Physical Sciences and Mathematics Commons^™

Forage Legumes: Their Importance And Management In Profitable Livestock Systems, Ben M. Goff

Kentucky Grazing Conference

The landscape of most Kentucky operations is heavily dominated by the utilization of cool-season grasses as the primary source of forage for livestock. However, legumes species, such alfalfa and red or white clovers are an essential component to a complete forage-livestock system. Relative to grasses alone, incorporating legumes into a mixture has the benefits of improving the nutritive value of the available forage in the field, extending the grazing season by increasing the yield of forage during the early summer months, and providing a more economical source of N compared to commercial fertilizers. This paper will briefly describe each of …

Maximizing Stocker Gains On Pastures, Jeff Lehmkuhler

Kentucky Grazing Conference

Stocker enterprises by definition utilize pasture forages to add weight to light weight feeder cattle. These operations add value to calves by assimilating small groups of calves and combining them into larger uniform packages. Stocker operators also enhance quality through livestock husbandry practices that “upgrade” feeders which could include castrating bulls, dehorning, improving immunity and other attributes. In an effort to optimize profit margins, stocker operators must manage feeders to ensure high rates of gain while finding a balance in stocking rates that provide adequate gains per acre.

Grazing Method: Tool Or Toolbox?, Garry D. Lacefield

Kentucky Grazing Conference

This conference makes the 15th consecutive year we have devoted a full day to Grazing. Kentucky is a great state for grazing animals since we have a relatively long pasture season, can grow many forage grasses and legumes and a long tradition of producing quality animal products from quality pasture. We have tremendous potential to improve our overall grazing efficiency and the discussion throughout the day will address many of the practical strategies for improvements.

Foreword And Kfgc Award Winners [2014], Garry D. Lacefield, Christi L. Forsythe

Kentucky Grazing Conference

No abstract provided.

Keck-I Mosfire Spectroscopy Of Compact Star-Forming Galaxies At Z ≳ 2: High Velocity Dispersions In Progenitors Of Compact Quiescent Galaxies, Guillermo Barro, Jonathan R. Trump, David C. Koo, Avishai Dekel, Susan A. Kassin, Dale D. Kocevski, Sandra M. Faber, Arjen Van Der Wel, Yicheng Guo, Pablo G. Pérez-González, Elisa Toloba, Jerome J. Fang, Camilla Pacifici, Raymond Simons, Randy D. Campbell, Daniel Ceverino, Steven L. Finkelstein, Bob Goodrich, Marc Kassis, Anton M. Koekemoer, Nicholas P. Konidaris, Rachel C. Livermore, James E. Lyke, Bahram Mobasher, Hooshang Nayyeri, Michael Peth, Joel R. Primack, Luca Rizzi, Rachel S. Somerville, Gregory D. Wirth, Adi Zolotov

Physics and Astronomy Faculty Publications

We present Keck-I MOSFIRE near-infrared spectroscopy for a sample of 13 compact star-forming galaxies (SFGs) at redshift 2 ≤ z ≤ 2.5 with star formation rates of SFR ~ 100 M _☉ yr^–1 and masses of log(M/M _☉) ~10.8. . . .

For the remainder of the abstract, please visit:

http://dx.doi.org/10.1088/0004-637X/795/2/145

Warming Reduces Tall Fescue Abundance But Stimulates Toxic Alkaloid Concentrations In Transition Zone Pastures Of The U.S., Rebecca L. Mcculley, Lowell P. Bush, Anna E. Carlisle, Huihua Ji, Jim A. Nelson

Plant and Soil Sciences Faculty Publications

Tall fescue pastures cover extensive acreage in the eastern half of the United States and contribute to important ecosystem services, including the provisioning of forage for grazing livestock. Yet little is known concerning how these pastures will respond to climate change. Tall fescue's ability to persist and provide forage under a warmer and wetter environment, as is predicted for much of this region as a result of climate change, will likely depend on a symbiotic relationship the plant can form with the fungal endophyte, Epichloë coenophiala. While this symbiosis can confer environmental stress tolerance to the plant, the endophyte …

The Bulge–Disc Decomposed Evolution Of Massive Galaxies At 1 < Z < 3 In Candels, V. A. Bruce, J. S. Dunlop, R. J. Mclure, M. Cirasuolo, F. Buitrago, R. A. A. Bowler, T. A. Targett, E. F. Bell, D. H. Mcintosh, A. Dekel, S. M. Faber, H. C. Ferguson, N. A. Grogin, W. Hartley, Dale D. Kocevski, A. M. Koekemoer, D. C. Zoo, E. J. Mcgrath

