Physical Sciences and Mathematics Commons^™

Cerulean Warbler (Setophaga Cerulea) And Associated Species Response To Operational Silviculture In The Central Appalachian Region, Gretchen Emily Nareff

Graduate Theses, Dissertations, and Problem Reports

In this study, I assessed the response of Cerulean Warblers (Setophaga cerulea) and 5 additional songbird species to timber harvests prescribed through operational silviculture. The research took place in relatively contiguous mature deciduous forests in 4 states in the central Appalachian region—Kentucky, Pennsylvania, Virginia, and West Virginia, USA.

For the first part of the study, I collected Cerulean Warbler abundance and territory data through point counts and territory mapping, respectively. I used the point count data to model Cerulean Warbler abundance pre- and post-harvest at 5 study areas (Kentucky [n=1], Virginia [n=2], West Virginia [n=2]) and post-harvest at …

Beneath The Gypsum Dunes: Cenozoic History Of Wind And Water From A Core Drilled At White Sands, New Mexico, Jackson Bentley Jakeway

Graduate Theses, Dissertations, and Problem Reports

White Sands, New Mexico is the largest gypsum dune field on planet Earth, the result of reworking of gypsum deposits. The dunes have been well studied, but the Cenozoic history preceding the formation of the dune field has been poorly studied. A core drilled to a depth of 192 ft (58.5 m) beneath the modern dune field contains deposits from saline lakes, sandflats, perennial freshwater lakes, perennial brackish to saline lakes, and saline mudflats.

The core is composed of bottom-growth bedded gypsum, gypsum sandstone and siltstone, mixed siliciclastic-gypsum sandstones and siltstones, laminated siliciclastic mudstones, gypsum mudstones, and carbonate mudstones. Bottom-growth …

Photoluminescent Zirconium Complexes For Visible Light Photoredox Catalysis, Yu Zhang

Graduate Theses, Dissertations, and Problem Reports

Early transition metals like zirconium are attractive candidates for the design of luminescent molecules based on earth-abundant elements. Here, a series of zirconium complexes carrying two pyrrolyl-based ligands have been synthesized and characterized. These complexes are photoluminescent upon excitation with visible light and exhibit remarkably long emission lifetimes of hundreds of μs in solution at room temperature. Computational studies using time-dependent density functional theory (TD-DFT) were conducted to identify the nature of the luminescent excited states as mixed intra-ligand/ligand-to-metal charge-transfer (ILCT/LMCT) states. The electrochemistry studies revealed multiple reversible redox events for each zirconium complex. Furthermore, the excited state of the …

Electrochemical Detection Of Fentanyl Using Screen-Printed Carbon Electrodes With Confirmatory Analysis Of Fentanyl And Its Analogs In Oral Fluid Using Liquid Chromatography-Tandem Mass Spectrometry, Colby E. Ott

Graduate Theses, Dissertations, and Problem Reports

Utilizing screen-printed carbon electrodes (SPCEs), a fast, simple, and sensitive approach toward the detection, identification, and quasi-quantitation of fentanyl was achieved both in an electrochemical cell and as a drop on the electrode surface. Electro-oxidation of fentanyl at the electrode was demonstrated using adsorptive stripping square-wave voltammetry between -0.5 V and +1.6 V with 100 mM Tris-HCl buffer at pH 8.5 as supporting electrolyte. Parameter optimization was conducted during method development to include supporting electrolyte and pH, electrochemical technique, pre-treatment and equilibration time, and various surface modifications. The simplest method utilizing an unmodified SPCE was determined to be appropriate for …

Exploring The Diffuse Neutral Hydrogen In And Around Nearby Galaxies, Amy Sardone

Graduate Theses, Dissertations, and Problem Reports

We explore the environment of 36 nearby galaxies in neutral hydrogen (H I) as part of the MeerKAT H I Observations of Nearby Galactic Objects; Observing Southern Emitters (MHONGOOSE) survey with the Robert C. Byrd Green Bank Telescope (GBT), and the Imaging Galaxies Intergalactic and Nearby En- vironment (IMAGINE) survey with the Parkes Radio Telescope. We obtained deep observations of each of these galaxies, reaching column density detection sensitivities as low as NHI ∼ 1e17 cm^−2, which allowed us to quantify the amount of diffuse H I in both samples of galaxies. This allows us to search for evidence of …

Browsing Via Sonification, Taylor C. Cutlip

Graduate Theses, Dissertations, and Problem Reports

Based on unexpected results in her previous research, Dr. Frances Van Scoy became inspired to develop a tool that allows the user to navigate spaces using auditory instead of visual cues to detect objects or anomalies in a given space in an effort to overcome the encountered obstacles. This problem report details the work of one of her grad students in exploring different open source software for developing the tool as well as research into gestures and other considerations when furthering this research into the third dimension at a future date.

