Physical Sciences and Mathematics Commons^™

Incorporating Sustainability Into Urban Infrastructures: The Tension Between Bio-Cultural Aspects And Environmental Considerations, Shane Epting

Open Access Theses & Dissertations

The following arguments focus on how to think about sustainability as it relates to technology and the non-human world within an anthropocentric framework. We end up with a picture showing that humankind needs to change the ways in which we look at anthropocentric concerns. Secondly, the discussion that leads up to the final picture details the urgency that guides the thinking behind the implementation of sustainability. Because, as the West learns to live in an entirely new sense that is consistent with holding humankind's desire for existence as a permanent situation, one finds that this notion must be paramount for …

A Third-Order Non-Oscillatory Finite-Volume Transport Scheme For Atmospheric Modeling, Kiran Kumar Katta

Open Access Theses & Dissertations

Atmospheric numerical modeling has been going through drastic changes over the past decade, mainly to utilize the massive computing capability of the petascale systems. This obliges the modelers to develop grid systems and numerical algorithms that facilitate exceptional level of scalability on these systems. The numerical algorithms that can address these challenges should have the local properties such as the high on-processor operation count and minimum parallel communication i.e. high parallel efficiency, it should also satisfy the following properties such as inherent local and global conservation, high-order accuracy, geometric flexibility, non-oscillatory advection, positivity preservation.

In the present work, A Third-order …

Assessment Of Intra-Urban Traffic-Related Air Pollution On Asthmatic Children's Exposure At Schools In The Paso Del Norte Region, Amit Ugamraj Raysoni

Open Access Theses & Dissertations

Traffic-related air pollution can be a major public health concern in any urban area. This problem is compounded in the Paso del Norte region that has experienced rapid economic growth, and a substantial number of people living in close vicinity of major roadways. The desert surroundings, arid weather, frequent temperature inversions, heavy border traffic at the international ports of entry between El Paso and Ciudad Juárez, and poorly maintained vehicle fleet further exacerbates this problem. A growing body of air quality and epidemiologic research has discerned the linkage between traffic emissions and respiratory disorders.

Initial health investigations in the Paso …

The Exploratory Value Of Agent-Based Models In Social Science, Ricardo Andress Rivera

Open Access Theses & Dissertations

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A Sparse Representation Technique For Classification Problems, Reinaldo Sanchez Arias

Open Access Theses & Dissertations

In pattern recognition and machine learning, a classification problem refers to finding an algorithm for assigning a given input data into one of several categories. Many natural signals are sparse or compressible in the sense that they have short representations when expressed in a suitable basis. Motivated by the recent successful development of algorithms for sparse signal recovery, we apply the selective nature of sparse representation to perform classification. In order to find such sparse linear representation, we implement an l₁-minimization algorithm. This methodology overcomes the lack of robustness with respect to outliers. In contrast to other classification …

Algorithms For Training Large-Scale Linear Programming Support Vector Regression And Classification, Pablo Rivas Perea

Open Access Theses & Dissertations

The main contribution of this dissertation is the development of a method to train a Support Vector Regression (SVR) model for the large-scale case where the number of training samples supersedes the computational resources. The proposed scheme consists of posing the SVR problem entirely as a Linear Programming (LP) problem and on the development of a sequential optimization method based on variables decomposition, constraints decomposition, and the use of primal-dual interior point methods. Experimental results demonstrate that the proposed approach has comparable performance with other SV-based classifiers. Particularly, experiments demonstrate that as the problem size increases, the sparser the solution …

Nummulites Biofabrics As Tool For Quality Evaluation Of The Eocene Jdeir Formation Reservoirs Nw Offshore, Libya, Abdusalam Ali Agail

Open Access Theses & Dissertations

The southern Tethys margin constitutes an important hydrocarbon reservoir. It is formed mainly of Nummulite rich facies of the Jdeir Formation deposited during the Eocene epoch (Late Ypresian age) in the giant El-Bouri oil field-Sabratah Basin-NW Libya. Deposits of the Jdeir Formation directly overlay the Jirani dolomite and Bilal Formation, and unconformably underlay the Tellil Group and Ghallil Formation.

