Physical Sciences and Mathematics Commons^™

3d Robotic Sensing Of People: Human Perception, Representation And Activity Recognition, Hao Zhang

Doctoral Dissertations

The robots are coming. Their presence will eventually bridge the digital-physical divide and dramatically impact human life by taking over tasks where our current society has shortcomings (e.g., search and rescue, elderly care, and child education). Human-centered robotics (HCR) is a vision to address how robots can coexist with humans and help people live safer, simpler and more independent lives.

As humans, we have a remarkable ability to perceive the world around us, perceive people, and interpret their behaviors. Endowing robots with these critical capabilities in highly dynamic human social environments is a significant but very challenging problem in practical …

Study Of Ferroelectric Oxides And Field Effect In Complex Oxides Heterostructures, Lu Jiang

Doctoral Dissertations

With the rapid development of technology, the need for novel materials and state-of-theart devices is growing fast. Complex oxides which have strongly correlated electrons are favorable candidates for materials industry, due to their rich phase diagrams and multiple functions. Especially, ferroelectric oxides is very promising materials in the industry for storage, due to their bistable polarization states triggered by external electrical field. This thesis is centered on ferroelectric oxides, analyzing their lattice structures and investigating the interface of ferroelectrics and other complex oxides to examine the potential of the heteostructures in the application in electronic devices.

The most notable feature …

Atomic And Molecular Laser-Induced Breakdown Spectroscopy Above A Titanium Target, Alexander Charles Woods

Doctoral Dissertations

The goal of this research is to use optical emission spectroscopy to investigate the processes occurring subsequent to laser ablation of a titanium sample. Laser-induced breakdown spectroscopy provides a procedure for atomic and molecular identification for particular constituents of a laser-induced plasma. Atomic spectral line shapes provide a diagnostic tool for characterizing laser induced plasma, particularly within the first hundreds of nanoseconds. Molecular recombination and/or excitation of selected molecules can lead to simultaneous detection of atomic and molecular species via spectral analysis. Nonlinear fitting of synthetic molecular spectra, calculated via diatomic quantum theory, provides tools for identification, temperature measurement, and …

Theoretical Studies Of The Growth And Functionality Of Layered Materials, Wei Chen

Doctoral Dissertations

In this thesis, we present several projects on the growth and functionality of layered materials, using density functional theory (DFT) method and phenomenological modeling approach. Beyond the understanding of growth mechanisms and exploration of properties, we propose novel avenues to realize controllable growth processes and layered materials with desirable properties. The contents have three major parts:

(1) Graphene growth on Cu(111) and Ni(111) substrates. We first demonstrate that the inherent multi-orientational degeneracy of the graphene islands on Cu(111) in the early stages of nucleation could result in the prevalence of grain boundaries (GBs). Next, we propose a possible solution to …

New Remote Sensing Methods For Detecting And Quantifying Forest Disturbance And Regeneration In The Eastern United States, Michael Joseph Hughes

Doctoral Dissertations

Forest disturbances, such as wildfires, the southern pine beetle, and the hemlock woolly adelgid, affect millions of hectares of forest in North America with significant implications for forest health and management. This dissertation presents new methods to quantify and monitor disturbance through time in the forests of the eastern United States using remotely sensed imagery from the Landsat family of satellites, detect clouds and cloud-shadow in imagery, generate composite images from the clear-sky regions of multiple images acquired at different times, delineate the extents of disturbance events, identify the years in which they occur, and label those events with an …

Probing The Size Dependent Chemical Properties Of Metals In Reduced Dimension, Xiangshi Yin

Doctoral Dissertations

Heterogeneously catalyzed reactions typically start with adsorption and dissociation of reactant molecules on the surface of a solid catalyst. In many instances, this is followed by surface diffusion of the adsorbed species, chemical reaction, and removal of the product molecule. According to the Sabatier principle, optimal catalytic performance requires that the bonding between the adsorbate molecule and the surface should neither be too strong nor too weak. This bonding strength is directly related to the catalyst’s surface electronic structure and hence, electronic structure modification would seem a promising approach for tuning catalytic activity.