Autonomous Systems With Reuse: A Survey On The State-Of-The-Practice, Denny Laverne Hood Iii

Graduate Theses, Dissertations, and Problem Reports

This problem report presents the results of an anonymous online survey that was used to collect information about software systems that use model-based software engineering, contain autonomy and where software reuse plays an important role. Recent advancements in computation ability and the emergence of decision-making algorithms have increased interest in and use of autonomy in applications areas such as aeronautics, automotive, military, and space industries. In these application domains, autonomy is used to reduce costs, reduce reaction times, and improve performance. Due to the emerging nature of autonomy, very little research has been done regarding the level of autonomy of …

Three Essays On Water Economics, Fahad Alzahrani

Graduate Theses, Dissertations, and Problem Reports

This dissertation consists of three essays that explore the impacts of changes in public water quality, reliability, and raw water source. The first essay explores the relationship between episodes of contaminated drinking water and health care expenditures in the United States. Using panel data from 48 contiguous states from 2000 to 2011 and spatial econometrics modeling methods, the results indicate that there is positive and statistically significant impact on per capita health care expenditures from the percentage of a state’s population exposed to contamination episodes. The second essay examines the problem of water supply reliability due to aging infrastructure of …

X-Ray Fluorescence Applications In Mudrock Characterization: Investigations Into Middle Devonian Stratigraphy, Appalachian Basin, Usa, Keithan Garrett Martin

Graduate Theses, Dissertations, and Problem Reports

Mudrocks are characterized by nanometer-scale pore sizes and nano-darcy permeability, which plays a significant role in hydrocarbon flow during production. Resulting from these characteristics, mudrocks were exclusively considered a source rock, which charged overlying, more porous mediums. Hydraulic fracturing, a technology used to create artificial fractures to liberate hydrocarbons from the reservoir, enabled natural gas to be produced from mudrock reservoirs economically. Over the last fifteen years, this technology motivated research efforts to understand reservoir characteristics of mudrock. These investigations significantly improved our knowledge of mudrock systems, but have also highlighted key areas that are undeveloped and/or where conflicting hypotheses …

Deep Learning For Image Restoration And Robotic Vision, Yixin Du

Graduate Theses, Dissertations, and Problem Reports

Traditional model-based approach requires the formulation of mathematical model, and the model often has limited performance. The quality of an image may degrade due to a variety of reasons: It could be the context of scene is affected by weather conditions such as haze, rain, and snow; It's also possible that there is some noise generated during image processing/transmission (e.g., artifacts generated during compression.). The goal of image restoration is to restore the image back to desirable quality both subjectively and objectively. Agricultural robotics is gaining interest these days since most agricultural works are lengthy and repetitive. Computer vision is …

Empirical Studies Related To Open Questions Regarding Geomagnetic Storms, Bruce Patrick Tepke

Graduate Theses, Dissertations, and Problem Reports

Earth’s magnetosphere is subject to disturbances, as evidenced by variations of the geomagnetic field in space and on the ground. It is generally understood that most such disturbances are controlled by variations in the solar wind, with interplanetary magnetic field orientations directed southward opposite to Earth’s dipole magnetic axis being most conducive to energy transfers into the magnetosphere, thus resulting in more disturbed intervals. However, the exact functional form for solar wind driving of the magnetosphere has been widely studied, with proposed functional forms varying from the simple half-wave electric rectifier to expressions with a much more complicated dependence upon …

Multimodal Approach For Malware Detection, Jarilyn M. Hernandez Jimenez

Graduate Theses, Dissertations, and Problem Reports

Although malware detection is a very active area of research, few works were focused on using physical properties (e.g., power consumption) and multimodal features for malware detection. We designed an experimental testbed that allowed us to run samples of malware and non-malicious software applications and to collect power consumption, network traffic, and system logs data, and subsequently to extract dynamic behavioral-based features. We also extracted code-based static features of both malware and non-malicious software applications. These features were used for malware detection based on: feature level fusion using power consumption and network traffic data, feature level fusion using network traffic …

