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All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

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Full-Text Articles in Physical Sciences and Mathematics

Cluster Analysis For Acid Rain Data In Norway, Ali Ghafourian May 1983

Cluster Analysis For Acid Rain Data In Norway, Ali Ghafourian

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

This paper gives a description of three well known clustering methods, and discusses the advantages and disadvantages of each. Then, the results of these three clustering methods are compared through examining them on a specific set of data.


The Shape Seeker Algorithm, Ladawn Haws May 1982

The Shape Seeker Algorithm, Ladawn Haws

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

This paper gives a brief description of several well known fuzzy objective function clustering algorithms, and discusses the convergence properties of this type of algorithm. The Shape Seeker algorithm, an adaptive norm algorithm, is then described in detail, and convergence established. It is compared to the other algorithms by examining the clusterings it produces on several data sets.


Structure And Petrography Of The Tertiary Volcanic Rocks Between Death Creek And Dairy Valley Creek (Box Elder Co.), Utah, E. Matthew Hare May 1982

Structure And Petrography Of The Tertiary Volcanic Rocks Between Death Creek And Dairy Valley Creek (Box Elder Co.), Utah, E. Matthew Hare

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Several volcanic flows lie between Death Creek and Dairy Valley Creek, near Etna, Utah. The major, central portion of the volcanic flows is composed of dacite and dacite vitrophyre. An elongate ridge in the southeastern corner of the study area and several small outcrops in Death Creek Valley are composed of rhyolite and rhyolite vitrophyre. Additional rock types include conglomerate, volcanic ash, and tuffaceous sedimentary rock of the Tertiary Salt Lake Formation, Paleozoic limestone, and Tertiary basalt.

Dacite and dacite vitrophyre samples are porphyritic, containing phenocrysts of plagioclase, quartz, biotite, amphibole, orthopyroxene, and iron-titanium oxides. Rhyolite and rhyolite vitrophyre samples …


Influence Of Photosynthetic Photon Flux Density On Uv-Binduced Photoinhibition In Soybean Leaves: Comparison Of Preconditioning And Concomitant Light Treatments, Charles W. Warner May 1982

Influence Of Photosynthetic Photon Flux Density On Uv-Binduced Photoinhibition In Soybean Leaves: Comparison Of Preconditioning And Concomitant Light Treatments, Charles W. Warner

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Previous studies indicate that the degree of UV-Binduced photosynthetic inhibition may be highly dependent upon the photosynthetic photon flux density (PPFD, total quantum flux in the waveband 400-700 nm) incident on a plant. This study illustrates that Essex soybean leaves (Glycine max) preconditioned under high PPFD suffered less UV-B-induced photoinhibition than when preconditioned under low PPFD. However, sensitivity to UV-B increased when soybean leaves received high-PPFD as a concomitant treatment.

The relative msgnitude of UV-B-induced damage was similar for both light-limited and light-saturated photosynthesis. This probably indicates that UV-B is inhibiting fundamentally different photosynthetic processes.

Soybean leaves preconditioned …


The Visual Decision Making Process As A Technique For Redistributing Outdoor Recreation Use, Martha Gail Hahn May 1982

The Visual Decision Making Process As A Technique For Redistributing Outdoor Recreation Use, Martha Gail Hahn

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The demand for recreation on public lands has been growing steadily, resulting in undesirable impacts on certain resources as well as recreation experiences. The problem addressed by this research is the uneven distribution of recreational use that causes a concentration of impacts. This thesis describes the development and testing of a method to reduce the uneven/concentrated recreation use occurring on the public lands.

The basic objectives of the study were to determine the effectiveness of redistributing recreationists by the use of photographs and a decisional process using photographic information and to identify its potential as a tool in meeting management …


Petrology Of The Lower Middle Cambrian Langston Formation, North-Central Utah And Southeastern Idaho, Gary Jay Buterbaugh May 1982

Petrology Of The Lower Middle Cambrian Langston Formation, North-Central Utah And Southeastern Idaho, Gary Jay Buterbaugh

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The Lower Middle Cambrian Langston Formation was studied in the Bear River Range of north-central Utah and southeasternmost Idaho and the Wellsville Mountains of north-central Utah. The depositional textures and sedimentary structures preserved within the rocks were compared with characteristics of similar modern sediments and ancient rock to determine environments of deposition, paleogeography, diagenetic alteration and pattern of dolomitization.