Nummulite accumulations are good indicators for hydrocarbon studies and they have been targets for numerous studies around the world. Nummulite "Large foraminifera" tests are usually identified by two forms: A-form and B-form. Previous studies have highlighted many different aspects of foraminifers …

A Bland–Altman Comparison Of The Lead Care® System And Inductively Coupled Plasma Mass Spectrometry For Detecting Low-Level Lead In Child Whole Blood Samples, Christina Sobin, Tanner Schaub, Natali Parisi, Eva De La Riva

Selected Works Temporary Series

Chronic childhood lead exposure, yielding blood lead levels consistently below 10 μg/dL, remains a major public health concern. Low neurotoxic effect thresholds have not yet been established. Progress requires accurate, efficient, and cost-effective methods for testing large numbers of children. The LeadCare® System (LCS) may provide one ready option. The comparability of this system to the “gold standard” method of inductively coupled plasma mass spectrometry (ICP-MS) for the purpose of detecting blood lead levels below 10 μg/dL has not yet been examined. Paired blood samples from 177 children ages 5.2–12.8 years were tested with LCS and ICP-MS. Triplicate repeat tests …

Characterization Of Mantle/Crust Interactions Using Pb Isotope Analyses Of Lavas In The Southern Rio Grande Rift, New Mexico, Lynnette Crocker

Open Access Theses & Dissertations

The Pb isotope composition of volcanic rocks in the Rio Grande Rift (RGR) can be used to investigate the interaction of mantle melts with continental lithosphere, and has important implications for the composition of the lithosphere. We suggest some compositional signatures may pre-date current tectonic processes. Existing data from several volcanic fields in New Mexico show a converging pattern on a very limited Pb isotope range, corresponding to lower crustal xenolith compositions from Kilbourne Hole. The different volcanic fields show Pb isotope trends diverging from this lower crustal composition, likely depicting mixing with different upper crustal reservoirs. These very common, …

Chromium(Iii/Vi) Binding To Magnetite (Fe3o4), Hausmannite (Mn3o4), And Jacobsite (Mnfe2o4) Nanomaterials, Jeffrey Edward Hernandez

Open Access Theses & Dissertations

Chromium is a very versatile metal that is used for many applications in the world. Two of the most common ions of chromium that occur naturally are Cr(III) and Cr(VI). These two oxidation states have very different heath effects in living organisms. Cr(III) is relatively non-toxic to living organisms; however, Cr(VI) is very toxic to most living organisms This study was conducted to find a simple and cost effective method to sequester these two common ionic species of chromium from sources of water that are adjacent to or that are affected by other water sources contaminated by these two ions. …

On Relational Quantum Mechanics, Oscar Acosta

Open Access Theses & Dissertations

A problem facing quantum mechanics is that there are a number of views or interpretations available that purport to 'explain' quantum mechanics. In this paper I discuss and analyze the view of relational quantum mechanics by Carlo Rovelli in the context of theoretical underdetermination. I will show that even though Rovelli offers a view that consolidates some of the aspects of competing theories it still falls short of breaking out of the theoretical underdetermination. The criteria that I have used to consider a theory successful in this context is one that increases the predictive output of quantum theory. Lacking an …

Bayesian Nonparametric Regression With A Flexible Error Term Distribution, Courtney Marie Barnes

Open Access Theses & Dissertations

Datasets often exhibit heavy tailed behavior and standard analyses are often heavily influenced by outliers. We propose a nonparametric regression model whose error term distribution is a mixture of a normal and a Student t distribution. This results in a model that is more resistant to outliers compared to a model with a normal error term.

Identifying Influential Observations Through The Intraclass Correlation Coefficient, Angel De Jesus Davalos

Open Access Theses & Dissertations

In this thesis, we analyze the performance of adapting the DFBETA statistic for identifying influential observations on the intraclass correlation coefficient under the assumptions of the one-way random effects model. Additionally, we introduce an approach for transforming negative intraclass correlation coefficient estimation values using the method of moments estimator. We apply this method on a data set of repeated blood pressure measurements, after which we will investigate implications of identifying influential observations.

