Physical Sciences and Mathematics Commons^™

Generalizations Of The Arcsine Distribution, Rebecca Rasnick

Electronic Theses and Dissertations

The arcsine distribution looks at the fraction of time one player is winning in a fair coin toss game and has been studied for over a hundred years. There has been little further work on how the distribution changes when the coin tosses are not fair or when a player has already won the initial coin tosses or, equivalently, starts with a lead. This thesis will first cover a proof of the arcsine distribution. Then, we explore how the distribution changes when the coin the is unfair. Finally, we will explore the distribution when one person has won the first …

Transparency And Communication Patterns In Human-Robot Teaming, Shan Lakhmani

Electronic Theses and Dissertations

In anticipation of the complex, dynamic battlefields of the future, military operations are increasingly demanding robots with increased autonomous capabilities to support soldiers. Effective communication is necessary to establish a common ground on which human-robot teamwork can be established across the continuum of military operations. However, the types and format of communication for mixed-initiative collaboration is still not fully understood. This study explores two approaches to communication in human-robot interaction, transparency and communication pattern, and examines how manipulating these elements with a robot teammate affects its human counterpart in a collaborative exercise. Participants were coupled with a computer-simulated robot to …

Chemistry And Dissipation At Mineral Surfaces In The Space Environment, William Tucker

Electronic Theses and Dissertations

The composition and morphology of mineral surfaces is known to play an important role in various phenomena relevant to planetary science. For example, the synthesis and processing of complex organics likely occurs at mineral surfaces strongly affected by the space environment. Furthermore, the dissipative and adhesive properties of dust grains may depend strongly on the chemical state of the surface including the presence of dangling bonds, adsorbates, and radicals. In this dissertation, experimental results are first presented which demonstrate that mineral grains subjected to high temperatures in a reducing environment lead to iron nanoparticles which are strongly catalytic for the …

Biogeochemical Effects Of Sea Level Rise-Induced Transitions Within Coastal Wetlands, Havalend Steinmuller

Electronic Theses and Dissertations

As sea level rise (SLR) affects coastal wetlands, ecosystem responses can include vertical accretion, landward transgression, or submergence. Sea level rise-induced transitions can alter key biogeochemical transformations within wetland soils, impacting the ability of these systems to provide ecosystem services, specifically carbon (C) storage and water quality regulation. Through a series of complementary laboratory and field-based studies, biogeochemical responses to salinity, vegetation shifts, and submergence were investigated. Changes in nutrient dynamics associated with saltwater intrusion were evaluated by artificially adding saline water to different freshwater wetland soil types, indicating that potential exports of critical nutrients (forms of nitrogen, phosphorus, and …

Chemistry And Structure Of Ru/Sio2 And Ru/Al2o3 Interfaces, Sameer Ezzat

Electronic Theses and Dissertations

The resistivity size effect in nanoscale metals is of both scientific and technological interest, the latter due to its importance to interconnects between transistors in integrated circuits. In this work we report the variation of resistivity associated with surface scattering of ex-situ annealed single crystal Ru thin films grown on sapphire substrates by sputter deposition. A set of samples were overcoated with dielectric and subjected to a variety of reducing and oxidizing anneals. The changes in the chemistry and structure of the dielectric interface induced by the anneals, as determined by x-ray reflectivity and x-ray photoelectron spectroscopy measurements, are related …

Detection Of Mercury Through Surface Plasmon Resonance Of Immobilized Gold Nanorods, Khang Trieu

Electronic Theses and Dissertations

Mercury is a known environmental pollutant that can damage the brain, heart, kidney and lungs upon exposure. Emissions from fossil fuel plants can release mercury into the air, where it can settle into the water supply and be exposed to human and aquatic life. The use of gold nanorods functionalized on solid substrates as a mercury sensor in tap water samples is investigated herein. The functionalization of the substrates involves the physical immobilization of the nanorods onto the solid surface through the use of (3-mercaptopropyl)trimethoxysilane (MPTMS). The immobilization of the nanorods drastically increases their stability, allowing for use in complicated …

Novel Fuel-Producing Fungi And Methodologies For Increasing Fuel Production, Yuemin Wang Kovaleff

