Physical Sciences and Mathematics Commons^™

Controlling Degradation With Force And Light, Brad Davis

Dissertations

Stimuli-responsive polymers respond to changes in their environment by altering their physical and chemical properties. Their responsiveness allows them to be used as sensors, mechanical actuators, delivery systems, and can yield either elongated lifetimes through healing mechanisms or shortened lifetimes through triggered degradation. Still a growing field in polymer science, researchers seek to expand the capabilities of these materials by improving their specificity, range, and mechanisms of both the stimuli and the response. The work presented explores stimuli-responsive materials, focusing on mechanical and light stimuli, and how to gain control of the response by specific changes in the polymeric material. …

Critical Behavior In Evolutionary And Population Dynamics, Stephen Ordway

Dissertations

This study is an exploration of phase transition behavior in evolutionary and population dynamics, and techniques for predicting population changes, across the disciplines of physics, biology, and computer science. Under the looming threat of climate change, it is imperative to understand the dynamics of populations under environmental stress and to identify early warning signals of population decline. These issues are explored here in (1) a computational model of evolutionary dynamics, (2) an experimental system of decaying populations under environmental stress, and (3) a machine learning approach to predict population changes based on environmental factors. Through the lens of critical phase …

Colloidal Quantum Dot (Cqd) Based Mid-Wavelength Infrared Optoelectronics, Shihab Bin Hafiz

Dissertations

Colloidal quantum dot (CQD) photodetectors are a rapidly emerging technology with a potential to significantly impact today’s infrared sensing and imaging technologies. To date, CQD photodetector research is primarily focused on lead-chalcogenide semiconductor CQDs which have spectral response fundamentally limited by the bulk bandgap of the constituent material, confining their applications to near-infrared (NIR, 0.7-1.0 um) and short-wavelength infrared (SWIR, 1-2.5 um) spectral regions. The overall goal of this dissertation is to investigate a new generation of CQD materials and devices that advances the current CQD photodetector research toward the technologically important thermal infrared region of 3-5 ?m, known as …

On Non-Linear Network Embedding Methods, Huong Yen Le

Dissertations

As a linear method, spectral clustering is the only network embedding algorithm that offers both a provably fast computation and an advanced theoretical understanding. The accuracy of spectral clustering depends on the Cheeger ratio defined as the ratio between the graph conductance and the 2nd smallest eigenvalue of its normalizedLaplacian. In several graph families whose Cheeger ratio reaches its upper bound of Theta(n), the approximation power of spectral clustering is proven to perform poorly. Moreover, recent non-linear network embedding methods have surpassed spectral clustering by state-of-the-art performance with little to no theoretical understanding to back them.

The dissertation includes work …

Advances In Modeling Gas Adsorption In Porous Materials For The Characterization Applications, Max A. Maximov

Dissertations

The dissertation studies methods for mesoporous materials characterization using adsorption at various levels of scale and complexity. It starts with the topic introduction, necessary notations and definitions, recognized standards, and a literature review.

Synthesis of novel materials requires tailoring of the characterization methods and their thorough testing. The second chapter presents a nitrogen adsorption characterization study for silica colloidal crystals (synthetic opals). These materials have cage-like pores in the range of tens of nanometers. The adsorption model can be described within a macroscopic approach, based on the Derjaguin-Broekhoff-de Boer (DBdB) theory of capillary condensation. A kernel of theoretical isotherms is …

Exploring, Understanding, Then Designing: Twitter Users’ Sharing Behavior For Minor Safety Incidents, Mashael Yousef Almoqbel

Dissertations

Social media has become an integral part of human lives. Social media users resort to these platforms for various reasons. Users of these platforms spend a lot of time creating, reading, and sharing content, therefore, providing a wealth of available information for everyone to use. The research community has taken advantage of this and produced many publications that allow us to better understand human behavior. An important subject that is sometimes discussed and shared on social media is public safety. In the past, Twitter users have used the platform to share incidents, share information about incidents, victims and perpetrators, and …