A New Green Chemistry Method Based On Plant Extracts To Synthesize Gold Nanoparticles, Milka Odemariz Montes Castillo

Open Access Theses & Dissertations

Extraordinary chemical and physical properties exhibited by nanomaterials, as compared to their bulk counterparts, have made the area of nanotechnology a growing realm in the past three decades. It is the nanoscale size (from 1 to 100 nm) and the morphologies of nanomaterials that provide several properties and applications not possible for the same material in the bulk. Magnetic and optical properties, as well as surface reactivity are highly dependent on the size and morphology of the nanomaterial. Diverse nanomaterials are being widely used in molecular diagnostics as well as in medicine, electronic and optical devices. Among the most studied …

Pwisegen: A Genetic Algorithms-Based Framework For Pairwise Test Set Generation, Pedro Flores

Open Access Theses & Dissertations

Pairwise testing is a combinatorial testing approach that can be used to reduce the number of test cases dramatically for a software system. It specializes in the type of testing where the outcome of a system depends on the combination of several input parameters. This technique is widely used when there is not enough time to try out all possible combinations of the input parameters involved, because that would be very time consuming. The purpose of pairwise testing technique is to avoid testing all possible value combinations that a system can receive, and to preferably take a representative sample of …

A New Photochemical Method For The Preparation Of Amino Acid-α-Phenylthioesters And Peptide-α-Phenylthioesters, Tyrone Hogenauer

Open Access Theses & Dissertations

We describe the development of a novel resin with a photoreactive N-acylnitroindoline linker that allows for the synthesis of amino acid- (in solution) or peptide-α-thioesters using standard Fmoc/t-Bu standard solid phase peptide synthesis (SPPS). Recent advances have shown that the yields of this thioesterification reaction have dramatically increased due to a simple change in the order of addition of reagents. Upon illumination with UV-light, in the presence of N-hydroxybenzotriazole (HOBt), the amino acid- or peptide-α-OBt ester is generated by direct photo-release from the nitroindoline linker with minimal epimerization, followed by reaction with thiophenol in the dark to produce amino acid-α-phenylthioesters …

Ontology-Driven Discovery Of Scientific Computational Entities, Pearl W. Brazier

Open Access Theses & Dissertations

Many geoscientists use modern computational resources, such as software applications, Web services, scientific workflows and datasets that are readily available on the Internet, to support their research and many common tasks. These resources are often shared via human contact and sometimes stored in data portals; however, they are not necessarily available for metadata annotations that can assist in collaborative research or machine processing. Scientists' knowledge of their resources and processes are at risk of being lost. A scientist-driven discovery environment, which assumes a level of technical expertise generally possessed by a geoscientist, is needed to enable discovery and comparisons of …

Enthalpies Of Mixing Of Water And Alkoxyethanols, John Enriquez

Open Access Theses & Dissertations

Alkoxyethanols [C_mH_2m+1·(OC₂H₄)·OH] (conveniently abbreviated to C_mE₁) are a subgroup of the alkyl poly(ethylene glycol) mono-ethers. They are small relatives of a large number of non-ionic detergents. The thermodynamic properties of their mixing in water have been shown to be good sources of information about the interactions of both hydrophilic and hydrophobic groups with water. Theses alkoxyethanols, or glycol ethers, are the ether derivatives of ethylene glycol where one hydroxyl functional group is substituted for an alkoxy functional group. Our group has already published results for aqueous excess properties …

Understanding The Promotion Effect: A Density Functional Theory Study Based On High Resolution Transmission Electron Microscopy Images For Mos2-Cobalt Promoted Interfaces, Manuel A. Ramos

Open Access Theses & Dissertations

Many studies had been done in order to understand promotion effect and structure/function in unsupported catalyst. Results indicated that d-electrons play an important role promoting catalytical active sites at the edges of MoS2 catalytically structures. Sulfur removal from crude oil, occurs on the edge of molybdenum di-sulfide (MoS2) nano structures, due to promotion of MoS2 nano structures with nickel or cobalt in sulfur-terminated or molybdenum-terminated edge planes. The promotion leads to formation of so-called CoMoS phase (MoS2/Co9S8) first discovered by meaning of Mössbauer spectroscopy, much more CoMoS phase usually called unsupported catalytical particles, have been topic of great interest in …

Iron And Manganese Based Nanomaterials For The Removal Of Selenite And Selenate From Aqueous Solution, Christina Marie Gonzalez