Physics and Astronomy Faculty Publications

We present the results of a new and improved study of the morphological and spectral evolution of massive galaxies over the redshift range 1 < z < 3. Our analysis is based on a bulge–disc decomposition of 396 galaxies with M_* > 10¹¹ M_⊙ uncovered from the Cosmic Assembly Near-infrared Deep Extragalactic Legacy Survey (CANDELS) Wide Field Camera 3 (WFC3)/IR imaging within the Cosmological Evolution Survey (COSMOS) and UKIRT Infrared Deep Sky Survey (UKIDSS) UDS survey fields. We find that, by modelling the H₁₆₀ image of each galaxy with a combination of a de Vaucouleurs bulge (Sérsic index n = 4) and an exponential disc (n = 1), we can then …

The Decomposed Bulge And Disc Size–Mass Relations Of Massive Galaxies At 1 < Z < 3 In Candels, V. A. Bruce, J. S. Dunlop, R. J. Mclure, M. Cirasuolo, F. Buitrago, R. A. A. Bowler, T. A. Targett, E. F. Bell, D. H. Mcintosh, A. Dekel, S. M. Faber, H. C. Ferguson, N. A. Grogin, W. Hartley, Dale D. Kocevski, A. M. Koekemoer, D. C. Koo, E. J. Mcgrath

Physics and Astronomy Faculty Publications

We have constructed a mass-selected sample of M_* > 10¹¹ M_⊙ galaxies at 1 < z < 3 in the CANDELS UKIDSS UDS and COSMOS fields and have decomposed these systems into their separate bulge and disc components according to their H₁₆₀-band morphologies. By extending this analysis to multiple bands, we have been able to conduct individual bulge and disc component SED fitting which has provided us with stellar-mass and star formation rate estimates for the separate bulge and disc components. Having utilized the new decomposed stellar-mass estimates, we confirm that the bulge components display a stronger size evolution than the discs. The median sizes of the bulge components is 3.09 ± 0.20 times smaller than similarly massive local galaxies over the …

Interactive Comment On “Iodine Oxide In The Global Marine Boundary Layer” By C. Prados-Roman Et Al., Marcelo I. Guzman

Chemistry Faculty Publications

No abstract provided.

Lattice-Tuned Magnetism Of Ru4+(4D4) Ions In Single Crystals Of The Layered Honeycomb Ruthenates Li2Ruo3 And Na2Ruo3, J. C. Wang, Jsaminka Terzic, T. F. Qi, Feng Ye, Shujuan Yuan, Saicharan Aswartham, S. V. Streltsov, D. I. Khomskii, Ribku K. Kaul, Gang Cao

Physics and Astronomy Faculty Publications

We synthesize and study single crystals of the layered honeycomb lattice Mott insulators Na₂RuO₃ and Li₂RuO₃ with magnetic Ru⁴⁺(4d⁴) ions. The newly found Na₂RuO₃ features a nearly ideal honeycomb lattice and orders antiferromagnetically at 30 K. Single crystals of Li₂RuO₃ adopt a honeycomb lattice with either C2/m or more distorted P2₁/m below 300 K, depending on detailed synthesis conditions. We find that Li₂RuO₃ in both structures hosts a well-defined magnetic state, in contrast to …

Accurate Determination Of The Free–Free Gaunt Factor – I. Non-Relativistic Gaunt Factors, P. A. M. Van Hoof, R. J. R. Williams, K. Vollk, Marios Chatzikos, Gary J. Ferland, M. Lykins, R. L. Porter, Ye Wang

Physics and Astronomy Faculty Publications

Modern spectral synthesis codes need the thermally averaged free–free Gaunt factor defined over a very wide range of parameter space in order to produce an accurate prediction for the spectrum emitted by an ionized plasma. Until now no set of data exists that would meet this need in a fully satisfactory way. We have therefore undertaken to produce a table of very accurate non-relativistic Gaunt factors over a much wider range of parameters than has ever been produced before. We first produced a table of non-averaged Gaunt factors, covering the parameter space ¹⁰log ϵ_i = −20 to +10 …