Gradient Free Sign Activation Zero One Loss Neural Networks For Adversarially Robust Classification, Yunzhe Xue

Dissertations

The zero-one loss function is less sensitive to outliers than convex surrogate losses such as hinge and cross-entropy. However, as a non-convex function, it has a large number of local minima, andits undifferentiable attribute makes it impossible to use backpropagation, a method widely used in training current state-of-the-art neural networks. When zero-one loss is applied to deep neural networks, the entire training process becomes challenging. On the other hand, a massive non-unique solution probably also brings different decision boundaries when optimizing zero-one loss, making it possible to fight against transferable adversarial examples, which is a common weakness in deep learning …

Solar Flares As Observed In The Low Frequency Microwave Gyrosynchrotron Emission, Shaheda Begum Shaik

Dissertations

Solar flares involve the sudden catastrophic release of magnetic energy stored in the Sun’s corona. This dissertation focuses on investigating the low frequency, optically-thick gyrosynchrotron emission during solar flares for its spatial and spectral dynamics, characteristics, and role in the flare process.

The first part of this dissertation first addresses the spectral dynamics and characteristics of the source morphology. The high-resolution spectra of a set of microwave bursts observed by the Expanded Owens Valley Solar Array (EOVSA) during its commissioning phase in the 2.5-18 GHz frequency range with 1-s time resolution are presented here. Out of the 12 events analyzed …

Towards Adversarial Robustness With 01 Lossmodels, And Novel Convolutional Neural Netsystems For Ultrasound Images, Meiyan Xie

Dissertations

This dissertation investigates adversarial robustness with 01 loss models and a novel convolutional neural net systems for vascular ultrasound images.

In the first part, the dissertation presents stochastic coordinate descent for 01 loss and its sensitivity to adversarial attacks. The study here suggests that 01 loss may be more resilient to adversarial attacks than the hinge loss and further work is required.

In the second part, this dissertation proposes sign activation network with a novel gradient-free stochastic coordinate descent algorithm and its ensembling model. The study here finds that the ensembling model gives a high minimum distortion (as measured by …

Modeling Dewetting, Demixing, And Thermal Effects In Nanoscale Metal Films, Ryan Howard Allaire

Dissertations

Thin film dynamics, particularly on the nanoscale, is a topic of extensive interest. The process by which thin liquids evolve is far from trivial and can lead to dewetting and drop formation. Understanding this process involves not only resolving the fluid mechanical aspects of the problem, but also requires the coupling of other physical processes, including liquid-solid interactions, thermal transport, and dependence of material parameters on temperature and material composition. The focus of this dissertation is on the mathematical modeling and simulation of nanoscale liquid metal films, which are deposited on thermally conductive substrates, liquefied by laser heating, and subsequently …

Modeling And Design Optimization For Membrane Filters, Yixuan Sun

Dissertations

Membrane filtration is widely used in many applications, ranging from industrial processes to everyday living activities. With growing interest from both industrial and academic sectors in understanding the various types of filtration processes in use, and in improving filter performance, the past few decades have seen significant research activity in this area. Experimental studies can be very valuable, but are expensive and time-consuming, therefore theoretical studies offer potential as a cost-effective and predictive way to improve on current filter designs. In this work, mathematical models, derived from first principles and simplified using asymptotic analysis, are proposed for: (1) pleated membrane …

Shale Softening Based On Pore Network And Laboratory Investigations, Di Zhang

Dissertations

This dissertation consists of two major parts: Firstly, experimental investigation of four major shale softening mechanisms and quantifications of structural parameters. Secondly, numerical simulations of nano-scale flow behaviors using the previous experiments determined parameters based on modified pore network modeling.

