Physical Sciences and Mathematics Commons^™

Data Collection And Machine Learning Methods For Automated Pedestrian Facility Detection And Mensuration, Joseph Bailey Luttrell Iv

Dissertations

Large-scale collection of pedestrian facility (crosswalks, sidewalks, etc.) presence data is vital to the success of efforts to improve pedestrian facility management, safety analysis, and road network planning. However, this kind of data is typically not available on a large scale due to the high labor and time costs that are the result of relying on manual data collection methods. Therefore, methods for automating this process using techniques such as machine learning are currently being explored by researchers. In our work, we mainly focus on machine learning methods for the detection of crosswalks and sidewalks from both aerial and street-view …

Designing Dynamic And Degradable Polymeric Materials With Thiol-X Chemistries, Reese Sloan

Dissertations

With plastic production poised to increase in coming years, there arises a need to develop new polymeric materials designed to combat the global pollution crisis. A commonly utilized approach in addressing this challenge is to employ a responsive functional moiety into the polymer architecture. Thiol-X reactions, a commonly utilized class of “click” reactions, have garnered broad implementation in new stimuli-responsive materials. This work specifically focuses on utilizing radical-mediated thiol-ene coupling and base-catalyzed thiol-isocyanate reactions to develop a library of ternary thiol-ene/thiourethane covalent adaptable networks (CANs) and hydrolytically labile poly(thioether ketal) thermoplastics. CANs are a class of network materials capable of …

Tropical Cyclone Storm Surge Detection In Slash Pine Radial Growth Along The Northern Gulf Of Mexico Coastline, Alyssa C. Crowell

Master's Theses

My thesis examines the ecological impact of tropical cyclone (TCs) storm surge on coastal slash pine (Pinus elliottii var. elliottii Engelm) communities along the Gulf of Mexico in the southern United States (U.S.). Previous research has shown slash pine radial growth trends can be examined to identify long and short-term growth changes associated with TC passage, providing insight into overall stand health and resiliency through time. However, this previous research encompasses just one site in Mississippi. My thesis expands the spatial footprint of TC-surge impact on slash pine radial growth with the addition of three new sites.

I examined …

Sedimentary Characteristics And Associated Carbon And Nutrients Of Overbank Sediments Deposited During The 2018, 2019, And 2020 Floods In Embanked Floodplains Along The Lower Mississippi River Near Natchez, Mississippi, Rachel Kelk

Master's Theses

The Lower Mississippi River (LMR) experienced major floods in 2018, 2019, and 2020. Sediment deposition in the embanked floodplains during floods represent important storage and sequestration opportunities for carbon and nutrients from ~40% of the continental USA. This research aims to compare depositional thicknesses, organic matter (OM), carbon (C), nitrogen (N), phosphorous (P) concentrations, and grain sizes in floodplain sediments deposited by the combined 2018-19 floods to the 2020 flood along the LMR near Natchez, Mississippi. Greater depositional thicknesses in 2018-19 are best explained by their combined flood durations; the 2019 flood was the longest in recorded history. Slightly higher …

Emplacement Of The Dadeville Complex Of The Southernmost Inner Piedmont Within The 7.5 Min. Cusseta Quadrangle, Chambers County, Alabama: Channel Flow, Klippe Kinematics, Or Orogen Parallel Translation, Timothy Black

Master's Theses

The Appalachian Mountains have a complex geologic history spanning three orogenic periods, the Taconic, the Acadian/Neoacadian, and Alleghanian orogenies. The Inner Piedmont of the Appalachian Mountains within Alabama contains two distinct lithologic complexes, the Dadeville Complex, and the Opelika Complex separated by the Stonewall Line. These complexes were formed during an arc-back arc fringing system during the Taconic orogeny and emplaced and recorded peak metamorphism during the Acadian orogeny.

The Dadeville Complex is an allochthonous arc terrain built on extended Laurentian crust. The mode of transportation and accretion after formation is not well understood, which has implications for the role …

Fine-Tuning A 𝑘-Nearest Neighbors Machine Learning Model For The Detection Of Insurance Fraud, Alliyah Stout

Honors Theses

Billions of dollars are lost within insurance companies due to fraud. Large money losses force insurance companies to increase premium costs and/or restrict policies. This negatively affects a company’s loyal customers. Although this is a prevalent problem, companies are not urgently working toward bettering their machine learning algorithms. Underskilled workers paired with inefficient computer algorithms make it difficult to accurately and reliably detect fraud.

