Physical Sciences and Mathematics Commons^™

Standard Interval Computation Algorithm Is Not Inclusion-Monotonic: Examples, Marina Tuyako Mizukoshi, Weldon Lodwick, Martine Ceberio, Olga Kosheleva, Vladik Kreinovich

Departmental Technical Reports (CS)

When we usually process data, we, in effect, implicitly assume that we know the exact values of all the inputs. In practice, these values comes from measurements, and measurements are never absolutely accurate. In many cases, the only information about the actual (unknown) values of each input is that this value belongs to an appropriate interval. Under this interval uncertainty, we need to compute the range of all possible results of applying the data processing algorithm when the inputs are in these intervals. In general, the problem of exactly computing this range is NP-hard, which means that in feasible time, …

How Viscosity Of An Asphalt Binder Depends On Temperature: Theoretical Explanation Of An Empirical Dependence, Edgar Daniel Rodriguez Velasquez, Vladik Kreinovich

Departmental Technical Reports (CS)

Pavement must be adequate for all the temperatures, ranging from the winter cold to the summer heat. In particular, this means that for all possible temperatures, the viscosity of the asphalt binder must stay within the desired bounds. To predict how the designed pavement will behave under different temperatures, it is desirable to have a general idea of how viscosity changes with temperature. Pavement engineers have come up with an empirical approximate formula describing this change. However, since this formula is purely empirical, with no theoretical justification, practitioners are often somewhat reluctant to depend on this formula. In this paper, …

Why In Mond -- Alternative Gravitation Theory -- A Specific Formula Works The Best: Complexity-Based Explanation, Olga Kosheleva, Vladik Kreinovich

Departmental Technical Reports (CS)

Based on the rotation of the stars around a galaxy center, one can estimate the corresponding gravitational acceleration -- which turns out to be much larger than what Newton's theory predicts based on the masses of all visible objects. The majority of physicists believe that this discrepancy indicates the presence of "dark" matter, but this idea has some unsolved problems. An alternative idea -- known as Modified Newtonian Dynamics (MOND, for short) is that for galaxy-size distances, Newton's gravitation theory needs to be modified. One of the most effective versions of this idea uses so-called simple interpolating function. In this …

Epistemic Vs. Aleatory: Case Of Interval Uncertainty, Marina Tuyako Mizukoshi, Weldon Lodwick, Martine Ceberio, Vladik Kreinovich

Departmental Technical Reports (CS)

Interval computations usually deal with the case of epistemic uncertainty, when the only information that we have about a value of a quantity is that this value is contained in a given interval. However, intervals can also represent aleatory uncertainty -- when we know that each value from this interval is actually attained for some object at some moment of time. In this paper, we analyze how to take such aleatory uncertainty into account when processing data. We show that in case when different quantities are independent, we can use the same formulas for dealing with aleatory uncertainty as we …

Decision Making Under Uncertainty With A Special Emphasis On Geosciences And Education, Laxman Bokati

Open Access Theses & Dissertations

In many practical situations, we need to make a decision. In engineering, we need to decideon the best design of a system, and, for existing systems - on the best control strategy. In financial applications, we need to decide what is the best way to invest money. In geosciences, we need to decide whether we should explore a possible mineral deposit - or whether we should perform more experiments and measurements (and what exactly). In some cases, we can compute the exact consequences of each decision - e.g., if we are controlling a satellite. However, in many other cases, we …

Generation Of Phase Transitions Boundaries Via Convolutional Neural Networks, Christopher Alexis Ibarra

Open Access Theses & Dissertations

Accurate mapping of phase transitions boundaries is crucial in accurately modeling the equation of state of materials. The phase transitions can be structural (solid-solid) driven by temperature or pressure or a phase change like melting which defines the solid-liquid melt line. There exist many computational methods for evaluating the phase diagram at a particular point in temperature (T) and pressure (P). Most of these methods involve evaluation of a single (P,T) point at a time. The present work partially automates the search for phase boundaries lines utilizing a machine learning method based on convolutional neural networks and an efficient search …

Rational Design Of Precisely Tailored Electrocatalysts For Efficient And Durable Electrocatalytic Devices, Mohmed Sanad Noufal

