Physical Sciences and Mathematics Commons^™

High-Brightness Beamline For X-Ray Spectroscopy At The Advanced Light Source, Rupert C. Perera, G. Jones, Dennis W. Lindle

Chemistry and Biochemistry Faculty Research

Beamline 9.3.1 at the Advanced Light Source (ALS) is a windowless beamline, covering the 1-6 keV photon-energy range, designed to achieve the goals of high energy resolution, high flux, and high brightness at the sample. When completed later this year, it will be the first ALS monochromatic hard-x-ray beamline, and its brightness will be an order-of-magnitude higher than presently available in this energy range. In addition, it will provide flux and resolution comparable to any other beamline now in operation. To achieve these goals, two technical improvements, relative to existing x-ray beamlines, were incorporated. First, a somewhat novel optical design …

Design And Performance Of The Advanced-Light-Source Double-Crystal Monochromator, G. Jones, S. Ryce, Dennis W. Lindle, B. A. Karlin, J. C. Woicik, Rupert C. Perera

Chemistry and Biochemistry Faculty Research

A new “Cowan type” double-crystal monochromator, based on the boomerang design used at National Synchrotron Light Source (NSLS) beamline X-24A, has been developed for beamline 9.3.1 at the Advanced Light Source (ALS), a windowless ultrahigh vacuum beamline covering the 1-6 keV photon-energy range. Beamline 9.3.1 is designed to simultaneously achieve the goals of high energy resolution, high flux, and high brightness at the sample. The mechanical design of the monochromator has been simplified, and recent developments in technology have been included. Measured mechanical precision of the monochromator shows significant improvement over existing designs. In tests with x-rays at NSLS beamline …

Structure Of Woody Riparian Vegetation In Great Basin National Park, S. D. Smith, K. J. Murray, F. H. Landau, A. M. Sala

Life Sciences Faculty Research

The community composition and population structure of the woody riparian vegetation in Great Basin National Park are described. Community analyses were accomplished by sampling 229 plots along an elevational gradient of 8 major stream systems in the Park. TWINSPAN analysis identified 4 primary species groups that were characterized by Populus tremuloides (aspen), Abies concolor (white fir), Rosa woodsii (Woods rose), and Populus angustifolia (narrowleaf cottonwood) as dominants, respectively. Detrended Correspondence Analysis (DECORANA) showed that the most important environmental factors associated with the distribution of species were elevation and slope, with flood-related physiographic factors having a secondary effect. Analysis of size-class …

Baseline Water Quality Data Inventory And Analysis: Lake Mead National Recreation Area, Volume Ii Of Ii, National Park Service

Publications (WR)

This document presents the results of surface-water-quality data retrievals for Lake Mead National Recreation Area (LAME) from five of the United States Environmental Protection Agency's (EPA) national databases: (1) Storage and Retrieval (STORET) database management system; (2) River Reach File (RF3); (3) Industrial Facilities Discharge (IFD); (4) Drinking Water Supplies (DRINKS); and (5) Flow Gages (GAGES). This document is one product resulting from a cooperative contractual endeavor between the National Park Service's Servicewide Inventory and Monitoring Program, the National Park Service's Water Resources Division (WRD), and Horizon Systems Corporation to retrieve, format, and analyze water quality data for all units …

Baseline Water Quality Data Inventory And Analysis: Lake Mead National Recreation Area, Volume I Of Ii, National Park Service

Publications (WR)

This document presents the results of surface-water-quality data retrievals for Lake Mead National Recreation Area (LAME) from five of the United States Environmental Protection Agency's (EPA) national databases: (1) Storage and Retrieval (STORET) database management system; (2) River Reach File (RF3); (3) Industrial Facilities Discharge (IFD); (4) Drinking Water Supplies (DRINKS); and (5) Flow Gages (GAGES). This document is one product resulting from a cooperative contractual endeavor between the National Park Service's Servicewide Inventory and Monitoring Program, the National Park Service's Water Resources Division (WRD), and Horizon Systems Corporation to retrieve, format, and analyze water quality data for all units …

Structural Analysis Of The Hurricane Fault In The Transition Zone Between The Basin And Range Province And The Colorado Plateau, Washington County, Utah, Meg E. Schramm

UNLV Theses, Dissertations, Professional Papers, and Capstones

This study defines fault segments and segment boundaries along the Hurricane fault in southwestern Utah and determines the geometric and kinematic relationship to other regional structures. Fault segment identification is critical for understanding fault processes and seismic risk; segment length is the maximum earthquake rupture length along a fault. Segment boundaries may act as barriers to earthquake propagation.

