Physical Sciences and Mathematics Commons^™

3dq: Threat Dome Visibility Querying On Mobile Devices, James Carswell, Keith Gardiner, Junjun Yin

Articles

3DQ (Three Dimensional Query) is our mobile spatial interaction (MSI) prototype for location and orientation aware mobile devices (i.e. today's sensor enabled smartphones). The prototype tailors a military style threat dome query calculation using MSI with hidden query removal functionality for reducing “information overload” on these off-the-shelf devices. The effect gives a more accurate and expected query result for Location-Based Services (LBS) applications by returning information on only those objects visible within a user’s 3D field-of-view. Our standardised XML based request/response design enables any mobile device, regardless of operating system and/or programming language, to access the 3DQ web-service interfaces.

Mechanistic Studies Of In Vitro Cytotoxicity Of Poly(Amidoamine) Dendrimers In Mammalian Cells, Sourav Prasanna Mukherjee, Fiona Lyng, Amaya Garcia, Maria Davoren, Hugh Byrne

Articles

Poly(amidoamine) (PAMAM) dendrimer nanoparticles have been demonstrated to elicit a well defined cytotoxicological response from mammalian cell lines, the response increasing systematically with dendrimer generation and number of surface amino groups. In this work, using generation G4, G5, and G6 dendrimers, this systematic response is furthermore demonstrated for the generation of reactive oxygen species, lysosomal activity, and the onset of apoptosis and levels of DNA damage. The results are consistent with a pathway of localisation of PAMAM dendrimers in the mitochondria leading to ROS production causing oxidative stress, apoptosis and DNA damage. ROS production is co-located in the mitochondria, and …

Influence Of Hybrid Organic–Inorganic Sol–Gel Matrices On The Photophysics Of Amino-Functionalized Uv-Sensitizers, Mohamed Oubaha, R. Copperwhite, Catherine Boothman, A. Ovsianikov, R. Kiyan, V. Purlys, M. O'Sullivan, Colette Mcdonagh, B. Chichkov, R. Gadonas, B.D. Maccraith

Articles

Recent interest in photolithographic processes employing single and two-photon absorption processes have afforded advanced opportunities to fabricate both planar and three-dimensional microstructures. The fabrication of such structures is dependent on the local polymerization of the organic moieties using photoinitiating molecules, and a key parameter to consider is the dependency of the photoreactivity of these initiators on the matrices in which they are dispersed. To our knowledge, there has been no comprehensive investigation reported on the photoreactivity dependency of commercially available photoinitiators inserted within hybrid sol–gel materials. The aim of this paper is to highlight and explain the influence of the …

Inverse Scattering Transform For The Degasperis–Procesi Equation, Adrian Constantin, Rossen Ivanov, Jonatan Lenells

Articles

We develop the Inverse Scattering Transform (IST) method for the Degasperis- Procesi equation. The spectral problem is an sl(3) Zakharov-Shabat problem with constant boundary conditions and finite reduction group. The basic aspects of the IST such as the construction of fundamental analytic solutions, the formulation of a Riemann-Hilbert problem, and the implementation of the dressing method are presented.

Topology In Composite Spatial Terms, John D. Kelleher, Robert J. Ross

Conference papers

People often refer to objects by describing the object's spatial location relative to another object, e.g. the book on the right of the table. This type of referring expression is called a spatial locative expression. Spatial locatives have three major components: (1) the target object that is being located (the book), (2) the landmark object relative to which the target is being located (the table), and (3) the description of the spatial relationship that exists between the target and the landmark (on the right of ). In English spatial relationships are often described using spatial prepositions. The set of English …

A Suggested Building Block Geometry Without Continuous Radial Joints Of Possible Relevance For Particle Detectors, Jim Mcgovern

Articles

A geometry for concentrc shells or tubes, built-up from a single rhombohedral block type, is described. Continuous radial joints are avoided.

In Vitro Enabling Technologies For Use In The Aquatic Environment, Colm J. O'Dowd

Doctoral

O’Dowd, C., Mothersill, C.E., Cairns, M.T., Austin, B., Lyng, F.M., McClean, B. and Murphy, J.E.J. Assessing the mitochondrion as a biomarker of fish tissue damage using g radiation as a stress model in vitro.

