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Articles 1051 - 1080 of 3529
Full-Text Articles in Physical Sciences and Mathematics
Natural Sunlight Photodegradation Of Halogenated Disinfection Byproducts In Water, Ibrahim Abusallout
Natural Sunlight Photodegradation Of Halogenated Disinfection Byproducts In Water, Ibrahim Abusallout
Electronic Theses and Dissertations
Disinfection byproducts (DBPs) presence in wastewater effluents and receiving waters may impact the quality of drinking water during water reuse practices. Natural solar photolysis is one of the biogeochemical processes that may lead to decreased DBPs concentrations in water. The purpose of this dissertation is to determine the fate of chlorinated, brominated and iodinated DBPs in surface water by natural sunlight photolysis and investigate the use of solar-based advanced oxidation processes (AOPs) for removal of DBPs in water. Total organic halogen (TOX) was used to measure total chlorinated- (TOCl), brominated- (TOBr) and iodinated-DBPs (TOI) in water. The first objective was …
Land Cover Changes Within And Around Protected Areas In Côte D’Ivoire From 1986 To 2017: A Case Study Of The Mabi-Yaya-Songan-Tamin Reserved Forests, Olena Boiko
Electronic Theses and Dissertations
Tropical forests mitigate climate change, provide habitat for the most biologically diverse terrestrial communities, and yield ecosystem services that support human wellbeing. These forests are some of the most threatened ecosystems because of the increasing human impact on the environment. Côte d’Ivoire has one of the highest deforestation rates in sub-Saharan Africa, and the expansion of agriculture to produce cash crops, such as cocoa and rubber, is presented as the primary reason for forest loss. These changes are apparent even within the boundaries of the protected areas, which raises concerns about the effectiveness of the protection strategies. This project illustrates …
Effect Of Water Velocity And Temperature On Energy Use, Behavior, And Mortality Of Pallid Sturgeon Scaphirhynchus Albus Larvae, Joseph Thomas Mrnak
Effect Of Water Velocity And Temperature On Energy Use, Behavior, And Mortality Of Pallid Sturgeon Scaphirhynchus Albus Larvae, Joseph Thomas Mrnak
Electronic Theses and Dissertations
Pallid Sturgeon Scaphirhynchus albus are a federally endangered species endemic to the Missouri River basin. Natural reproduction has been limited for decades and a recruitment bottleneck is hypothesized to occur during the larval stage of development. Understanding factors that affect survival of Pallid Sturgeon larvae is key given their critical status and ongoing recovery efforts. In this study, I evaluated the effects of water velocity and temperature on energy use, behavior, and mortality of endogenously feeding Pallid Sturgeon larvae (< 25 mm TL). In the first experiment, I examined the effect of water velocity (0 – 8.3 cm s−1) on larval growth, energy density, swimming activity, and mortality. Larval growth rate at 16.3 °C was similar across …
Effect Of Mineral Ions On The Functional Properties Of Starch Films, Aliza Sigdel
Effect Of Mineral Ions On The Functional Properties Of Starch Films, Aliza Sigdel
Electronic Theses and Dissertations
Essential minerals are indispensable inorganic micronutrients that modulate vital physiological functions at the molecular level. Their deficiency, though required in small amounts, impairs health significantly. Their supplementation through diet is prudent and carbohydrates standout as favorable choice. Carbohydrates, starches and polysaccharides, exhibit unique chemical structures and functionalities, and interact with mineral ions in several ways. The aim of this research is to investigate the effect of mineral ions on the physicochemical properties, tensile strength and in vitro starch digestion of starch-films. Corn starch and potato starch along with Fe2+, Mn2+, Cu2+ and Zn2+ ions have been chosen as model starch …
Repairable Moment-Resisting Steel Buildings, Heath William Pederson
Repairable Moment-Resisting Steel Buildings, Heath William Pederson
Electronic Theses and Dissertations
Current seismic design codes ensure life safety for buildings, but structural members may significantly yield or even fail under strong earthquakes. A new design approach is to implement connections that localize the yielding and failure to fuses. A more sophisticated approach is to be able to replace the fuses after the event. The present study was carried out to develop repairable moment-resisting (MR) connections for steel buildings and to investigate their seismic performance through nonlinear finite element analyses (FEA). Two details were proposed using buckling restrained fuses (BRFs) and buckling restrained reinforcement (BRR). Test data was collected from the literature …
