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Full-Text Articles in Physical Sciences and Mathematics

Co2 Reduction Under Periodic Illumination Of Zns, Ruixin Zhou, Marcelo I. Guzman May 2014

Co2 Reduction Under Periodic Illumination Of Zns, Ruixin Zhou, Marcelo I. Guzman

Chemistry Faculty Publications

The photoreduction of CO2 to formate (HCOO) in sphalerite (ZnS) aqueous suspensions is systematically studied in the presence of Na2S hole scavenger. A series of cut-on filters at λcut-on ≥ 280, 295, 305, 320, and 400 nm are used to measure the reaction rate of formate production. The dependence of the measured reaction rates on λcut-on indicates that a wavelength of λ = 345 nm is associated with the actual bandgap of the semiconductor nanocrystallites suspended in water. The results from apparent quantum yield measurements during periodic illumination experiments suggest that (1) valence-band …


Co2 Recycling Using Microalgae For The Production Of Fuels, Michael H. Wilson, John Groppo, Andrew Placido, S. Graham, S. A. Morton Iii, Eduardo Santillan-Jimenez, Aubrey Shea, Mark Crocker, Czarena Crofcheck, Rodney Andrews Mar 2014

Co2 Recycling Using Microalgae For The Production Of Fuels, Michael H. Wilson, John Groppo, Andrew Placido, S. Graham, S. A. Morton Iii, Eduardo Santillan-Jimenez, Aubrey Shea, Mark Crocker, Czarena Crofcheck, Rodney Andrews

Center for Applied Energy Research Faculty and Staff Publications

CO2 capture and recycle using microalgae was demonstrated at a coal-fired power plant (Duke Energy’s East Bend Station, Kentucky). Using an in-house designed closed loop, vertical tube photobioreactor, Scenedesmus acutus was cultured using flue gas as the CO2 source. Algae productivity of 39 g/(m2 day) in June–July was achieved at significant scale (18,000 L), while average daily productivity slightly in excess of 10 g/(m2 day) was demonstrated in the month of December. A protocol for low-cost algae harvesting and dewatering was developed, and the conversion of algal lipids—extracted from the harvested biomass—to diesel-range hydrocarbons via catalytic …


Shallow Groundwater Monitoring Associated With The Deep Saline Reservoir Co2 Storage Test In Hancock County, Kentucky, E. Glynn Beck Jan 2014

Shallow Groundwater Monitoring Associated With The Deep Saline Reservoir Co2 Storage Test In Hancock County, Kentucky, E. Glynn Beck

Report of Investigations--KGS

A carbon dioxide injection test well was drilled in 2009 to a depth of 8,126 ft below ground surface in Hancock County, Kentucky. Six hundred ninety tons of CO2 was successfully injected into Knox Group saline aquifers. Two domestic wells (MB and GB) and two domestic springs (CA and RC) were sampled to monitor any potential changes in groundwater quality associated with possible migration of CO2 from deeper saline aquifers into shallow freshwater aquifers. The four sites were sampled for pH, bicarbonate, total dissolved solids, turbidity, anions, total dissolved metals, dissolved inorganic carbon, total CO2, and …