Open Access Theses & Dissertations

Due to their superior conversion efficiency, high power density, and green nature, sustainable energy technologies such as Fuel cells and Zinc-air batteries, once installed to produce green hydrogen fuel as well as energy storage devices, are expected to play an essential role in reducing the environmental effect of human transportation by replacing fossil fuels. However, the current bottleneck for the low-temperature polymer membrane fuel cells that dominate the fuel cell vehicle market is the sluggish kinetics of the oxygen reduction reaction (ORR) at the cathode. The slow ORR kinetics significantly reduce the efficiency of chemical-electrical energy conversion. Similarly, hydrogen production …

Identifying Particulate Matter Spatial Variation In The El Paso Del Norte Region Using Land-Use Regression Modeling And Data Obtained From A Network Of Low-Cost Sensors, Leonardo Demetrio Vazquez-Raygoza

Open Access Theses & Dissertations

The emergence and rise in popularity of low-cost sensors for atmospheric observation aresetting a new precedent in identifying emission hotspots and providing high-resolution spatial and temporal data. Furthermore, low-cost sensors are becoming popular among institutions and the public, allowing community scientists to become more involved in air quality monitoring. However, concerns about the accuracy and precision of low-cost sensors have been questioned. Most recent research has focused on the utility of real-time monitoring and calibration requirements for these sensors. A low-cost monitoring project has deployed sensors in the El Paso del Norte region in low and high annual average daily …

Radio Frequency Fingerprinting And Its Application To Scada Environments, Evan White

Open Access Theses & Dissertations

With the introduction of IoT into ICS and smartgrid environments there has been a mod-ernization of communication protocols through the internet. This has led to the use of features such as TCP/IP but with it comes modernized attack vectors against these sys- tems. These attacks can be Man In the Middle (MITM), rogue device communication and device cloning. To prevent these attacks, this thesis deploys Radio Frequency Fingerprint- ing (RFF) techniques to verify the uniqueness and legitimacy of known devices. It is crucial to employ security measures within ICS that do not add to the network complexity as this effects …

Applications Of Micro-X-Ray Fluorescence (Μxrf) Techniques To Ore Formation Questions In Economic Geology, Hannah Adwoa Buamono

Open Access Theses & Dissertations

Advances in x-ray optics over the past decade have enabled a new generation of benchtop micro energy-dispersive x-ray fluorescence (µXRF/EDS) instruments to analyze samples with an x-ray spot size of 25 microns or less and detection limits of tens to hundreds of parts per million. The analysis of samples from mineral (ore) deposits may illustrate some of the capabilities and limitations of these instruments applied to geoscience problems. The qualitative elemental analysis process allows the production of detailed elemental maps which, together with line scan profiles and other petrographic and geochemical evidence, leads to a better definition of key chemical, …

Time Series Classification With Multistage Modeling Using Deep Learning, James Arthur

Open Access Theses & Dissertations

Time series classification (TSC) can be efficiently implemented with several techniques. Many techniques are based on analyzing 1-D signals in the time series data. In this work, we make an intrinsic analytical implementation of a new time series classification that involves a two-stage process. Firstly, by using Recurrence Plots (RP), we transform the time series into 2D images. The second stage consists in taking advantage of deep learn- ing models to perform our classification. The image illustration of time series introduces different feature types that are not available for all 1D signals, and therefore our classifi- cation problem is treated …

Transportation Asset Management For The Electric Road System, Kamalen Maria Santos Diaz

Open Access Theses & Dissertations

Electric road systems (ERS) have been presented as a new solution towards a sustainable transportation future, fueling the widespread adoption of electric vehicles by eliminating range anxiety, reducing battery size, and being regional friendly. These systems consist of four components: electric power supply, roads, vehicles, and operations. Much of the early research conducted on ERS has been on how to initially construct these systems by focusing on the first three components, however, there is limited knowledge on how ERS will impact traditional road operations after the systems are in place. Transportation Asset Management (TAM), a major focus within the transportation …

Online/Incremental Learning To Mitigate Concept Drift In Network Traffic Classification, Alberto R. De La Rosa