In-Silico Design And Synthesis Of Selective Estrogen Receptor Modulators Targeting Ovarian Cancer, John Apraku
In-Silico Design And Synthesis Of Selective Estrogen Receptor Modulators Targeting Ovarian Cancer, John Apraku
Electronic Theses and Dissertations
The established records of the safety of Ormeloxifene along with its favorable bioavailability and ability to inhibit rapid cell proliferation in the endometrium during embryonic implantation has made it one of the best drug candidates for controlling undesirable rapid cell growth such as endometriosis and cancerous tumor conditions. Recent studies have confirmed the effectiveness of Ormeloxifene to suppress and inhibit epithelial-mesenchymal transition process as evidenced by repression of N-cadherin, slug, snail, vimentin, MMPs, β-catenin/TCF-4 transcriptional activity and induce the expression of pGSK3b. Recently conducted studies have revealed the dynamic binding of ormeloxifene with β-catenin, GSK3b, CDK4, and other downstream EGFR. …
Petrology, Provenance, And Depositional Setting Of The Lower Tallahatta Formation (Meridian Sand) In Grenada County, Mississippi, Husamaldeen Zubi
Petrology, Provenance, And Depositional Setting Of The Lower Tallahatta Formation (Meridian Sand) In Grenada County, Mississippi, Husamaldeen Zubi
Electronic Theses and Dissertations
The Meridian Sand represents the lowermost member of the Middle Eocene Tallahatta Formation, which is found in the Gulf Coast region of the United States. Five stratigraphic sections in Grenada County were measured and described. Twenty-one sand and sandstone samples, and 2 mud samples were collected from all sections. Textural analyses were performed on all 23 samples to determine their lithologic properties. Petrographic descriptions and modal analyses were performed on thin sections made from the 21 sand and sandstone samples, and 400 grains were point counted in each sample. Geochemical analyses were carried out on all sand, sandstone, and mud …
Near-Infrared High Efficiency Organic Dye Sensitized Solar Cells (Dscs) And Biological Fluorescent Imaging Dyes, Yanbing Zhang
Near-Infrared High Efficiency Organic Dye Sensitized Solar Cells (Dscs) And Biological Fluorescent Imaging Dyes, Yanbing Zhang
Electronic Theses and Dissertations
With the energy consumption increase every year, the non-renewable energy sources such as fossil fuels, natural gas, and coal will not sustain forever. In this case, searching for a way to develop a renewable energy source is an emergency. For decades, dye-sensitized solar cells (DSCs) have received intensive attention due to their high power conversion efficiency and low material cost. This dissertation describes efforts to design and synthesize near-infrared organic dyes to apply to two systems: first, for use in the improvement of DSCs by the optimization of electron rich components such as ullazine and cross-conjugated -bridges to increase photon-to-electricity …
Organic Sensitizers For High Efficiency Dye-Sensitized Solar Cells, Adithya Peddapuram
Organic Sensitizers For High Efficiency Dye-Sensitized Solar Cells, Adithya Peddapuram
Electronic Theses and Dissertations
After the industrial revolution in 19th-century energy, demand has increased exponentially. Relying on fossil fuels long term is not a good option due to their non-renewable nature and concerns about burning fossil fuels raising carbon dioxide levels in atmosphere. This dissertation describes, utilizing sunlight for electricity production with dye-sensitized solar cells (DSCs). DSCs are an attractive solar technology due to processing advantages over traditional solar cells. To improve the stability of DSCs, strong surface binding dyes are important. This work studies the dual anchor dual donor (DD-π-AA) dye framework with various donors (electron rich π-systems) and π-bridges (electron neutral π-systems). …
Acoustic Radiation Force On A Fluid To Fluid Boundary By Phase Plate Focused Ultrasound, Robert Lee Lirette
Acoustic Radiation Force On A Fluid To Fluid Boundary By Phase Plate Focused Ultrasound, Robert Lee Lirette
Electronic Theses and Dissertations
In this study, the physics and applications of the ultrasonic radiation force at the interface between two immiscible fluids were investigated. These studies were performed using low-profile discrete-stepped lenses to the modify the phase of the incident radiation generating multiple field morphologies. In its first application to acoustics, a fraxicon lens was developed to approximate the field generated by an axicon. This type of lens creates a minimally diffractive Bessel beam and long depth of focus that is useful in ultrasonic imaging, therapy, and non-destructive evaluation techniques. Fields modified by fraxicon, Fresnel, and axicon lenses were characterized experimentally by scanning …