The rocks of the Langston Formation were divided into eleven different rock types. These eleven rock types were formed within four recognizable lithofacies: 1) upper peritidal; 2) inner carbonate shelf; 3) inner clastic shelf; and 4) outer clastic shelf.

The general …


Petrology Of The Middle Cambrian Blacksmith Formation, North-Central Utah, Howard William Hay Jr. May 1982

Petrology Of The Middle Cambrian Blacksmith Formation, North-Central Utah, Howard William Hay Jr.

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The dolostones and dolomitic limestones of the Middle Cambrian Blacksmith Formation were studied in the Bear River and Malad Ranges and the Wellsville Mountains of north-central Utah. The depositional textures and sedimentary structures retained within the rocks form the basis of subdivisions of measured sections, interpretation of depositional paleogeography, and reconstruction of environments.

Other studies of modern carbonate environments and their ancient analogues provided the basis for interpretation of the depositional textures found within the rocks of the Blacksmith Formation. Four identifiable lithofacies were recognized within the study area. These facies include: (1) oolite shoal; (2) restricted lagoon; (3) low- …


Petrology And Mineralogy Of Tertiary Volcanic Rocks In The Vicinity Of The Rozel Hills And Black Mountain, Box Elder County, Utah, Elizabeth R. Greenman May 1982

Petrology And Mineralogy Of Tertiary Volcanic Rocks In The Vicinity Of The Rozel Hills And Black Mountain, Box Elder County, Utah, Elizabeth R. Greenman

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Two basalt flows and an andesite fissure eruption occur in the Rozel Hills - Black Mountain area in Box Elder County, Utah. Both basalt flows are aphanitic, and contain olivine, plagioclase, augite, and opaque oxides. They may be distinguished both chemically and on the basis of their textures. Unit 2 basalt is finer grained, and appears to be associated with a fault in the Black Mountain area. Chemically, it is similar to high-iron lavas in the Craters of the Moon, Idaho area. It has higher alkali, total iron, and titanium contents that Unit 1 basalt. Unit 1 basalt is similar …


Chemical Changes In Groundwater Of Northern Utah Valley, Utah, Paul E. Fairbanks May 1982

Chemical Changes In Groundwater Of Northern Utah Valley, Utah, Paul E. Fairbanks

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Northern Utah Valley is one of the fastest growing areas of Utah and has increasing needs for domestic, industrial, and agricultural water. To meet these needs, groundwater and surface water systems must be understood to maximize their use. Chemical studies of the sediment mineralogy and related water-chemistry give insight to the movement of the water.

There are three major aquifers present in the valley: shallow Pleistocene; deep Pleistocene; and Tertiary. They are composed of sands and gravels and are separated by confining layers (aquitards) composed mostly of clay. Along the flanks of the bordering mountains there are undifferentiated aquifers which …


Habitat Used By Ruffed Grouse In Northern Utah, Judith L. Landry May 1982

Habitat Used By Ruffed Grouse In Northern Utah, Judith L. Landry

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Vegetation structure of sites used by ruffed grouse (Bonasa umbellus) hens with brood, solitary grouse, drumming males, and nesting hens in northern Utah was measured in 1979 and 1980. Univariate statistical techniques were used to determine general habitat characteristics of each group and discriminant function analysis was applied to the data to differentiate among groups. Most nests were located in maple stands (Acer grandidentatum and A. negundo) with dense tree canopies, low shrubs, and sparse ground vegetation. Drumming logs were most commonly found in densely stocked stands of aspen (Populus tremuloides) mixed with maple or chokecherry (Prunus virginiana) having a …