The goal of this study is to understand the idea of -Nearest Neighbors ( -NN) and to use this classification technique to accurately detect fraudulent auto insurance claims. Using -NN requires choosing a value and a …

Analysis Of Covid-19 And Vaccine Administration In Mississippi, Megan Sickinger

Honors Theses

In this work, we develop a simple mathematical model to observe the spread of COVID-19 and vaccine administration in Mississippi. Based on the well-known Kermack-McKendrick Susceptible-Infected-Removed epidemiological model, the ASIRD−V model has eight ordinary differential equations that split infected populations and recovered populations into vaccinated and unvaccinated populations. After determining that the system is reliable for real-world applications, we investigate and determine the stability and equilibrium points of this system. The system is found to be disease-free when R0 < 1 and endemic when R0 > 1. We use MATLAB to numerically solve the system and optimize the model’s parameters over four short periods, two with the …

Fluid Pathways In Magmatic Fluid-Dominated Hydrothermal System: Upper Resurgent Cone, Brothers Volcano, New Zealand, Esther G. Goita

Honors Theses

The Tonga-Kermadec Arc is an active volcanic arc located between New Zealand and Fiji. The arc expands over an approximate distance of 2530 km. The Kermadec Arc is currently host to over 30 volcanoes, the majority of which are submarine. The magmatic activity along the arc is characterized by the convergence between the Pacific and Australian plates. Brothers volcano is the most active hydrothermal system along the Kermadec arc and hosts two distinct hydrothermal systems, one magmatic fluid dominated, and the other seawater dominated, making the site perfect for studying nascent volcanogenic massive sulfide formation and fluid pathways. The International …

Large Scale Disease Modeling, Walker Mattox

Master's Theses

In this we study large scale disease modeling. After understanding the mechanics behind the SIR disease model in an ODE sense, we will apply this knowledge to model disease spread in more and more increasing advanced cellular automata. Eventually, some of our cellular automata will include long distance travel. From this discrete data, we can then build an SIR model in the PDE sense to display large scale disease spread.

A New Model For Predicting The Drag And Lift Forces Of Turbulent Newtonian Flow On Arbitrarily Shaped Shells On The Seafloor, Carley R. Walker, James V. Lambers, Julian Simeonov

Dissertations

Currently, all forecasts of currents, waves, and seafloor evolution are limited by a lack of fundamental knowledge and the parameterization of small-scale processes at the seafloor-ocean interface. Commonly used Euler-Lagrange models for sediment transport require parameterizations of the drag and lift forces acting on the particles. However, current parameterizations for these forces only work for spherical particles. In this dissertation we propose a new method for predicting the drag and lift forces on arbitrarily shaped objects at arbitrary orientations with respect to the direction of flow that will ultimately provide models for predicting the sediment sorting processes that lead to …

Analysis Of Fossil Pollen From A Pleistocene Cypress Forest Preserved On The Northern Gulf Of Mexico Continental Shelf, Kathryn Joyce Garretson

Master's Theses

This study presents the findings of fossil pollen analysis performed on terrestrial sediments preserved on the northern Gulf of Mexico continental shelf (site hereafter known as the Underwater Forest or DF). This research aims to establish vegetation composition on a continental shelf glacial refuge and provide a better understanding of vegetation response to sea-level rise. Two cores (15DF1 and 15DF3B) located at different locations within the forest were recovered and analyzed. Pollen results from both cores were similar, with high percentages of Taxodium and Nyssa pollen in the lowermost sections reflecting an assemblage typical of contemporary baldcypress swamps. Pollen assemblages …

Understanding Biogeochemical And Physical Controls On Methane Air-Sea Exchange Fluxes In The Pacific Ocean, Sarah Raney

Master's Theses

Methane and trace element samples were collected on GEOTRACES GP15 Pacific Meridional Transect (PMT) cruise conducted between the Aleutian Islands (57 °N) and Tahiti (20 °S) from September to November 2018. Uncertainty in methane air-sea exchange fluxes was determined using a propagation of errors approach. Fluxes ranged from -0.88 to 4.9 µmol CH₄ m^-2 d^-1. Average CH₄ flux along the Alaskan margin was 2.2 ± 2.9 µmol CH₄ m^-2 d^-1. Methane fluxes decreased moving southward and increased to their open ocean maximum around 20 °N before declining in equatorial waters. Near …