Observation Of D0 Meson Nuclear Modifications In Au+Au Collisions At √SNn=200  Gev, J. Kevin Adkins, Renee Fatemi, Suvarna Ramachandran, G. Webb, L. Adamczyk, G. Agakishiev, M. M. Aggarwal, Z. Ahammed, I. Alekseev, J. Alford, C. D. Anson, A. Aparin, D. Arkhipkin, E. C. Aschenauer

Physics and Astronomy Faculty Publications

We report the first measurement of charmed-hadron (D⁰) production via the hadronic decay channel (D⁰→K⁻+π⁺) in Au+Au collisions at √^S_NN=200  GeV with the STAR experiment. The charm production cross section per nucleon-nucleon collision at midrapidity scales with the number of binary collisions, N_bin, from p+p to central Au+Au collisions. The D⁰ meson yields in central Au+Au collisions are strongly suppressed compared to those in p+p scaled by N_bin, for transverse momenta p_T>3  GeV/c …

Crystal Structure Of 4,5-Bis-(3,4,5-Trimethoxyphenyl)-2H-1,2,3-Triazole Methanol Monosolvate, Nikhil Reddy Madadi, Narsimha Reddy Penthala, Shobanbabu Bommagani, Sean Parkin, Peter A. Crooks

Chemistry Faculty Publications

The title compound, C₂₀H₂₃N₃O₆·CH₃OH, was synthesized by [3 + 2] cyclo­addition of (Z)-2,3-bis­(3,4,5-tri­meth­oxy­phen­yl)acrylo­nitrile with sodium azide and ammonium chloride in DMF/water. The central nitro­gen of the triazole ring is protonated. The dihedral angles between the triazole ring and the 3,4,5-tri­meth­oxy­phenyl ring planes are 34.31 (4) and 45.03 (5)°, while that between the 3,4,5-tri­meth­oxy­phenyl rings is 51.87 (5)°. In the crystal, the mol­ecules, along with two methanol solvent mol­ecules are linked into an R ⁴ ₄(10) centrosymmetric dimer by N—H⋯O and O—H⋯N hydrogen bonds.

Crystal Structure Of (E)-13-{4-[(Z)-2-Cyano-2-(3,4,5-Trimethoxyphenyl)Ethenyl]Phenyl}Parthenolide Methanol Hemisolvate, Narsimha Reddy Penthala, Shobanbabu Bommagani, Venumadhav Janganati, Sean Parkin, Peter A. Crooks

Chemistry Faculty Publications

The title compound, C₃₃H₃₅NO₆ [systematic name: (Z)-3-(4-{(E)-[(E)-1a,5-dimethyl-9-oxo-2,3,7,7a-tetra­hydro­oxireno[2′,3′:9,10]cyclo­deca­[1,2-b]furan-8(1aH,6H,9H,10aH,10bH)-yl­idene]meth­yl}phen­yl)-2-(3,4,5-tri­meth­oxy­phen­yl)acrylo­ni­trile methanol hemisolvate], C₃₃H₃₅NO₆·0.5CH₃OH, was prepared by the reaction of (Z)-3-(4-iodo­phen­yl)-2-(3,4,5-tri­meth­oxy­phen­yl)acrylo­nitrile with parthenolide [systematic name: (E)-1a,5-dimethyl-8-methyl­ene-2,3,6,7,7a,8,10a,10b-octa­hy­dro­oxireno[2′,3′:9,10]cyclo­deca­[1,2-b]furan-9(1aH)-one] under Heck reaction conditions. The mol­ecule is built up from fused ten-, five- (lactone) and three-membered (epoxide) rings with a {4-[(Z)-2-cyano-2-(3,4,5-tri­meth­oxy­phen­yl)ethen­yl]phen­yl}methyl­idene group as a substituent. The 4-[(Z)-2-cyano-2-(3,4,5-tri­meth­oxy­phen­yl)ethen­yl]phenyl group on the parthenolide exocyclic double bond is …

Northeast‐Oriented Transpression Structure In The Northern New Madrid Seismic Zone: Extension Of A Shear Zone Across The Reelfoot Fault Stepover Arm, Edward W. Woolery, Ali Almayahi

Earth and Environmental Sciences Faculty Publications

High‐resolution seismic‐reflection profiles recently acquired 12 km northeast of the New Madrid seismic zone’s Reelfoot thrust and along the central axis of the Reelfoot rift, imaged steeply dipping N30°E striking faults that have uplifted and arched post‐Paleozoic sediments in a manner consistent with a dextral strike‐slip component of displacement. The subparallel fault strands have been traced 1.4 km between reflection profiles. In order to evaluate the structure’s potential regional scale, the strike was projected northeast 22 km to its intersection with a nearby industry profile. At the intersection, this lower‐resolution profile exhibits a discrete 0.75 km wide structure with style …