Normal fault segmentation only recently has received attention and has never been studied along the Hurricane fault. The fault changes strike along its length, and is thus a segmented fault. This study documents one nonconservative segment boundary and two fault segments, the …

Drip Irrigation, An Adaptive Strategy, Heather A. Grant Digeorge

UNLV Theses, Dissertations, Professional Papers, and Capstones

Adaptation has always played a role in the survival of man. In today's Southwest we are quickly approaching a water shortage. Agriculture is the second largest user of water. One way to save water is by conservation. Drip irrigation would save vast amounts of water currently lost to inefficiency. Drip irrigation will become an option in the adaptation in agriculture.

Determining Recreational Visitor Carrying Capacity: The Case Of Black Canyon At Lake Mead National Recreation Area, Kenneth C. Forman

UNLV Theses, Dissertations, Professional Papers, and Capstones

Lake Mead and Lake Mohave, created by Hoover and Davis Dams respectively, were combined, along with much of the surrounding area, into the Lake Mead National Recreation Area in 1964. The enabling legislation is specific about the duty the National Park Service has to the public to create and maintain this, and other, national recreation areas for the benefit of the visitors, the environment, and future generations. By investigating human impacts on the physical environment (water quality, litter, etc.) and by querying park users on their opinions (with respect to crowding, visitor behavior, etc.), insight can be gained about appropriate …

Study Of Existing Information Concerning Water Quality Within Lake Mead, Vicki Scharnhorst, Southern Nevada Water Authority

Publications (WR)

The purpose of Task 010A15M of the Southern Nevada Water Authority (SNWA) Treatment and Transmission Facility (TTF) contract is to conduct a study of existing information concerning water quality within Lake Mead and identify additional water quality studies that are needed to supplement existing data. The objective of this task is not to discuss treatability of the raw water source; this is addressed by Task 010A18M, "Define Water Treatment Requirements." In addition, a narrative on the effect of pending Safe Drinking Water Act amendments and a determination of treated water quality goals is included in Task 010A16M, "Review Safe Drinking …

Identification Of Tire Leachate Toxicants And A Risk Assessment Of Water Quality Effects Using Tire Reefs In Canals, S. M. Nelson, G. Mueller, D. C. Hemphill, U.S. Bureau Of Reclamation

Publications (WR)

Cover is an important component of aquatic habitat and fisheries management. Fisheries biologists often try to improve habitats through the addition of natural and artificial material to improve cover diversity and complexity. Habitat-improvement programs range from submerging used Christmas trees to more complex programs using sophisticated artificial habitat modules. Used automobile tires have been employed in the large scale construction of reefs and fish attractors in marine environments and to a lesser extent in freshwater and have been recognized as a durable, inexpensive and long-lasting material which benefits fishery communities.

Recent studies by the U.S. Bureau of Reclamation have quantified …

Spectral Analysis Of The Flow Behavior Of Big Spring, Kings Canyon National Park, California, Linda Urzendowski

UNLV Theses, Dissertations, Professional Papers, and Capstones

Big Spring, the resurgence of a karst aquifer in the Lilburn Cave system (Kings Canyon National Park, California), displays the uncommon phenomena of ebb and flow discharge during periods of high runoff.

Hydrograph analyses indicate that the portion of Lilburn Cave between the Z-Room and Big Spring is primarily a conduit flow aquifer. The power spectra strongly indicate a nonlinear system, with evidence of quasi-linear behavior found on a smaller scale. The transfer and kernel function indicate that no additional significant inputs or outputs to the system exist. The bench-scale model built to simulate the ebb and flow cycles in …

The Geology Of The Tuff Of Bridge Spring: Southern Nevada And Northwestern Arizona, Shirley Ann Morikawa

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Tuff of Bridge Spring (TBS) is a regionally-widespread, andesite to rhyolite (59.50 to 74.91 wt. %) ash-flow tuff of mid-Miocene age (ca. 15.2 Ma) that is exposed in the northern Colorado River extensional corridor of southern Nevada and northwestern Arizona. Determination of the areal distribution, geochronology, lithology, geochemistry, and internal stratigraphy of the TBS is important for its establishment as a reliable stratigraphic reference horizon for tectonic reconstructions of the extensional corridor during the middle Miocene. Based on reoccurring patterns of major and trace element variation, the TBS is divided into constant Cr/variable SiO₂ and variable Cr/variable SiO …

Analysis And Evaluation Of The Workplace Exposure Assessment Workbook Developed By Keith Tait Including Some Recommended Revisions, Lisa Hebberd

UNLV Theses, Dissertations, Professional Papers, and Capstones

Some risk due to the contamination of workplace environments is an inevitable part of human lives. These risks can often be reduced by improving the control of environmental pollution in the workplace. An extremely important challenge for any industry is to develop a mechanism to identify acceptable levels of safety, or "acceptable risk" in the workplace for specific situations, and to assure adequate quality control over measured or calculated exposure concentrations and their possible contributions to adverse health effects.

