Physical Sciences and Mathematics Commons^™

Completing And Improving The Collection Of Data For Carbon Reporting, Madeline Petty

Mahurin Honors College Capstone Experience/Thesis Projects

Global carbon emissions from individual, organizational, and institutional activities influence the environment. Organizations and institutions use sustainability reporting methods to regularly track and report metrics relating to emissions from collective activity, yet data needed for such reporting can be difficult and time-consuming to collect. Multiple institutions, particularly universities, often use digital, standardized carbon footprint reporting tools to help overcome these challenges. Still, using digital reporting tools does not alleviate all challenges faced in regular carbon reporting due to the lack of data collection structure among university departments. This scholarly activity attempted to calculate the carbon footprint of Western Kentucky University …

Teloportwrapper: A New Tool For Understanding The Dynamic World Of Fungal Telomere Ends, Trey Stansfield

Mahurin Honors College Capstone Experience/Thesis Projects

Telomeres are repetitive DNA sequence motifs found at eukaryote chromosome ends. Telomeres help protect chromosome ends from DNA damage and promote chromosome stability. Chromosomes play important roles in aging, mutation, and cancer. Eukaryotic pathogens also use telomeres to mutate and manage virulence genes. In response to chromosome end breakage newly formed telomeres, called de novo telomeres, are formed to recreate the lost telomere and sub-telomeric regions.

Magnaporthe oryzae is a fungal pathogen which causes wheat blast, a deadly plant disease in wheat. Magnaporthe oryzae is also known for its highly variable sub-regions which show high amounts of induced variability due …

Simulating The Machine Translation Of Low-Resource Languages By Designing A Translator Between English And An Artificially Constructed Language, Michaela Snyder

Mahurin Honors College Capstone Experience/Thesis Projects

Natural language processing (NLP), or the use of computers to analyze natural language, is a field that relies heavily on syntax. It would seem intuitive that computers would thrive in this area due to their strict syntax requirements, but the syntax of natural languages leaves them unable to properly parse and generate sentences that seem normal to the average speaker. A subfield of NLP, machine translation, works mainly to computerize translation between different languages. Unfortunately, such translation is not without its weaknesses; language documentation is not created equal, and many low-resource languages—languages with relatively few kinds of documentation, most often …

Comparison Of Groundwater Chemistry And Associated Biodiversity Of Sulfidic Karst Habitats In Southcentral Kentucky, Kendall Wheeler

Mahurin Honors College Capstone Experience/Thesis Projects

In most ecosystems, primary production is conducted by plants or photosynthetic microbes; however, extremophilic sulfur-oxidizing bacteria can use hydrogen sulfide gas (H2S) as an electron donor to produce metabolic energy in a type of metabolism called chemoautotrophy. These ecosystems are a prominent feature of some karst landscapes, and two have been observed in the Mammoth Cave system, Sulphur River in Parker Cave and Marianne’s Pass in Mammoth Cave National Park respectively.

Sulfidic water is ubiquitous in southcentral Kentucky and is strongly associated with hydrocarbon deposits. This oil boom of the 1880s in this region predates most environmental regulation and records …

Building Coleus Academy, Janessa Unseld

Mahurin Honors College Capstone Experience/Thesis Projects

Coleus Academy, a nonprofit e-learning platform, has been created to address the deficits left by the de-emphasis and, at times, outright omission of practical skill-centric education in American curriculums. There exists a gap between the degree of knowledge necessary to engage with adult life and the extent of that knowledge that is actually possessed by emerging adults. Prominent legislations are among the numerous efforts to address this issue. However, there is a deeply fractured market where resources are proving too expensive, too sparse, or hyper-specific to the point of limited usability. Compounded with disparities in when, where, and to whom …

Rosalie Edge And The Modern Environmental Movement, Elizabeth Claire Coleman

Mahurin Honors College Capstone Experience/Thesis Projects

This thesis examines and follows the actions of an understudied activist in the environmentalist movement: Rosalie Edge. This thesis relies and encourages a combination of conservation, environmentalism, and historical women’s history in America. Rosalie Edge’s work as an environmentalist created a new and effective way for environmentalists to advocate for the environment around them. She created a pamphlet medium that invited scientists and other conservationists to publish writings and opinions that went against what the Audubon Society, the Biological Survey, and legislators were doing and publishing. The research for this project combines analysis from other professionals in the field with …

