms for the creation of the model parameters and associated data sets. Our first algorithm creates the network arcs using orbital mechanics. We have also created a novel way to …


The Effects Of Side-Channel Attacks On Post-Quantum Cryptography: Influencing Frodokem Key Generation Using The Rowhammer Exploit, Michael Jacob Fahr Aug 2022

The Effects Of Side-Channel Attacks On Post-Quantum Cryptography: Influencing Frodokem Key Generation Using The Rowhammer Exploit, Michael Jacob Fahr

Graduate Theses and Dissertations

Modern cryptographic algorithms such as AES and RSA are effectively used for securing data transmission. However, advancements in quantum computing pose a threat to modern cryptography algorithms due to the potential of solving hard mathematical problems faster than conventional computers. Thus, to prepare for quantum computing, NIST has started a competition to standardize quantum-resistant public-key cryptography algorithms. These algorithms are evaluated for strong theoretical security and run-time performance. NIST is in the third round of the competition, and the focus has shifted to analyzing the vulnerabilities to side-channel attacks. One algorithm that has gained notice is the Round 3 alternate …


A Comparison Of Relict And Active Terrestrial Patterned Ground As An Analog For Mars, John Paul Knightly Jr. Aug 2022

A Comparison Of Relict And Active Terrestrial Patterned Ground As An Analog For Mars, John Paul Knightly Jr.

Graduate Theses and Dissertations

Patterned ground is a ubiquitous landform in periglacial regions of Earth and is also present across the mid to high latitudes of Mars. The association of terrestrial patterned ground to the presence of subsurface water ice in the form of permafrost that develops a seasonal ‘wet’ active layer during the summer thaw prompted further investigation of patterned ground on Mars. The Phoenix spacecraft was sent to the surface of the north polar plains of Mars to investigate an area of patterned ground where water ice was predicted to occur. The confirmation of subsurface water ice at the Phoenix landing site …


Competing Behaviors Of Thermoregulation And Ambush Foraging In The Timber Rattlesnake (Crotalus Horridus Horridus): A Mechanistic Assessment Of Thermal Conduction, Larry K. Kamees Aug 2022

Competing Behaviors Of Thermoregulation And Ambush Foraging In The Timber Rattlesnake (Crotalus Horridus Horridus): A Mechanistic Assessment Of Thermal Conduction, Larry K. Kamees

Graduate Theses and Dissertations

The interaction between the biophysical environment and ectotherm morphology elicits behaviors designed to maintain internal body temperature (Tb) within a range that promotes physiological functions. The short-term requirements of mass (energy requirements) and heat balance are subject to tradeoffs imposed by the organisms current physiological (heat and mass budgets) and environmental (biophysical, demographic, social, and predation) constraints and available resources. In temperate forests, extreme temperatures are common in summer even with intermittent sun exposure due to dense canopy cover. In Spring and Fall, temperatures can range from below freezing to 35 ℃ in 24 hrs. An ambush predator like the …


Changes Of Winter Severity In Arkansas During 1901-2100, Christian Garcia Aug 2022

Changes Of Winter Severity In Arkansas During 1901-2100, Christian Garcia

Graduate Theses and Dissertations

The objective of this study was to quantify the winter severity in a way that was reproduceable and easy to understand. The Accumulated Winter Severity Seasonal Index (AWSSI) was chosen for this reason and was used to quantify winter severity by season across the state of Arkansas. The variables that go into the AWSSI calculation are maximum daily temperature, minimum daily temperature, daily snowfall, and daily snow depth. When the snowfall and snow depth were missing, they can be estimated using daily temperature and precipitation. Then the estimated snowfall and snow depth can be subsequently used to quantify the winter …


Cohomology Of The Symmetric Group With Twisted Coefficients And Quotients Of The Braid Group, Trevor Nakamura Aug 2022

Cohomology Of The Symmetric Group With Twisted Coefficients And Quotients Of The Braid Group, Trevor Nakamura

Graduate Theses and Dissertations

In 2014 Brendle and Margalit proved the level $4$ congruence subgroup of the braid group, $B_{n}[4]$, is the subgroup of the pure braid group generated by squares of all elements, $PB_{n}^{2}$. We define the mod $4$ braid group, $\Z_{n}$, to be the quotient of the braid group by the level 4 congruence subgroup, $B_{n}/B_{n}[4]$. In this dissertation we construct a group presentation for $\Z_{n}$ and determine a normal generating set for $B_{n}[4]$ as a subgroup of the braid group. Further work by Kordek and Margalit in 2019 proved $\Z_{n}$ is an extension of the symmetric group, $S_{n}$, by $\mathbb{Z}_{2}^{\binom{n}{2}}$. A …