Observation Of Non-Isotropic Auger Angular Distribution In The C(1s) Shape Resonance Of Co, Oliver Hemmers, Franz Heiser, J. Eiben, R. Wehlitz, U. Becker

Environmental Studies Faculty Publications

Angle-resolved high-resolution C(KVV) Auger spectra of CO were taken in the vicinity of the C(1s) σ^* shape resonance. These spectra show clear evidence for the theoretically predicted anisotropic K-shell Auger emission in molecules. Complementary results from angle-resolved photoion spectroscopy show that the small size of the observed effect is, besides the varying intrinsic anisotropy of the Auger decay, also due to a smaller anisotropy in the primary absorption process than originally predicted but in good agreement with more recent calculations. Contrary to this, satellite Auger transitions show unexpectedly large anisotropies.

Multiplet-Changing Auger Transitions In Valence Double Photoionization, U. Becker, Oliver Hemmers, B. Langer, I. Lee, A. Menzel, R. Wehlitz, M. Ya Amusia

Environmental Studies Faculty Publications

The decay of valence satellite states in neon above the first double-ionization threshold has been studied experimentally and theoretically. Special emphasis was given to differentiate between two decay modes: valence Auger and valence-multiplet Auger decay. It is shown that the latter process is predominant in the low kinetic energy part of the spectrum. The main structures of this low-energy Auger spectrum could be designated by help of calculated transition energies and decay rates.

High-Energy Behavior Of The Double Photoionization Of Helium From 2 To 12 Kev, Jon C. Levin, Ivan A. Sellin, B. M. Johnson, Dennis W. Lindle, R. D. Miller, Y. Azuma, H. G. Berry, D.-H. Lee, N. Berrah

Chemistry and Biochemistry Faculty Research

We report the ratio of double-to-single photoionization of He at several photon energies from 2 to 12 keV. By time-of-Aight methods, we find a ratio consistent with an asymptote at 1.5%±0.2%, essentially reached by h v≈4 keV. Fair agreement is obtained with older shake calculations of Byron and Joachain [Phys. Rev. 164, 1 (1967)], of Aberg [Phys. Rev. A 2, 1726 (1970)], and with recent many-body perturbation theory (MBPT) of Ishihara, Hino, and McGuire [Phys. Rev. A 44, 6980 (1991)]. The result lies below earlier MPBT calculations by Amusia et al. [J. Phys. B 8 …

Southern Nevada Effluent Wetlands: A Proposed Cooperative Venture Between The Bureau Of Reclamation & City Of Las Vegas, Bureau Of Reclamation

Publications (WR)

Throughout North America there is a growing interest in constructed wetlands, both as relatively inexpensive, low-maintenance systems for removing nutrients from wastewater, and as a means of using municipal wastewater to enhance wildlife habitat and create public use opportunities. Because wetlands appear to have good potential as a component in the overall management of scarce water resources, the Bureau of Reclamation (Reclamation) has undertaken several cooperative research and demonstration projects to evaluate their effectiveness in a variety of local environments. While a number of projects have demonstrated that wetlands can be beneficially employed to improve water quality, few such projects …

The Impact Of A Water-Imposed Interruption Of Growth In The Las Vegas Region, William T. White, Thomas M. Carroll, R. Keith Schwer

Publications (WR)

This study is prompted by the expectation that water supplies for the Las Vegas Valley, both those used currently and those additional quantities available from existing sources, cannot sustain significant further economic growth of the region beyond the year 2006.

There are five parts to this study. Part I uses a regional econometric (REMI) model to project the growth of the Las Vegas region to natural maturity, essentially unconstrained by an overriding water shortage.

Part II is a reinforcing cross-section analysis of metropolitan areas in the United States to learn the most common natural growth patterns and those that have …

Depositional Environments And Paleoecology Of The Lower Ordovician Pogonip Group, Opd Unit, Arrow Canyon Range, Clark County, Nevada, Jeffrey K. Donovan

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Opd Unit of the Pogonip Group is a slope-forming carbonate sequence that crops out in the Arrow Canyon Range 75 miles north of Las Vegas, Nevada. It is composed mainly of grainstones, packstones, and intraformational conglomerates and also contains Calathium-bearing bioherms composed dominantly of wackestones. These rocks were deposited in a shallow-water, high-energy, subtidal, tropical marine environment. Nuia and Nuia-crinoid shoals developed on this shallow ramp and the area was frequently disturbed by storms.

