Physical Sciences and Mathematics Commons^™

High Pressure Effects On Electron Transport And Structure Of Colossal Magnetoresistive Materials, Congwu Cui

Dissertations

Pressure effects on the electronic, magnetic properties and structure of several typical colossal magnetoresistive manganites, La_0.60Y_0.07Ca_0.33MnO₃, Pr_1-xCa_xMn0₃ (X = 0.25, 0.30, 0.35), Nd_1-xSr_xMnO₃ (x = 0.45, 0.50), were explored through high pressure resistivity and structure measurements. It was shown that pressure up to ~7 GPa induces more complicated charge, spin and lattice state changes than in the low pressure range explored previously. In La_0.60Y_0.07Ca_0.33MnO₃, pressure induces a local atomic structure transformation at a critical …

Pharmacophore Derivation Using Discotech And Comparison Of Semi-Emperical, Ab Initio And Density Functional Comfa Studies For Sigma 1 And Sigma 2 Receptor-Ligands, Dawoon Jung

Dissertations

This study describes the development of pharmacophore and CoMFA models for sigma receptor ligands. CoMFA studies were performed for 48 bioactive sigma 1 receptorligands using [H³ ](+) pentazocine as the radioligand, for 30 PCP derivatives for sigma 1 receptor-ligands using [³H](+)SK-F 10047 as the radioligand and for 24 bioactive sigma 2 receptor-ligands using the radioligand [H³](+)DTG in the presence of pentazocine. Distance Comparisons (DISCOtech) was used as the starting point for CoMFA studies. The conformers, derived by DISCOtech were optimized using AMi, or HF/3-21G* in Gaussian 98. The optimized geometries were aligned with the pharmacophore, …

Nonlinear Optical Properties Of Novel Nanostructured Ion Implanted Laser Ablated Silicon Using Femtosecond Pulse Excitation, Elaine Nicole Lalanne

Dissertations

The study of the nonlinear optical properties of novel nanostructured ion implanted and laser ablation of Silicon is motivated by the need for materials that exhibit large values of the real part of the third order nonlinear susceptibility (χ⁽³⁾_Re). This property is essential for light controlled phase or refractive index modulation at low power, where the optical properties are used for optical switching devices. Previous nanosecond (ns) measurements indicated values of-2.8 x 10 ^-5; esu ( γ = 532 nm) for χ⁽³⁾_Re.

The characterization of nonlinear optical properties of the samples was studied …

Image Enhancement Techniques Applied To Solar Feature Detection, Artur J. Kowalski

Dissertations

This dissertation presents the development of automatic image enhancement techniques for solar feature detection. The new method allows for detection and tracking of the evolution of filaments in solar images. Series of H-alpha full-disk images are taken in regular time intervals to observe the changes of the solar disk features. In each picture, the solar chromosphere filaments are identified for further evolution examination. The initial preprocessing step involves local thresholding to convert grayscale images into black-and-white pictures with chromosphere granularity enhanced. An alternative preprocessing method, based on image normalization and global thresholding is presented. The next step employs morphological closing …

Application Of Adaptive Optics To The Spectroscopic Investigation Of Small-Scale Solar Structures, Klaus Hartkorn

Dissertations

We study bright points, umbral dots and the G-band using a two-dimensional spectrometer and an Adaptive Optics system, which allows us to record high-resolution dopplergrams and residual intensity images. We find evidence that bright points are smaller than 120 km in diameter. Bright points are situated exclusively in regions of enhanced G-band brightness and do not show a change in their shape or a displacement in their position of more than 120 km horizontally over a height range from 0 km to 320 km above photospheric level T = 1. We do not find velocity differences of more than 100 …

The Tragedy Of The Rivers: Building Authority Over The British Water Environment, Kevin B. Vichcales

Dissertations

"The Tragedy of the Rivers: Building Authority over the British Water Environment" examines the problem of rivers as common public resources in modern Britain. Viewed historically, the enduring problem of environmental pollution control in Britain has been the establishment of regulating authority over aspects of nature that are regarded simultaneously as economic resources, public utilities, and public amenities. Legislators, subject to pressure from industrial polluters, political parties, and advocates for environmental quality, sought at different times to locate authority at local, regional, national and extra-national levels. Each effort failed to resolve the issue of authority over the environment, because administrative …