Quantum Dots In Two-Dimensional Tungsten Diselenide, Jeb Allen Michael Stacy Aug 2022

Quantum Dots In Two-Dimensional Tungsten Diselenide, Jeb Allen Michael Stacy

Graduate Theses and Dissertations

This work focuses on the investigation of single and double quantum dots in two-dimensional transition metal dichalcogenide tungsten diselenide (WSe_2) as a means to evaluate the valley degree of freedom as a potential qubit and ambipolar tungsten diselenide monolayers as single photon sources. Gate-defined quantum dots in monolayer and bilayer WSe_2 were fabricated and characterized. Single dot devices are gated from above and below the WSe_2 to accumulate a hole gas. Temperature dependence of Coulomb-blockade peak height is consistent with single-level transport. Excited-state transport in the quantum dot is shown for both monolayer and bilayer devices. Magnetic field dependence of …


Constraint-Aware, Scalable, And Efficient Algorithms For Multi-Chip Power Module Layout Optimization, Imam Al Razi Aug 2022

Constraint-Aware, Scalable, And Efficient Algorithms For Multi-Chip Power Module Layout Optimization, Imam Al Razi

Graduate Theses and Dissertations

Moving towards an electrified world requires ultra high-density power converters. Electric vehicles, electrified aerospace, data centers, etc. are just a few fields among wide application areas of power electronic systems, where high-density power converters are essential. As a critical part of these power converters, power semiconductor modules and their layout optimization has been identified as a crucial step in achieving the maximum performance and density for wide bandgap technologies (i.e., GaN and SiC). New packaging technologies are also introduced to produce reliable and efficient multichip power module (MCPM) designs to push the current limits. The complexity of the emerging MCPM …


Catalytic Activity Of Tungsten-Dioxo And Tungsten-Diimido Complexes, Kayla Denike Aug 2022

Catalytic Activity Of Tungsten-Dioxo And Tungsten-Diimido Complexes, Kayla Denike

Graduate Theses and Dissertations

Due to the significant decline in the availability of petrochemical resources and the increasing demand for the useful olefin mixtures extracted from oil, a sustainable and efficient alternative to these materials has become vital. Fortunately, renewable biomass derived materials may serve as a sustainable solution to the limited resources problem. Molecules derived from the degradation of biomasses are highly oxygenated and highly functionalized. Developing processes to efficiently defunctionalize these oxygen-rich materials will lead to potential up-conversion to carbon chemicals. Homogeneous catalytic deoxygenation processes present an opportunity to access valuable carbon commodity chemicals from biomass derived polyols. This dissertation details the …


Improving Computation For Hierarchical Bayesian Spatial Gaussian Mixture Models With Application To The Analysis Of Thz Image Of Breast Tumor, Jean Remy Habimana Aug 2022

Improving Computation For Hierarchical Bayesian Spatial Gaussian Mixture Models With Application To The Analysis Of Thz Image Of Breast Tumor, Jean Remy Habimana

Graduate Theses and Dissertations

In the first chapter of this dissertation we give a brief introduction to Markov chain Monte Carlo methods (MCMC) and their application in Bayesian inference. In particular, we discuss the Metropolis-Hastings and conjugate Gibbs algorithms and explore the computational underpinnings of these methods. The second chapter discusses how to incorporate spatial autocorrelation in linear a regression model with an emphasis on the computational framework for estimating the spatial correlation patterns.

The third chapter starts with an overview of Gaussian mixture models (GMMs). However, because in the GMM framework the observations are assumed to be independent, GMMs are less effective when …


Environmental Communication: Changing The Attitude-Behavioral Gap In Science Communication Utilizing Strategic Messaging, Carrie Helgeson Nelms Aug 2022

Environmental Communication: Changing The Attitude-Behavioral Gap In Science Communication Utilizing Strategic Messaging, Carrie Helgeson Nelms

Graduate Theses and Dissertations

National Polls in the United States consistently find the public’s beliefs and attitudes about climate change and other environmental issues significantly diverge from those held by the science community. A communication gap between the findings on the causes and effects of environmental issues and the public’s inability to interpret or refuse to accept these findings are possible causes of this divergence. This communication gap constitutes a threat to society because of inaction to environmental problems and points to needed changes in scientific messaging that better informs and motivates behavioral change. The present research employed a strategic message design to affect …


Hiding In Plain Sight: Accounting For Rate Heterogeneity In Trait Evolution Models, James Boyko Aug 2022

Hiding In Plain Sight: Accounting For Rate Heterogeneity In Trait Evolution Models, James Boyko