Hydraulic fracturing is widely applied to economical gas production from shale reservoirs. Still, the gradual swelling of the clay micro/nano-pores due to retained fluid from hydraulic fracturing causes a gradual reduction of gas production. Four different gas-bearing shale samples are investigated to quantify the expected shale swelling due to hydraulic fracturing. These shale samples are subject to heated deionized (DI) …

Data-Driven Learning For Robot Physical Intelligence, Leidi Zhao

Dissertations

The physical intelligence, which emphasizes physical capabilities such as dexterous manipulation and dynamic mobility, is essential for robots to physically coexist with humans. Much research on robot physical intelligence has achieved success on hyper robot motor capabilities, but mostly through heavily case-specific engineering. Meanwhile, in terms of robot acquiring skills in a ubiquitous manner, robot learning from human demonstration (LfD) has achieved great progress, but still has limitations handling dynamic skills and compound actions. In this dissertation, a composite learning scheme which goes beyond LfD and integrates robot learning from human definition, demonstration, and evaluation is proposed. This method tackles …

Participatory Learning: Measuring Learning And Educational Technology Acceptance, Erick Sanchez Suasnabar

Dissertations

Participatory Learning (PL) integrates several learning approaches, engaging students throughout the entire assignment process for both online and face-to-face courses. Beyond simply providing a solution, students also craft a problem (problem-based learning), grade each other (peer assessment and feedback), evaluate themselves (self-assessment), and can view others’ work (learning by example). This dissertation research explores the resulting learning effects. Contributions to both educational and Information Systems research include extending an early PL model and experiments that applied the PL approach to examinations, by validating and testing new constructs based on user activity and critical thinking. In addition, the study explores a …

Analysis Of Container Throughput: Demand Forecast And Seaport Competitiveness Assessment, Hussain Talat Sulaimani

Dissertations

Seaports play a crucial role in the container industry, where they act as important nodes in the transport chain to facilitate international trade. In a competitive market, port capacity plays a significant role in defining its competitive position to attract demand and avoid congestion. Failing to provide suitable capacity results in the loss of market share. Therefore, port decision-makers face the challenge of maintaining and developing suitable port facilities to provide efficient services to port users. One of the aspects that decision-makers consider in the planning and development process is analyzing container demand. The analysis of container demand can be …

Designing Collaborative Lifelogging To Facilitate Learning In Collaborative Physical-Recreation Communities, Sayed Mousa Ahmadi Olounabadi

Dissertations

Since the 1940s, researchers have envisioned lifelogging as the systematic capture and utilization of lived experiences for augmenting learning, performance, and community Unfortunately, this vision was never actualized since few, if any, systems support lifelogging in the term's original sense. Technologies that emerged through the Quantified-Self (QS) movement allowed users to monitor and track almost every life aspect. However, the decontextualized self-tracking data QS systems produced are unsuitable for supporting learning and community engagement, and therefore have not made lifelogging a reality yet. Central to this dissertation is understanding how to augment learning and community through lifelogging. This is particularly …

Reserve Price Optimization In Display Advertising, Achir Kalra

Dissertations

Display advertising is the main type of online advertising, and it comes in the form of banner ads and rich media on publishers' websites. Publishers sell ad impressions, where an impression is one display of an ad in a web page. A common way to sell ad impressions is through real-time bidding (RTB). In 2019, advertisers in the United States spent nearly 60 billion U.S. dollars on programmatic digital display advertising. By 2022, expenditures are expected to increase to nearly 95 billion U.S. dollars. In general, the remaining impressions are sold directly by the publishers. The only way for publishers …

Advances In Deep Learning With Applications To Computer Vision And Astronomy, Zhihang Hu

Dissertations

Deep Learning has spanned a variety of applications in computer vision as well as computational astronomy. These two aspects obtained similar data structure, therefore, their solutions can be transferable between each other. This dissertation look into two video-related tasks in computer vision and propose a novel problem in computational astronomy.

Specifically, acquiring an in-depth understanding of videos has been a cornerstone problem in computer vision. This problem has been studied by various researchers from different perspectives, among which video prediction has attracted much attention. Video prediction aims to generate the pixels of future frames given a sequence of context frames. …

Novel Statistical Modeling Methods For Traffic Video Analysis, Hang Shi

Dissertations

Video analysis is an active and rapidly expanding research area in computer vision and artificial intelligence due to its broad applications in modern society. Many methods have been proposed to analyze the videos, but many challenging factors remain untackled. In this dissertation, four statistical modeling methods are proposed to address some challenging traffic video analysis problems under adverse illumination and weather conditions.