There have been many studies along this …

Quantum Tuning Of Plasmons In Ultrathin Metal Films, Ao Teng

Doctoral Dissertations

The surface plasmon is a coherent charge density oscillation localized at a metal surface. It can couple with light and the resulting plasmon-polariton hybrid mode is confined to volumes that are much smaller than the classical diffraction limit of light. Nano-plasmonics is a rapidly evolving field where light manipulation at the nanoscale may lead to novel applications. However, as the size of plasmonic devices approaches the quantum-size regime, the macroscopic picture of plasmon may no longer be valid. To elucidate the influence of the discretization of the single particle spectrum on the collective plasmon response, we performed a systematic study …

Characterizing The Relationship Of Part Of The Inner Piedmont And Pine Mountain Window, Georgia, From Detailed Geologic Mapping, Geochemistry, Geochronology, And Structural Analysis At The Southwestern End Of The Cat Square Terrane, Justin Randolph Rehrer

Masters Theses

Geologic investigations at the southwestern end of the Cat Square terrane (CSt) in central Georgia provided new insight into the complex tectonic history of the Pine Mountain window (PMw) and neighboring Inner Piedmont terranes. Detailed 1:24,000-scale geologic mapping of an approximately 180 km2 area near Barnesville, Georgia has provided the foundation for further geochemical, geochronologic, and structural analyses refining models for tectonic development and emplacement of the CSt and PMw.

Whole-rock geochemical analyses of several CSt amphibolites yielded data suggesting a continental back-arc setting for genesis of the Cat Square basin (CSb). Major element data confirm derivation from a basaltic …

The Isotope Effect On Proton Conduction And Glass Transition In Phosphoric Acid, Maximilian Ferdinand Heres

Masters Theses

Hydrogen fuel cells combine hydrogen and oxygen to create water and electricity. Polymer electrolyte membranes (PEM) make up barriers within the fuel cell allowing only protons to pass through, while keeping other components separate. Many PEM contain phosphoric acid (PA) as a building block due to its excellent proton conducting properties. Improved ionic conductivity in PEM can lead to the development of better, more efficient fuel cells.

While ionic conductivity in PA at high temperatures is extensively characterized, the low temperature dynamics are not so well explored. Below the glass transition, molecular motion is frozen and proton motion is forced …

Statistical Mechanics And Schramm-Loewner Evolution With Applications To Crack Propagation Processes, Christopher Borut Mesic

Masters Theses

Schramm-Loewner Evolution (SLE) has both mathematical and physical roots that extend as far back as the early 20th century. We present the progression of these humble roots from the Ideal Gas Law, all the way to the renormalization group and conformal field theory, to better understand the impact SLE has had on modern statistical mechanics. We then explore the potential application of the percolation exploration process to crack propagation processes, illustrating the interplay between mathematics and physics.

An Analysis Of The Suspended Sediment Rating Curve Parameters In The Upper Mississippi River Basin At The Monthly And Annual Levels, Vi Thi Tuong Tran

Masters Theses

Suspended sediment rating curve parameters were analyzed to investigate the relationship of suspended load and discharge in the Upper Mississippi River Basin (UMRB) at the annual and monthly levels. The rating curve parameters were obtained from the power function of load and discharge: Load = a × (Discharge)^b [(Discharge)^b]. The function was solved by ordinary least squares regression on its logarithmic form.

The annual rating coefficient a and exponent b ranged from 0 to 0.25 (kg/s)(s/m³)^b [(kg/s)(s/m^3)^b] and from 0.91 to 4.27, respectively. The monthly rating coefficient a and exponent b ranged from 0 to 0.239 …

Radiation-Induced Radicals In Polyurea-Crosslinked Silica Aerogel, Benjamin Michael Walters

Masters Theses

Free radicals are atoms or molecules with an odd number of electrons in an outer shell. Since electrons typically occur in pairs, this leaves one electron that is unpaired. In seek of another electron to pair with, free radicals react with and steal electrons from neighboring molecules, which then become free radicals themselves. This can start a chain reaction, cascading into large scale damage.