Electronic Theses and Dissertations

An endophytic fungus Hypoxylon sp. (BS15) has recently been isolated and found to produce volatile organic compounds (VOCs) that have potential relevance as hydrocarbon fuels. In the work described here, the traditional refined carbohydrate (e.g., sucrose) diet source was replaced by simple sugars produced using a solvent free green chemistry mechanocatalytic method involving ball milling in the solid. BS15 is able to grow on this degraded cellulose as well as the more traditional potato dextrose broth. The volatile compounds produced from both media were largely the same. Unfortunately, it is observed that long term in vitro growth of BS15 results …

Synthetic Design And Characterization Of Polycyclic Aromatic Compounds In Molecular And Extended System, Gavin Pour

Electronic Theses and Dissertations

The work presented herein focuses on the synthesis and characterization of polycyclic aromatic compounds for a wide variety of toxicological, analytical, and electronic applications. First, the modular synthesis of 12 dibenzo- and naphtho- fluoranthene polycyclic aromatic hydrocarbons (PAHs) via a Pd-catalyzed five-membered ring closing procedure is discussed. By understanding the various modes through which the Pd migrates during transformation, structural rearrangements were bypassed, obtaining regioselectivity through various redesigns in the synthetic route. Each compound in the serious was rigorously characterized via 1D/2D NMR, absorption and emission spectroscopy as well as cyclic voltammetry, which shows vast differences due to small structural …

Facies And Diagenesis Analyses Of The Fort Terrett Formation Of The Lower Cretaceous Edwards Group, Near Junction, Texas, Richard Alden Urwin Jr.

Electronic Theses and Dissertations

The Fort Terrett Formation was deposited on the western edge of the Comanche Shelf in central Texas. The predominate lithology of the Fort Terrett Formation is limestone which caps the hills that surround Junction, Texas. Deposition of the Fort Terrett Formation occurred within shallow, quiet waters during the Lower Cretaceous. Rose (1974) developed a general stratigraphic correlation and lithostratigraphic framework for the Cretaceous Shelf and established a regional correlation. Four stratigraphic divisions have been recognized in the Fort Terrett Formation. These are: a basal nodular unit, a burrowed unit, a dolomitic unit, and the Kirschberg evaporites. Wilkerson (2018) provided the …

A Multi-Plot Assessment Of Vegetation Structure Using A Micro-Unmanned Aerial System (Uas) In A Semi-Arid Savanna Environment., Nicholas E Kolarik

Electronic Theses and Dissertations

Unmanned Aerial Systems (UAS) have emerged as a capable platform for measuring vegetation health, structure and productivity. Products derived from UAS imagery typically have much finer spatial resolutions than traditional satellite or aircraft imagery, allowing the spectral and structural heterogeneity of vegetation to be mapped and monitored with more detail. This study uses UAS-captured imagery from the Chobe Enclave of northern Botswana. Flights were conducted across a gradient of savanna sites classified as grass-, shrub-, or tree-dominated. We compare multiple approaches for extracting woody vegetation structure from UAS imagery and assess correlations between in situ field measurements and UAS estimates. …

Lithium Molybdate-Sulfur Battery., Ruchira Ravinath Dharmasena

Electronic Theses and Dissertations

Rechargeable energy storage systems play a vital role in today’s automobile industry with the emergence of electric vehicles (EVs). In order to meet the targets set by the department of energy (DOE), there is an immediate need of new battery chemistries with higher energy density than the current Li- ion technology. Lithium–sulfur (Li–S) batteries have attracted enormous attention in the energy-storage, due to their high specific energy density of 2600 Wh kg^-1 and operational voltage of 2.0 V. Despite the promising electrochemical characteristics, Li-S batteries suffer from serious technical challenges such as dissolution of polysulfides Li₂S_{x …}

Synthetic Methods And Biological Applications Of Nitrogen Heterocycles To Compounds Of Biological Interest., Jarrid Ronnebaum