There is an ever-increasing need for biomarkers to identify toxic stress in the aquatic environment. Such techniques need to be accurate, expeditious, ethical and economical. Typically, in vitro based platforms fit these criteria however many of these systems often undergo ‘assay drift’ and consequently do not fully represent the real-life situation.

In recent years, there has been growing interest in the mitochondrion and its (dys)function …

A Life Cycle Cost Analysis Of Large-Scale Thermal Energy Storage Technologies For Buildings Using Combined Heat And Power, Kenneth Gaine, Aidan Duffy

Conference Papers

Buildings account for approximately 40% of energy consumption and greenhouse gas (GHG) emissions in developed economies, of which approximately 55% of building energy is used for heating and cooling. The reduction of building-related GHG emissions is a high international policy priority. For this reason and because there are many technical solutions for this, these polices should involve significant improvements in the uptake of small-scale energy efficient (EE) systems. However the widespread deployment of many technologies, must overcome a number of barriers, one of which is a temporal (diurnal or seasonal) mismatch between supply and demand. Costeffective thermal storage solutions have …

The Generation Of Domestic Electricity Load Profiles Through Markov Chain Modelling, Aidan Duffy, Fintan Mcloughlin, Michael Conlon

Conference Papers

Micro-generation technologies such as photovoltaics and micro-wind power are becoming increasing popular among homeowners, mainly a result of policy support mechanisms helping to improve cost competiveness as compared to traditional fossil fuel generation. National government strategies to reduce electricity demand generated from fossil fuels and to meet European Union 20/20 targets is driving this change. However, the real performance of these technologies in a domestic setting is not often known as high time resolution models for domestic electricity load profiles are not readily available. As a result, projections in terms of reducing electricity demand and financial paybacks for these micro-generation …

Proceedings Of The Sixth International Natural Language Generation Conference (Inlg 2010)., John D. Kelleher, Brian Mac Namee, Ielka Van Der Sluis

Conference papers

No abstract provided.

Rapid Multi-Class Multi-Residue Method For The Confirmation Of Chloramphenicol And Eleven Nitroimidazoles In Milk And Honey By Liquid Chromatography Tandem Mass Spectrometry, Mark Cronly, Patrice Behan, Barry Foley, Liam Regan, Sheila Martin, Michael Doyle, Edward Malone

Articles

A confirmatory method has been developed to allow for the analysis of eleven nitroimidazoles and also chloramphenicol in milk and honey samples. These compounds are classified as A6 compounds in annex IV of council regulation 2377/90 and therefore prohibited for the use in animal husbandry. Milk samples are extracted by acetonitrile with addition of NaCl, while honey samples are first dissolved in water before a similar extraction. Honey extracts undergo a hexane wash to remove impurities. Both milk and honey extracts are evaporated to dryness and reconstituted in initial mobile phase. These are then injected onto an LC-MS/MS system and …

A Systematic Study Of The Effect Of Silver On The Chelation Of Formic Acid To A Titanium Precursor And The Resulting Effect On The Anatase To Rutile Transformation Of Tio2, Nicholas Nolan, Michael Seery, Steve Hinder, Linda Healy, Suresh Pillai

Articles

Anatase to rutile transition in an unmodified synthetic titania usually occurs at a temperature range of 600 – 700 °C. Various methods such as addition of metallic and non-metallic dopants and modifying the precursor have previously been reported to influence the anatase to rutile transition temperature. In the current study, the effect of addition of increasing amounts of silver to the extent of chelation of a formate group to a titanium precursor and the resulting effects on the transformation of anatase to rutile has been studied. The addition of silver (0, 1, 3 and 5 mol %) on the anatase …

Information Hiding Using Stochastic Diffusion For The Covert Transmission Of Encrypted Images, Jonathan Blackledge