Carbon Cycling And Critical Zone Dynamics In An Urbanized Karst Groundwater System, Amy Hourigan

Masters Theses & Specialist Projects

Increasing atmospheric CO₂ concentrations are correlated to rising global temperatures. Investigating the cumulative global carbon cycling processes is important to understand and quantify the global carbon cycle. By investigating basic geochemical parameters, EpCO₂, DIC, and δ¹³C_DIC, at four sites along Lost River Cave (LRC), in Bowling Green, Kentucky, concentrations, fluxes and sources of C dissolved in groundwater were determined. Urban karst groundwater systems, compared to more natural karst landscapes, typically exhibit widespread impervious, heat-absorbing surfaces, urban heat island effects, and increased anthropogenic groundwater inputs and localized CO₂ emissions. Carbonate hydrogeochemical …

Ua12/2/1 College Heights Herald, Vol. 93, No. 1, Wku Student Affairs

WKU Archives Records

WKU campus newspaper reporting campus, athletic and Bowling Green, Kentucky news. This issue contains articles:

• The Great American Eclipse
• Kast, Monica. Timothy Caboni Talks Budget in Meeting with Editors
• DeLetter, Emily. Back Home – Timothy Caboni
• Collins, Emma. Campus Construction Continues with Completion of Restaurant – The Den
• Ziege, Nicole. Student Government Association President Signs Anti-discrimination Letter – Andi Dahmer
• Alvey, Rebekah. New Space Serves as Link to Downtown Businesses – Gordon Ford College of Business
• Henderson, Andrew. Hey, How Are Ya?
• Editorial Cartoon re: Eclipsse
• Huff, Taylor. Eclipse of Morality – U.S. Government
• Gabhart, Ebonee. Analyzing What Constitutes a …

An Integrated Gis & Flood Vulnerability Index Approach To Evaluating Risk & Environmental Equity In Urban Karst Communities, Chloe Cooper

Masters Theses & Specialist Projects

This study examines how the usage of an integrated GIS (Geographic Information Systems), flood vulnerability assessment, and management approaches can aid in hazard response planning in karst groundwater systems, particularly in urban environments. In order to also better understand the impacts of flood events on socially vulnerable groups, this research was focused on historically excluded communities. Additionally, place-based vulnerabilities were primarily assessed based upon three main factors in the vulnerability framework and how these components intersect: social, environmental conditions, and economic. By understanding which areas of the City of Bowling Green, an iconic urban karst area, are most vulnerable and …

Evaluation Of Silver Nanoparticles Attached To Methylene Blue As An Antimicrobial Agent And Its Cytotoxicity, Somon Hakimov

Masters Theses & Specialist Projects

Antibiotics resistance is considered as one of the greatest public health challenges of our time. In this work, we have synthesized silver nanoparticles (Ag NPs) using pulsed liquid ablation in different medium of growth and later combined with methylene blue (MB) to evaluate its potential as an effective photodynamic therapy agent. Ag NPs were synthesized by pulsed laser ablation technique in Polyvinylpyrrolidone (PVP), citrate, and Polyvinyl alcohol (PVA). The Ag NPs were characterized using transmission electron microscopy (TEM), UV-Visible (UV-Vis), and photoluminescence (PL) spectra. Next, Ag NPs were coupled with MB and used to deactivate the Gram-negative bacteria, Escherichia coli …

Robust Sensor Design For The Novel Reduced Models Of The Mead-Marcus Sandwich Beam Equation, Ahmet Aydin

Masters Theses & Specialist Projects

Novel space-discretized Finite Differences-based model reductions are proposed for the partial differential equations (PDE) model of a multi-layer Mead-Marcus-type beam with (i) hinged-hinged and (ii) clamped-free boundary conditions. The PDE model describes transverse vibrations for a sandwich beam whose alternating outer elastic layers constrain viscoelastic core layers, which allow transverse shear. The major goal of this project is to design a single boundary sensor, placed at the tip of the beam, to control the overall dynamics on the beam.