Generalized Radial Transport Model For Interpreting Convergent Flow Tracer Tests In Fractured Rock, Md Lal Mamud
Generalized Radial Transport Model For Interpreting Convergent Flow Tracer Tests In Fractured Rock, Md Lal Mamud
Electronic Theses and Dissertations
The double-porosity Generalized Radial Transport (GRT) model is an extension of the generalized radial flow approach developed for hydraulic test interpretation. In both approaches, a flow dimension characterizes the change in flow area versus radial distance from the borehole. The GRT model collapses to a 1D, radial, and spherical advection dispersion equation (ADE) for integer flow dimensions of 1, 2, and 3, respectively. And, the model also transforms to sub-linear, sub-radial, sub-spherical and eventually transform to super-spherical transport model for non-integer flow dimension, n of 0 < n < 1, 1 < n < 2, 2 < n < 3 and n >3 respectively. Non-integer flow dimensions, especially sub-radial, are commonly reported from pumping tests in …
Cramer Type Moderate Deviations For Random Fields And Mutual Information Estimation For Mixed-Pair Random Variables, Aleksandr Beknazaryan
Cramer Type Moderate Deviations For Random Fields And Mutual Information Estimation For Mixed-Pair Random Variables, Aleksandr Beknazaryan
Electronic Theses and Dissertations
In this dissertation we first study Cramer type moderate deviation for partial sums of random fields by applying the conjugate method. In 1938 Cramer published his results on large deviations of sums of i.i.d. random variables after which a lot of research has been done on establishing Cramer type moderate and large deviation theorems for different types of random variables and for various statistics. In particular results have been obtained for independent non-identically distributed random variables for the sum of independent random to estimate the mutual information between two random variables. The estimates enjoy a central limit theorem under some …
Detrital Zircon Provenance And Correlation Of Two Newly Discovered Ripley Formation Bentonites: Pontotoc County, Mississippi, Elizabeth Jayne Vitale
Detrital Zircon Provenance And Correlation Of Two Newly Discovered Ripley Formation Bentonites: Pontotoc County, Mississippi, Elizabeth Jayne Vitale
Electronic Theses and Dissertations
Two newly discovered bentonite deposits in northern and southern Pontotoc County, Mississippi occur in the Upper Cretaceous outcrop in a banded pattern on the northeastern margin of the Mississippi Embayment (MSE). The entire Ripley Formation (Fm) consists of ~73 m of fossiliferous clay, sand, and calcareous sand beds. The bentonites are located stratigraphically within the Chiwapa Sandstone Member (CSM) at the top of the Ripley Fm and stratigraphically lie above previously mined bentonites in central Pontotoc County. Since the northern and southern bentonites differ stratigraphically from the previously mined bentonites, it is possible that there are other unknown bentonite deposits …
Manifoldlike Causal Sets, Miremad Aghili
Manifoldlike Causal Sets, Miremad Aghili
Electronic Theses and Dissertations
The content of this dissertation is written in a way to answer the important question of manifold likeness of causal sets. This problem has importance in the sense that in the continuum limit and in the case one finds a formalism for the sum over histories, the result requires to be embeddable in a manifold to be able to reproduce General Relativity. In what follows I will use the distribution of path length in a causal set to assign a measure for manifold likeness of causal sets to eliminate the dominance of nonmanifold like causal sets. The distribution of interval …
Variability Of E. Coli In Streambed Sediments And Its Implication For Water Quality, Sadia Salam
Variability Of E. Coli In Streambed Sediments And Its Implication For Water Quality, Sadia Salam
Electronic Theses and Dissertations
Fecal indicator bacteria (FIB), including E. coli, are the number one cause of water quality impairments in the United States according to the USEPA. FIB are used as a predictor to identify the possible presence of pathogens in waterbodies. E. coli is a useful indicator of gastrointestinal (GI) related illnesses from contact with fresh water. While surface water is routinely monitored for water quality, streambed sediments are rarely considered as a source of FIB to the overlying water column. This study focuses on understanding the variation of E. coli concentrations in streambed sediments and the potential impact of sediment sources …