Analyzing Satisfiability And Refutability In Selected Constraint Systems, Piotr Jerzy Wojciechowski

Graduate Theses, Dissertations, and Problem Reports

This dissertation is concerned with the satisfiability and refutability problems for several constraint systems. We examine both Boolean constraint systems, in which each variable is limited to the values true and false, and polyhedral constraint systems, in which each variable is limited to the set of real numbers R in the case of linear polyhedral systems or the set of integers Z in the case of integer polyhedral systems. An important aspect of our research is that we focus on providing certificates. That is, we provide satisfying assignments or easily checkable proofs of infeasibility depending on whether the instance …

Object-Based Supervised Machine Learning Regional-Scale Land-Cover Classification Using High Resolution Remotely Sensed Data, Christopher A. Ramezan

Graduate Theses, Dissertations, and Problem Reports

High spatial resolution (HR) (1m – 5m) remotely sensed data in conjunction with supervised machine learning classification are commonly used to construct land-cover classifications. Despite the increasing availability of HR data, most studies investigating HR remotely sensed data and associated classification methods employ relatively small study areas. This work therefore drew on a 2,609 km2, regional-scale study in northeastern West Virginia, USA, to investigates a number of core aspects of HR land-cover supervised classification using machine learning. Issues explored include training sample selection, cross-validation parameter tuning, the choice of machine learning algorithm, training sample set size, and feature selection. A …

Discerning The Diets Of Sweep-Feeding Eurypterids Through Analyses Of Mesh-Modified Appendage Armature, Emily Samantha Hughes

Graduate Theses, Dissertations, and Problem Reports

Eurypterids were a group of aquatic chelicerates that lived throughout most of the Paleozoic. While swimming eurypterids are generally considered to be active predators, the benthic stylonurine eurypterids appear to have had a mode of life similar to modern horseshoe crabs with the exception of two clades, the Stylonuroidea and the Mycteropoidea, both of which independently evolved modifications for sweep-feeding on their anterior appendages. Among extant suspension feeders, it has been shown that there is a linear correlation between the average spacing of feeding structures and prey sizes. This relationship was extrapolated to the sweep-feeding stylonuroid and mycteropoid eurypterids in …

A Machine-Aided Seismic Signal Analysis Workflow For Subsurface Faults And Facies Visualization And Interpretation, South Central Anadarko Basin, Oklahoma, Wade Martin

Graduate Theses, Dissertations, and Problem Reports

Seismic attribute analysis enhances the understanding of subsurface geology and has continually gained traction in the oil and gas industry since the 1970’s. Many seismic attributes are available for petroleum geoscientists. This research intends to provide insight to an analytical attribute workflow for rock property estimation in the Anadarko basin of Oklahoma that is prolific in oil and gas exploration, with a particular focus on seismic texture. 3-D volumes processed for seismic texture facies and structure enhance geophysical investigation and interpretation of amplitude data. This study will contribute valuable insight to reservoir studies and the potential for texture attribute well …

Edge Colorings Of Graphs On Surfaces And Star Edge Colorings Of Sparse Graphs, Katherine M. Horacek

Graduate Theses, Dissertations, and Problem Reports

In my dissertation, I present results on two types of edge coloring problems for graphs.

For each surface Σ, we define ∆(Σ) = max{∆(G)| G is a class two graph with maximum degree ∆(G) that can be embedded in Σ}. Hence Vizing’s Planar Graph Conjecture can be restated as ∆(Σ) = 5 if Σ is a sphere. For a surface Σ with characteristic χ(Σ) ≤ 0, it is known ∆(Σ) ≥ H(χ(Σ))−1, where H(χ(Σ)) is the Heawood number of the surface, and if the Euler char- acteristic χ(Σ) ∈ {−7, −6, . . . , −1, 0}, ∆(Σ) is already …

Non-Target Analyses Of Novel Psychoactive Substances; Inherent Variation In Gcms Relative Abundances And Gas Phase Hydrogen Deuterium Exchange Isomer Discrimination, Kristin Michelle Kelly