Evaluation Of Low-Temperature Geothermal Potential In Cache Valley, Utah, Janet L. De Vries May 1982

Evaluation Of Low-Temperature Geothermal Potential In Cache Valley, Utah, Janet L. De Vries

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The purpose of this research was to continue the assessment of the low-temperature geothermal resources of Cache Valley, Utah initiated by the Utah Geological and Mineral Survey. Field work consisted of locating 90 wells and springs throughout the study area, collecting water samples for later laboratory analyses, and field measurement of pH, temperature, bicarbonate alkalinity, and electrical conductivity. Na+, K+, Ca+2 , Mg+2 , SiO2, Fe, SO4-2, Cl-, F-, and total dissolved solids were determined in the laboratory.

Temperature profiles were measured in 12 additional, …


Genesis Of A Vertisol And An Associated Palexeroll In Northern Utah, Robert C. Graham May 1982

Genesis Of A Vertisol And An Associated Palexeroll In Northern Utah, Robert C. Graham

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The genetic relationship between a Vertisol and an associated Mollisol with an argillic horizon was studied. These soils are taxadjuncts of the Hawkins and Ostler series, respectively. They occur in the Wasatch Mountains of northern Utah and have similar parent materials, altitudes, and slope percentages. Ostler soils have a dense cover of Gambel oak (Quercus gambelii) and occur preferentially on north aspects. Mule's ear (Wyethia amplexicaulis) is the dominant vegetation on Hawkins soils, which are most frequent on south aspects. Erosion is prevalent on Hawkins soils because the mule's ear does not adequately cover the soil …


On The Transport Equations For Anisotropic Plasmas, Abdallah R. Barakat May 1982

On The Transport Equations For Anisotropic Plasmas, Abdallah R. Barakat

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

First, I attempt to present a unified approach to the study of transport phenomena in multicoponent anisotropic space plasmas. In the limit of small temperature anisotropies this system of generalized transport equations reduces to Grad's 13-moment system of transport equations. In the collisionless limit, the generalized transport equations account for collisionless heat flow, collisionless viscosity, and large temperature anisotropies. Also, I show that with the appropriate assumptions, the system of generalized transport equations reduces to all of the other major systems of transport equations for anisotropic plasmas that have been derived to date.

Next, for application to aeronomy and space …


Least Squares Estimation Of The Pareto Type I And Ii Distribution, Ching-Hua Chien May 1982

Least Squares Estimation Of The Pareto Type I And Ii Distribution, Ching-Hua Chien

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The estimation of the Pareto distribution can be computationally expensive and the method is badly biased. In this work, an improved Least Squares derivation is used and the estimation will be less biased. Numerical examples and figures are provided so that one may observe the solution more clearly. Furthermore, by varying the different methods of estimation, a comparing of the estimators of the parameters is given. The improved Least Squares derivation is confidently employed for it is economic and efficient.


The Use Of Contingency Table Analysis As A Robust Technique For Analysis Of Variance, Mei-Eing Chiu May 1982

The Use Of Contingency Table Analysis As A Robust Technique For Analysis Of Variance, Mei-Eing Chiu

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The purpose of this paper is to compare Analysis of Variance with Contingency Table Analysis when the data being analyzed do not satisfy Analysis of Variance assumptions. The criteria for comparison are the powers of the Standard variance-ratio and the Chi-square test.

The test statistic and powers were obtained by Monte Carlo.

1. Calculate test statistic for each of 100 trials, this process was repeated 12 times. Each time different combination of means and variances were used.

2. Powers were obtained for each of 12 combinations of means and variances.

Whether Analysis of Variance or Contingency Table Analysis is a …


Parameter Estimation In Nonstationary M/M/S Queueing Models, Pensri Vajanaphanich May 1982

Parameter Estimation In Nonstationary M/M/S Queueing Models, Pensri Vajanaphanich

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

If either the arrival rate or the service rate in an M/M/S queue exhibit variability over time, then no steady state solution is available for examining the system behavior. The arrival and service rates can be represented through Fourier series approximations. This permits numerical approximation of the system characteristics over time.