Using Social Network Analysis To Examine The Connections Within A Noyce Community’S Facebook Group, Amanda Jensen
Using Social Network Analysis To Examine The Connections Within A Noyce Community’S Facebook Group, Amanda Jensen
Electronic Theses and Dissertations
One of the successes of the Rural Enhancement of Mathematics And Science Teachers (REMAST) Scholarship Program at South Dakota State University is the community we have built. This community has been built through a summer conference and a closed Facebook group. As we near the end of our Phase II Noyce funding, we are using social network analysis to examine the connections within the REMAST Facebook group. What we learn in this research project will be useful to other Noyce projects as it is a model for developing a strong professional learning community. In order to determine information about the …
Investigating Anions And Hydrophobicity Of Deep Eutectic Solvents By Experiment And Computational Simulation, Amos Kwabena Dwamena
Investigating Anions And Hydrophobicity Of Deep Eutectic Solvents By Experiment And Computational Simulation, Amos Kwabena Dwamena
Electronic Theses and Dissertations
Deep eutectic solvents are a new generation of ionic liquid-like solvents formed by combining hydrogen bond acceptor with hydrogen bond donor which result in the depression of the melting point of the solvent. Like ionic liquids, anions play a critical role in tuning the polarity, physicochemical properties, and thermodynamic behavior of deep eutectic solvent (DES). Choline chloride is the most widely used quaternary ammonium salt (QAS) in the literature and has remarkable advantages from reduced cost to low toxicity and volatility. Choline bromide and choline iodide are other QAS that have not been used often for DES synthesis and applications, …
Advanced Analysis Of Compounds Of Toxicological Importance By Ice Concentration Linked With Extractive Stirrer (Icecles) Gc-Ms And Rp-Hplc-Esi-Ms-Ms, Joseph K. Dzisam
Advanced Analysis Of Compounds Of Toxicological Importance By Ice Concentration Linked With Extractive Stirrer (Icecles) Gc-Ms And Rp-Hplc-Esi-Ms-Ms, Joseph K. Dzisam
Electronic Theses and Dissertations
Cyanide and nitrosoamines (NAs) are ubiquitous compounds, found in our food and water, either by natural process or through man-made activities. The toxicity of cyanide is exerted by its ability to inhibit metalloenzymes such as cytochrome c oxidase, causing concomitant cascades of biochemical effects such as lactic acidosis, inhibition of ATP production, respiratory seizure, and potential death. Nitrosoamines, on the other hand, undergo biotransformation (metabolic activation in cytochrome P450) in the body to produce unstable intermediates that alkylate DNA, causing mutations, and leading to carcinogenesis. In order to further the advancement of a promising cyanide, cobinamide (Cbi), an LC-MS-MS method …
Diversifying Cornfields By Interseeding Cover Crops: Practical Implications And The Response Of Invertebrate Communities, Michael Bredeson
Diversifying Cornfields By Interseeding Cover Crops: Practical Implications And The Response Of Invertebrate Communities, Michael Bredeson
Electronic Theses and Dissertations
The lack of suitable habitat conditions for beneficial organisms in simplified agroecosystems leads to unstable invertebrate communities and overreliance on chemical control of herbivores. It is possible to manage pest populations without agrichemicals by manipulating farmland so that herbivores are impaired by plant-driven bottom-up and enemy-driven top-down antagonisms. Interseeding cover crops between established crop rows is a method used by farmers to improve habitat suitability for natural enemies and hinder host-finding, feeding and movement by herbivores. Here I address three important research gaps related to interseeding cover crops. A calcium carbonate seed coating, used to improve seed-broadcasting efficiency, was tested …
Effects Of Energy Development On Movements, Home Ranges, And Resource Selection Of White-Tailed Deer In The Western Dakotas, Bailey S. Gullikson
Effects Of Energy Development On Movements, Home Ranges, And Resource Selection Of White-Tailed Deer In The Western Dakotas, Bailey S. Gullikson
Electronic Theses and Dissertations
Oil and natural gas development has increased in recent years and research is needed to assess potential impacts on white-tailed deer (Odocoileus virginianus) populations. Our objectives were to document movements, home ranges, and resource selection of female white-tailed deer in response to energy development in the western Dakotas. Our study areas included Dunn County, North Dakota, an area with current oil and gas development, and Grant County, North Dakota, and Perkins County, South Dakota, areas without current oil and gas development. We captured and fitted 150 female deer with Very High Frequency (VHF) collars across study sites, and …