Hydrolytically Degradable Thermosets With Tunable Degradation Profiles Via Ketal-Based Crosslinks, Benjamin Alameda

Dissertations

Thermoset polymer networks are ubiquitous in the construction of high-performance materials due to their excellent mechanical properties, solvent resistance, and thermomechanical performance. However, the crosslinked structure that instills these materials with favorable performance also makes them incredibly resistant to degradation and are nearly impossible to recycle – adding to the ever-growing problem of plastic pollution. Hydrolytically degradable thermosets have emerged as a potentially sustainable alternative to traditional thermosets by affording networks that are inherently degradable in aqueous environments. This dissertation focuses on the development of hydrolytically degradable thermoset networks with tunable degradation behavior through the implementation of ketal-based crosslinks. Given …

A Comparison Of Natural, Living, And Hardened Shorelines Ability To Prevent Coastal Erosion And Maintain A Healthy Ecosystem, Gabrielle Spellmann

Master's Theses

It is important to find a suitable method to protect the U.S. Gulf Coast shoreline, since its’ low elevation and the Loop current make it vulnerable to sea level rise. I focused on two manmade methods, hardened, and living shorelines, of coastal protection for when the natural marsh suffers excess erosion rates. Living shorelines are a suite of shoreline conservation and restoration techniques that usually involve some sort of hardened structure that dampens wave energy so that the native vegetation behind it can take root and stabilize the shoreline. This study looked at six different sites, all containing a natural, …

Analyzing And Detecting Android Malware And Deepfake, Md Shohel Rana

Dissertations

Rapid advances in artificial intelligence (AI), machine learning (ML), and deep learning (DL) over the past several decades have produced a variety of technologies and tools that, among numerous cybersecurity issues, have enticed cybercriminals and hackers to design malware for the Android operating systems and/or manipulate multimedia. For example, high-quality and realistic fake videos, images, or audios have been created to spread misinformation and propaganda, foment political discord and hate, or even harass and blackmail people; these manipulated, high-quality and realistic videos became known recently as Deepfake. There has been much work done in recent years on malware analysis and …

Privacy-Aware And Hardware-Based Accleration Authentication Scheme For Internet Of Drones, Tom Henson

Master's Theses

Drones are becoming increasingly present into today’s society through many different means such as outdoor sports, surveillance, delivery of goods etc. With such a rapid increase, a means of control and monitoring is needed as the drones become more interconnected and readily available. Thus, the idea of Internet of drones (IoD) is formed, an infrastructure in place to do those types of things. However, without an authentication system in place anyone could gain access or control to real time data to multiple drones within an area. This is a problem that I choose to tackle using a Field Programmable Gate …

Investigation Of N-Sulfonyliminium Ion Triggered Cyclizations For The Synthesis Of Piperidine Scaffolds, Kaitlyn Birkhoff

Honors Theses

In consideration of the on-going global pandemic, immediate access to Food and Drug Administration approved pharmaceutical medications and vaccines is a matter of utmost priority to our national healthcare system. One significant modality in managed care is the dispensation of prescription drugs for the prevention or treatment of illnesses and diseases. According to the Centers for Disease Control and Prevention, physicians order and provide over 2.9 billion prescriptions each year with analgesics, antihyperlipidemics, and dermatological agents being the most prescribed therapeutic classes. Within those classes exists a disparate variety of chemical structures that must be prepared on a metric ton …

Techniques For The Enantioselective Asymmetric Synthesis Of Benzyl Substituted Malonic Acid Esters, Madison Hansen

Honors Theses

A popular method for the enantioselective synthesis of substituted malonic half esters is hydrolysis via Pig Liver Esterase (PLE), however some substrates produce low enantiomeric excess, namely benzyl-substituted malonic esters. Presented here are alternative methods explored for this synthesis, the first being phase-transfer catalyzed hydrolysis via N-benzyl quaternary ammonium salts derived from cinchona alkaloids. The second method utilized chiral auxiliary directed benzylation with auxiliaries including menthol and oxazolidinones. Though unsuccessful, this research provided valuable groundwork in the investigation for the enantioselective asymmetric synthesis of benzyl-substituted malonic acid esters.