Graduate Theses, Dissertations, and Problem Reports

Novel psychoactive substances (NPSs) are synthetically derived compounds designed to mimic the effects of other illicit drugs. An endless cycle of NPSs continually reach the drug market due to limitations in drug legislation creating two problems: (1) non-availability of standards and (2) multiple isobars indistinguishable even to high resolution mass spectrometry. Gas chromatography-mass spectrometry (GCMS) is the most common instrument used for compound identification in non-targeted seized drug analysis. Compound identification using this technique relies on mass spectra where the percent relative abundances (%RAs) of all m/z values are compared manually or searched against a library database. Lacking standards, laboratories …

Evaluation Of Ufp Number Concentrations Near A Natural Gas Transmissions Station, John M. Thornsbury

Graduate Theses, Dissertations, and Problem Reports

Identifying UFP number concentrations near a natural gas compressor station is key to understanding ambient exposures associated with the transmission station. Developing an atmospheric survey to characterize these concentrations was key in understanding ambient exposures. The aims of this study are to compare and contrast number concentrations taken in a hollow, near the transmission station to those of the background. From this, it would be possible to identify whether or not the compressor station was a contributing factor to peaks and spikes in number concentrations.

This study begins with a review of what UFPs are, how they react in different …

The Impact Of Hii Regions On The Interstellar Medium Of Our Galaxy, Matteo Luisi

Graduate Theses, Dissertations, and Problem Reports

The interstellar medium (ISM) of our Galaxy contains low-density diffuse ionized gas known as the warm ionized medium (WIM). O- and B-type stars emit large amounts of ionizing radiation and it is believed that a fraction of this radiation escapes from their fully ionized HII regions and into the ISM where it is responsible for maintaining the ionization of the WIM. Here we aim to better understand how the radiation produced by OB stars is able to leak from the HII regions, how the radiation field changes during this process, and how the radiation affects the ambient ISM. Using Green …

Impacts Of Climate Change On Water Balance Components In The Central Appalachian Mountains, Usa, Brandi Anne Gaertner

Graduate Theses, Dissertations, and Problem Reports

This research investigated the impact of climate and land cover on water balance components including evapotranspiration and runoff in the mountainous central Appalachian region of the United States. The first studyanalyzed trends in climatologic, hydrologic, and growing season length variables, identified the important variables effecting growing season length changes, and evaluated the influence of a lengthened growing season on increasing evapotranspiration trends. The results showed that growing season length has increased, on average, by ~22 days and evapotranspiration has increased ~12 mm. The second study quantified long-term historical and future climate trends, evaluated water balance sensitivity to change, and quantified …

Structural Style And Stratigraphic Architecture Of The Northeastern Brooks Range, Alaska, Benjamin G. Johnson

Graduate Theses, Dissertations, and Problem Reports

The Arctic Alaska–Chukotka microplate is a large Mesozoic–Cenozoic composite terrane that resides at the northern limit of the North American Cordillera. Although its Mesozoic origins are assuredly linked to the opening of the Amerasian Basin of the Arctic Ocean, its Paleozoic origins can be linked to at least three separate paleocontinents, including northern Laurentia, Baltica, and Siberia. Across the Arctic Alaska portion of the microplate, an internal, mid-Paleozoic suture zone presumably separates rocks of the North Slope subterrane (Laurentian affinity) from a collection of smaller subterranes in the southern Brooks Range and Seward Peninsula (Baltic affinity).

The mountains of the …

Security Bug Report Classification Using Feature Selection, Clustering, And Deep Learning, Tanner D. Gantzer

Graduate Theses, Dissertations, and Problem Reports

As the numbers of software vulnerabilities and cybersecurity threats increase, it is becoming more difficult and time consuming to classify bug reports manually. This thesis is focused on exploring techniques that have potential to improve the performance of automated classification of software bug reports as security or non-security related. Using supervised learning, feature selection was used to engineer new feature vectors to be used in machine learning. Feature selection changes the vocabulary used by selecting words with the greatest impact on classification. Feature selection was able to increase the F-Score across the datasets by increasing the precision. We also explored …

Identification Of Burnt Smokeless Gunpowders Through Physical Characteristics, Cameron Taylor Hartwig

Graduate Theses, Dissertations, and Problem Reports

Firearms are one of the most commonly used weapons by violent criminals throughout the United States. In crimes involving the discharge of a firearm, residues from the combustion products are deposited on the shooter and in the firing direction. Some of the residues left behind are unburnt and partially burnt particles of the propellant. The most common propellant used in modern firearms is smokeless powder. The identification of particles as smokeless powder and the determination of the brand of the powder are two ways a forensic examiner may be able to utilize smokeless powder evidence. The determination of the brand …