Open Access Theses & Dissertations

Communication networks play a large role in our everyday lives. COVID19 pandemic in 2020 highlighted their importance as most jobs had to be moved to remote work environments. It is possible that the spread of the virus, the death toll, and the economic consequences would have been much worse without communication networks. To remove sole dependence on one equipment vendor, networks are heterogeneous by design. Due to this, as well as their increasing size, network management has become overwhelming for network managers. For this reason, automating network management will have a significant positive impact. Machine learning and software defined networking …

Application Of Flo-Sic To F-Electron Systems: Sixth Row Elements And Ligated Molecules, Alexander Irun Johnson

Open Access Theses & Dissertations

Density functional theory - the most widely used theoretical method to study atoms,molecules, and solids - suffers from the well-known self-interaction error. A solution to the problem was suggested by Perdew and Zunger [1], who showed the self-interaction error can be removed with self-interaction correction. In 2014, Pederson showed a unitary transformation can be performed on the Kohn-Sham orbitals to generate Fermi-Löwdin orbitals which improve atomization energies, and avoid the computational costs of solving the localization equations.[2] This method is known as the Fermi-Löwdin Orbital Self-Interaction Correction (FLO-SIC). Until now, the FLO-SIC methodology has been used for atoms not containing …

A Case Study In Design, Construction, And Operation Of A Meromictic Solar Pond In Texas, Usa, Bianca Paola Meneses Brassea

Open Access Theses & Dissertations

Over the last four decades, meromictic solar ponds have been the subject of limnological studies and engineering research. A case of practical interest is the salinity gradient solar pond (SGSP). SGSP science and technologies have been systemically advanced in El Paso, Texas. This dissertation aims to share lessons learned in designing, constructing, and operating the El Paso Solar Pond, a NaCl-based solar pond that achieved high-temperature performance over two decades, commencing in 1984. Many of the practical lessons learned have not been published and are thus not readily available in archival journals, and this contribution provides a remedy. The value …

Hydrothermal Alteration Targeting And Geophysical Mineral Exploration Of Eureka And Sylvanite Mining Districts, Southwest New Mexico, Kenneth Singh

Open Access Theses & Dissertations

As part of the southwestern North American porphyry copper province, mining of natural resources in New Mexico has historically played a crucial role in economic development for over 150 years including this project area in the Little Hatchet Mountains. The northern half of the Little Hatchet Mountains lies in Grant County and includes the Eureka Mining District (EMD) whereas the southern half is in Hidalgo County and includes the Sylvanite Mining District (SMD), 38 miles southeast of Lordsburg. The EMD, a copper and silver-lead mining district from 1880-1961, had a total estimated production from the Laramide veins of 2.9 million …

Insights On The Behavior Of Nano-Copper In The Agroecosystem: Mycorrhizal Associations With Spearmint (Mentha Spicata), Suzanne Annette Apodaca

Open Access Theses & Dissertations

Nanotechnology offers significant potential benefits to our society, including the agriculture sector. With the advancement of nano-enabled agrochemicals towards sustainable and efficient agricultural practices, it is essential to address environmental issues associated with the use of nanoscale materials. The same properties that give promise to applications of nanotechnology in modern agriculture could have unintended consequences on ecosystem dynamics. A point of concern for risk management is the impact of engineered nanomaterials (ENMs) to beneficial microbial communities, which support a variety of ecosystem services.

Use of copper (Cu) products in agriculture are based on their abundance, role as a micronutrient, and …

Spectroscopic Study Of Bi5ti3feo15 Aurivillius Compound For Multifunctional Applications, Mariana Castellanos

Open Access Theses & Dissertations

No abstract provided.