Keywords: Pig Liver Esterase, Enantioselectivity, Phase-Transfer Catalysis, Cinchona Alkaloids, Quaternary Ammonium …

Synthesis Of Molecular Probes For The Detection Of Toxic Analytes, Rashid Mia

Dissertations

Two different types of molecular probes have been synthesized. The first family of probes is the coumarin class of compounds. These chemodosimters are referred to as Low Molecular Weight Fluorescent probes (LMFP). The other type of molecular probe is a macrocycle known as a pillar[5]arene receptor.

The chemodosimters (2.12a-c and 3.12a) were synthesized in four to five steps. The photophysical properties were extensively studied in various solvent systems (DMSO, CH₃CN, DMF, MeOH, EtOH, Me₂CO, MeCO₂Et, CHCl₃, C₆H₅Me, and C₆H₆). Dimethyl sulfoxide (DMSO) …

Multi-Valued Solutions For The Equation Of Motion, Darcy-Jordan Model, As A Cauchy Problem: A Shocking Event, Chandler Shimp

Master's Theses

Shocks are physical phenomenon that occur quite often around us. In this thesis we examine the occurrence of shocks in finite amplitude acoustic waves from a numerical perspective. These waves, or jump discontinuities, yield ill-behaved solutions when solved numerically. This study takes on the challenge of finding both single- and multi-valued solutions.

The previously unsolved problem in this study is the representation of the Equation of Motion (EoM) in the form of the Darcy-Jordan model (DJM) and expressed as a dimensionless IVP Cauchy problem. Prior attempts to solve have resulted only in implicit solutions or explicit solutions with certain initial …

Chitosan Graphene Composite Fabrication And Characterization For Treatment Of Harmful Algal Blooms And Toxins, Sarah Zetterholm

Master's Theses

Chitosan graphene composites were fabricated and characterized as a management strategy for harmful algal blooms (HABs) caused by various species of cyanobacteria. These chitosan graphene materials were compared to previously studied chitosan graphene-oxide composites in both material properties and HAB treatment. In previous studies, adsorption of the cyanobacteria onto the surface of the composite materials has been observed. Investigations of the pure materials for these composites are also included in this study to determine whether removal is a result of charge interactions with the composite, or as an inherent property of the graphene or graphene oxide. Initial results suggest that …

Controlling Degradation With Force And Light, Brad Davis

Dissertations

Stimuli-responsive polymers respond to changes in their environment by altering their physical and chemical properties. Their responsiveness allows them to be used as sensors, mechanical actuators, delivery systems, and can yield either elongated lifetimes through healing mechanisms or shortened lifetimes through triggered degradation. Still a growing field in polymer science, researchers seek to expand the capabilities of these materials by improving their specificity, range, and mechanisms of both the stimuli and the response. The work presented explores stimuli-responsive materials, focusing on mechanical and light stimuli, and how to gain control of the response by specific changes in the polymeric material. …

Polycyclic Aromatic Hydrocarbons And The Microbiomes Of Two Benthic Species, Samantha Ells

Master's Theses

The presence of oil has been shown to affect the microbiomes of the water column, sediments, and organisms, both by altering the diversity and the composition of those microbial communities. If the microbiome is altered it may no longer provide benefits to its host organism, impacting its ability to survive. Thus, it is important to understand the effects of large-scale contamination events including the Deepwater Horizon oil spill. This study set out to examine the effects of oil exposure on the microbiome of two benthic species, southern flounder (Paralichthys lethostigma) and eastern oysters (Crassostrea virginica) to further understand the effects …

On A Stochastic Model Of Epidemics, Rachel Prather

Master's Theses

This thesis examines a stochastic model of epidemics initially proposed and studied by Norman T.J. Bailey [1]. We discuss some issues with Bailey's stochastic model and argue that it may not be a viable theoretical platform for a more general epidemic model. A possible alternative approach to the solution of Bailey's stochastic model and stochastic modeling is proposed as well. Regrettably, any further study on those proposals will have to be discussed elsewhere due to a time constraint.