Reconciling The Dissonance Between Historic Preservation And Virtual Reality Through A Place-Based Virtual Heritage System., Danny J. Bonenberger

Graduate Theses, Dissertations, and Problem Reports

This study explores a problematic disconnect associated with virtual heritage and the immersive 3D computer modeling of cultural heritage. The products of virtual heritage often fail to adhere to long-standing principles and recent international conventions associated with historic preservation, heritage recording, designation, and interpretation. By drawing upon the geographic concepts of space, landscape, and place, along with advances in Geographic Information Systems, first-person serious games, and head-mounted Virtual Reality platforms this study envisions, designs, implements, and evaluates a virtual heritage system that seeks to reconcile the dissonance between Virtual Reality and historic preservation. Finally, the dissertation examines the contributions and …

Application Of Lidar To 3d Structural Mapping, Bertrand Gaschot

Graduate Theses, Dissertations, and Problem Reports

The rugged, densely forested terrain of the West Virginia Appalachian Valley and Ridge Province has made it difficult for field-based studies to agree on the structure of the highly deformed Silurian-Devonian cover strata. In this study, we demonstrate a 3D approach to geologic mapping utilizing the structural information revealed in a “bare-earth” 1-m Lidar DEM of the Smoke Hole Canyon. The completed 3D map was integrated with kinematic forward modeling carried out in MOVE^TM to provide information on the parameters required to form the major structures observed. Additionally, land surface attributes generated using geomorphometric analysis of the Lidar allowed …

Petrophysical And Geomechanical Characterization Of The Marcellus Shale In The Appalachian Basin, Yixuan Zhu

Graduate Theses, Dissertations, and Problem Reports

In recent years, more and more attention is paid to shale gas and hydrocarbon liquids exploration and exploitation in unconventional reservoirs. With the development of horizontal drilling and hydraulic fracturing, production from unconventional reservoirs has been greatly increased. However, not all wells, regions and basins harbor highly successful shale gas and liquids producers. In order to improve the production efficiency and reduce the cost of projects, detailed analysis needs to be undertaken to characterize the reservoir. As opposed to conventional reservoirs, extraction of gas in the unconventional reservoir is dependent not only on the reservoir quality, but also on completion …

Factors Influencing Survival, Productivity, And Population Growth Of Eastern Wild Turkeys In Northeastern South Dakota, Reina M. Tyl

Graduate Theses, Dissertations, and Problem Reports

The population of eastern wild turkeys in northeastern South Dakota appeared to be expanding soon after reintroduction in the 1990s, however, recent harvest trends suggest declining abundance in the region. Spring turkey hunting expenditures are projected to be around $6.5 million in South Dakota, with about $3 million of those expenditures occurring within the northeastern prairie region. However, the number of birds harvested during the spring prairie firearm season has been declining since 2010. Due to concerns about a declining population, the autumn hunting season was closed in 2014. The cause of the apparent decline is unclear. Updated demographic information …

Using Lidar To Approximate Keystone Structure And Evaluate Management Practices In Potential Habitats Of The Endangered Karner Blue Butterfly (Lycaeides Melissa Samuelis), Brandyn Balch

Graduate Theses, Dissertations, and Problem Reports

Keystone structure is the spatial structure required by a given species, at a scale that is determined by that species’ needs and mobility. The endangered Karner blue butterfly (Lycaeides melissa samuelis, hereafter KBB) has a keystone structure that incorporates trees and bushes to provide the mixture of sun and shade required to fulfil its life functions. Airborne light detection and ranging (lidar) is a potentially invaluable tool for characterizing keystone structures. However, lidar has yet to be utilized to evaluate structural suitability of KBB habitats. Therefore, I investigated the use of lidar for characterizing critical attributes of KBB habitat structure, …

Infinite Matroids And Transfinite Sequences, Martin Andrew Storm

Graduate Theses, Dissertations, and Problem Reports

A matroid is a pair M = (E,I) where E is a set and I is a set of subsets of E that are called independent, echoing the notion of linear independence. One of the leading open problems in infinite matroid theory is the Matroid Intersection Conjecture by Nash-Williams which is a generalization of Hall’s Theorem. In [31] Jerzy Wojciechowski introduced µ- admissibility for pairs of matroids on the same ground set and showed that it is a necessary condition for the existence of a matching. A pair of matroids (M,W) with common ground set E is µ-admissible if a …