Conference papers

A principal weakness of all encryption systems is that the output data can be `seen' to be encrypted. In other words, encrypted data provides a 'flag' on the potential value of the information that has been encrypted. In this paper, we provide a novel approach to `hiding' encrypted data in a digital image. We consider an approach in which a plaintext image is encrypted with a cipher using the processes of `stochastic diffusion' and the output quantized into a 1-bit array generating a binary image cipher-text. This output is then `embedded' in a host image which is undertaken either in …

Highly Visible Light Active Tio2-Xnx Heterojunction Photocatalysts, Vinodkumar Etacheri, Michael Seery, Steven Hinder, Suresh Pillai

Articles

Nitrogen doped anatase-rutile heterojunctions are successfully synthesized through an ethylene-diaminetetraacetic acid (EDTA) modified sol-gel process.An FT-IR study of EDTA modified TiO2 gel confirms the existence of an ionic intermediate (as indicated by a Δν value of 233 cm-1).Differential scanning calorimetry (DSC), X-ray diffraction (XRD), and Raman spectroscopy are employed to study the phase evolution, phase purity, and crystallite size of samples. Formations of O-Ti-N and N-Ti-N bonds in calcined samples are confirmed using XPS and FT-IR spectro- scopy. AllEDTAmodified samples show significantly higher visible light photocatalytic activity than the unmodified sample. The most active nitrogen doped heterojunction obtained at 400C …

Solar Radiation Investigations; A Foundation Study, Alanna Maguire

Doctoral

Skin cancer is a global epidemic that is increasing annually. However, our knowledge of the mechanisms involved in skin carcinogenesis is relatively poor. Investigative studies to date have predominantly employed fluorescent UV A and I or UVB lamps. The information gained from such studies has pioneered this area of research effectively, however, the typical unimodal Gaussian distribution of such irradiators do not reflect that of solar radiation nor do they account for potential waveband interactions. Advancing technologies in solar simulation have opened up this field to more environmentally and biologically relevant exposures, not only in terms of distribution but also …

Handling Concept Drift In Text Data Stream Constrained By High Labelling Cost, Patrick Lindstrom, Sarah Jane Delany, Brian Mac Namee

Conference papers

In many real-world classification problems the concept being modelled is not static but rather changes over time - a situation known as concept drift. Most techniques for handling concept drift rely on the true classifications of test instances being available shortly after classification so that classifiers can be retrained to handle the drift. However, in applications where labelling instances with their true class has a high cost this is not reasonable. In this paper we present an approach for keeping a classifier up-to-date in a concept drift domain which is constrained by a high cost of labelling. We use …

Input-Output Analysis Of Irish Construction Sector Greenhouse Gas Emissions, Adolf Acquaye, Aidan Duffy

Articles

Ireland is committed to limiting its greenhouse gas (GHG) emissions to 113% of 1990 levels over the period 2008-12 and to 84% of 2005 levels by 2020 under the Kyoto Agreement and the EU’s ’20 20’ by 2020 respectively. National policies have targeted many industry sectors but have failed to directly tackle GHG emissions associated with construction activity. This paper estimates energy and GHG emissions intensities of the Irish construction sector and subsectors and estimates its contribution to Irish national emissions. This information is used to identify and assess the impacts of policy measures which would result in a reduction …

A Raman Spectroscopy Study Of The Solubilisation Of Swcnts By Polycyclic Aromatic Hydrocarbons, Sourabhi Debnath, Qiaohuan Cheng, Theresa Hedderman, Hugh Byrne

Articles

The effectiveness of polycyclic aromatic hydrocarbons (PAHs) for selective solubilisation of single walled carbon nanotubes (SWCNTs) has been studied by Raman spectroscopy. Polyphenyl and polyacene PAHs of different lengths are used. Selective interaction between the PAHs and SWCNT is investigated by analyzing the Raman radial breathing modes the frequency positioning of which yields information concerning the diameter distribution of the SWCNT sample. Samples were dispersed at concentrations below the debundling limit and deposited on quartz substrates. A combination of four laser excitation energies was utilized to establish the distribution of diameters present. The results show that the PAHs interact with …

Measuring Variations Of Mimicry By Means Of Prosodic Cues In Task-Based Scenarios And Conversational Speech, Brian Vaughan, Celine De Looze

Other resources

Here, we address the measurement of mimicry, that is when speakers’ speech variations look like parallel patterns.