First, a new foreground detection method is presented to detect the foreground objects in videos. A novel Global Foreground Modeling (GFM) method, which estimates a global probability density function for the foreground and applies the Bayes decision rule …

Ensemble Data Fitting For Bathymetric Models Informed By Nominal Data, Samantha Zambo

Dissertations

Due to the difficulty and expense of collecting bathymetric data, modeling is the primary tool to produce detailed maps of the ocean floor. Current modeling practices typically utilize only one interpolator; the industry standard is splines-in-tension.

In this dissertation we introduce a new nominal-informed ensemble interpolator designed to improve modeling accuracy in regions of sparse data. The method is guided by a priori domain knowledge provided by artificially intelligent classifiers. We recast such geomorphological classifications, such as ‘seamount’ or ‘ridge’, as nominal data which we utilize as foundational shapes in an expanded ordinary least squares regression-based algorithm. To our knowledge …

Doping Of Conjugated Polymers: Preparation, Characterization And Device Fabrication, Kan Tang

Dissertations

Semiconducting conjugated polymers (CPs) as emerging materials for advanced electronic applications such as sensors, OPVs, and OEFTs has become an intriguing research topic in the past decades. It opens a new avenue of “flexible” electronics, which has shown great potential in next-generation electronic devices.

However, due to the nature of CP materials and related solution processing techniques, unlike almost perfectly crystalline silicon materials, CPs in the solid-state often exhibit much lower crystallinity if it is not complete amorphous, which severely hinder the electronic property and optical property of the materials. The crystallinity of CPs in a film is often uniquely …

Photopolymer Networks With Tunable Command Destruct Properties, William Walker

Dissertations

Photoinduced thiol-catalyzed hydrogen abstraction and beta-scission of acyclic benzylidene acetals is demonstrated as a new route to “command-destruct” polymer thermosets. Using this approach, we show that poly(thioether acetal) networks synthesized via thiol-ene photopolymerization rapidly degrade to alkyl benzoate byproducts when triggered with light, transitioning from solid to liquid within seconds. The light-driven construction and destruction processes, accessible via distinct differences in kinetics, are readily amendable for photopatterning, additive/subtractive manufacturing, and wavelength-selective applications.

The first chapter of this dissertation details the development of command-destruct poly(thioether acetal) networks via a previously unexplored mechanism for polymer degradation. The degradation mechanism is confirmed via …

"Not In My Town": A Community's Response To Water And Soil Pollution, Karolina Staros

Dissertations

At the core of this dissertation is the acknowledgment that social movements are complex networks of people who face many obstacles in their efforts to achieve social change. One critique of social movements is that their goals and mission are limited to short term ideas and not long-term, systemic transformation. The lack of long term, systemic change can be observed when social movement groups mobilize for the same cause over and over again with what appears to be little progress over a period of time. The exact blueprint for a social movement’s success does not exist, but it is posited …

Understanding Potential Climate Change Impacts On Water Resources Within A Fractured Rock Watershed In Northern Togo, Mahawa-Essa Mabossani Akara

Dissertations

More than 72% of sub-Saharan Africa land surface is comprised of hard rock with fractured rock aquifers supplying water to an estimated 25% of the rural population. Given low porosity and storativity, fractured rock aquifers are particularly vulnerable to stresses such as projected population growth and climate variability. General circulation models of sub-Saharan Africa predict increases in temperature and in occurrences of extreme precipitation trends, such as flooding and drought. Adaptation strategies that promote optimal uses of water resources have emerged, although, most focus exclusively on surface water resources. This project investigates the potential impact of climate change on surface …

Synthesis And Characterization Of Novel Organic Ligands With Their Complexes Of Platinum, Copper And Uranium, Mustafa Adnan Yasin Aldulaimi

