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- Synthesis (6)
- Flavonoids (3)
- Lamiaceae (3)
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- Antibacterial activity (2)
- Biological studies (2)
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- Heterogeneous catalysis (2)
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- Iridoid glycosides (2)
- Microwave synthesis (2)
- Phenylethanoid glycosides (2)
- Polyacrylamide (2)
- Polyimide (2)
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- Semicarbazones (2)
- Steroid (2)
- Trace elements (2)
- Triterpenoids (2)
- X-ray structure (2)
- ^1H NMR (2)
- (2E)-2 (1)
- 1 (1)
- 1-ethyl-1 (1)
- 15-deoxycampanuloic acid (1)
Articles 31 - 60 of 78
Full-Text Articles in Physical Sciences and Mathematics
Iridoid, Flavonoid, And Phenylethanoid Glycosides From Wiedemannia Orientalis, Zühal Güvenalp, Hi̇lal Özbek, Türesi̇n Ünsalar, Cavi̇t Kazaz, L. Ömür Demi̇rezer
Iridoid, Flavonoid, And Phenylethanoid Glycosides From Wiedemannia Orientalis, Zühal Güvenalp, Hi̇lal Özbek, Türesi̇n Ünsalar, Cavi̇t Kazaz, L. Ömür Demi̇rezer
Turkish Journal of Chemistry
Five iridoid glycosides, lamiide, ipolamiide, ipolamiidoside, 6\beta-hydroxyipolamiide, and 5-hydroxy-8-epi-loganin; 5 flavonoid glycosides, apigenin 7-O-\beta-glucopyranoside, luteolin 5-O-\beta- glucopyranoside, isorhamnetin 3-O-rutinoside, quercetin 3-O-rutinoside, and apigenin 7-O-(6''-O-trans-p-coumaroyl) \beta-glucopyranoside; and a phenylethanoid glycoside, acteoside (= verbascoside), were isolated from the aerial parts of Wiedemannia orientalis (Lamiaceae). Their structures were identified using spectral methods (UV, 1D- and 2D-NMR, and EI-MS).
Electrochemical Synthesis Of N-Methylpyrrole And N-Methylcarbazole Copolymer On Carbon Fiber Microelectrodes, And Their Characterization, A. Sezai̇ Saraç, Erkan Doğru, Murat Ateş, Eli̇f Altürk Parlak
Electrochemical Synthesis Of N-Methylpyrrole And N-Methylcarbazole Copolymer On Carbon Fiber Microelectrodes, And Their Characterization, A. Sezai̇ Saraç, Erkan Doğru, Murat Ateş, Eli̇f Altürk Parlak
Turkish Journal of Chemistry
Copolymer films of N-methylpyrrole (N-MPy) and N-methylcarbazole (N-MCz) were synthesized electrochemically onto single carbon fiber microelectrodes (CFMEs). Deposition conditions on the carbon fiber, influence of the monomer concentrations on the copolymerization of P[N-methylpyrrole-co-N-methylcarbazole] P[N-MPy-co-N-MCz], and the electrochemistry of the resulting homopolymer and copolymers were studied using cyclic voltammetry, FTIR-ATR, in-situ spectroelectrochemistry, a UV-vis spectrophotometer, and a 4-point probe conductometer. The effects of current density, supporting electrolyte type, temperature, and monomer concentrations on the formation of the film were studied. Redox parameters and stability of charged films were obtained by cyclic voltammetry. The most stable copolymer was obtained in lithium perchlorate-acetonitrile …
Synthesis, Characterization, Crystal Structure And Thermal Behavior Of N'-(4-Chlorobenzoyl)-N,N-Di-N-Butylthiourea And Its Nickel Complex, Hakan Arslan, Ulrich Flörke, Nevzat Külcü, Esra Kayhan
Synthesis, Characterization, Crystal Structure And Thermal Behavior Of N'-(4-Chlorobenzoyl)-N,N-Di-N-Butylthiourea And Its Nickel Complex, Hakan Arslan, Ulrich Flörke, Nevzat Külcü, Esra Kayhan
Turkish Journal of Chemistry
We report the synthesis, structural characterization and thermal behavior of N'-(4-chlorobenzoyl)-N,N-di-n-butylthiourea (HL) and its nickel complex (NiL_2). Some physical properties of the prepared compounds were investigated using elemental analyses, IR, ^1H-NMR, and magnetic susceptibility. The molecular structures of HL and NiL_2 were determined by single crystal X-ray diffraction. HL is a monoclinic, space group P2_1/c with a = 10.7457(5) Å, b = 15.5909(8) Å, c = 10.4536(5) Å, \beta = 104.398(1)°, and V = 1696.34(14) Å^3 with Z = 4 for d_{calc} = 1.280 g/cm^3. NiL_2 is a triclinic, space group P-1 with a = 8.561(3) Å, b = 16.643(6) …
Chemistry Of Bicyclic Endoperoxides Derived From Dihydropyridine Derivatives: Attempted Synthesis Of Polyhydroxypiperidine Derivatives, Emi̇ne Salamci, Beyhan Bayram, Meti̇n Balci
Chemistry Of Bicyclic Endoperoxides Derived From Dihydropyridine Derivatives: Attempted Synthesis Of Polyhydroxypiperidine Derivatives, Emi̇ne Salamci, Beyhan Bayram, Meti̇n Balci
Turkish Journal of Chemistry
To achieve the synthesis of azasugar derivatives with the utilization of singlet oxygen, pyridine was used as the starting material. The reduction of pyridine followed by a singlet oxygen reaction afforded cyclic aza-endoperoxides (14 and 16). However, many attempts were made to convert the aza-endoperoxides to the corresponding di- and triacetates without success. However, the base-catalyzed rearrangement of 14 gave unprecedented rearrangement products 23 and 24.