Multiobjective Optimal Control Problems With Endpoint And State Constraints, Kirsty J. Eisenhart

Dissertations

In this thesis we consider nonsmooth multiobjective optimal control problems in terms of a general preference on [Special characters omitted.]. The optimal control problems considered involve differential inclusion, endpoint constraints and state constraints. No convexity assumption is needed on the differential inclusion. Examples of common preferences are given, and the idea of approximating a preference is introduced. Euler-Lagrange necessary conditions and a form of the maximum principle are developed for closed preferences (and those that can be approximated by closed preferences) in terms of the limiting subdifferential. As a consequence, this is the first result in the literature for lexicographical …

Experimental And Modeling Studies Of Formation Of Products Of Incomplete Combustion And Chlorocarbon Incineration, Roman Brukh

Dissertations

The two-stage combustor facility was used to investigate the process of chlorocarbon incineration and formation of products of incomplete combustion. For this purpose methylene chloride was used as a chlorine-containing compound. The propose of this research was to obtain a better understanding of the incineration process of chlorocarbons, such as methylene chloride, especially regarding its destruction efficiency and formation of products of incomplete combustion. For measuring near-real time very low concentrations of benzene and methylene chloride, on-line microtrap gas chromatography system was used.

The experimental system was validated using a known combustion reaction mechanism from literature. Modeling of combustion process …

Handgrip Pattern Recognition, Zong Chen

Dissertations

There are numerous tragic gun deaths each year. Making handguns safer by personalizing them could prevent most such tragedies. Personalized handguns, also called "smart" guns, are handguns that can only be fired by the authorized user. Handgrip pattern recognition holds great promise in the development of the smart gun.

Two algorithms, static analysis algorithm and dynamic analysis algorithm, were developed to find the patterns of a person about how to grasp a handgun. The static analysis algorithm measured 160 subjects' fingertip placements on the replica gun handle. The cluster analysis and discriminant analysis were applied to these fingertip placements, and …

Closed-Loop Control Of Vortex Shedding By Means Of Lorentz Force, Xiaoyun Sun

Dissertations

When an incompressible fluid flows past a circular cylinder, vortex shedding occurs as soon as the Reynolds number exceeds about 40. Vortex shedding is usually undesirable, as it generates a significant increase in drag, as well an oscillating lift force on the cylinder leading to cross-stream structural vibrations. Flow control to either delay the appearance of vortex shedding or fully suppress it has attracted much attention during the last decade. The focus of this dissertation is to control vortex shedding from a circular cylinder by applying an external electromagnetic field. As in previous works, the latter is generated by electrodes …

Thermochemistry And Kinetics In Pyrolysis And Oxidation Of Oxygenated Chlorocarbons And Chlorinated Aromatics, Li Zhu

Dissertations

Thermochemical. properties, Δf_H°₂₉₈, S°₂₉₈, and Cp°(T) (5<=T/K<=6000), are determined using different ab inifio and density functional theory methods for three chloromethyl radicals, CH₂Cl, CHCl₂, CCl₃, all chlorobenzenes from monochlorobenzene to hexachlorobenzene, and all chlorophenols from ortho-, meta-, para-chlorophenol to pentachlorophenol. The B3LYP/6-31G(d,p) method is used in the structure optimization. The B3LYP/6-31G(3df,2p), QCISD(T)/6-3 I G(d,p), and CB S-Q methods are used in single point calculations of total electronic energies. Harmonic vibration frequencies are scaled for zero point energies and thermal corrections. Isodesmic reaction(s) are utilized at each calculation level to determine Δf_H°₂₉₈ of each species. Contributions to S°₂₉₈ and Cp°(T) from …

Geochemical And Isotopic Characteristics Associated With High Conductivities In A Shallow Hydrocarbon-Contaminated Aquifier, Franklyn D. Legall