Electronic Theses and Dissertations

Thalidomide analogues were synthesized utilizing optimized click conditions from 3-azidoglutarimide and an array of arylacetylenes or N-ethynyl/N-propargyl phthalimide derivatives. The intermediate, 3-azidoglutarimde, was pivotal and yielded a new and scalable synthesis. The reaction conditions utilized a copper sulfate/sodium ascorbate system in aqueous tetrahydrofuran to propagate the dipolar cycloaddition reactions between the azidoglutarimide and the alkynyl coupling partners. The first explored substrates were substituted arylalkynes to optimize the click reaction. Arylalkynes selected were to exhibit similar electron deficient rings to mimic phthalimide. Along with the synthesis of click thalidomide analogues, click analogue of the antiangiogenic and more potent …

A Study On Radiative Pion Capture As A Source Of Background In The Search For Muon To Electron Conversion At The Mu2e Experiment., Joseph Leibson

Electronic Theses and Dissertations

The following thesis will cover the process of radiative pion capture in the Mu2e experiment at Fermi National Accelerator Laboratory. Radiative pion capture (RPC) is a process that is able to mimic the signal of an electron spawned from the neutrino-less conversion of a muon. In this paper we will discuss the current Standard Model accepted by physicists, and discuss charged lepton flavor violation, which is the motivation behind Mu2e. This paper will cover the theory behind Mu2e and RPC, as well as the apparatus involved in the Mu2e experiment. Next, software and simulations used to carry out the RPC …

Development Of Granulated Adsorbent For Clean-Up Of Water Contaminated By Cesium, Esther Alorkpa

Electronic Theses and Dissertations

A study was conducted on sol-gel synthesis of an adsorbent (phosphotungstic acid embedded in silica gel, H-PTA/SiO­₂) of radioactive cesium. A novelty of this work is covalent bonding of PTA to the surface of solid support that prevents leaching from the surface of the material. The sample was granulated with a binder, aluminium oxide (γ-Al₂O₃). Solid-state NMR and FT-IR spectroscopy were used to confirm the presence of Keggin units of PTA in the bound materials. Thermal analysis of H-PTA/SiO­₂ - γ-Al₂O₃ (50 %) showed that the water content in the …

The Relativistic Harmonic Oscillator And The Generalization Of Lewis' Invariant, Daniel Reinhart

Electronic Theses and Dissertations

In this thesis, we determine an asymptotic solution for the one dimensional relativistic harmonic oscillator using multiple scale analysis and relate the resulting invariant to Lewis' invariant. We then generalize the equations leading to Lewis' invariant so they are relativistically correct. Next we attempt to find an asymptotic solution for the general equations by making simplifying assumptions on the parameter characterizing the adiabatic nature of the system. The first term in the series for Lewis' invariant corresponds to the adiabatic invariant for systems whose frequency varies slowly. For the relativistic case we find a new conserved quantity and seek to …

Applications Of Geometric And Spectral Methods In Graph Theory, Lauren Morey Nelsen

Electronic Theses and Dissertations

Networks, or graphs, are useful for studying many things in today’s world. Graphs can be used to represent connections on social media, transportation networks, or even the internet. Because of this, it’s helpful to study graphs and learn what we can say about the structure of a given graph or what properties it might have. This dissertation focuses on the use of the probabilistic method and spectral graph theory to understand the geometric structure of graphs and find structures in graphs. We will also discuss graph curvature and how curvature lower bounds can be used to give us information about …

Evaluating Software Testing Techniques: A Systematic Mapping Study, Mitchell Mayeda

Electronic Theses and Dissertations

Software testing techniques are crucial for detecting faults in software and reducing the risk of using it. As such, it is important that we have a good understanding of how to evaluate these techniques for their efficiency, scalability, applicability, and effectiveness at finding faults. This thesis enhances our understanding of testing technique evaluations by providing an overview of the state of the art in research. To accomplish this we utilize a systematic mapping study; structuring the field and identifying research gaps and publication trends. We then present a small case study demonstrating how our mapping study can be used to …

Multidimensional Spectroscopy Of Mixed-Cation Perovskite Thin Films, Geoffrey Michael Diederich

Electronic Theses and Dissertations

Metal halide perovskite (MHP) thin films are currently undergoing an intense re- search thrust due to the excellent performance of MHP based photovoltaic (PV) devices, which have the potential to revolutionize the worlds energy production via a unique combination of low-cost fabrication and high power conversion efficiency (PCE). However, the vast majority of research is currently aimed at incremental improvements in device PCE, resulting in a body of work without the foundational understanding of the charge-carrier dynamics of the system upon photoexcitation.