Graduate Theses and Dissertations

Within the last four decades, phylogenetic comparative methods have become the defacto method of analysis for comparative biologists. The availability of high-quality comparative datasets has been matched by an explosion of possible phylogenetic models. In large part, the efforts to increase the realism of phylogenetic comparative methods has been successful as evidenced by their widespread use. To this extensive literature, my contributions are modest. I have focused my dissertation work on two main themes. First, most phenotypic evolution is not independent of other phenotypes. Changes in a particular character may influence changes in another and modeling these characters in isolation …


Weakly Q-Convex Domains And Bounded Q-Subharmonic Exhaustion Functions, Emily Foss Aug 2022

Weakly Q-Convex Domains And Bounded Q-Subharmonic Exhaustion Functions, Emily Foss

Graduate Theses and Dissertations

We generalize the Diederich-Fornaess index to bounded weakly q-convex domains with bounded q-subharmonic exhaustion functions. Sufficient conditions for this generalized Diederich-Fornæss index to have a given lower bound are proved. We show this generalized index is positive on bounded weakly q-convex domains with C^3 boundaries. Additionally, we prove sufficient conditions for this generalized index to equal one. For example, we show that if the domain has Property ( ̃(Pq ) ) then the domain has high hyperconvexity.


Quantum Transport And Electric-Field Effects In Layered Topological Semimetals And Magnetic Materials, Arash Fereidouni Ghaleh Minab Aug 2022

Quantum Transport And Electric-Field Effects In Layered Topological Semimetals And Magnetic Materials, Arash Fereidouni Ghaleh Minab

Graduate Theses and Dissertations

This dissertation describes transport experiments on quantum devices in layered Dirac nodal line topological semimetals and antiferromagnetic materials down to a few layers. We used gate-induced effects to alter the transport properties of these materials.

First, we introduced current annealing in topological semimetals to achieve high-quality devices. We demonstrate current annealing to substantially improve the electronic transport properties of 2D topological semimetal flakes. Contact resistance and resistivity were improved by factors up to 2,000,000 and 20,000, respectively, in devices based on exfoliated flakes of two topological semimetals, ZrSiSe and BaMnSb2. Using this method, carrier mobility in ZrSiSe improved by a …


The Cosmic History Of X-Ray Binary Evolution, Woodrow Gilbertson Aug 2022

The Cosmic History Of X-Ray Binary Evolution, Woodrow Gilbertson

Graduate Theses and Dissertations

The Chandra Deep Fields provide an extraordinary window into the high-energy history of the cosmos. Observations of non-active galaxies within the deep fields can be leveraged to extract information about the formation and evolution of X-ray binaries (XRBs). Previous studies have suggested that the evolution of XRB luminosity can be expressed a function of physical parameters such as star formation rate, stellar mass, stellar age, and metallicity. The goal of this work is to develop and implement a complete physical parameterization for the luminosity of XRB populations, which can be utilized for a variety of further studies.

Chapter 1 provides …


Study Of Thermoelectric And Lattice Dynamics Properties Of 2d Layered Mx (M = Sn, Pb; X = S, Se, Te) And Zrs2 Compounds Using First-Principles Approach, Abhiyan Pandit Aug 2022

Study Of Thermoelectric And Lattice Dynamics Properties Of 2d Layered Mx (M = Sn, Pb; X = S, Se, Te) And Zrs2 Compounds Using First-Principles Approach, Abhiyan Pandit

Graduate Theses and Dissertations

The aim of this dissertation is the investigation of thermoelectric and lattice dynamics properties of two-dimensional (2D) MX (M = Sn, Pb; X = S, Se, Te) and ZrS2 compounds based on the first-principles density functional theory. The dimensionality reduction (e.g., using 2D structure) of bulk materials is found to have enhanced thermoelectric efficiency. This enhancement is attributed to the increase of the Seebeck coefficient as a result of higher electronic density of states near the Fermi level in low-dimensional materials. In addition, lowering the dimensionality increases phonon scattering near interfaces and surfaces in 2D materials, which leads to a …


Materials Design For Energy Applications Using Ab- Initio Calculations, Hind Hemaidee Alqurashi Aug 2022

Materials Design For Energy Applications Using Ab- Initio Calculations, Hind Hemaidee Alqurashi