Dissertations

In-situ vertical resistivity probes (VRPs) deployed at a hydrocarboncontaminated site in SW Michigan showed high soil conductivities within the contaminated zone. Within this zone, different phases of hydrocarbon impact were recognized, namely, zones with residual and dissolved phase hydrocarbons (RDH) and zones where these phases coexist with free product (RDFH). Bulk soil conductivities were highest ( 12 to 30 mS/m) in the zone with RDFH compared to the RDH zone (10 to 25 mS/m). Groundwater chemistry and stable carbon isotope data from closely spaced vertical samples within the anomalous conductive zones were used to provide evidence for biodegradation and to …

Geoelectrical Response Of An Aged Lnapl Plume: Implications For Monitoring Natural Attenuation, Douglas D. Werkema Jr.

Dissertations

The geoelectric stratigraphy at a site impacted with light non-aqueous phase liquids (LNAPLs) is investigated for its link to natural biodegradation, its contribution to the conductive model for aged (i.e. mature) LNAPL contaminated sites, and the relationship to the natural hydrologic regime. The highest conductivities (lowest resistivities) were observed in portions o f soils where LNAPL was in residual and free phase. Corroborating evidence from bacteria enumeration from soil close to the vertical resistivity probe (VRP) installations show orders-of-magnitude increase in both heterotrophic and oil degrading microbes at the depths where the conductivity was at a maximum. The coincidence o …

Load Balancing And Congestion Avoidance Routing, Konstantinos N. Kokkinos

Dissertations

Today’s high speed backbone networks are expected to support a wide range of communication-intensive applications. One of the most important issues in Quality of Service (QoS) is efficient routing. Many QoS routing solutions have been published lately for different criteria of QoS requirements and resource constraints. In this dissertation we focus on the design of regular network topologies and suggest efficient routing schemes to reduce the probability of hot spot creation in the network. Furthermore, we provide a detection of congestion mechanism that reroutes traffic to maintain balancing with small communication cost. Several theoretical results relatively to network traffic balancing …

Robust Residuals And Diagnostics In Autoregressive Time Series, Kirk W. Anderson

Dissertations

One of the goals of model diagnostics is outlier detection. In particular, we would like to use the residuals, appropriately standardized, to “flag” outliers. Hopefully, our (robust) procedure has yielded a fit that resists undue influence by outlying points, while simultaneously drawing attention to these interesting points via residual analysis. In this study we consider several different methods of standardizing the residuals resulting from autoregression. A large sample approximation for the variance of rank-based first order autoregressive time series residuals is developed. This provides studentized residuals, specific to the time series model and estimation procedure. Simulation studies are presented that …

New Statitstical Methods For The Estimation Of The Mean And Standard Deviation From Normally Distributed Censored Samples, Abou El-Makarim Abd El-Alim Aboueissa

Dissertations

The main objective of this dissertation is to estimate the mean /x and standard deviation cr of a normal population from left-censored samples. We have developed new methods for calculating estimates for the mean and standard deviation of a normal population from left-censored samples. Some of these methods based on traditional estimating procedures. A new method of obtaining the Cohen maximum likelihood estimates for fx and cr without the aid of an auxiliary table will be introduced. This new method will be used to extend Cohen table of estimating the Cohen A-parameter that is required for calculating the maximum likelihood …

On Rank-Based Considerations For Generalized Linear Models And Generalized Estimating Equation Models, Diana R. Cucos

Dissertations

This study discusses rank-based robust methods for estimation of parameters and hypotheses testing in the generalized linear models (GLM) and generalized estimating equations (GEE) setting. The robust estimates are obtained by minimizing a Wilcoxon drop in dispersion function for linear or nonlinear regression models. In addition, diagnostic tools for outliers and influential observations are being developed. These models are generalizations of linear and nonlinear models. They allow for both nonlinear mean functions and heteroscedasticity of their random errors. This makes them quite useful in practice. Rank-based inference has been developed for linear models over the last thirty years. This inference …