For (i), it is first shown that the PDE model is exactly observable by the so-called nonharmonic Fourier series approach. However, …

Towards The Determination Of Estrone And 17Β-Estradiol In Dairy Cattle Waste Using Solid Phase And Stir Bar Sorptive Extractions With Liquid Chromatography-Mass Spectrometry And Gas Chromatography-Mass Spectrometry, Pallavi Ragi

Masters Theses & Specialist Projects

Steroidal hormones are naturally produced as a part of many physiological processes and are excreted in the urine and feces of animals and humans. Farm animals in concentrated animal feeding operations (CAFOs) are routinely implanted with synthetic and natural hormones to enhance growth and production, contributing significantly to environmental steroid hormone contamination. Every year around 49 tons of estrogens are generated by livestock waste in the United States alone. Due to rainfall and runoff, these steroid hormones reach the environment when animal waste is applied as manure. Studies show that estrogens and other steroidal hormones present in the surface waters …

Real-Time Monitoring Of Paraquat Photodegradation Using Colloidal Gold Surface Enhanced Raman Spectroscopy, Nathan Wilson

Masters Theses & Specialist Projects

Monitoring chemical reactions in aqueous solution is a challenge because most instrumental techniques either are not suited for the rapid timescales, are not sensitive enough to detect products at low concentrations, or do not have sufficient structure-to-spectrum relationships. Raman spectroscopy is a promising method to monitor reactions, as it is fast, dependent on chemical structure, and has little interference from water. However, Raman scattering is generally very weak. Surface-enhanced Raman spectroscopy (SERS) improves the signal strength of Raman spectroscopy by using a metal surface plasmon, or oscillation of the surface’s electrons, to allow for highly selective and sensitive detection and …

Factors Influencing Tree Growth In A Bottomland Hardwood Along The Green River In Kentucky, Caleb Miller

Masters Theses & Specialist Projects

In bottomland hardwood forests, large fluctuations in moisture availability can lead to stress from both flooded and drought conditions. These forests can have a complex species composition with different water use and drought strategies. The bottomlands in which these species co-occur can have a complex spatial distribution of alluvial sediments due to the meandering and migration of river or stream channels, which may impact the hydrology, nutrient dynamics, and productivity. At Western Kentucky University's Green River Preserve, approximately 9 ha of bottomland hardwood forest were planted in 2006. Although these hardwoods have received equal amounts of sunlight, rainfall, and wind, …

Liquid Chromatography With Tandem Mass Spectrometry Method Development For The Determination Of Β–Defensins In Bovine Milk, Symone T. Whalin

Masters Theses & Specialist Projects

Bovine mastitis, caused by a wide array of pathogens, results in a substantial economic loss for the dairy cattle livestock industry. β-defensins are a part of the bovine’s innate immune system and act as the first line of defense against mastitis. Only foundational research has been done on β-defensins’ ability to treat and prevent mastitis. There have been no analytical methods reported in the literature for analyzing β-defensins in bovine milk. This research aims to create an analytical approach to determine β-defensins in bovine milk. It is challenging to determine an analyte in a complex sample matrix, and milk is …

Canary: An Automated Approach To Security Scanning And Remediation, David Wiles

Masters Theses & Specialist Projects

Modern software has a smaller attack surface today than in the past. Memory-safe languages, container runtimes, virtual machines, and a mature web stack all contribute to the relative safety of the web and software in general compared to years ago. Despite this, we still see high-profile bugs, hacks, and outages which affect major companies and widely-used technologies. The extensive work that has gone into hardening virtualization, containerization, and commonly used applications such as Nginx still depends on the end-user to configure correctly to prevent a compromised machine.

In this paper, I introduce a tool, which I call Canary, which can …

Generation & Kinetic Studies Of Porphyrin Chromium-Oxo Intermediates, Iyanu Olumide Ojo

Masters Theses & Specialist Projects

Recent emerging applications of chromium porphyrin complexes are generating increasing interest in oxidation chemistry and catalysis. Its recent application as metal-organic frames in spintronic devices supports the rich electronic system of chromium metal. Through the past decades, first-row transition metalloporphyrins have served as biomimetic oxidation catalysts and models of cytochrome P450 enzymes. However, the oxygen atom transfer mechanism of chromium porphyrin complexes, most especially in sulfide oxidation reactions, has been scarcely investigated.