Estimating Soil Organic Carbon In Cultivated Soils Using Soil Test Data, Remote Sensing Imagery From Satellites (Landsat 8 And Plantscope), And Web Soil Survey Data, Muhammed Halil Koparan
Estimating Soil Organic Carbon In Cultivated Soils Using Soil Test Data, Remote Sensing Imagery From Satellites (Landsat 8 And Plantscope), And Web Soil Survey Data, Muhammed Halil Koparan
Electronic Theses and Dissertations
Soil organic carbon (SOC) is an important soil parameter of cultivated soils that needs to be monitored and mapped regularly to enhance soil health and productivity. SOC levels in cultivated areas is difficult to monitor for farmers and is costly to analyze using traditional methods. The objective of this study was to estimate surface SOC distribution in selected soils of Major Land Resource Areas (MLRA) 102A (Rolling Till Plain, Brookings County, SD) and 103 (Central Iowa and Minnesota Till Prairies, Lac qui Parle County, MN) using soil sample data, Web Soil Survey (WSS) data, and satellite imagery (Landsat 8 and …
Stream Flow Analysis Of The Big Sioux River Just South Of Brookings, South Dakota, Samuel Ruppert
Stream Flow Analysis Of The Big Sioux River Just South Of Brookings, South Dakota, Samuel Ruppert
Electronic Theses and Dissertations
Floods are the most common type of natural disaster in the world and one of the most damaging. Changes in climate conditions such as precipitation and temperature are causing changes in stream flow. This means that in order to better understand flooding and possibly develop a system for making flood predictions, stream flow needs to be analyzed more closely. The primary objective of this thesis is to analyze the Big Sioux River just south of Brookings, South Dakota, both annually and seasonally. The United States Geological Survey (USGS) has stream gauges placed in rivers and streams all over the United …
The Economic And Social Values Associated With Small South Dakota Lakes, Aaron Patrick Sundmark
The Economic And Social Values Associated With Small South Dakota Lakes, Aaron Patrick Sundmark
Electronic Theses and Dissertations
The valuation of small fishing lakes is a vital component in understanding the importance of fishing and of recreational resources, in general. Knowing the values associated with such lakes is essential when prioritizing management activities. The overall value of a lake as a resource for human benefit is estimated as the summation of both instrumental and non-instrumental values. Instrumental values consist of economic and utilitarian values, as well as the values that a lake provides from ecosystem services. Non-instrumental values consider what the lake is worth as a good of its own, such as aesthetic, moral, and spiritual values gained …
Assessing Freshwater Mussel (Bivalvia: Unionidae) Assemblages And Effects Of Eutrophication On Pyganodon Grandis In Lakes Of Eastern South Dakota, Katherine M. Wollman
Assessing Freshwater Mussel (Bivalvia: Unionidae) Assemblages And Effects Of Eutrophication On Pyganodon Grandis In Lakes Of Eastern South Dakota, Katherine M. Wollman
Electronic Theses and Dissertations
Globally, the family Unionidae is the most threatened group of freshwater fauna. South Dakota is well known for its agricultural production, leading to cultural eutrophication from enhanced fertilizers and sediments. This impact can alter species presence, age, growth and mortality. Objectives of this study were to 1) implement the first comprehensive lake survey of freshwater mussels in eastern South Dakota lakes and document distribution, occurrence and relative abundance, 2) evaluate relationships between age, growth and mortality of Pyganodon grandis and lake trophic state. Freshwater mussels were sampled in 2017 from 116 proportionally and randomly selected natural lakes and reservoir basins …
Development Of A Data-Driven Patient Engagement Score Using Finite Mixture Models, Eric Bae
Development Of A Data-Driven Patient Engagement Score Using Finite Mixture Models, Eric Bae
Electronic Theses and Dissertations
Patient activation measure (PAM) is widely adopted by health care providers to access individual's knowledge, skill, and confidence for managing one's health and healthcare. Patient activation measure (PAM), licensed by Insignia Health, is widely adopted by health care providers to access individual's knowledge, skill, and confidence for managing one's health and healthcare. Multiple studies corroborate the effectiveness of activation measure in predicting most health behaviors, including preventive behaviors, healthy behaviors, self-management behaviors, and health information seeking. However, PAM is heavily dependent on subjective patient-reported data, which are often incomplete. The purpose of this study is to develop an objective statistical …