Function-On-Scalar Regression For Genetic Association Studies, Olga A. Vsevolozhskaya, Dmitri V. Zaykin, Qing Lu

Olga A. Vsevolozhskaya

We propose a general framework to perform gene/region based analysis of sequencing data by regressing a functional response on one or multiple scalar predictors. Next generation sequencing technologies make it possible to uncover genetic information from millions of variants. Since the observed sequenced variants are very close in their genetic positions, we can consider them to be realizations of random continuous functions. Therefore, instead of analyzing multiple individual genetic variants per subject, we can estimate the underlying continuous function and treat it as a functional response in a regression model. Smoothing splines are used to fit these functional responses by …

Anisotropic Magnetoresistance In Antiferromagnetic Sr2Iro4, C. Wang, H. Seinige, Gang Cao, J.-S. Zhou, J. B. Goodenough, M. Tsoi

Physics and Astronomy Faculty Publications

We report point-contact measurements of anisotropic magnetoresistance (AMR) in a single crystal of antiferromagnetic Mott insulator Sr₂IrO₄. The point-contact technique is used here as a local probe of magnetotransport properties on the nanoscale. The measurements at liquid nitrogen temperature reveal negative magnetoresistances (up to 28%) for modest magnetic fields (250 mT) applied within the IrO₂ a−b plane and electric currents flowing perpendicular to the plane. The angular dependence of magnetoresistance shows a crossover from fourfold to twofold symmetry in response to an increasing magnetic field with angular variations in resistance from 1% to 14%. We …

Functional Analysis Of Variance For Association Studies, Olga A. Vsevolozhskaya, Dmitri V. Zaykin, Mark C. Greenwood, Changshuai Wei, Qing Lu

Olga A. Vsevolozhskaya

While progress has been made in identifying common genetic variants associated with human diseases, for most of common complex diseases, the identified genetic variants only account for a small proportion of heritability. Challenges remain in finding additional unknown genetic variants predisposing to complex diseases. With the advance in next-generation sequencing technologies, sequencing studies have become commonplace in genetic research. The ongoing exome-sequencing and whole-genome-sequencing studies generate a massive amount of sequencing variants and allow researchers to comprehensively investigate their role in human diseases. The discovery of new disease-associated variants can be enhanced by utilizing powerful and computationally efficient statistical methods. …

Novel Image Markers For Non-Small Cell Lung Cancer Classification And Survival Prediction, Hongyuan Wang, Fuyong Xing, Hai Su, Arnold J. Stromberg, Lin Yang

Statistics Faculty Publications

BACKGROUND: Non-small cell lung cancer (NSCLC), the most common type of lung cancer, is one of serious diseases causing death for both men and women. Computer-aided diagnosis and survival prediction of NSCLC, is of great importance in providing assistance to diagnosis and personalize therapy planning for lung cancer patients.

RESULTS: In this paper we have proposed an integrated framework for NSCLC computer-aided diagnosis and survival analysis using novel image markers. The entire biomedical imaging informatics framework consists of cell detection, segmentation, classification, discovery of image markers, and survival analysis. A robust seed detection-guided cell segmentation algorithm is proposed to accurately …

Characterizing The Ab Doradus Moving Group Via High-Resolution Spectroscopy And Kinematic Traceback, Kyle Mccarthy, Ronald J. Wilhelm

Physics and Astronomy Faculty Publications

We present a detailed analysis of 10 proposed F and G members of the nearby, young moving group AB Doradus (ABD). Our sample was obtained using the 2.7 m telescope at the McDonald Observatory with the coude echelle spectrograph, achieving R ~ 60,000 and signal-to-noise ratio ~200. We derive spectroscopic T _eff, log(g), [Fe/H], and microturbulance (v_t ) using a bootstrap method of the TGVIT software resulting in typical errors of 33K in T _eff, 0.08 dex in log(g), 0.03 dex in [Fe/H], and 0.13 km s^–1 in v_t . …