Sedimentology And Shallow Groundwater Responses Of A Coastal Marsh Along A Salinity Gradient: A Case Study In Grand Bay National Estuarine Research Reserve, Mississippi, James Thompson

Master's Theses

Climate change and relative sea level rise is resulting in saltwater intrusion and inundation of coastal marshes. This study investigates factors affecting marsh hydrology, including sediment composition, seasonal variability, and coastal storms in Grand Bay National Estuarine Research Reserve (NERR) near Pascagoula, Mississippi. Analysis of sediment includes color, organic matter, carbonate, magnetic susceptibility, and particle size. Shallow groundwater hydrologic trends between Summer 2015 and Fall 2016 are established along a salinity gradient at four sites using water levels, temperature, and conductivity monitored at the surface and in piezometers at depths of 0.75m, 1.5m, and 2.25m.

Sediment analysis indicates reducing conditions …

A Modified Preconditioned Conjugate Gradient Method For Approximating The Scattering Amplitude, Samson Ayo

Master's Theses

In this thesis, we look at an iterative method for approximating the scattering amplitude that involves solving two linear systems: a forward system Ax=b and an adjoint system A^Ty=g. Once these two systems are solved, the scattering amplitude, defined by g^Tx=y^Tb is easily obtained.

We derive a conjugate gradient-like iteration for a nonsymmetric saddle point matrix that is constructed to have a real positive spectrum. We investigate the use of Schur Complement preconditioners with block-diagonal factorization to speed up the convergence of our method and compare …

Differences In Erosion Rates And Elevation Among Natural, Living And Hardened Shorelines In Mississippi, And Alabama, Brittany Juneau

Honors Theses

Shoreline erosion is a phenomenon that currently threatens both natural ecosystems and human settlements along the coast. With trends showing gradual sea level rise as a result of climate change, erosion is becoming an increasing threat to these communities. This research aims to provide more insight into the relationship between shoreline morphology and three shoreline protection techniques: natural marsh, living shoreline, and hardened structures. Six sites along the Alabama and Mississippi coast that had all three shoreline types were evaluated to determine what the average erosion rate and slope was for each shoreline. Erosion rates were calculated by image analysis …

Ensemble Data Fitting For Bathymetric Models Informed By Nominal Data, Samantha Zambo

Dissertations

Due to the difficulty and expense of collecting bathymetric data, modeling is the primary tool to produce detailed maps of the ocean floor. Current modeling practices typically utilize only one interpolator; the industry standard is splines-in-tension.

In this dissertation we introduce a new nominal-informed ensemble interpolator designed to improve modeling accuracy in regions of sparse data. The method is guided by a priori domain knowledge provided by artificially intelligent classifiers. We recast such geomorphological classifications, such as ‘seamount’ or ‘ridge’, as nominal data which we utilize as foundational shapes in an expanded ordinary least squares regression-based algorithm. To our knowledge …

Doping Of Conjugated Polymers: Preparation, Characterization And Device Fabrication, Kan Tang

Dissertations

Semiconducting conjugated polymers (CPs) as emerging materials for advanced electronic applications such as sensors, OPVs, and OEFTs has become an intriguing research topic in the past decades. It opens a new avenue of “flexible” electronics, which has shown great potential in next-generation electronic devices.

However, due to the nature of CP materials and related solution processing techniques, unlike almost perfectly crystalline silicon materials, CPs in the solid-state often exhibit much lower crystallinity if it is not complete amorphous, which severely hinder the electronic property and optical property of the materials. The crystallinity of CPs in a film is often uniquely …

Photopolymer Networks With Tunable Command Destruct Properties, William Walker

Dissertations

Photoinduced thiol-catalyzed hydrogen abstraction and beta-scission of acyclic benzylidene acetals is demonstrated as a new route to “command-destruct” polymer thermosets. Using this approach, we show that poly(thioether acetal) networks synthesized via thiol-ene photopolymerization rapidly degrade to alkyl benzoate byproducts when triggered with light, transitioning from solid to liquid within seconds. The light-driven construction and destruction processes, accessible via distinct differences in kinetics, are readily amendable for photopatterning, additive/subtractive manufacturing, and wavelength-selective applications.

The first chapter of this dissertation details the development of command-destruct poly(thioether acetal) networks via a previously unexplored mechanism for polymer degradation. The degradation mechanism is confirmed via …