Ionizing radiation can tear through molecules, just as bullets can tear through things that we see. If free radicals can be detected, and seen to increase in a material upon radiation exposure, this can indicate molecular …

Calcitized Evaporites In The Precambrian: Deposition And Diagenesis In A Low Sulfate Ocean, Ashley René Manning Berg

Masters Theses

One of the most profound byproducts of the Great Oxidation Event (GOE) was the onset of oxidative weathering on land and the riverine delivery of sulfate to marine systems. The marine sulfur system therefore plays a critical role in reconstructing the oxygenation of the early Earth. Although the exact nature of marine oxygenation in aftermath of GOE remains uncertain, examination and modeling of marine sulfate suggest that sulfate concentrations remained below 2 millimolar (mM) until at least the middle Mesoproterozoic, and may have only reached about 10 mM in the latest Neoproterozoic. Such a low concentration of marine sulfate had …

Measuring Carbon Dioxide (Co2) Flux Of Agricultural Practices In Sub-Saharan Africa, Debra Blumberg O'Dell

Masters Theses

Agriculture has an important role in addressing two of the world’s most pressing problems: meeting global food demand and mitigating climate change. If agriculture is not practiced sustainably it will fail to meet future food demand and likely intensify the pace of global climate change. There are some agricultural practices, such as Conservation Agriculture, that can produce food sustainably and have the potential to mitigate climate change. However it is not clear which agricultural practices contribute to climate mitigation and by how much. By measuring the carbon dioxide (CO2) emissions of specific agricultural practices, the ability of practices to sequester …

Aluminum Monoxide Emission Measurements Following Laser-Induced Breakdown For Plasma Characterization, David Michael Surmick

Masters Theses

In this work, spectroscopic emissions from laser ablated aluminum samples are used to characterize the time dependent decay of laser-induced plasma. The plasma is created by tightly focusing nanosecond pulsed laser radiation. Time resolved measurements of the plasma are made with a gated, intensified linear diode array coupled to an optical multichannel analyzer and/or an intensified charged coupled device. Time resolution is achieved by synchronizing the laser with the measurement rate of the array detector.

Computed diatomic molecular aluminum monoxide emissions were used to infer the temperature of the plasma as a function of time. This was completed by comparing …

Comparison Of Triangle And Tetrad Discrimination Methodology In Applied, Industrial Manner, Sara Lyn Carlisle

Masters Theses

The triangle method has been widely used in the food industry for many years when conducting sensory discrimination testing. Recently, however, another discrimination testing method, the tetrad, has begun to gain popularity. Based on currently published research, the tetrad method possesses statistical advantages over the triangle and would require fewer panelists, reduce testing time, and use less sample material. More testing is needed to confirm these advantages in an applied, industrial approach on a wider range of products. Over thirty triangles and thirty tetrads with untrained panelists have been completed in order to compare the two methods. Products tested ranged …

Thick Target Yield Of Th-229 Via Low Energy Proton Bombardment Of Th-232, Justin Reed Griswold

Masters Theses

Actinium-225 is one of the more effective radioisotopes used in alpha radioimmunotherapy. Due to its ten-day half-life, it is more efficient to create its precursor, ²²⁹Th [Thorium-229] (t_1/2[half-life] = 7932 ± 55 years). In this work, ²²⁹Th was produced via 40 MeV [Mega electron Volts] proton bombardment of a thick ²³²Th [Thorium-232] target. The irradiation took place at the Holifield Radioactive Ion Beam Facility (HRIBF) at Oak Ridge National Lab (ORNL). The target, consisting of 23 stacked natural thorium foils (137 mg/cm² [milligrams per square centimeter] each), was irradiated with 50 nA [nanoamps] of …