Resolvability In Graphs, Varaporn Saenpholphat

Dissertations

The distance d (u, v ) between two vertices u and v in a connected graph G is the length of a shortest u - v path in G . For an ordered set W = { w1 , w2 , [Special characters omitted.] &cdots; , wk } of vertices in G and a vertex v of G , the code of v with respect to W is the k -vector cW (v ) = (d ( v, w1 ),d (v, w 2 ), [Special characters omitted.] &cdots; , d …

Resonances Of Periodic Metal-Dielectric Structures At The Infrared Wavelength Region, Oren Sternberg

Dissertations

Metal meshes have been used as reflectors in radar receivers for wavelength much longer than the periodic constant of the conducting wires and as optical reflectors in a FabryPerot in the far infrared. Cross shaped metal meshes can be used as band pass filters but the design theory and near field properties have not been known.

Transmittance of thin, single-layer and multiplayer metal meshes has been investigated using Micro-Strips, yielding numerical solutions of Maxwell's equations. The near field effect was studied for two alignment configurations of cross shaped metal meshes, both free standing and with dielectrics, and transmission line theory …

Thermal Treatment Of Organic Contaminated Solids And Waste : Experiment, Model And Mass Balance, Hsien-Tsung Chern

Dissertations

A number of processes can be used to remediate contaminated soils. The thermal technologies for remediation of contaminated soils are summarized in this study. Each of these treatment process along with their system components are identified and described. Waste applicability is included for each treatment technology. A detailed list of feasible treatment processes is presented with descriptions of site demonstration results to aid ill selection of a given process. Technology status is summarized to provide current information on the processes.

Energy components are discussed for cost requirement and safety considerations in thermal treatment applications. It is determined that the heat …

A Microfabricated Microconcentrator For Sensors And Chromatography, Minhee Kim

Dissertations

The detection and quantitative measurement of trace components is a challenging task. The key component in such an instrument is the concentration step where the analytes are accumulated before the analysis. In this research, simple and inexpensive processes for the microfabrication of microconcentrator that can be used with sensors and as an injector in GC were developed. Analytes are selectively concentrated in the microconcentrator. Rapid electrical heating of the microconcentrator releases the adsorbed species as a 66 concentration pulse", which serves as an injection for the detection system. The relatively small size of the microconcentrator allows it to be heated …

Development Of Membrane Extraction Techniques For Water Quality Analysis, Dawen Kou

Dissertations

This research involved the development of membrane-based analytical techniques as applied to various aspects of water quality analysis. Gas injection membrane extraction was developed for fast on-line analysis of volatile organic compounds in water. Gas injection of aqueous samples increased the speed of membrane extraction. The aqueous boundary layer effects encountered during water elution was reduced. Axial mixing of the sample with a gaseous eluent was minimal, and this eliminated the tailing in the permeation profiles. The overall effect was significantly faster penneation. The overall diffusion coefficient during gas injection was found to be seven times the value during aqueous …

Catalytic Reduction Of Nitric Oxide By Solid Carbonaceous Material Under Lean Condition, Shan Xiao

Dissertations

The reactions of O₂, NO_x and soot from Diesel exhaust over Cu containing catalysts can significantly reduce soot and NO_x emissions while producing N₂ and CO₂. The author has evaluated the performance of Cu ion exchanged ZSM-5 and Cu adsorbed on Granulated Activated Carbon (Cu-GAC) using GAC as a surrogate for soot in a packed bed reactor. CO, formed primarily by the oxidation of GAC with O₂, appears to be a stable intermediate in the reduction of NO. With experimental parameters chosen to simulate Diesel exhaust conditions, Cu-GAC is much more …

Knowledge Discovery And Modeling In Genomic Databases, Michael M. Yin

Dissertations

This dissertation research is targeted toward developing effective and accurate methods for identifying gene structures in the genomes of high eukaryotes, such as vertebrate organisms. Several effective hidden Markov models (HMMs) are developed to represent the consensus and degeneracy features of the functional sites including protein-translation start sites, mRNA splicing junction donor and acceptor sites in vertebrate genes. The HMM system based on the developed models is fully trained using an expectation maximization (EM) algorithm and the system performance is evaluated using a 10-way cross-validation method. Experimental results show that the proposed HMM system achieves high sensitivity and specificity in …