As a definition of mimicry, we often read in the literature description such as mimicry is “The situation where the observed behaviours of two inter-actants although dissimilar at the start of the interaction are moving towards behavioral matching”. These types of descriptions imply that mimicry is a linear phenomenon and that speakers tend to imitate over time. However, it can be assumed, especially when studying spontaneous speech, that there are rather phases of mimicry and non-mimicry and that mimicry should be rather …

Dispersion Of Single-Walled Carbon Nanotubes In Organic Solvents, Qiaohuan Cheng

Doctoral

This thesis contains a systematic study of the dispersion of pristine HiPco Single Walled Carbon Nanotubes (SWNTs) in a series of organic solvents. A double beamed UV-Vis-NIR absorption spectrometer coupled with an integrating sphere was employed to demonstrate the dispersibility of SWNTs in different solvents. Raman Spectroscopy and Atomic Force Microscopy (AFM) were used to confirm the debundling and exfoliation of SWNTs aggregates. An investigation of the solubility of SWNTs in four chlorinated aromatic solvents demonstrated that the similarity in structure between solvent molecules and nanotube sidewall is not a dominant factor to obtain stable SWNT solutions. A comparative study …

Dual-Action Hygienic Coatings: Benefits Of Hydrophobicity And Silver Ion Release And Surface Analysis, Niall Stobie, Brendan Duffy, John Colreavy, Patrick Mchale, Steven Hinder, Declan Mccormack

Articles

Coatings that demonstrate reduced attachment of crystalline precipitates and the medical device colonising Staphylococcus epidermidis were prepared by the immobilisation of silver doped perfluoropolyether–urethane siloxane thin films on glass substrates. The presence of stratified hydrophobic perfluoropolyether groups protects the coating surface from the attachment of crystalline hydrophilic species such as chlorides and phosphates, whilst silver ion release inhibited attachment of S. epidermidis and subsequent biofilm formation in vitro. The release of silver ions protects the perfluoro groups from the hydrophobic interactions of S. epidermidis cells, which can reduce the hydrophobicity of the protective coating. These coatings also exhibited significant antibacterial …

The Camassa-Holm Hierarchy And Soliton Perturbations, Georgi Grahovski, Rossen Ivanov

Conference papers

The theory of soliton perturbations is considered. The focus is on the usefulness of the so-called Generalised Fourier Transform (GFT). This is a method that involves expansions over the complete basis of “squared solutions” of the spectral problem, associated to the soliton equation. The Inverse Scattering Transform for the corresponding hierarchy of soliton equations can be viewed as a GFT where the expansions of the solutions have generalised Fourier coefficients given by the scattering data. The GFT provides a natural setting for the analysis of small perturbations to an integrable equation: starting from a purely soliton solution one can ’modify’ …

Two Soliton Interactions Of Bd.I Multicomponent Nls Equations And Their Gauge Equivalent, Vladimir Gerdjikov, Georgi Grahovski

Conference papers

Using the dressing Zakharov-Shabat method we re-derive the effects of the two-soliton interactions for the MNLS equations related to the BD.I-type symmetric spaces. Next we generalize this analysis for the Heisenberg ferromagnet type equations, gauge equivalent to MNLS.

Seeing Is Believing: Body Motion Dominates In Multisensory Conversations, Cathy Ennis, Rachel Mcdonnell, Carol O'Sullivan

Articles

In many scenes with human characters, interacting groups are an important factor for maintaining a sense of realism. However, little is known about what makes these characters appear realistic. In this paper, we investigate human sensitivity to audio mismatches (i.e., when individuals’ voices are not matched to their gestures) and visual desynchronization (i.e., when the body motions of the individuals in a group are mis-aligned in time) in virtual human conversers. Using motion capture data from a range of both polite conversations and arguments, we conduct a series of perceptual experiments and determine some factors that contribute to the plausibility …

A Model For Predicting Extragalactic Jet Lifetimes, Daniel S. Spicer, Robert Bingham, Stephen O'Sullivan

Articles

Abstract. In this letter, we propose a model to explain the disintegration of ex- tragalactic jets and to predict the associated timescale. The model assumes that a jet is current and charge neutral as well as collimated at its source; however, the forward electron current gradually decays producing a magnetic field transverse to the direction of jet propagation. This growing transverse magnetic field eventually causes the jet to disintegrate.