Modeling Celiac Disease, Jillian M. Trask

Masters Theses

Those who suffer from Celiac Disease have an autoimmune response to the protein complex gluten. The goal of this work is to better understand the biological mechanisms in Celiac Disease through modeling with a system of ordinary differential equations. We first develop a model for the way in which gluten induces a response in zonulin in those with Celiac Disease and estimate parameters for such a model using limited data. We then extend this model to include the interactions between zonulin and the permeability of the intestine, and the effect of this interaction on the immune response. Finally, we perform …

Numerical Methods And Algorithms For High Frequency Wave Scattering Problems In Homogeneous And Random Media, Cody Samuel Lorton

Doctoral Dissertations

This dissertation consists of four integral parts with a unified objective of developing efficient numerical methods for high frequency time-harmonic wave equations defined on both homogeneous and random media. The first part investigates the generalized weak coercivity of the acoustic Helmholtz, elastic Helmholtz, and time-harmonic Maxwell wave operators. We prove that such a weak coercivity holds for these wave operators on a class of more general domains called generalized star-shape domains. As a by-product, solution estimates for the corresponding Helmholtz-type problems are obtained.

The second part of the dissertation develops an absolutely stable (i.e. stable in all mesh regimes) interior …

Models Linking Epidemiology With Immunology And Ecology, Eric Shu Numfor

Doctoral Dissertations

Optimal control can be used to design intervention strategies for the control of infectious diseases and predator-prey systems. In this dissertation, we studied models encapsulating two relatively new areas of mathematical biology, which combine epidemiology with immunology and ecology.

We formulated immuno-epidemiological models of coupled within-host model of ordinary differential equations and between-host model of ordinary differential equations and partial differential equations, using the Human Immunodeficiency Virus (HIV) for illustration, and set a framework for optimal control of immuno-epidemiological models. By constructing an iterative sequence from a representation formula for a solution to the linked model and using the fixed-point …

Multistep Kinetic Monte Carlo, Holly Nichole Johnson Clark

Doctoral Dissertations

Kinetic Monte Carlo (KMC) uses random numbers to simulate the time evolution of processes with well-defined rates. We analyze a multi-step KMC algorithm aimed at speeding up the single-step procedure and apply the algorithm to study a model for the growth of a surface dendrite. The growth of the dendrite is initiated when atoms diffusing on a substrate cluster due to lower hopping rates for highly coordinated atoms. The boundary of the cluster is morphologically unstable when the flux of new atoms is supplied in the far field, a scenario that could be generated by masking a portion of a …

Spatial Dynamic Models For Fishery Management And Waterborne Disease Control, Michael Robert Kelly Jr.

Doctoral Dissertations

As the human population continues to grow, there is a need for better management of our natural resources in order for our planet to be able to produce enough to sustain us. One important resource we must consider is marine fish populations. We use the tool of optimal control to investigate harvesting strategies for maximizing yield of a fish population in a heterogeneous, finite domain. We determine whether these solutions include no-take marine reserves as part of the optimal solution. The fishery stock is modeled using a nonlinear, parabolic partial differential equation with logistic growth, movement by diffusion and advection, …

A Study Of The Structure Of Light Tin Isotopes Via Single-Neutron Knockout Reactions, Andrew Franklin Ayres

Doctoral Dissertations

The region around 100 Sn [100Sn] is important because of the close proximity to the N=Z=50 magic numbers, the rp process, and the proton drip-line. Alpha decay measurements show a reversal in the spin-parity assignments of the ground and first excited states in 101 Sn [101Sn] compared to 105 Te [105Te]. However, the lightest odd- mass tin isotope with a firm spin-parity assignment is 109 Sn [109Sn]. The d 5/2 [d5/2] and g 7/2 [g7/2] single-particle states above N=50 are near degenerate, evidenced by the excitation energy of the first excited state in 101 Sn at only 172 keV. The …

Structural Dynamics And Charge Transport In Room Temperature Ionic Liquids, Philip James Griffin

Doctoral Dissertations

Room temperature ionic liquids are an important class of materials due to their chemical tunability and numerous advantageous physicochemical properties. As a result, ionic liquids are currently being investigated for use in a wide array of chemical and electrochemical applications. Despite their great potential, however, the relationship between the chemical structure and physicochemical properties of ionic liquids is not well understood.