Open Access Theses & Dissertations

Selenium, a naturally occurring element in the environment, is an essential nutrient for humans and animals. However, there is a narrow range between selenium deficiency and toxicity. Selenium in natural waters generally has a concentration of < 10 ppb (parts per billion); however, in the San Joaquin Valley of California concentrations of selenium ranging from 140 to 1400 ppb have been observed. Anthropogenic practices such as agricultural irrigation drainage, coal burning power plants, combustion of fossil fuels, and mining operations are increasing selenium concentrations in aqueous environments. Once in aqueous environments, selenium exists primarily as the two inorganic oxoanions selenite (SeO32-) and selenate (SeO42-). Both of these selenium oxoanions are known to bioaccumulate and can cause embryotoxic and teratogenic effects to waterfowl. There has been a variety of treatment technologies developed for remediation of both selenium oxoanions in water including bacterial reduction, membrane filtration, chemical reduction, reverse osmosis, and solar ponds. However, these treatment technologies are not cost efficient. In this study an alternative treatment technique known as adsorption was used with three synthetic nanomaterials consisting of an iron oxide, manganese oxide, and an iron/manganese oxide. The pH profiles, time dependencies, competitive anion effects, and adsorption isotherms were performed with each of the nanomaterials for both selenite and selenate. In addition, X-ray absorption spectroscopy (XAS) studies were performed to determine both the oxidation state and binding coordination of the selenium oxoanion binding to the nanomaterials.

The investigation revealed the non microwave-assisted and microwave-assisted synthetic Fe3O4 and Mn3O4 nanomaterials, as well as the non microwave-assisted synthetic MnFe2O4 nanomaterial had the phases of magnetite, hausmannite, and Jacobsite, while the grain sizes were 27, 25, 25, 34, and 27 nm, respectively. The optimal binding of selenium oxoanions for all nanomaterials examined was reached at pH 4. Both non microwave-assisted and microwave-assisted Fe3O4 …

Modeling Geographic Awareness Of Road Networks For Consistency Verification, Ari Kassin

Open Access Theses & Dissertations

Problems related to transportation and inspection of valuable or sensitive assets such as commercial products and materials, cultural items and works of art, and hazardous materials share similarities and can be modeled by a core set of abstract entities including a payload, a vehicle, a driver, and an inspector. To make the load handling capabilities of security monitoring and inspection systems more scalable, security can be increased by reducing the variability of transportation routes to a finite set of authorized routes between trip origin and destination locations. Then trip anomalies, which are unexpected trip variations, can be used in inspection …

Microstructure And Property Evaluation Of Lifepo4 Thin Films For Application In Microbatteries, Jose Marcos Mares

Open Access Theses & Dissertations

The shortage of fossil fuels and the requirements to produce clean, environmental friendly, efficient, and economical energy are the principal problems in the context of energy technology for current and future generations. Therefore, advanced energy storage and conversion capabilities with higher capacity and efficiency are desired. Currently, there is an enormous interest in the development of high energy density rechargeable batteries for use in domestic applications, automotive industries and portable electronic applications. The present research focuses on the development of LiFePO4 thin films for solid-state thin-film microbatteries. The present effort was performed with a specific purpose of understanding the effect …

Test Case Automation For Specification Patterns System And Composite Propositions, Cuauhtemoc Munoz

Open Access Theses & Dissertations

Specifying software properties is a common activity in the software development process. Software properties are often written in a natural language such as English. However, the ambiguity in natural languages makes validation and verification time-consuming and error-prone. Specifying software properties in formal languages such as Linear Temporal Logic (LTL) or Computation Tree Logic (CTL) enables the use of formal verification tools such as model checkers. Nevertheless, formal languages require software developers to have a strong background in mathematics and logic.

The specification Patterns System (SPS) and Composite Propositions (CPs) use a higher-level abstraction to specify software properties formally. The SPS …

The Impact Of Cartel Related Violence On Ongoing Traumatic Stress And Self-Medication In Young Adults Living Along The U.S./México Border, Thom J. Taylor

Open Access Theses & Dissertations

Ongoing Potentially Traumatic Stress (OPTS) as a result of violence and insecurity along the U.S./México border remains understudied. Many residents of the border may be both indirectly and directly exposed to potentially traumatic events on an ongoing basis, particularly in the city of Cd. Juárez, México. The present study examined the impact of the violence and insecurity on daily traumatic stress levels and the potential for self-medication via alcohol, cigarettes, and illicit drugs within Spanish speaking young adult residents and commuters to Cd. Juárez, Chihuahua, México. Participants (N = 121) completed multiple online reports of location in and travel to …