Oil Particle Analysis Using Machine Learning And Holography Imaging, Daniel Cruz

Open Access Theses & Dissertations

Holographic cameras show potential as a sensor to monitor oil spills. Holographic cameras record the light interference from particles in a volume of space, producing an image called a hologram. Processing these holograms is known as hologram reconstruction. It produces a representation of particles located in three-dimensional space. These cameras can record precise shapes and sizes of particles in a volume of water. However, it is very time-consuming and resource-intensive to process the images. Most algorithms that perform particle analysis require the hologram reconstruction step. The well-documented hybrid method is one such algorithm. Machine learning is one possible technique that …

Direct Ink Write And Thermomechanical Characterization Of Thermoset Composites, Sergio Dante Favela

Open Access Theses & Dissertations

This research will be divided into two sections. The first section discusses direct ink writing and thermomechanical characterization for thermoset composites. The thermoset ink is prepared with fillers aiding the printing process by modifying the rheology of the ink and geometry retention by allowing for the part to have an initial UV cure step. Three specimen formulations with different weight percentages were printed by material extrusion in the shape of tensile specimens following ASTM standard D638 to characterize the mechanical properties at room temperature, 100â?? and 200â??. Furthermore, the ink resin was characterized through DSC, TGA, and rheology testing. The …

Infiltration-Controlled Combustion Of Lithium And Magnesium Powders And Reactions Of Lithium With Oxygen And Carbon Dioxide, Kevin Samuel Estala Rodriguez

Open Access Theses & Dissertations

Chemical heat integrated power systems are of great interest for space missions where solar energy, nuclear energy, and batteries are not available or are not practical to use. A new concept of a power system is a metal combustor coupled with a chemical oxygen generator, where the generated oxygen infiltrates through the metal powder or combustion products. The combustion of lithium and magnesium powders under these conditions has not been studied yet. The present work investigates combustion of magnesium powder and stabilized lithium metal powder (SLMP) ignited by a laser inside a closed chamber filled with O2 or CO2. It …

Sulfonated Styrene Grafted Sebs/Abs Made By Additive Manufacturing For Ion Exchange Applications, Avianna Elaine Gallegos

Open Access Theses & Dissertations

An interpenetrating polymer network (IPN) for cation exchange applications was synthesized from a blend of styrene-ethylene/butylene-styrene (SEBS) and acrylonitrile butadiene styrene (ABS), which was 3D printed, grafted with crosslinked polystyrene (PS), and sulfonated. A method for styrene grafting was applied to reduce the damage to polymer phases caused by the sulfonation reaction. Styrene and divinylbenzene monomers were introduced to the IPN and induced with heat treatment to polymerize in situ. The graft copolymerization reaction was enhanced with varying quantities of benzoyl peroxide as a chemical initiator. The samples were subsequently sulfonated with chlorosulfonic acid in dichloroethane and functionalized for ion …

Black And Brown Carbon Optical Characterization In The El Paso - Ciudad Juarez Airshed, Pamela I. Lara

Open Access Theses & Dissertations

Black (EBC) and Brown (BrC) Carbon are ubiquitous constituents of atmospheric particulate matter that affect peopleâ??s health, disrupt ecosystems, and modulate local and global climate. Tracking the local deposition and sources of these aerosol particles is essential to better understanding their multidimensional environmental impact. The main goal of the current study is to measure the absorption coefficient (Babs) of particles within the Planetary Boundary Layer (PBL) of the El Paso (US)–Ciudad Juárez (Mexico) airshed and assess the contribution of black and brown carbon particles to the total optical absorption. Measurements were taken during winter (January, 2022), spring (May, 2022), and …

Synthetic Data Generation For Intelligent Inspection Of Structural Environments, Noshin Habib

Open Access Theses & Dissertations

Automated detection of cracks and corrosion in pavements and industrial settings is essential to a cost-effective approach to maintenance. Deep learning has paved the path for vast levels of improvement in the area. Such models require a plethora of data with accurate ground truth and enough variation for the model to generalize to the data, which is notwidely available. There has been recent progress in computer graphics being used for the creation of synthetic data to address the issue of deficient data availability, but it is limited to specific objects, such as cars and human beings. Textures and deformities within …

Modulation Of Non-Diffracting Hermite Gaussian Beams And Nonlinear Optical Microscopy For Nanoscale Sulfur Imaging, Gilberto Navarro

