Utilizing Suas-Based Remote Sensing For Sustainable Outdoor Recreational Trail Design And Monitoring, Isaac C. Kinder

Graduate Theses, Dissertations, and Problem Reports

This study utilizes sUAS-based remote sensing and hydrologic models to analyze and predict locations susceptible to water-based trail erosion. Erosion is frequently cited as the most significant environmental impact of trails and often requires costly design and management considerations. A professionally designed trail totaling 4 km in length was segmented based on presence or absence of water-based erosion for analyses and then flown with sUAS technology. Three Logistic regression (LR) models were generated utilizing several hydrologic terrain models of varying resolutions to determine the effects of spatial resolution on the models’ predictive accuracies. Receiver operator characteristics, kappa, and overall accuracy …

Estimating Home Range Size And Density Of White-Tailed Deer (Odocoileus Virginianus) In West Virginia, Sarah M. Pesi

Graduate Theses, Dissertations, and Problem Reports

Big game hunting is an important source of revenue and recreation in the United States. Of big game species, white-tailed deer (Odocileus virginianus) are the most heavily pursued. White-tailed deer are a widespread generalist species, capable of existing at high densities. Hunting is often used as the primary method of managing deer populations, particularly in the eastern United States, where there is a lack of large predators. When populations reach high densities, there can be negative effects on the environment and conflicts with humans. Managers must consider both creating adequate hunting opportunities and reducing negative impacts when managing …

C–H Alkylation Of Diol Substrates Using Bifunctional Boronic Acid Catalysts, Matthew Ryan Ross

Graduate Theses, Dissertations, and Problem Reports

Boronic acid catalysts in combination with a Lewis base have been used in previous work to perform site-selective C–H alkylation reactions targeting the α-hydroxy C–H bond of diols through a photoredox activated hydrogen atom transfer. This is done by accessing a tetracoordinate boronic acid – Lewis base complex which then mediates the hydrogen atom transfer. The research hypothesizes that combining the boronic acid and Lewis base into one molecule not only simplifies the reaction but also has the potential to unlock C–H alkylation sites previously inaccessible. This is plausible because the Lewis base portion of the synthesized bifunctional boronic acid …

A Multi-Wavelength Determination Of The Total Luminosity And Star Formation Rate Of The Milky Way, Joshua L. Mascoop

Graduate Theses, Dissertations, and Problem Reports

The star formation rate (SFR) of the Milky Way is poorly understood in comparison to the SFR of other galaxies. In order to better find the Galaxy's place in the universe, it is imperative to understand the star formation activity occurring within it. We characterize the Galactic \hii\ region luminosity function (LF) at multiple infrared and radio wavelengths using a sample of 797 first Galactic quadrant \hii regions compiled from the WISE Catalog of Galactic \hii Regions. This sample is statistically complete for all regions powered by single stars of type O9.5V and earlier.

We find that neither a single …

Photoinduced Alpha-Hydroxy C–H Alkylation Of Mono-Alcohols Via Hydrogen Atom Transfer (Hat) Of An Activated Boron-Containing Complex, Courtney Deanna Glenn

Graduate Theses, Dissertations, and Problem Reports

Hydroxy (-OH) groups are one of the most abundant functional groups found in natural products and pharmaceuticals with many of these compounds containing multiple alcohol classes. The ability to selectively functionalize a specific α-OH C–H bond in the presence of other competitive sites would provide straightforward access to new, potentially bioactive compounds. In recent literature, photoredox catalysis has been implemented to perform site and stereoselective α-OH C–H functionalization of cis-diol containing substrates. Incorporating an organoboron cocatalyst into these systems have proven to be crucial in decreasing the bond dissociation energy (BDE) and increasing hydricity of the α-OH C–H bond …

Evaluating Land Cover Change And Opportunities For Bioenergy Crop Development On Surface Mine Sites In West Virginia, U.S.A., Kenzie D. Kohrs

Graduate Theses, Dissertations, and Problem Reports

Surface mining can impact land cover, forests, and water quality. Current reclamation strategies include revegetation with herbaceous species due to the ease and speed of cover establishment. Herbaceous and woody biomass crops have been used in various studies to reclaim surface mines and act as an alternative to nonrenewable energy sources. The objectives of this study were to quantify the state of vegetation growth on former surface mines in West Virginia over a 9-year period and identify suitable acreage for bioenergy production. During 2011 to 2020, we found that over 40,000 acres had been converted to forest and 40,000 acres …