Rare's Implementation Strategies Of Environmental Conservation In Indonesia, Alvaro Arvizo

Open Access Theses & Dissertations

Like most developing nations, Indonesia is at a crucial stage in its modern political and economic history. Opposing forces are constantly at work, a government struggling to make Indonesia a modern nation and the economic demands of a growing population. This presents the country with a multitude of problems. One of several is that nature's resources are exploited for personal economic gain with no regard for the long-term effects. This is a major concern for environmental conservation and non-profit government organizations (NGOs) worldwide. The American NGO Rare is at the forefront of this issue. Its aim is to meet community …

Bagc.M: Three Dimensional Gravity Modeling Software With An Application In Death Valley, Ca, Brian Eugene Eslick

Open Access Theses & Dissertations

Basin Anomaly Gravity Calculator (BAGC.m) is a 3D interactive gravity modeling package designed to create, edit, and calculate the gravitational attraction of basin models entirely within the MATLABTM environment. Gravity anomalies are calculated using the Rectangular Prism Method (Bott, 1960; Kane, 1962; and Plouff, 1966) which subdivides earth models into regularly spaced rectangular prisms. This approach requires large 3D matrices to store most realistic earth models. The process of model editing is simplified by storing basins as 2D gridded files which define the depth to the boundary between basement rock and sedimentary fill for each model cell. In order to …

Studies Of Earthquakes Stress Drops, Seismic Scattering, And Dynamic Triggering In North America, Christian Rene Escudero Ayala

Open Access Theses & Dissertations

I use the Relative Source Time Function (RSTF) method to determine the source properties of earthquakes within southeastern Alaska-northwestern Canada in a first part of the project, and earthquakes within the Denali fault in a second part. I deconvolve a small event P-arrival signal from a larger event by the following method: select arrivals with a tapered cosine window, fast fourier transform to obtain the spectrum, apply water level deconvolution technique, and bandpass filter before inverse transforming the result to obtain the RSTF. I compare the source processes of earthquakes within the area to determine stress drop differences to determine …

Renewable Energy Integration: An Approach For Micro-Grid Optimization., Nicolas Lopez

Open Access Theses & Dissertations

This thesis explores the Renewable Energy Integration Problem beginning with a literature review on the different sources of electrical energy classified as Non-Renewable and Renewable, stating that the integration of renewable sources within the pre-existing Power-Grids is a current worldwide problem that is being addressed with different approaches.

The impossibility to exactly model the different equations relating the electric output of the renewable energy sources as they relate with meteorological factors, makes the renewable sector a stochastic component of the overall mathematical model, where it can be concluded that most of the problem is in the area of the forecast. …

Investigations Of Grade Control, Macarthur Mine, Yerington, Nevada: An Oxidized Porphyry Copper System, Joseph Daniel Louis Lori

Open Access Theses & Dissertations

Supergene enriched, low-grade oxidized porphyry copper deposits are of great economic value. Oxidized porphyry sections are economic targets because even low-grade prospects have the potential to produce low-cost copper in an environmentally friendly fashion due to easy leachability and high recovery rates of the oxide mineralization. The MacArthur Mine, in the historic Yerington mining district of Nevada, is the focus of this study. The MacArthur is a tilted oxidized porphyry deposit, partially mined by open pit methods, hosted in the Jurassic Bear Quartz Monzonite of the Yerington batholith. The objective of the study is to define controls of copper oxide …

A Gis-Based Emission And Air Quality Impact Assessment For Evaluating Transportation Mitigation Measures, Jose Maria Mares

Open Access Theses & Dissertations

The research presented here develops a framework that assesses a transportation project's air quality impact. The framework not only integrates transportation and emission modeling but also improves the accuracy of the emission estimates. In order to do this, the framework makes use of six modules: environmental conditions data input, GIS database, emission modeling, transportation network, post-processing, and graphical presentation. Each module aims to improve the quality and accuracy of the inputs used by MOBILE6.2. In addition, the framework has the capability, among other features, of presenting the emission estimates in a GIS-based modeling platform that enables the analyst to spatially …