Prairie Dogs And Livestock In Rangeland Systems: Balancing Biodiversity And Production In The Northern Mixed-Grass Prairie, Jameson Robert Brennan
Prairie Dogs And Livestock In Rangeland Systems: Balancing Biodiversity And Production In The Northern Mixed-Grass Prairie, Jameson Robert Brennan
Electronic Theses and Dissertations
A major constraint of beef production within the Standing Rock Reservation has been identified as a reduction in rangeland quality due in large part to wide-scale colonization by black-tailed prairie dogs (Cynomys ludovicianus). The desire exists within the community to design a holistic framework which incorporates livestock management with the goal of increasing production and rangeland health while still maintaining increased diversity associated with prairie dogs. Prairie dogs reduce the carrying capacity of cattle on rangelands by up to 50% on occupied hectares through direct consumption of vegetation and waste due to clipping to improve detection of predators. Livestock stocking …
Ligand Effect On Gold Nanomolecules Demonstrated Using Aliphatic, Aromatic And Bulky Thiolate Ligands, Milan Rambukwella
Ligand Effect On Gold Nanomolecules Demonstrated Using Aliphatic, Aromatic And Bulky Thiolate Ligands, Milan Rambukwella
Electronic Theses and Dissertations
Atomically precise thiolate protected gold nanoparticles (AuNPs) known as gold nanomolecules (AuNMs) are intensely pursued owing to their feasibility to elucidate their structure by single crystal X-ray crystallography. They have distinct number of Au atoms (n) and thiolate (-SR, R-hydrocarbon chain) ligands (m) with molecular formula of the form [Aun(SR)m]. AuNMs are made of a gold core protected by a thiolate-monolayer and possess size-dependent properties conferred by quantum confinement. Atomic precision has been achieved in the 1-3 nm range and crystal structures of several AuNMs ranging from 18 to 279gold atoms have been studied. They provide significant insights into the …
Towards Misleading Connection Mining, Md Main Uddin Rony
Towards Misleading Connection Mining, Md Main Uddin Rony
Electronic Theses and Dissertations
This study introduces a new Natural Language Generation (NLG) task – Unit Claim Identification. The task aims to extract every piece of verifiable information from a headline. The Unit Claim identification has applications in other domains; such as fact-checking where the identification of each verifiable information from a check-worthy statement can lead to an effective fact-check. Moreover, the extracting of the unit claims from headlines can identify a misleading news article, by mapping evidence from contents. For addressing the unit claim identification problem, we outlined a set of guidelines for data annotation, arranged in-house training for the annotators and obtained …
Probing Atypical Noncovalent Interactions Using Electronic Structure Theory, Katelyn Mae Dreux
Probing Atypical Noncovalent Interactions Using Electronic Structure Theory, Katelyn Mae Dreux
Electronic Theses and Dissertations
Some of the most important topics in modern chemistry involve noncovalent interactions in a variety of ways, from pharmacological processes to materials design. Due to the comparatively weak nature of these interactions, they can be difficult to investigate experimentally. Beyond what might be considered the ‘typical’ noncovalent interactions such as hydrogen bonding or London dispersion, there are less well known noncovalent interactions such as coordinate covalent, dihydrogen, and nonconventional hydrogen bonding, which have been the focus of much of this research. Through the use of electronic structure theory, fundamental information about the structure, energetics, and molecular properties of noncovalently bound …
Effects Of Grazing And Fire On Soil Microbial Communities And Hydrological Processes In The Northern Great Plains Grassland, Jacob Comer
Electronic Theses and Dissertations
Historic grazing and fire regimes have been altered with the development of the livestock industry in the Northern Great Plains and have resulted in a reduction of diversity across all scales. As alternative land surface disturbances are developed to combat the loss of diversity, their potential to serve as a sustainable land surface disturbance should be evaluated. To determine the ability of an alternative grazing strategy to serve as a sustainable land surface disturbance, the reaction of the soil microbial community and soil hydrological processes should be evaluated. Objectives of this study were to: 1) evaluate the impact of alternative …