An Exploration Of Misconceptions In Introductory Physics, Christopher Mattthew Wheatley

Graduate Theses, Dissertations, and Problem Reports

The study of student misconceptions about physics concepts has long been an important area of inquiry in physics education research (PER). The research discussed in this dissertation builds upon the developments in PER by exploring the prevalence of consistently held undergraduate student misconceptions in introductory calculus-based physics. This thesis explores the nature of student misconceptions, mistakes, and naive answering patterns in both introductory undergraduate Newtonian mechanics and electromagnetism by applying a network analytic technique called module analysis to student responses to different concept inventories from institutions of various levels of incoming physics preparation. Each study applying these methods also demonstrates …

Modeling The Dynamics Of Radiation Belt Electrons And Ring Current Protons, Xingzhi Lyu

Graduate Theses, Dissertations, and Problem Reports

Earth’s inner magnetosphere is a highly dynamic region with various charged particle populations and current systems. The radiation belts, composed of relativistic electrons and protons, is an environment that can pose significant risks to both spacecraft and humans in space; while the fluctuations of ring current, an electric current flowing around the earth consisting of energetic electrons and ions, can lead to severe disruptions in ground-based electrical systems. In this dissertation, we first modeled the long-term evolution of ring current protons based on the measurements of Van Allen Probes. By implementing a 1D radial diffusion model with charge exchange loss, …

Exploring Crystal Polymorphism In Additive-Assisted Chemical Vapor-Deposited Transition Metal Chalcogenides And Oxides, Lawrence Kirimi Mubwika

Graduate Theses, Dissertations, and Problem Reports

Crystal polymorphism is a phenomenon in which compounds with the same chemical formula can be crystallized into different crystal structures. This phenomenon can be observed in elemental materials, such as diamond and graphite, as well as in compounds, such as the trigonal (1H) or octahedral (1T) prismatic MoS₂. Crystals can also exhibit polytypism by stacking different polymorphs in a certain order, with the stacking sequence determining the variation between polytypes. Although all polymorphs and polytypes have the same chemical composition, each polymorph and polytype possesses unique electronic and physical properties.

This study explores the additive-assisted chemical vapor deposition …

Quantifying Chemical Erosion In The Lithologically-Heterogenous Appalachian Valley And Ridge, Amelia Jayne Zanoni

Graduate Theses, Dissertations, and Problem Reports

Quantifying chemical erosion in the lithologically-heterogenous Appalachian Valley and Ridge

Amelia J. Zanoni

The interplay between physical and chemical erosion is well understood in landscapes underlain by a uniform rock type, but many regions are underlain by a mixture of rock types with varying erosion resistance and solubility. We used measurements of stream-water chemistry to estimate chemical erosion rates in the Appalachian Valley and Ridge, a region where the mechanisms of lithologic control over topography are poorly understood. Newly acquired stream water samples were collected from 51 locations across the research area during the Fall of 2023. The sampled waters …

Investigation Of Deoxyfluorination Of Alkyl Alcohols Using Pentafluoropyridines Through A Covalent Intermediate, Christopher Allen Bias

Graduate Theses, Dissertations, and Problem Reports

Organofluorines are an omnipresent class of organic molecules, especially in pharmaceuticals. Selective fluorination of drug molecules allows for the influence of properties including metabolic activity, solubility, and intrinsic potency. Deoxyfluorinations are typically performed via generation of nucleophilic fluoride from a deoxyfluorination agent. Traditionally, diethylaminosulfur trifluoride (DAST) is the reagent of choice for these reactions, and it remains a popular reagent today. However, it has a propensity to form elimination side products and explode. Several research groups have recently developed new classes of deoxyfluorination agents including imidazole-based reagents (PhenoFluor) and sulfonyl fluorides (PyFluor) that exhibit better functional group tolerance and much …

(Non-) Recovery Of An Agricultural Stream From Straightening And Dredging, Aras Anderson Mann

Graduate Theses, Dissertations, and Problem Reports

In recent history, natural, meandering streams have been straightened and dredged to reduce flooding. While this practice can be effective in reducing flooding locally, it often results in the degradation of stream water quality and aquatic ecosystems. A straighter channel inherently increases the stream gradient, which could increase flow velocity, shear stress, and potentially downstream sediment yield. Studies have shown that straightened, channelized streams often begin to return to a meandering pattern 35-50 years post-channelization. Yet cross-sectional surveys and air photo analysis of the stream reach in this study, Deckers Creek, indicate little to no observable trend of the stream …