An example of an M/M/S representation of the operations of emergency treatment at Logan Regional hospital is presented. It requires numerical integration of the differential equation for L(t), the expected number of customers in the system at time t.


Nonpoint Source Transport Model For Indicator Bacteria From Western Rangeland Watersheds, Everett P. Springer May 1982

Nonpoint Source Transport Model For Indicator Bacteria From Western Rangeland Watersheds, Everett P. Springer

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Grazing is a primary land use in much of the western United States, but little is known about grazing impacts on water quality. The most sensitive water quality indicators of grazing are the fecal indicator bacteria. The objective of this study was to develop a general transport model describing the movement of fecal indicator bacteria from upland sources to channel systems.

Model development was done using simulated rainfall and a runoff surface 30.48 m by 1.83 m.

Initially the runoff surface was smooth concrete and was used to examine the effects of distance from the outlet on coliform counts by …


Linear Regression Of The Poisson Mean, Duane Steven Brown May 1982

Linear Regression Of The Poisson Mean, Duane Steven Brown

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The purpose of this thesis was to compare two estimation procedures, the method of least squares and the method of maximum likelihood, on sample data obtained from a Poisson distribution. Point estimates of the slope and intercept of the regression line and point estimates of the mean squared error for both the slope and intercept were obtained. It is shown that least squares, the preferred method due to its simplicity, does yield results as good as maximum likelihood.

Also, confidence intervals were computed by Monte Carlo techniques and then were tested for accuracy. For the method of least squares, confidence …


Numerical Methods (Finite Element) For Time-Dependent Partial Differential Equations, Masaji Watanabe May 1982

Numerical Methods (Finite Element) For Time-Dependent Partial Differential Equations, Masaji Watanabe

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

This paper surveys reasons why the Ritz method and the Galerkin method are not efficient and why these methods can not be applied directly, for time dependent problems. It also introduces methods that are used for those problems. For a linear boundary value problem defined by a positive definite symmetric (self-adjoint) operator, the existence and the convergence of the Ritz approximation are guaranteed. In non-symmetric case, Lax-Milgram lemma assures the existence and the convergence of the Galerkin approximation for H1/2(Ω)-elliptic operator. Since time-dependent problems are hyperbolic or parabolic, the existence and the convergence of approximations by those methods are not …


The Transport And Intracellular Distribution Of Iron In The Basidiomycete, Ustilago Sphaerogena, Charles W. Passavant May 1981

The Transport And Intracellular Distribution Of Iron In The Basidiomycete, Ustilago Sphaerogena, Charles W. Passavant

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The transport and intracellular distribution of iron in Ustilago sphaerogena via the native siderochrome ferrichrome A has been examined. Evidence is presented which suggests the involvement of deferriferrichrome in iron transport when the metal is supplied to the cell as ferrichrome A. This process requires both oxygen and ATP synthesis and may require a transmembrane electrochemical gradient. Once inside the cell, iron derived from ferrichrome A is rapidly distributed, with a major fraction found in the mitochondria, presumably as heme.

The kinetics of ferrichrome and ferrichrome A uptake have also been investigated. The Km of transport of ferrichrome was …


Higher Plant Acclimation To Solar Ultraviolet-B Radiation, Ronald Robberecht May 1981

Higher Plant Acclimation To Solar Ultraviolet-B Radiation, Ronald Robberecht

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Plant acclimation to natural and intensified solar UV-B irradiance was investigated in three species, Oenothera stricta Ledeb., Rumex obtusifolius L., and R. patientia L. The objectives of this study were to determine: (1) the relationship between plant sensitivity and epidermal UV attenuation, (2) the effect of phenotypic changes in the leaf epidermis, resulting from UV-B exposure, on plant sensitivity to UV radiation, and (3) the plasticity of these changes in the epidermis leading to plant acclimation to UVB radiation.