This thesis begins with the development of a phase-modulated multidimensional coherent spectroscopy (PM-MDCS) experiment. PM-MDCS is an ultrafast …

Development And Characterization Of An Inexpensive Single-Particle Fluorescence Spectrometer For Detection And Classification Of Pollen And Other Bioaerosols, Benjamin E. Swanson

Electronic Theses and Dissertations

Atmospheric aerosols are ubiquitous throughout the Earth’s atmosphere and can be important with respect to environmental systems and human health. Pollen particles are a class of primary biological aerosol particles (PBAPs) that cost the United States billions of dollars a year in loss of productivity and healthcare costs due to allergy and respiratory effects. Traditional methods of pollen detection rely on collection and subsequent identification by visual microscopy, yet few measurement stations exist in the United States. As such, current pollen forecasting models have relatively high prediction uncertainty, especially in regions without sampling stations. Recently, laser-induced fluorescence instrumentation has been …

Coupling Of Light's Orbital Angular Momentum To A Quantum Dot Ensemble, Alaa A. Bahamran

Electronic Theses and Dissertations

We theoretically and experimentally investigate the transfer of orbital angular momentum from light to an ensemble of semiconductor-based nanostructures composed of lead sulfide quantum dots. Using an ensemble of quantum dots offers a higher cross-section and more absorption of twisted light fields compared to experimentally challenging single-nanostructure measurements. However, each quantum dot (except for on-center) sees a displaced light beam parallel to its own axis of symmetry. The transition matrix elements for the light-matter interaction are calculated by expressing the displaced light beam in terms of the appropriate light field centered on the nanoparticles. The resulting transition rate induced by …

Decidability For Residuated Lattices And Substructural Logics, Gavin St. John

Electronic Theses and Dissertations

We present a number of results related to the decidability and undecidability of various varieties of residuated lattices and their corresponding substructural logics. The context of this analysis is the extension of residuated lattices by various simple equations, dually, the extension of substructural logics by simple structural rules, with the aim of classifying simple equations by the decidability properties shared by their extensions. We also prove a number of relationships among simple extensions by showing the equational theory of their idempotent semiring reducts coincides with simple extensions of idempotent semirings. On the decidability front, we develop both semantical and syntactical …

Nanoscale Thermal Transport In Thermally Isolated Nanostructures, Brian G. Green

Electronic Theses and Dissertations

Experiments with nanoscale structures, designed to measure some of their thermal and optical properties, are the subjects of this dissertation. We studied the transport of thermal energy in systems of nanoparticles, and used the method of transient thermoreflectance to monitor those dynamics, and assess whether thermal transport features special to nanoscale systems emerged. This same method was also used to study the thermal transport of a single system of layered membranes. Optical properties were investigated using computational simulations of a nanoparticle system, using the method of finite-difference time-domain simulation.

In nanoparticle studies, there are two features of interest special to …

Development Of A Hek293 Cell Line To Show Inhibition Of Tau Aggregation, Justin Ray Shady

Electronic Theses and Dissertations

Intracellular deposition of aggregated tau is the hallmark of several different tauopathies, the most widespread of these being Alzheimer's disease. Tau is a highly soluble, intrinsically disordered, microtubule associated protein. Tau's native function is to stabilize microtubule formation in the axons of neurons. Post translational modification such as hyperphosphorylation as well as several familial mutations allow tau to nucleate and form fibrils. These fibrils can recruit healthy monomers onto their ends in a fashion described as template-assisted growth. Tau has 6 isoforms that vary by the inclusion or exclusion of two N-terminal repeats and the inclusion or exclusion of the …

Applied Machine Learning For Classification Of Musculoskeletal Inference Using Neural Networks And Component Analysis, Shaswat Sharma

Electronic Theses and Dissertations

Artificial Intelligence (AI) is acquiring more recognition than ever by researchers and machine learning practitioners. AI has found significance in many applications like biomedical research for cancer diagnosis using image analysis, pharmaceutical research, and, diagnosis and prognosis of diseases based on knowledge about patients' previous conditions. Due to the increased computational power of modern computers implementing AI, there has been an increase in the feasibility of performing more complex research.