No More Active Galactic Nuclei In Clumpy Disks Than In Smooth Galaxies At Z ~ 2 In Candels/3d-Hst*, Jonathan R. Trump, Guillermo Barro, Stéphanie Juneau, Benjamin J. Weiner, Bin Luo, Gabriel B. Brammer, Eric F. Bell, W. N. Brandt, Avishai Dekel, Yicheng Guo, Philip F. Hopkins, David C. Koo, Dale D. Kocevski, Daniel H. Mcintosh, Ivelina Momcheva, S. M. Faber, Henry C. Ferguson, Norman A. Grogin, Jeyhan Kartaltepe, Anton M. Koekemoer, Jennifer Lotz, Michael Maseda, Mark Mozena, Kirpal Nandra, David J. Rosario, Gergory R. Zeimann

Physics and Astronomy Faculty Publications

We use CANDELS imaging, 3D-HST spectroscopy, and Chandra X-ray data to investigate if active galactic nuclei (AGNs) are preferentially fueled by violent disk instabilities funneling gas into galaxy centers at 1.3 < z < 2.4. We select galaxies undergoing gravitational instabilities using the number of clumps and degree of patchiness as proxies. The CANDELS visual classification system is used to identify 44 clumpy disk galaxies, along with mass-matched comparison samples of smooth and intermediate morphology galaxies. We note that despite being mass-matched and having similar star formation rates, the smoother galaxies tend to be smaller disks with more prominent bulges compared to the clumpy galaxies. The lack of smooth extended disks is probably a general feature of the z ~ 2 galaxy population, and means we cannot directly compare with the clumpy and smooth extended disks observed at lower redshift. We find that z ~ 2 clumpy galaxies have slightly enhanced AGN fractions selected by integrated line ratios (in the mass-excitation method), but the spatially resolved line ratios indicate this is likely due to extended phenomena rather than nuclear AGNs. Meanwhile, the X-ray data show that …

Piecing The Puzzle Together: A Revisit To Transcript Reconstruction Problem In Rna-Seq, Yan Huang, Yin Hu, Jinze Liu

Computer Science Faculty Publications

The advancement of RNA sequencing (RNA-seq) has provided an unprecedented opportunity to assess both the diversity and quantity of transcript isoforms in an mRNA transcriptome. In this paper, we revisit the computational problem of transcript reconstruction and quantification. Unlike existing methods which focus on how to explain the exons and splice variants detected by the reads with a set of isoforms, we aim at reconstructing transcripts by piecing the reads into individual effective transcript copies. Simultaneously, the quantity of each isoform is explicitly measured by the number of assembled effective copies, instead of estimated solely based on the collective read …

Tunable Magnetic Properties Of Transition Metal Doped Mos2, Antonis N. Andiotis, Madhu Menon

Physics and Astronomy Faculty Publications

We report a detailed investigation of the electronic and magnetic properties of the transition metal (TM) doped two-dimensional (2D) MoS₂ using ab initio calculations. The doping is achieved by substituting two or more Mo atoms by TM atoms of the 3d series. Additionally, the effect of codoping on the 2D MoS₂ by cation-cation and cation-anion pairs is also investigated. Our results demonstrate that the TM doping of 2D MoS₂ leads to a significant reduction of the energy gap and the appearance of magnetic features whose major characteristic is the ferromagnetic coupling of the TM dopants. The …

Alleviating Polarity-Conflict At The Heterointerfaces Of Ktao3/Gdsco3 Polar Complex-Oxides, Justin K. Thompson, J. Hwang, John Nichols, John G. Connell, S. Stemmer, Sung S. Ambrose Seo

Physics and Astronomy Faculty Publications

We have synthesized and investigated the heterointerfaces of KTaO₃ (KTO) and GdScO₃ (GSO), which are both polar complex-oxides along the pseudo-cubic [001] direction. Since their layers have the same, conflicting net charges at interfaces, i.e., KO(−1)/ScO₂(−1) or TaO₂(+1)/GdO(+1), forming the heterointerface of KTO/GSO should be forbidden due to strong Coulomb repulsion, the so-called polarity conflict. However, we have discovered that atomic reconstruction occurs at the heterointerfaces between KTO thin-films and GSO substrates, which effectively alleviates the polarity conflict without destroying the hetero-epitaxy. Our result demonstrates one of the important ways to create artificial heterostructures …

On The Momentum Dependence Of The Flavor Structure Of The Nucleon Sea, Jen-Chieh Peng, Wen-Chen Chang, Hai-Yang Cheng, Tie-Jiun Hou, Keh-Fei Liu, Jian-Wei Qiu