In this study, high-valent chromium-oxo porphyrin species, namely Cr^IV-oxo and Cr^V-oxo species, with electron-donating tetramesitylporphyrin(TMP) ligand were successfully generated and characterized with UV-vis, ESI-MS, …

Jillson, Willard Rouse, 1890-1975 (Mss 682), Manuscripts & Folklife Archives

MSS Finding Aids

Finding aid only for Manuscripts Collection 682. Writings and supporting materials of Willard Rouse Jillson, State Geologist of Kentucky, author and historian. Includes manuscripts, page proofs, photographic negatives, and promotional pamphlets for his books.

Towards Semiconductor Nanorods With Nickel/Iron Cocatalyst., Kehinde Ayorinde

Masters Theses & Specialist Projects

The adverse effects associated with the utilization of fossil fuels has led to the need to provide an alternative cleaner energy. Photocatalytic hydrogen evolution reaction via water splitting provides a renewable pathway to generating energy. Our photocatalyst system includes a semiconductor component (CdSe/CdS core/shell nanorods) to capture light and an attached metal (cocatalyst) for the hydrogen evolution reaction. Platinum is an effective metal catalyst for this reaction due to strong proton binding energy that easily facilitates the reduction of water to produce hydrogen gas. However, due to the high cost of platinum, there is a need to find a less …

Synthetic, Photophysical, And Catalytic Studies Of Light-Harvesting Macrocyclic Complexes, Fox Bratcher

Masters Theses & Specialist Projects

Chromophores are an important class of compounds in Nature and industry, with several hundred thousand tons produced annually as dyes and pigments. Alone, these compounds absorb light unto themselves; however, several of these compounds can be combined to produce a beneficial cascading transfer of energy to a core chromophore.

In this study, photophysical properties of several covalent and axially borondipyrromethene (BODIPY)-conjugated complexes of porphyrin and salphen scaffolds have been evaluated in a series of emission and catalytic studies. In the porphyrin systems, a beneficial excited energy transfer (EET) from the BODIPY moieties to the porphyrin core was observed; however, only …

Semantic Completeness Of Intuitionistic Predicate Logic In A Fully Constructive Meta-Theory, Ian Ray

Masters Theses & Specialist Projects

A constructive proof of the semantic completeness of intuitionistic predicate logic is explored using set-generated complete Heyting Algebra. We work in a constructive set theory that avoids impredicative axioms; for this reason the result is not only intuitionistic but fully constructive. We provide background that makes the thesis accessible to the uninitiated.

A Monte Carlo Analysis Of Seven Dichotomous Variable Confidence Interval Equations, Morgan Juanita Dubose

Masters Theses & Specialist Projects

Department of Psychological Sciences Western Kentucky University There are two options to estimate a range of likely values for the population mean of a continuous variable: one for when the population standard deviation is known and another for when the population standard deviation is unknown. There are seven proposed equations to calculate the confidence interval for the population mean of a dichotomous variable: normal approximation interval, Wilson interval, Jeffreys interval, Clopper-Pearson, Agresti-Coull, arcsine transformation, and logit transformation. In this study, I compared the percent effectiveness of each equation using a Monte Carlo analysis and the interval range over a range …

Reinforcement Learning With Deep Q-Networks, Caleb Cassady

Masters Theses & Specialist Projects

In the past decade, machine learning strategies centered on the use of Deep Neural Networks (DNNs) have caught the interest of researchers due to their success in complicated classification and prediction problems. More recently, these DNNs have been applied to reinforcement learning tasks with state of- the-art results using Deep Q-Networks (DQNs) based on the Q-Learning algorithm. However, the DQN training process is different from standard DNNs and poses significant challenges for certain reinforcement learning environments. This paper examines some of these challenges, compares proposed solutions, and offers novel solutions based on previous research. Experiment implementation available at https://github.com/caleb98/dqlearning.

K-Means Clustering Using Gravity Distance, Ajinkya Vishwas Indulkar

Masters Theses & Specialist Projects

Clustering is an important topic in data modeling. K-means Clustering is a well-known partitional clustering algorithm, where a dataset is separated into groups sharing similar properties. Clustering an unbalanced dataset is a challenging problem in data modeling, where some group has a much larger number of data points than others. When a K-means clustering algorithm with Euclidean distance is applied to such data, the algorithm fails to form good clusters. The standard K-means tends to split data into smaller clusters during a clustering process evenly.