Epidermal UV transmittance was found to differ in magnitude and spectral distribution among the three species examined in this study. Epidermal …


Effect Of Mild Water Stress And Enhanced Ultraviolet-B Irradiation On Leaf Growth Of Rumex Obtusifolius L. And Rumex Patientia L. (Polygonaceae)., Steve R. Holman May 1981

Effect Of Mild Water Stress And Enhanced Ultraviolet-B Irradiation On Leaf Growth Of Rumex Obtusifolius L. And Rumex Patientia L. (Polygonaceae)., Steve R. Holman

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Leaves of Rumex obtusifolius L. and R. patientia L.were exposed to combinations of mild water stress and enhanced ultraviolet-B irradiation during their ontogeny. Two UV-B treatments (enhanced UV-B and control) and three water stress treatments (-0.0 MPa, -0.2 MPa and -0.4 MPa rooting medium matric potentials) were employed. The impact of the stress interaction was assessed on the basis of changes in leaf area, average adaxial epidermal cell size, and total number of adaxial epidermal cells per leaf. Although the level of UV-B irradiation applied was insufficient to significantly alter leaf growth at any given water stress, UV-B did interact …


Some Morphological And Chemical Responses Of Blackbrush (Coleogyne Ramosissima) To Goat Browsing: Influences On Dietary Blackbrush Selection By Goats And Cattle, Frederick D. Provenza May 1981

Some Morphological And Chemical Responses Of Blackbrush (Coleogyne Ramosissima) To Goat Browsing: Influences On Dietary Blackbrush Selection By Goats And Cattle, Frederick D. Provenza

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Domestic goats were used to modify the growth form of blackbrush, a spinescent shrub occurring in nearly monospecific stands on several million hectares of rangeland in the southwestern United States. The objective of this research was to evaluate goat browsing as a means of improving these rangelands for cattle. Winter goat browsing stimulated spring twig growth from basal and axillary buds which resulted in increased production.

Twig production by heavily browsed plants (>95 percent removal of current season's twigs) was a function of precipitation, soil depth, branch location on the plant, and period of rest after browsing. As precipitation …


Natural Pastures Of The Macquarie Region Of New South Wales: Their Origin, Composition And Management, David Leslie Michaelk May 1981

Natural Pastures Of The Macquarie Region Of New South Wales: Their Origin, Composition And Management, David Leslie Michaelk

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Two experiments were conducted in the semi-arid (400 millimeter annual rainfall) Macquarie region of New South Wales, Australia, at the Trangie Agricultural Research Station (31° 59'S; 147° S7'E), to examine (a) the way botanical parameters can be used to separate grazing and climatic impacts on range vegetation, and (b) how this delineation affects application of range science tenets (site, condition and trend) to different pasture types.

Two range sites were studied: Site 1, a light soil type, was dominated by annual grasses, legumes and forbs, whereas perennial grasses (mainly Chloris acieularis and Chloris truncata) dominated the heavy soils of …


Fall Regrowth Of Crested Wheatgrass And Fourwing Saltbush, Noor Mohammad May 1981

Fall Regrowth Of Crested Wheatgrass And Fourwing Saltbush, Noor Mohammad

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

During 1980-81, studies with crested wheatgrass (Agropyron desertorum) and fourwing saltbush (Atriplex canescens) were conducted in controlled environment growth chambers as well as under field conditions to achieve the following objectives:

1. To determine the effect of nitrogen fertilizer on the water use efficiency.

2. To determine the effects of various temperature, water stress and nitrogen treatments on the productivity, nitrogen content and carbohydrate reserves.