Graduate Theses and Dissertations

The structural, dynamical, electronic, and thermoelectric properties of rock-salt and wurtzite Cd1-xZnxO alloys, VTiRhZ (Al, Ga, In, Si, Ge, Sn) and ZrTiRhZ (Ge, Sn) quaternary Heusler alloys (QHAs) were investigated using density functional theory (DFT) and semi-classical Boltzmann transport theory. From these calculations, the alloys were identified as potential materials for future thermoelectric applications. Furthermore, the magnetic and spin-polarization properties of these QHAs were investigated. The total magnetic moments were found to be integer values for all QHAs. In addition, all studied QHAs except VTiRhAl possess a half-metallic behavior with a 100% spin-polarization. The half-metallic ferromagnetic behavior makes them promising …


Examining The Expression Patterns Of Desulfotalea Psychrophila Dsrab Operon And Pit At Subfreezing Temperatures And Different Concentrations Of Sulfate Salts As A Model For Mars And Icy Worlds Survival And Colonization, Sergio Luis Mosquera Mora Aug 2022

Examining The Expression Patterns Of Desulfotalea Psychrophila Dsrab Operon And Pit At Subfreezing Temperatures And Different Concentrations Of Sulfate Salts As A Model For Mars And Icy Worlds Survival And Colonization, Sergio Luis Mosquera Mora

Graduate Theses and Dissertations

Since ancient times, Humanity has been fascinated with the idea of what lies beyond the borders of our planet. Fortunately, the combined efforts of many nations have made it possible to send unmanned spacecraft to orbit planets located close to Earth. These missions have the principal goal to collect data that could help us understand the basic environmental conditions that persist on those planets, or for evidence of past or present life. Equally important, landers and rovers have been successfully deployed to start the in-situ exploration of many planets of the Solar System. Among them, Mars has been extensively studied …


Analysis Of Seismicity And Related Seismic Risk In Muslim Countries: Case Studies From Afghanistan And Pakistan, Ikramuddin Bahram Aug 2022

Analysis Of Seismicity And Related Seismic Risk In Muslim Countries: Case Studies From Afghanistan And Pakistan, Ikramuddin Bahram

Graduate Theses and Dissertations

How communities respond to a natural hazard is influenced by how they perceive it. This dissertation evaluated the gap between intent and action regarding earthquake hazards in Muslim countries with a focus on Afghanistan and Pakistan. Cultural biases provided predictions of risk perceptions and risk-taking preferences that were often more powerful than measures of knowledge and experience. In Muslim communities, perception of risk was influenced by the teachings of Islam and related rituals, traditions, and culture.

This study evaluated the seismicity and earthquake hazard in Afghanistan and Pakistan. Assessments of seismic risk and perception of danger were conducted to examine …


Assessing Consumer Demand, Producer Profitability, And The Environmental Impacts Of Conservation Agriculture Adoption In Sub-Saharan Africa, Willy Byamungu Mulimbi Aug 2022

Assessing Consumer Demand, Producer Profitability, And The Environmental Impacts Of Conservation Agriculture Adoption In Sub-Saharan Africa, Willy Byamungu Mulimbi

Graduate Theses and Dissertations

This dissertation explores three aspects of conservation agriculture (CA) in the Sub-Saharan African region (SSA). The first article examines the demand side of CA and explores whether urban maize (Zea mays L.) consumers in the Democratic Republic of the Congo (DRC) would be willing to pay a premium for CA-produced maize flour. The second article estimates the effects CA provides to adopters and their farms in smallholder farming systems in the DRC, focusing on changes in soil properties and cowpea (Vigna unguiculata) yields. The final article uses a Life Cycle Assessment (LCA) approach to monetize the environmental impacts of adopting …


Structural Interpretation Of An Alkaline-Carbonatite Complex Using Gravity And Magnetic Methods At Magnet Cove, Arkansas, Chelsea Morgan Amaral Aug 2022

Structural Interpretation Of An Alkaline-Carbonatite Complex Using Gravity And Magnetic Methods At Magnet Cove, Arkansas, Chelsea Morgan Amaral

Graduate Theses and Dissertations

The Magnet Cove alkaline-carbonatite complex in the Ouachita Mountains of south-central Arkansas could be a valuable resource for rare earth elements, though it has not yet been thoroughly studied using geophysical methods, and existing geophysical models simplify its diverse nature. Prior to this study, the subsurface structure and extent of the Magnet Cove complex was poorly understood and, in general, the process of emplacement of alkaline carbonatite complexes worldwide is also not fully understood. The Magnet Cove complex hosts an extensive variety of rare rock types and mineral resources that contrast significantly to the sedimentary rocks into which they have …


Evaluation Of Carbon Isotopic Chemostratigraphy Of The Cedar Mountain Formation Of Utah, Clayton Forster Aug 2022

Evaluation Of Carbon Isotopic Chemostratigraphy Of The Cedar Mountain Formation Of Utah, Clayton Forster