Dissertations

Transition metal complexes of symmetrical and asymmetrical Schiff bases have played a significant role in the field of coordination, inorganic, and bioinorganic chemistry as models for biological, analytical, industrial, and pharmaceutical applications. Over recent years a great deal of interest has developed in new transition metal complexes of Schiff base ligand. The preparation of novel organic ligands is the most important step in the development of metal complexes that exhibit unique properties and novel reactivity. To highlight the presentation of this dissertation and to provide more detailed investigations, the dissertation was separated into six chapters according to the sequence of …

Computational Studies Of Carbon Nanocluster Solidification, Chathuri C. Silva

Dissertations

A subset of micron-size meteoritic carbon particles formed in red giant atmospheres show a core-rim structure, likely condensed from a vapor phase into super-cooled carbon droplets that nucleated graphene sheets (~40Å) on randomly oriented 5-atom loops during solidification, followed by coating with a graphite rim. Similar particles form during slow cooling of carbon vapor in the lab.

Here we investigate the nucleation and growth of carbon rings and graphene sheets using density functional theory (DFT). Our objectives: (1). explore different computational techniques in DFT-VASP for various carbon structures and compare the results with literature, (2). investigate the nucleation and growth …

Stereocontrolled Mannosylation By Hydrogen-Bond-Mediated Aglycone Delivery, Catherine Alex

Dissertations

Stereocontrolled Mannosylation by Hydrogen-Bond-Mediated Aglycone Delivery

Carbohydrates are the essential bio-molecules of life as they form the forefront of interactions with receptors, proteins, pathogens, or neighboring cells. On cell-surfaces, carbohydrates are mostly found as linear or branched glycoconjugates, and a majority of them are linked via either 1,2-cis or 1,2-trans O-glycosidic linkages. There is no template-driven pathway for achieving the synthesis of glycans unlike other biomolecules like proteins and nucleic acids. The synthesis of 1,2-trans glycosides can be reliably achieved via the neighboring group assistance. The synthesis of 1,2-cis glycosides is difficult because, beyond weak anomeric effects, there are …

Analysis Of The Primary Volatile Compositions In The Oort Cloud And Jupiter-Family Comets Towards The Goal Of Understanding Their Origin And Diversity, Mohammad Saki

Dissertations

Knowledge of the initial conditions present in the early solar nebula is required to understand the evolution and its current volatile content. Comets were some of the first objects to accrete in the solar nebula. They are among the most pristine (primitive) remnants of the solar system formation, and their present-day volatile composition likely reflects the composition and conditions where (and when) they formed. Therefore, they are fossils of the solar system formation. High-resolution near-infrared spectroscopy is a valuable tool for sampling the parent volatile (i.e., ices subliming directly from the nucleus) composition of comets via analysis of fluorescence emission …

Novel Low Temperature Properties Of Filled And Unfilled Single Crystal Irsb3, Matthew Cook

Dissertations

The skutterudite family of materials has garnered a lot of attention in the condensed matter community and it persists to be an important system for exploring the fundamental physics of solids. The initial interest into compounds with this common structure was due to their promising thermoelectric properties giving the possibility of efficient energy harvesting. Since, there has been a huge effort to systematically synthesize new filled skutterudite compounds, as nearly every type of strongly correlated behavior has been found within this family. As the field of topological materials has gained momentum, these materials have also been given a renewed interest …

Dominating Functions In Graphs, Maria Talanda-Fisher

Dissertations

Domination in graphs has become one of the most popular areas of graph the- ory, no doubt due to its many fascinating problems and applications to modern society, as well as the sheer mathematical beauty of the subject. While this area evidently began with the work by the French mathematician Claude Berge in 1958 and the Norwegian-American mathematician Oystein Ore in 1962, domination did not become an active area of research until 1977 with the appearance of the survey paper by Ernest Cockayne and Stephen Hedetniemi. Since then a large number of variations of domination have surfaced and provided numerous …