Structure-Reactivity Relationships Of L-Proline Derived Spirolactams And A-Methyl Prolinamide Organocatalysts In The Asymmetric Michael Addition Reaction Of Aldehydes To Nitroolefins., Fintan Kelleher, Sinead Kelly, John Watts, Vickie Mckee

Articles

L-Proline derived spirolactams and a-methyl prolinamides act as organocatalysts for the asymmetric conjugate addition of aldehydes to nitroolefins in excellent yields, with good diastereoselectivity and enantioselectivity. Furthermore, low catalyst loadings (5 mol%) and a low aldehyde molar excess (1.5 molar equivalents) were achieved.

Imaging Live Cells Grown On A Three Dimensional Collagen Matrix Using Raman Microspectroscopy, Franck Bonnier, Peter Knief, Basil Lim, Aidan Meade, Jennifer Dorney, Kunal Bhattacharya, Fiona Lyng, Hugh Byrne

Articles

Three dimensional collagen gels have been used as matrices for the imaging of live cells by Raman spectroscopy. The study is conducted on a human lung adenocarcinoma (A549) and a spontaneously immortalized human epithelial keratinocyte (HaCaT) cell line. The lateral resolution of the system has been estimated to be

Corrosion Protection Properties Of Various Ligand Modified Organic Inorganic Hybrid Coating On Aa 2024-T3, P.C. Rajath Varma, John Cassidy, Mohamed Oubaha, Colette Mcdonagh, John Colreavy, Brendan Duffy

Articles

The inclusion of zirconium precursors to prepare organosilane solgel coatings improves the corrosion protection performance of the coatings on aluminium and steel. The inherent differences in the hydrolysis rates of the silane and zirconium precursors, various ligands were used to control the hydrolysis by decreasing the number of reactive alkoxide group. Hybrid sols were synthesised using 3-(trimethoxysilyl) propylmethacrylate (MAPTMS) and zirconium n-propoxide chelated with organic ligands including different organic acids, acetyl acetone and 2 2’ bipyridyl. The effects of zirconia inclusion on the properties of the coatings were compared on the aerospace alloy AA 2024-T3.

Electrochemical analysis and salt spray …

The Maximal Pure Spectrum Of An Abelian Group, Brendan Goldsmith, Ruediger Goebel

Articles

This paper introduces the notion of the maximal pure spectrum of an Abelian group - this is the set of isomorphism classes of maximal proper pure subgroups - and focuses on the situation in which this spectrum is small. The converse situation is also examined i.e. given a collection of isomorphism classes of groups, can one find an Abelian group having precisely this collection as its maximal pure spectrum. Finally, it is shown that in some familiar situations, the answers to these questions may be undecidable.

Corrosion Protection Properties Of Various Ligand Modified Organic Inorganic Hybrid Coating On Aa 2024-T3, Rajath Varma, John Cassidy, Mohamed Oubaha, Colette Mcdonagh, John Colreavy, Brendan Duffy

Articles

The inclusion of zirconium precursors to prepare organosilane solgel coatings improves the corrosion protection performance of the coatings on aluminium and steel. The inherent differences in the hydrolysis rates of the silane and zirconium precursors, various ligands were used to control the hydrolysis by decreasing the number of reactive alkoxide group. Hybrid sols were synthesised using 3-(trimethoxysilyl) propylmethacrylate (MAPTMS) and zirconium n-propoxide chelated with organic ligands including different organic acids, acetyl acetone and 2 2’ bipyridyl. The effects of zirconia inclusion on the properties of the coatings were compared on the aerospace alloy AA 2024-T3. Electrochemical analysis and salt spray …