Estimating Inorganic Carbon Flux From Coal Mining Discharge Portals In The Bituminous Coal Field Region Of Pennsylvania, Lauren J. Rockwell

Graduate Theses, Dissertations, and Problem Reports

A fundamental driver of the adverse effects associated with coal mining is the interplay of water and oxygen within mined sites, leading to the creation of coal mine drainage (CMD). One often overlooked consequence of CMD is the release of geologically-bound carbon as carbon dioxide (CO₂). The interaction of CMD with carbonate rocks, specifically the presence of sulfuric acid driving the dissolution of these rocks, leads to the release of dissolved inorganic carbon (DIC). This study examined 25 CMD locations in an approximately 2,370 km² area within the bituminous coal field region of Pennsylvania (PA), specifically in …

Implementing Unmanned Aerial Vehicles To Collect Human Gait Data At Distance And Altitude For Identification And Re-Identification, Donn E. Bartram

Graduate Theses, Dissertations, and Problem Reports

Gait patterns are a class of biometric information pertaining to the way a person moves and poses. Gait information is unique to each person and can be used to identify and reidentify people. Historically, this task has been achieved through the use of multiple ground-based imaging sensors. However, as Unmanned Aerial Vehicles (UAVs) advance, they present the opportunity to evolve the process of persons identification and re-identification. Collecting human gait data using UAVs at distances ranging from 20m to 500m and altitudes ranging from 0m to 120m is a challenging task. The current biometric data collection methods, primarily designed for …

Studies On Depth And Torsion In Tensor Products Of Modules, Uyen Huyen Thao Le

Graduate Theses, Dissertations, and Problem Reports

This dissertation represents an in-depth exploration of two distinct yet interconnected research topics within commutative algebra: one centered around a conjecture of Huneke and R. Wiegand and the other concerns a depth inequality of Auslander. It consists of the following three papers as well as the author's work under the direction of Professor Olgur Celikbas:

• Remarks on a conjecture of Huneke and Wiegand and the vanishing of (co)homology, Journal of Mathematical Society of Japan Advance Publication. (joint work with Olgur Celikbas, Hiroki Matsui, and Arash Sadeghi).
• An extension of a depth inequality of Auslander, Taiwanese Journal of Mathematics, …

Exogenous Factors That Impact Huntingtin Aggregation, Adam Skeens

Graduate Theses, Dissertations, and Problem Reports

While expansion of a polyglutamine (polyQ) domain is the immediate cause of huntingtin (htt) aggregation associated with Huntington’s Disease (HD), other cellular factors modify aggregation. These include interactions with cellular membranes, protein biding partners, molecular crowding, and proteinaceous seeds. Here, two important factors are biophysically characterized: 1) the interaction of htt with endomembranes and 2) proteinaceous seeds obtained from a variety of htt-derived peptides. In the first project, the aggregation of htt at bilayer interfaces and in the presence of divalent cations was investigated. A major cellular factor implicated in altered htt aggregation is the binding of lipids. Furthermore, the …

On Eulerian Subgraphs And Hamiltonian Line Graphs, Yikang Xie

Graduate Theses, Dissertations, and Problem Reports

A graph {\color{black}$G$} is Hamilton-connected if for any pair of distinct vertices {\color{black}$u, v \in V(G)$}, {\color{black}$G$} has a spanning $(u,v)$-path; {\color{black}$G$} is 1-hamiltonian if for any vertex subset $S \subseteq {\color{black}V(G)}$ with $|S| \le 1$, $G - S$ has a spanning cycle. Let $\delta(G)$, $\alpha'(G)$ and $L(G)$ denote the minimum degree, the matching number and the line graph of a graph $G$, respectively. The following result is obtained. {\color{black} Let $G$ be a simple graph} with $|E(G)| \ge 3$. If $\delta(G) \geq \alpha'(G)$, then each of the following holds. \\ (i) $L(G)$ is Hamilton-connected if and only if $\kappa(L(G))\ge …

Copper-Catalyzed Dehydrogenative Decarboxylation Reactions Of Carboxylic Acids To Alkenes, Michael P. Stanton

Graduate Theses, Dissertations, and Problem Reports

Linear alpha olefins (LAOs) are important building blocks in the production of linear low-density polyethylene, a plastic used in products such as shrink wraps, plastic bags, tubing, plasticizers, among others. Commercial methods for generating LAOs utilize ethylene oligomerization, but this method is reliant on fossil fuels and leads to unselective product formation. Synthesis of LAOs from renewable resources, namely carboxylic acids, by decarbonylative dehydration strategies has been well studied, however, this method has inherent drawbacks rooted in the formation of internal olefin side-products through isomerization pathways. With the goal of avoiding internal isomerization, this thesis explores a dehydrogenative decarboxylation strategy …