3. To determine the effects of N fertilization on fall and spring regrowth.

Crested wheatgrass and fourwing saltbush plants were maintained in three growth chambers for 60 days under three temperature …


The Energy Expenditure Of Heifers Grazing Crested Wheatgrass Rangeland In West-Central Utah, Kris M. Havstad May 1981

The Energy Expenditure Of Heifers Grazing Crested Wheatgrass Rangeland In West-Central Utah, Kris M. Havstad

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The free-roaming ruminant requires energy for the demands of vii grazing, traveling and thermoregulation that are not required by its confined counterpart. Literature estimates of these additional costs range from 10 to 170 percent above maintenance. The uncertain magnitude of this increased demand and the factors that contribute to it impede the ability of the rangeland ruminant nutritionist to establish guidelines for the energy requirements of the free-roaming herbivore. This study was designed to estimate the energy expenditure of yearling Angus heifers while grazing a declining supply of available crested wheatgrass forage (Agropyron cristatum) on rangeland in west-central …


Lifestyle As A Determinant Of Participation Among Dispersed Forest Recreationists, John R. Butler May 1981

Lifestyle As A Determinant Of Participation Among Dispersed Forest Recreationists, John R. Butler

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

This study assesses the usefulness of lifestyle as a determinant of outdoor recreation behavior. Two objectives of the study are: (1) develop an operationalized concept of lifestyle that is based on theory, and (2) apply this concept in a model which uses lifestyle as a variable influencing recreation behavior.

The first objective was approached through an integrative review of the literature. Lifestyle was set in context of cultural theory. The basic postulate of the proposed theory of lifestyle is: If an individual's lifestyle is similar to that of another, certain social psychological processes are similar. Therefore, their patterns of needs, …


Growth-Form Analysis And Paleoecology Of The Corals Of The Late Ordovician Through Mid-Silurian Fish Haven And Laketown Formations, Bear River Range, North-Central Utah, Thomas B. Rich May 1981

Growth-Form Analysis And Paleoecology Of The Corals Of The Late Ordovician Through Mid-Silurian Fish Haven And Laketown Formations, Bear River Range, North-Central Utah, Thomas B. Rich

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Morphology of corals of the Late Ordovician through mid-Silurian Fish Haven and Laketown Formations were analyzed to document adaptations to inferred enviromental conditions, i.e., (bathymetry, illumination, sedimentation, currents, and energy), under which their enclosing sediment was deposited. Specimens and data were collected from six sites. Insoluble-residue tests were performed on the corals' matrices.

Individual corallites of radial-lensoidal corals radiate in all directions. Vertical growth, however, was restricted in turbulent conditions. Umbrellic, radial-lensoidal corals feature downward facing corallites, considered to be an adaptation to a well illuminated environment.

On tabular lensoidal corals, constituent corallites faces exclusively upward, an orientation needed under …


Seasonal Temperature Preference Of Adult Mountain Whitefish, Prosopium Williamsoni, Jean M. Ihnat May 1981

Seasonal Temperature Preference Of Adult Mountain Whitefish, Prosopium Williamsoni, Jean M. Ihnat

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Temperatures selected seasonally by adult mountain whitefish were measured in the laboratory in a horizontal gradient. Final preferendum estimates, based on acute (3-hour) preference tests conducted with fish acclimated to 5, 10, and 15 C each season, were 17.7 C (pre-spawning), 11.9 C (post-spawning), 9.9 C (winter), and 16.3 C (spring). Seasonal influence on temperature selection was evident on the basis of differences in final preferenda, covariance analysis of responses of laboratory-acclimated fish, and temperature selection by fish held at ambient river temperatures. Post-spawning and winter groups selected lower temperatures than did pre-spawning and spring groups. Pre-spawning fish selected temperatures …


Mechanism Of Two Homogeneous Reactions; Co Self Exchange And N2 Self Exchange, Alan L. Rockwood May 1981

Mechanism Of Two Homogeneous Reactions; Co Self Exchange And N2 Self Exchange, Alan L. Rockwood

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The two atom switching reactions referred to in the title were originally studied at temperatures greater than 2000°K in shock tubes by other investigators. For each reaction they proposed a direct four-center exchange mechanism in which one of the reactant molecules must be vibrationally excited, (the vibrational excitation mechanism or VEM). One of the predictions of the VEM is that molecules which are vibrationally hot but translationally cold should react through the four center transition state that leads to exchange.

Using a mercury photosensitization technique, it is shown in the present work that excitation of CO to high vibrational levels …