Within the field of orthopedic biomechanics, this research considers complex time-series dataset of the "sit-to-stand" motion of 48 Total Hip Arthroplasty (THA) patients that was collected by the Human Dynamics …

A Policy Mechanism For Federal Recommendation Of Security Standards For Mobile Devices That Conduct Transactions, Ariel Huckabay

Electronic Theses and Dissertations

The proliferation of mobile devices in the BRIC countries has prompted them to develop policies to manage the security of these devices. In China, mobile devices are a primary tool for payments. As a result, China instituted in 2017 a cyber security policy that applies to mobile devices giving China broad authority to manage cyber threats. The United States has a similar need for a cyber policy. Mobile devices are likely to become a primary payment tool in the United States soon. DHS has also identified a need for more effective security policy in mobile devices for government operations. This …

Application Of Retrograde Analysis To Fighting Games, Kristen Yu

Electronic Theses and Dissertations

With the advent of the fighting game AI competition, there has been recent interest in two-player fighting games. Monte-Carlo Tree-Search approaches currently dominate the competition, but it is unclear if this is the best approach for all fighting games. In this thesis we study the design of two-player fighting games and the consequences of the game design on the types of AI that should be used for playing the game, as well as formally define the state space that fighting games are based on. Additionally, we also characterize how AI can solve the game given a simultaneous action game model, …

Photoassisted Synthesis Of Complex Polyheterocycles Via Esipt-Driven Dearomative Intramolecular Cycloadditions, Dmitry Kuznetsov

Electronic Theses and Dissertations

This research is focused on the development of novel photoassisted synthetic methodologies that provide straightforward access to complex and diverse libraries of polyheterocycles from modularly assembled precursors. All methods are based on the dearomative cycloadditions between two components: (i) o-azaxylylenes, generated by the excited-state intramolecular proton transfer, and (ii) tethered arene groups.

We have demonstrated the synthetic utility of four new photoinduced processes that yield complex products amenable for post-photochemical modifications:

• [4+4] Cycloaddition of o-azaxylylenes to 1,3,4-oxadiazoles with subsequent dinitrogen extrusion. This reaction furnishes compounds outfitted with epoxide fragments, which undergo ring-openings with various nucleophiles; furthermore, the oxidized products …

Probabilistic Record Linkage With Elliptic Curve Operations, Shreya Dhiren Patel

Electronic Theses and Dissertations

Federated query processing for an electronic health record infrastructure enables large epidemiology studies using data integrated from geographically dispersed medical institutions. However, government imposed privacy regulations prohibit disclosure of patient's health record outside the context of clinical care, thereby making it difficult to determine which records correspond to the same entity in the process of query aggregation.

Privacy-preserving record linkage is an actively pursued research area to facilitate the linkage of database records under the constraints of regulations that do not allow the linkage agents to learn sensitive identities of record owners. In earlier works, scalability has been shown to …

Rapid-Scan Epr And Imaging, Yilin Shi

Electronic Theses and Dissertations

EPR imaging at low frequency is a powerful tool to obtain important biological information in vivo in a non-invasive way. Properties of nitroxide and trityl radical imaging reagents have been studied. Developments in rapid scan imaging techniques are reported that improve efficiency of experiments and user-friendliness of software.

Relaxation and signal-to-noise ratio (S/N) in pulse experiments on trityl radicals were measured at frequencies between 400 MHz and 1.5 GHz. Relaxation time increases as the frequency increases and the radical concentration decreases. Since relaxation time is a sensitive and accurate measure of oxygen pressure, this study provides criteria for the selection …

Parameter Estimation Of Stochastic Models Against Probabilistic Temporal Logic Behavioral Specifications, Arfeen Khalid

Electronic Theses and Dissertations

The inherent behavioral variability exhibited by stochastic systems makes it a challenging task for human experts to manually analyze them. Computational modeling of such systems helps in investigating and predicting the behaviors of their underlying processes but at the same time introduces the presence of several unknown parameters. A key challenge faced in this scenario is to determine the values of these unknown parameters against known behavioral specifications. The solutions that have been presented so far estimate the parameters of a given model against a single specification whereas a correct model is expected to satisfy all the behavioral specifications when …