Natural Fracture Evolution: Investigations Into The Middle Devonian Marcellus Shale, Appalachian Basin, Usa, Natalie Abigail Mitchell

Graduate Theses, Dissertations, and Problem Reports

Optimizing recovery from unconventional shale reservoirs has generated considerable research into optimal recovery methods through hydraulic fracturing design and shale reservoir characterization in the development of long-term hydrocarbon producers. Permeability at multiple scales from nanometer-scale pore sizes and nano-darcy permeability to completion-induced fractures defining a 100’s of meter stimulated reservoir volume plays a significant role in hydrocarbon flow during production in shale reservoirs. Preexisting cemented fractures in unconventional shale reservoirs are abundant and preferentially reactivate during induced hydraulic fracturing treatment to create necessary large-scale permeability. While previous investigations have significantly improved our knowledge of shale reservoirs, it has also highlighted …

Analytical Heat Transfer Modeling Of The Microwave Heating Process: A Focus On Carbon Black, Craig Offutt

Graduate Theses, Dissertations, and Problem Reports

Electronic waste (e-waste) has become a significant environmental issue due to the rapid advancement of technology, increasing demand for electronic devices, and shorter lifespan of electronics. One critical step in processing the e-waste involves ball milling as a means of preparing the recycling e-waste for the recovery of critical materials. Ball milling is a technique that involves the mechanical crushing and grinding of electronic waste to reduce its size and improve its reactivity during recovery. Our focused recovery technique is based on a microwave recovery technique of these critical materials from e-waste. The size and distribution of the e-waste with …

Forecasting And Optimizing Sensitivity To Low-Frequency Gravitational Waves, Andrew Ryan Kaiser

Graduate Theses, Dissertations, and Problem Reports

Pulsars are among the most exotic objects in our Universe. These rapidly
spinning, high magnetic field neutron stars can be used for a wide range of
scientific studies: from the makeup of their own extremely dense and poorly
understood interior to using their extremely regular signals to detect gravita-
tional waves (GWs). Pulsar timing continues to expand to broader communi-
ties, with larger and more sensitive radio telescopes planned and partnerships
between pulsar timing arrays (PTAs) that span the entire globe. A realm of
new physics with the detection of a background hum of gravitational waves
from black holes merging …

Effects Of Climate Change And Landscape-Scale Forest Management On Avian Communities, Abundance, And Nest Success In The Appalachian Mountains, Hannah L. Clipp

Graduate Theses, Dissertations, and Problem Reports

Birds are integral components of ecosystems and account for billions of dollars in tangible benefits to humans. As such, recent continental declines of bird species have ecological and economic consequences, providing the impetus for my dissertation research. I identified knowledge gaps and proposed novel questions about how birds in the Appalachian Mountains are influenced by changing environmental conditions due to climate change and forest management. The Appalachian Mountains encompass an important biogeographical region with high conservation value due to its myriad habitats and corresponding bird species diversity. Thus, there is a critical need to evaluate the effects of shifting climate …

Drift Orbit Bifurcation Effects On Earth’S Radiation Belt Electrons, Jinbei Huang

Graduate Theses, Dissertations, and Problem Reports

Energetic charged particles trapped in the Earth’s radiation belt form a hazardous space environment for artificial electronic systems and astronauts. The study of Earth's radiation belt is becoming increasingly important with the development of communication technology, which plays a significant role in modern society. Earth’s radiation belt is highly dynamic, and the electron flux can drop by several orders of magnitude within a few hours which is called radiation belt dropout. The fast dropout of energetic electrons in the radiation belt, despite its significance, has not been thoroughly studied. One of the most compelling outstanding questions in Earth's radiation belt …

Discovering And Understanding High Performance Materials Using Density Functional Theory: Quantum Mechanical Simulations And The Consequences Of Symmetry, Olivia M. Pavlic

Graduate Theses, Dissertations, and Problem Reports

There are two primary ways that atomic level modeling data is used: materials prediction and understanding materials properties. This dissertation work encom- passes two studies, each of which explore one application. Both studies rely on the highly successful density functional theory (DFT) formalism but differ in that two different implementations of DFT are used on two different high performance materials. The first study on bulk magnesium (Mg) metal alloys explores materials prediction and relies on VASP, a commercially maintained plane-wave DFT code which has been used extensively to successfully study a wide range of materials. [1] The approach used in …