Open Access Theses & Dissertations

Hermite Gaussian beams are the solutions of the scalar paraxial wave equation in Cartesian coordinates. A method was developed to modulate the intensity profile of non-diffracting Hermite Gaussian (HG) beams. The original HG beamâ??s intensity profile consists of high intense corner lobes and low intense central lobes which is not ideal for structured illumination in light-field microscopy. The modulated HG beams were generated by multiplying the original HGâ??s beam envelope by a super-Gaussian envelope to modify the intensity profile to attain equal intensity lobes. The propagation of the original HG beam and modulated HG beam were compared to determine that …

Metrological Challenges Of Practical Computer-Enhanced Measurements, Hector Alejandro Reyes

Open Access Theses & Dissertations

As technology progresses, sensors and computers become cheaper, so we can afford to perform more measurements and process the data faster. However, this also brings challenges.The goal of this thesis is to enumerate these challenges and to provide possible solutions. The first challenge is related to the fact that the existing metrological recommendations are mostly based on the previous practice, when we could only afford to have a small number of measurements. In this regard, our objective is to describe the related problem and to propose a solution to this problem. These description (on the example of the design of …

Fabrication And Characterization Of Iron-Based Catalysts For The Dehydrogenation Of Fossil Fuels, Victoria Isabel Reyes

Open Access Theses & Dissertations

For a prosperous and sustainable future, hydrogen is an encouraging solution due to its simple transition for industrial decarbonization and synergy for economic development. Paradoxically, current hydrogen production pathways release substantial amount of greenhouse gases into the atmosphere contributing to climate change. To keep up with increasing demand, hydrogen could be produced through microwave-assisted thermocatalytic dehydrogenation of fossil fuels without emitting carbon dioxide. This requires specified catalysts to meet the requirements of hydrogen yield and selectivity. The objective of the present research is to fabricate, characterize, and compare iron-based alumina (FeAl_x O_y) catalysts produced via solution combustion synthesis and iron-based …

Classification Of Nuclear Pastas Through Alpha Shapes Model, Daniela Ramirez Chavez

Open Access Theses & Dissertations

The nuclear pasta is important because is an astromaterial with incredible strength that may be a source for gravitational waves, which observe from the rotation of neutron stars. The characterization of the pasta is vital because the nuclear phases have transport properties - compressibility, neutrino opacity, thermal conductivity, and electrical conductivity - associated with their shape for which neutron stars may be sensitive. These properties could interpret observations of supernova neutrinos, magnetic field decay, and crust cooling of accreting neutron stars. Here, we study the nuclear pasta using alpha shapes to achieve a phase characterization with the Minkowski functionals (area, …

Magnetic Structures Of Sawtooth Olivines Mn2six 4 (X = S, Se) Determined Through Neutron Powder Diffraction, Melaku Sisay Tafere

Open Access Theses & Dissertations

In olivine chalcogenide Mn2SiX 4 (X = S, Se) compounds, the Mn lattice produces a sawtooth, which is of critical significance in magnetism due to the potential for manifesting at bands in the magnon spectrum, a crucial component in magnonics. The compounds Mn2SiS4 and Mn2SiSe4 in Mn2SiX 4 family undergo antiferromagnetic phase transitions at T â?? 85 K and â?? 66 K, respectively, as determined from the specific heat, Cp(T). The average and local crystal structuresare determined using synchrotron X-ray, neutron diffraction, and X-ray total scattering data followed by Rietveld and pair distribution function (PDF) analysis. It is found from …

Using Ground Penetrating Radar To Investigate Controls On Pedogenic Calcium Carbonate Distribution In Dryland Critical Zones, Nohemi Valenzuela Garay

Open Access Theses & Dissertations

Caliche or pedogenic calcium carbonate (CaCO3) layers are a common feature of arid soils, but the environmental controls on their distribution are not fully understood. Caliche layers are thought to play an important role in shallow subsurface water storage and movement, due to their water retention capacity and ability to impede vertical water transport (Hennessy et al., 1983). Therefore, caliche distribution and stability play a role in controlling water distribution in arid lands. However, due to its largely subsurface nature, caliche can be difficult to investigate and map without significant effort. I hypothesize that noninvasive geophysical methods, such as ground-penetrating …