Calathium-dominated carbonate mudmounds emerged on the Nuia and Nuia-crinoid shoals. Although Calathium dominated the mounds on a macroscopic scale, the mounds …

Evidence For Atomic Processes In Molecular Valence Double Ionization, U. Becker, Oliver Hemmers, B. Langer, A. Menzel, R. Wehlitz, W. B. Peatman

Environmental Studies Faculty Publications

Complete molecular valence-electron spectra were measured for CO. Unexpectedly, discrete lines at low kinetic energies were found, superimposed on a continuous energy spectrum representing direct double-ionization processes. The appearance of these lines is discussed in the context of the formation of the C⁺+O⁺ ion pair near its associated threshold at 38.4 eV. It is ascribed to valence-excited repulsive (CO⁺)^* states, which dissociate to a large part rapidly into atomic fragments before electronic relaxation takes place. From our spectra, partial cross sections for the different processes leading to dissociative valence double ionization are derived.

Fire In A Riparian Shrub Community: Postburn Water Relations In The Tamarix-Salix Association Along The Lower Colorado River, S. D. Smith, D. E. Busch

Life Sciences Faculty Research

Higher water potentials in recovering burned salt-cedar (Tamarix ramosissima) relative to unburned plants and the opposite situation in willow (Salix gooddingii) provide evidence that postfire water stress is reduced in the former but not the latter. Similarly, diurnal patterns of stomatal conductance in these taxa are consistent with the existence of more vigor in burned salt-cedar than willow. Plots of water potential and transpiration demonstrate that hydraulic efficiencies may contribute to differences in fire recovery.

Desorption Hysteresis In Five Ion Exchanged Montmorillonites, Jerry Paul Fairley

UNLV Theses, Dissertations, Professional Papers, and Capstones

It is generally believed that the formation of recalcitrant (slowly desorbing) fractions of volatile organic compounds (VOCs) in soils is due to diffusion of compounds to sorption sites inaccessible to bulk fluid. The exact nature of these sites, however, is not well understood. In clay minerals, researchers favor two probable areas for the storage of persistent contamination; sites between the clay lamella, or sites with clay particle aggregates.

To test the hypothesis that recalcitrant fractions are formed in interlamellar spaces, a Na/Ca Montmorillonite (Smectite) was ion exchanged with five different cations (K⁺, Na⁺, Ca⁺, …

Surface Structure Of √3x√3r 30 Cl/Ni(111) Determined Using Low-Temperature Angle-Resolved-Photoemission Extended Fine Structure, Li-Qiong Wang, Z. Hussain, Z. Q. Huang, A. E. Schach Von Wittenau, Dennis W. Lindle, D. A. Shirley

Chemistry and Biochemistry Faculty Research

A surface structural study of the √3 × √3 R30° Cl/Ni(111) adsorbate system was made using low-temperature angle-resolved photoemission extended fine structure. The experiments were performed along two emission directions, [111] and [110], and at two temperatures, 120 and 300 K. The multiple-scattering spherical-wave analysis determined that the Cl atom adsorbs in the fcc threefold hollow site, 1.837(8) Å above the first nickel layer, with a Cl-Ni bond length of 2.332(6) Å, and an approximate 5% contraction between the first and the second nickel layers (the errors in parentheses are statistical standard deviations only).

Electron-Energy And –Angular Distributions In The Double Photoionization Of Helium, R. Wehlitz, Franz Heiser, Oliver Hemmers, B. Langer, A. Menzel, U. Becker

Environmental Studies Faculty Publications

Photoelectron spectra of helium have been measured at different angles and at various energies above the double-ionization threshold up to 120 eV to investigate the behavior of the energy and angular distributions, of shake-off electrons. Both energy and angular distributions clearly show a U-shaped profile which turns to a flat curve near threshold pointing to a uniform intensity distribution over the kinetic energy for all angles in this excitation energy regime. Our results for the angular-distribution asymmetry parameter indicate qualitative agreement with theoretical predictions but fail to provide them quantitatively.