Bedrock Channel Geometry: Meter To Micron Scale Controls On Fluvial Incision, Nicholas J. Colaianne

Graduate Theses, Dissertations, and Problem Reports

The relative resistance of various rock types to incisional processes vary widely and the properties governing bedrock erodibility are poorly understood. Lithologic properties influencing erodibility are the culmination of a rock’s depositional, diagenetic, and exhumation processes. Difficulty identifying a convenient physical proxy for erodibility suggests examining evidence of these processes holistically may offer insight into the role of each in setting a rock’s resistance to incisional forces. In this study we use measured channel geometries along a short stretch of the Dry Fork, WV hosting three distinct lithologic settings to infer relative erodibility against measured and observed fluvial, lithologic, and …

Enantioselective Dearomatization Facilitated By Non-Covalent Interactions Of N-Heterocyclic Carbene Catalysts And Pyridinium Salts, Jack A. Patterson

Graduate Theses, Dissertations, and Problem Reports

Dihydropyridines are a practical organic scaffold commonly used for their pharmaceutical properties. Nucleophilic dearomatization of pyridines has proven to be a useful method in obtaining dihydropyridines. By using N-heterocyclic carbene (NHC) organocatalysts, dihydropyridines can be synthesized with high regioselectivity of the 1,4 regioisomer over the 1,2- regioisomer but often with low enantioselectivity. By incorporating non-covalent interaction contact points, we hypothesize that enantioselectivity can be enhanced. By synthesizing numerous NHCs, each proposed to exhibit a different type of non-covalent interaction (i.e., hydrogen bonding or ion pairing), an understanding of the secondary interactions within this reaction system can be studied and …

An Empirical Analysis Of Algorithms For Simple Stochastic Games, Cody William Klingler

Graduate Theses, Dissertations, and Problem Reports

This thesis presents the findings of a computational study on algorithms for Simple Stochastic Games (SSG). Simple Stochastic Games are a restriction of the Shapley stochastic model motivated by their applications in AI planning, logic synthesis, and theoretical computer science. This thesis seeks to empirically assess the performance of these algorithms to compensate for their lack of strong complexity results. Where applicable, we include both variations of algorithms where stable strategies are computed by a linear-programming and naive approach. These algorithms are evaluated on random inputs, in addition to specific difficult cases that were identified experimentally. We are interested in …

Longest Path And Cycle Transversal And Gallai Families, James A. Long Jr

Graduate Theses, Dissertations, and Problem Reports

A longest path transversal in a graph G is a set of vertices S of G such that every longest path in G has a vertex in S. The longest path transversal number of a graph G is the size of a smallest longest path transversal in G and is denoted lpt(G). Similarly, a longest cycle transversal is a set of vertices S in a graph G such that every longest cycle in G has a vertex in S. The longest cycle transversal number of a graph G is the size of a smallest longest cycle transversal in G and …

A Study Of Accidental Daughter Crystals In Fluid Inclusions In Bedded Halite From The Permian Opeche Shale And Cedar Hills Sandstone Of The Midcontinental United States, Ryan James Prchlik

Graduate Theses, Dissertations, and Problem Reports

Ancient acid-saline lakes of the midcontinental United States deposited bedded halite during Permian time. These deposits are not typically preserved at the surface, but drill cores of the Opeche Shale of North Dakota and Cedar Hills Sandstone of Kansas contain preserved beds of halite. Halite from these ancient lakes have primary fluid inclusions that contain Permian lake water. Also included are accidental daughter crystals that were trapped inside the fluid inclusions at time of halite precipitation. Both the fluid and daughter crystals inside bedded halite can tell us about the geochemistry of original lake waters of Pangea.

Petrography and laser …

Multimodal Neuron Classification Based On Morphology And Electrophysiology, Aqib Ahmad

Graduate Theses, Dissertations, and Problem Reports

Categorizing neurons into different types to understand neural circuits and ultimately brain function is a major challenge in neuroscience. While electrical properties are critical in defining a neuron, its morphology is equally important. Advancements in single-cell analysis methods have allowed neuroscientists to simultaneously capture multiple data modalities from a neuron. We propose a method to classify neurons using both morphological structure and electrophysiology. Current approaches are based on a limited analysis of morphological features. We propose to use a new graph neural network to learn representations that more comprehensively account for the complexity of the shape of neuronal structures. In …