Physics and Astronomy Faculty Publications

Difference between the u¯ and d¯ sea quark distributions in the proton was first observed in the violation of the Gottfried sum rule in deep-inelastic scattering (DIS) experiments. The parton momentum fraction x dependence of this difference has been measured over the region 0.02 < x < 0.35 from Drell–Yan and semi-inclusive DIS experiments. The Drell–Yan data suggested a possible sign-change for d¯(x) − u¯ (x) near x ~ 0.3, which has not yet been explained by existing theoretical models. We present an independent evidence for the d¯(x) − u¯ (x) sign-change at x ~ 0.3 from an analysis of the DIS data. We further discuss the x …

Scalable Synthesis Of 5,11-Diethynylated Indeno[1,2-B]Fluorene-6,12-Diones And Exploration Of Their Solid State Packing, Bradley D. Rose, Peter J. Santa Maria, Aaron G. Fix, Chris L. Vonnegut, Lev N. Zakharov, Sean R. Parkin, Michael M. Haley

Chemistry Faculty Publications

We report a new synthetic route to 5,11-disubstituted indeno[1,2-b]fluorene-6,12-diones that is amenable to larger scale reactions, allowing for the preparation of gram amounts of material. With this new methodology, we explored the effects on crystal packing morphology for the indeno[1,2-b]fluorene-6,12-diones by varying the substituents on the silylethynyl groups.

Crystal Structure Of 1-Methoxy-2,2,2-Tris(Pyrazol-1-Yl)Ethane, Ganna Lyubartseva, Sean Parkin, Morgan D. Coleman, Uma Prasad Mallik

Chemistry Faculty Publications

The title compound, C₁₂H₁₄N₆O, consists of three pyrazole rings bound via nitro­gen to the distal ethane carbon of meth­oxy ethane. The dihedral angles between the three pyrazole rings are 67.62 (14), 73.74 (14), and 78.92 (12)°. In the crystal, mol­ecules are linked by bifurcated C—H,H⋯N hydrogen bonds, forming double-stranded chains along [001]. The chains are linked via C—H⋯O hydrogen bonds, forming a three-dimensional framework structure. The crystal was refined as a perfect (0.5:0.5) inversion twin.

Recent Ideas On The Calculation Of Lepton Anomalous Magnetic Moments, Michael I. Eides

Physics and Astronomy Faculty Publications

We discuss the recent claim [G. Mishima, arXiv:1311.7109; M. Fael and M. Passera, arXiv:1402.1575 [Phys. Rev. D (to be published)]] about discovery of a nonperturbative quantum-electrodynamic contribution of order (α/π)⁵ to lepton anomalous magnetic moments. We explain why this nonperturbative correction does not exist.

Beam Energy Dependence Of Moments Of The Net-Charge Multiplicity Distributions In Au+Au Collisions At Rhic, J. Kevin Adkins, Renee Fatemi, Wolfgang Korsch, Suvarna Ramachandran, G. Webb, L. Adamczyk, G. Agakishiev, M. M. Aggarwal, Z. Ahammed, I. Alekseev, J. Alford, C. D. Anson, A. Aparin, D. Arkhipkin, E. C. Aschenauer

Physics and Astronomy Faculty Publications

We report the first measurements of the moments—mean (M), variance (σ²), skewness (S), and kurtosis (κ)—of the net-charge multiplicity distributions at midrapidity in Au+Au collisions at seven energies, ranging from √^S_NN=7.7 to 200 GeV, as a part of the Beam Energy Scan program at RHIC. The moments are related to the thermodynamic susceptibilities of net charge, and are sensitive to the location of the QCD critical point. We compare the products of the moments, σ²/M, Sσ, and κσ², with the expectations …

Low-Temperature Phase Transitions In A Soluble Oligoacene And Their Effect On Device Performance And Stability, J. W. Ward, K. P. Goetz, A. Obaid, Marcia M. Payne, P. J. Diemer, C. S. Day, John E. Anthony, O. D. Jurchescu

Chemistry Faculty Publications

The use of organic semiconductors in high-performance organic field-effect transistors requires a thorough understanding of the effects that processing conditions, thermal, and bias-stress history have on device operation. Here, we evaluate the temperature dependence of the electrical properties of transistors fabricated with 2,8-difluoro-5,11-bis(triethylsilylethynyl)anthradithiophene, a material that has attracted much attention recently due to its exceptional electrical properties. We have discovered a phase transition at T = 205 K and discuss its implications on device performance and stability. We examined the impact of this low-temperature phase transition on the thermodynamic, electrical, and structural properties of both single crystals and thin films …