Electron Correlation Leading To Double-K-Shell Vacancy Production In Li-Like Ions Colliding With Helium, Ali Sami Alnaser

Dissertations

Single and double K-shell vacancies in Li-like ions colliding with neutral helium target have been investigated using high-resolution Auger projectile spectroscopy. Be⁺, B²⁺, C³⁺, and O⁵⁺ Li-like ions were produced and accelerated to intermediate-to-high collision velocities where perturbative models are expected to be valid, using the Tandem Van de Graaff accelerator at Western Michigan University. Double-K-shell vacancies in atomic systems or so-called “ hollow ions” can be induced by different mechanism in ion-atom collisions. For intermediate-to-high velocity collisions where the collision time is small, the projectile ion can interact with only one of …

Visualization Methods: A Comparative Study Of New, Traditional And Robust Procedures, Kimberly Crimin

Dissertations

Two major goals in discriminant analysis are discrimination and classification. In discrimination, the goal is to describe graphically (visualization) different features of several known groups. In classification, the goal is to allocate unknown observations to one of several known groups. We have developed new visualization procedures based on traditional estimating procedures and also on robust estimating procedures. We have further developed robust classification procedures. We propose several robust classification procedures based on coordinatewise and affine equivariant, rank-based robust estimates. Empirical studies are performed over many different error distributions. These studies result in empirical efficiencies of the robust and traditional procedures. …

A New Type Of Particle Detector For Nuclear Scattering Experiments, Philip Ugorowski

Dissertations

A new detector was needed for counting recoil protons resulting from proton-proton (pp) elastic scattering during pion production experiments by the Polarized Internal Target Experiments (PINTEX) group at Indiana University Cyclotron Facility (IUCF). The previous silicon detectors were only usable forincoming protons up to 9 MeV, and a stopping power of at least 40 MeV was needed. In addition, the detector had to operate in nanotorr vacuum, and near strong varying magnetic fields, ruling out standard organic plastic scintillators and photomultiplier tubes. We needed to find the most suitable inorganic scintillator and another method of detecting the photons produced when …

Separable Preference Orders, Jonathan K. Hodge

Dissertations

Whenever a decision-maker must express simultaneously his or her preferences on several possibly related issues, the existence of interdependence among these preferences can lead to collective decisions that are unsatisfactory or even paradoxical. Intuitively, an individual’s preferences are said to be separable on a subset of issues if they do not depend on the choice of alternatives for issues outside the subset. Here we explore from a mathematical standpoint the properties of separable and nonseparable preference orders. We begin by formulating a general model of multidimensional preferences and we formally introduce the notions of separability and noninfluentiality. We study the …

Nonlinear Regression Based On Ranks, Asheber Abebe

Dissertations

This study presents robust methods for estimating parameters of nonlinear regression models. The proposed methods obtain estimates by minimizing rankbased dispersions instead of the Euclidean norm. We focus on the Wilcoxon and generalized signed-rank dispersion functions. Asymptotic properties of the estimators are established under mild regularity conditions similar to those used in least squares and least absolute deviations estimation. The study also shows that by considering the generalized signed-rank dispersion we obtain a class of estimators that encompasses most of the existing popular nonlinear regression estimators. As in linear models, these rank-based procedures provide estimators that are highly efficient. This …

Nonlinear Interfacial Stability Of Core-Annular Film Flows In The Presence Of Surfactants, Said A. Kas-Danouche

Dissertations

This work is an analytical and computational study of the nonlinear interfacial instabilities found in core-annular flows in the presence of surfactants. Core-annular flows arise when two immiscible fluids (for example water and oil) are caused to flow in a pipe under the action of ail axial pressure gradient. In one typical type of flow regime, the fluids arrange themselves so that the less viscous (e.g. water) lies in the region of high shear near the pipe wall, with the more viscous fluid occupying the core region. Tech nologically, this arrangement provides an advantage since the highly viscous fluid is …