The Sloan Sag: A Mid-Miocene Volcanotectonic Depression, North-Central Mccullough Mountains, Southern Nevada, Hayden L. Bridwell

UNLV Theses, Dissertations, Professional Papers, and Capstones

In the Hidden Valley area of the north-central McCullough Mountains, southern Nevada, mid-Miocene andesite and dacite domes, flows and pyroclastic units (the Sloan volcanics) partially fill a sag in the underlying Hidden Valley volcanics. The 13.5 km diameter sag formed during and/or after the eruption of the Sloan volcanics. Sagging was accommodated by a combination of movement on the McCullough Wash fault system, and subsidence into evacuated chambers.

Major, trace and rare-earth element geochemistry suggests that the rocks of the Sloan volcanics belong to four groups, each of which were produced by partial melting of chemically distinct sources. With the …

Measurement Of The Ratio Of Double-To-Single Photoionization Of Helium At 2.8 Kev Using Synchrotron Radiation, Jon C. Levin, Dennis W. Lindle, N. Keller, R. D. Miller, Y. Azuma, N. Berrah Mansour, H. G. Berry, Ivan A. Sellin

Chemistry and Biochemistry Faculty Research

We report the first measurement of the ratio of double-to-single photoionization of helium well above the double-ionization threshold. Using a time-of-flight technique, we find He⁺⁺/He⁺=1.6±0.3% at hν=2.8 keV. This value lies between calculations by Amusia (2.3%) and by Samson, who predicts 1.2% by analogy with electron-impact ionization cross sections of singly charged ions. Good agreement is obtained with older shake calculations of Byron and Joachain, and of Åberg, who predict 1.7%.

Anisotropy Of Polarized X-Ray Emission From Molecules, S. H. Southworth, Dennis W. Lindle, R. Mayer, P. L. Cowan

Chemistry and Biochemistry Faculty Research

Strongly anisotropic, polarized Cl K-V x-ray emission from gas-phase CF₃Cl has been observed following resonant excitation with a linearly polarized x-ray beam. Distinctively different angular distributions are observed for x-ray emission involving molecular orbitals of different symmetries. A classical model of the x-ray absorption-emission process accurately describes the observed radiation patterns.

Molecular-Orbital Studies Via Satellite-Free X-Ray Fluorescence: Cl-K Absorption And K–Valence-Level Emission Spectra Of Chlorofluoromethanes, Rupert C. Perera, P. L. Cowan, Dennis W. Lindle, R. E. Lavilla, T. Jach, R. D. Deslattes

Chemistry and Biochemistry Faculty Research

X-ray absorption and emission measurements in the vicinity of the chlorine K edge of the three chlorofluoromethanes have been made using monochromatic synchrotron radiation as the source of excitation. By selectively tuning the incident radiation to just above the Cl 1s single-electron ionization threshold for each molecule, less complex x-ray-emission spectra are obtained. This reduction in complexity is attributed to the elimination of multielectron transitions in the Cl K shell, which commonly produce satellite features in x-ray emission. The resulting "satellite-free" x-ray-emission spectra exhibit peaks due only to electrons in valence molecular orbitals filling a single Cl 1s vacancy. These …

Polarized X-Ray-Emission Studies Of Methyl Chloride And The Chlorofluoromethanes, Dennis W. Lindle, P. L. Cowan, T. Jach, R. E. Lavilla, R. D. Deslattes, Rupert C. Perera

Chemistry and Biochemistry Faculty Research

A new technique sensitive to molecular orientation and geometry, and based on measuring the polarization of x-ray emission, has been applied to the Cl-containing molecules methyl chloride (CH₃Cl) and the chlorofluoromethanes (CF₃Cl, CF₂Cl₂, and CFCl₃) in the gas phase. Upon selective excitation using monochromatic synchrotron radiation in the Cl K-edge (Cl 1s) near-threshold region, polarization-selective x-ray emission studies reveal highly polarized molecular valence x-ray fluorescence for all four molecules. The degree and the orientation of the polarized emission are observed to be sensitive to the incident excitation energy near …

High-Resolution Photoelectron Spectrometry Study Of Conjugate Shakeup Processes In The Li 1s Threshold Region, B. Langer, J. Viefhaus, Oliver Hemmers, A. Menzel, U. Becker

Environmental Studies Faculty Publications

Partial cross sections and angular-distribution asymmetry parameters of diagram and satellite lines associated with Li 1s photoionization were measured using synchrotron-radiation excitation. Special emphasis was given to a high-resolution study of the ¹P and ³P conjugate shakeup satellite lines testing qualitative predictions of the conjugate shakeup model: increasing σ and decreasing β values towards threshold, both being verified. Comparison with recent relaxed Hartree-Fock calculations shows good agreement for the ¹P satellite, but demonstrates also that the present theory does not seem to be able to describe the cross-section behavior of the ³P satellite correctly.