Graduate Theses and Dissertations

The Lower Cretaceous rocks of Utah preserve the origin of a multitude of dinosaur taxa, spread of angiosperms on the North American continent, and evolution of marsupial and eutherian mammals. However, the timing of deposition of these rocks is not well understood and must be determined to understand climatic controls on these biological events. Estimates of the age of the Cedar Mountain Formation and its constituent members range from Late Jurassic to early Late Cretaceous. Understanding the timing of deposition of the Cedar Mountain Formation is critical to dinosaurian and associated taxa studies as well as paleoclimate reconstructions from within …


Understanding Martian Salts And Their Implications For Liquid Water, Rachel Slank Aug 2022

Understanding Martian Salts And Their Implications For Liquid Water, Rachel Slank

Graduate Theses and Dissertations

Water is one of the key components for life as we know it. The existence of salts on Mars has been a large contributing factor to the possibility of habitability, due to their ability to allow liquid water to remain stable at colder temperatures. Salts, including perchlorates, chlorates, and chlorides, have been detected by multiple landers, rovers, and orbiters, and are now believed to be ubiquitous on Mars. One of the pathways to liquid brine solutions is through deliquescence. Deliquescence is the transition from a solid salt crystal into an aqueous solution when exposed to a humid atmosphere. This research …


Optimization Techniques For Soil Organic Carbon Prediction Using Mid-Infrared Spectroscopy, Minerva J. Dorantes Aug 2022

Optimization Techniques For Soil Organic Carbon Prediction Using Mid-Infrared Spectroscopy, Minerva J. Dorantes

Graduate Theses and Dissertations

Resource-efficient techniques for accurate soil carbon estimation are necessary to satisfy the increasing demand for spatiotemporal data. In the last thirty years, mid-infrared (MIR) soil spectroscopy has developed as an accurate, rapid, cost-effective, and non-destructive technique for soil organic carbon (SOC) analysis. In soil spectroscopy, a calibration model relates spectral data to a corresponding measured soil property and is subsequently used to predict this value from new spectral data. Various optimization techniques have been used to improve the statistical performance of calibrations; however, there is little consensus on the conditions that make these techniques effective. The objectives of this research …


The Effect Of Water Management And Ratoon Rice Cropping On Methane Emissions And Harvest Yield In Arkansas, Marguerita Leavitt Aug 2022

The Effect Of Water Management And Ratoon Rice Cropping On Methane Emissions And Harvest Yield In Arkansas, Marguerita Leavitt

Graduate Theses and Dissertations

Sustainable intensification of rice farming is crucial to meeting human food needs while reducing environmental impacts. Rice produces 8% of all anthropogenic CH4, which is a potent greenhouse gas. CH4 emissions can potentially be reduced by cultivation practices that minimize the number of days the fields are saturated, such as dry-seeding instead of water-seeding and irrigation using the alternate wetting and drying (AWD) technique instead of delayed, continuous flooding (DF). Ratoon cropping, wherein a second crop of rice is grown from the harvested stubble of the first crop, can be used to produce additional yield with minimal labor, but may …


Effective Knowledge Graph Aggregation For Malware-Related Cybersecurity Text, Phillip Ryan Boudreau Aug 2022

Effective Knowledge Graph Aggregation For Malware-Related Cybersecurity Text, Phillip Ryan Boudreau

Graduate Theses and Dissertations

With the rate at which malware spreads in the modern age, it is extremely important that cyber security analysts are able to extract relevant information pertaining to new and active threats in a timely and effective manner. Having to manually read through articles and blog posts on the internet is time consuming and usually involves sifting through much repeated information. Knowledge graphs, a structured representation of relationship information, are an effective way to visually condense information presented in large amounts of unstructured text for human readers. Thusly, they are useful for sifting through the abundance of cyber security information that …


Hierarchically Structured Photoelectrodes Via Atomic Layer Deposition, Justin Rowan Reed Demoulpied Aug 2022

Hierarchically Structured Photoelectrodes Via Atomic Layer Deposition, Justin Rowan Reed Demoulpied

Graduate Theses and Dissertations

In the search for a sustainable method to meet increasing energy needs, solar energy emerges as an underutilized, plentiful resource. Solar intermittency and requirements for transportation necessitate storing solar energy in the form of chemical bonds via artificial photosynthesis. Photoelectrochemical (PEC) water splitting generates hydrogen fuel from solar energy and water. A semiconducting material that successfully meets the complex requirements for building an industrially scalable PEC device has yet to emerge. This is leading to a reevaluation of materials previously overlooked within PEC research, mainly materials with limitations such as minimal charge carrier mobility and propensity to corrosion under illumination …