We propose a new K-means clustering algorithm to overcome the disadvantage by introducing a different …

Inflammatory Response To Sleep Fragmentation In Skeletal, Cardiac, And Smooth Muscle Tissues In Female Mice, Patton Allen

Mahurin Honors College Capstone Experience/Thesis Projects

Sleep is a critical process that the body undergoes. When sleep is interrupted, so that an individual is awakened for some period before going back into sleep, the sleep can be described as fragmented. Studies in the past have shown that sleep fragmentation (SF) promotes an inflammatory environment, especially in the brain and peripheral tissue. However, studies have not been conducted to observe inflammatory responses in muscle. To examine this, C57BL/6J female mice were subjected to either a control group (no SF) or a SF group which involved using an automated SF chamber to disrupt sleep every 2 min over …

Kentuckians' Perception Of The Environment And Use Of Outdoor Public Spaces, Grace Herrmann

Mahurin Honors College Capstone Experience/Thesis Projects

Understanding how people perceive the environment and built public outdoor spaces is valuable in determining the direction of future development in the state. Further, understanding the emotions relating to the environment, both the natural and built public environments is instrumental in guiding future planning. This project aimed to understand Kentuckians’ perception of the environment and their use of public outdoor spaces such as parks, farmer markets, bike lanes, and walking paths through the use of a digital survey. Respondents to this survey are Kentuckians over the age of 18. The digital survey was split into four sections. The first section …

Development Of Scent Detection And Categorization Algorithm Using Gas Chromatography And Machine Learning, Alex Driehaus

Mahurin Honors College Capstone Experience/Thesis Projects

There are many looking to connect human senses to quantifiable data. Scents are categorized by their descriptions into scent families. These include citrus, floral, and woody. Similar descriptors designate similar families, while different descriptors correlate with different families. Dravnieks compiled an Atlas of chemical descriptors [1]. Such descriptors are cinnamon, fruity, and cadaverous. By analyzing the applicability of these descriptors, the chemicals will be sorted into their scent families.

Gas chromatography generates sample-specific signals of voltage over time. Chromatograms of known scents will serve as a basis for a convolutional neural network. This algorithm will be trained on these signals …

Developing And Applying An Integrated Spatial Karst Evaluation And Management Priority Tool: Case Study In Tongass National Forest, Alaska, Usa, Christian Decelle

Masters Theses & Specialist Projects

Karst terrains are complex landscapes that are sensitive to human disturbance. Human activities have polluted and impacted many of these terrains around the world. To preserve these unique landscapes, many karst regions are protected and designated as national parks, geologic special areas, or UNESCO Biosphere Reserves. Despite the widespread general protection of karst landscapes globally, a review of each area’s management plan reveals there is no standardized method of cave and karst management or evaluation of karst impacts.

The non-standardization of karst management strategies may be due to the gap that exists between the needs of karst land managers and …

Investigating Epikarst Recharge Dynamics Under Agricultural Landuse Using Hydrometeorological And Isotopic Tracers, Austin Shane Deering

Masters Theses & Specialist Projects

Epikarst systems have complex recharge – discharge processes in telogenetic karst systems, including highly variable storage, flowpaths, and mixing dynamics. This research aimed to characterize the epikarst zone using hydrogen and oxygen isotopic tracers of these processes within south-central Kentucky’s Crumps Cave system located in the Pennyroyal Sinkhole Plain. Data and statistical analyses were applied to highresolution rainfall (RF), lysimeter (10 cm, 20 cm, 30 cm depths), and an epikarst Waterfall 1 (WF1) isotope data collected on a weekly basis between 2011-2018. These data were coupled with WF1 discharge measurements and weather station data collected at Crumps Cave Preserve during …

Manufacturing: The Qualitative Study Of A Transition To A Green Facility, Brandon David Staves

Masters Theses & Specialist Projects

This qualitative study focused on answering three core questions: How have facilities reduce pollutions in regards to the quality of air, water, land, light and noise? Which Types of pollution reduction projects are more or less successful to implement? What types of pollution are facilities focusing on and why? The results of the 15 companies surveyed show a variety of projects that facilities have used to reduce pollution, it also shows that cost is a major factor in the unsuccessful projects, and that facilities are actively focused on reducing Air, Land, and Water pollution. While the data shows a variety …