To this end, this dissertation presents experimental studies of the reorientational structural dynamics and charge transport properties of a variety of room temperature ionic liquids using quasielastic light scattering spectroscopy and broadband dielectric spectroscopy.

Studies of a series of …

Data Analytics Of University Student Records, Mark Blaise Decotes

Masters Theses

Understanding the proper navigation of a college curriculum is a daunting task for students, faculty, and staff. Collegiate courses offer enough intellectual challenge without the unnecessary confusion caused by course scheduling issues. Administrative faculty who execute curriculum changes need both quantitative data and empirical evidence to support their notions about which courses are cornerstone. Students require clear understanding of paths through their courses and majors that give them the optimal chance of success. In this work, we re-envision the analysis of student records from several decades by opening up these datasets to new ways of interactivity. We represent curricula through …

Structure Analysis Of Sn Bilayer Films On Si (111), Weisong Tu

Masters Theses

Chemical doping is a well-established method for controlling the electronic properties of bulk semiconductors and, e.g, complex oxide materials. In this process, dopant atoms are located at substitutional lattice locations, from where they introduce free charge carriers to the host material. These carriers greatly improve the electrical conductivity of the host material and can even induce an insulator-metal transition at high doping levels. Dopants, however, also introduce scattering centers that are detrimental to conductivity, especially in low-dimensional systems such as nanowires and ultrathin films. These problems can be overcome by using a modulation doping approach in which the dopant atoms …

Mineralized Microbialites As Archives Of Environmental Evolution Of A Hypersaline Lake Basin: Laguna Negra, Catamarca Province, Argentina, Joy Buongiorno

Masters Theses

Environmental fluctuations related to climate, biological productivity, and evaporation can be recorded by sedimentary archives within lacustrine depositional systems. Sediments within terminal, closed-basin lakes are amongst the most sensitive paleoenvironmental indicators, and have great potential for permitting detailed reconstruction of environmental conditions via a variety of geochemical and isotopic proxies. Microbialites, however, have been largely overlooked as repositories of paleoenvironmental data. Here, we investigate mineralized microbialites within Laguna Negra, a high-altitude (4100 meters above sea level) hypersaline, closed-basin lake in the Argentinian Puna region and explore the potential recovery of environmental signals from these unique sedimentary archives. Mineralized microbialites within …

Cross Sections Spring/Summer 2014, Department Of Physics And Astronomy

Cross Sections

No abstract provided.

Mathematically Modeling Fetal Electrocardiograms, Samuel Estes, Kiersten Utsey, Erick Kalobwe

Pursuit - The Journal of Undergraduate Research at The University of Tennessee

Abstract

Some of the most common and fatal birth defects are those related to the heart. In adults, possible heart conditions are often identified through the use of an electrocardiogram (ECG). However, due to the presence of other signals and noise in the recording, fetal eletrocardiography has not yet proven effective in diagnosing these defects. This paper develops a mathematical model of three-dimensional heart vector trajectories, which was used to generate synthetic maternal and fetal ECG signals. The dipole model is a useful simplification in which the electrical activity of the heart is viewed as a single time-varying vector originating …

Vehicle Multi-Pass Rut Volume And Mobility Power Study, William W. Barbour

Pursuit - The Journal of Undergraduate Research at The University of Tennessee

This paper presents the relationship between applied power by a wheeled vehicle to soil and the rutting effects. Specifically, a strong positive relationship was found between cumulative applied power and total rut volume across multiple passes by the vehicle over the same tracks. Field-testing was conducted using a high-mobility multi-purpose wheeled vehicle (HMMWV) and two distinct soil types. Sensors on the vehicle measured torque and angular velocity of each of the four wheels, from which applied power was calculated. A rut profile meter was used to document the shape of the rut after set numbers of passes and this profile …