Short And Effective Synthesis Of A Thiophene Analogue Of (\Pm)-4-Ipomeanol And Its Biological Evaluation, Jurgen Krauss, Doris Unterreitmeier, Franz Bracher
Short And Effective Synthesis Of A Thiophene Analogue Of (\Pm)-4-Ipomeanol And Its Biological Evaluation, Jurgen Krauss, Doris Unterreitmeier, Franz Bracher
Turkish Journal of Chemistry
The thiophene analogue of (\pm)-4-ipomeanol (1) was prepared in 2 steps starting from 3-iodothiophene and pent-4-yn-2-ol. The key steps were a Sonogashira reaction, followed by HgO catalysed hydratisation of the triple bond. The resulting thiophene was tested in the MTT assay for its cytotoxic activity against HL 60 cells.
Optical Fluoride Sensing With A Bay Region Functionalized Perylenediimide Dye, Funda Yukruk
Optical Fluoride Sensing With A Bay Region Functionalized Perylenediimide Dye, Funda Yukruk
Turkish Journal of Chemistry
A perylenedimiide (PDI) derivative functionalized at the perylene core (bay region) to carry phenyl boronic acid groups was shown to interact with fluoride with changes in the emission and absorption spectrum. These changes are most likely due to fluoride-induced aggregation and/or quenching of the perylenediimide dye. The dye is also selective; among halide ions, fluoride anions generate a significant response. Thus, this class of PDI derivatives is likely to be useful in practical fluoride sensing.
The Synthesis Of 4-Phenoxyphenylglyoxime And 4,4'-Oxybis(Phenylglyoxime) And Their Complexes With Cu(Ii), Ni(Ii) And Co(Ii), Ahmet Coşkun
The Synthesis Of 4-Phenoxyphenylglyoxime And 4,4'-Oxybis(Phenylglyoxime) And Their Complexes With Cu(Ii), Ni(Ii) And Co(Ii), Ahmet Coşkun
Turkish Journal of Chemistry
4-Acetyldiphenyl ether and 4,4'-diacetyldiphenyl ether were synthesized from diphenyl ether and acetyl chloride in the presence of AlCl_3 used as catalyst. Subsequently, their keto oxime and glyoxime derivatives were prepared. The metal complexes of the glyoximes such as Cu(II), Ni(II) and Co(II) were also prepared. The structures of these ligands and their complexes were identified by FT-IR, ^1H NMR and ^{13}C NMR spectral data, elemental analysis and magnetic measurements.
Spectroscopic Characterisation And Biological Applications Of Organotin(Iv) Derivatives Of 3-(N-Naphthylaminocarbonyl)-2-Propenoic Acid, Sajjad Ahmad, Moazzam H. Bhatti, Saqib Ali, Fiaz Ahmed
Spectroscopic Characterisation And Biological Applications Of Organotin(Iv) Derivatives Of 3-(N-Naphthylaminocarbonyl)-2-Propenoic Acid, Sajjad Ahmad, Moazzam H. Bhatti, Saqib Ali, Fiaz Ahmed
Turkish Journal of Chemistry
In an effort to develop new organotin materials for investigation and biocidal evaluation, a series of compounds with the general formula R_{4 - n}SnL_n (where R = CH_3, n-C_4H_9, C_6H_5, C_6H_5CH_2 and L = 3-(N-naphthylaminocarbonyl)-2-propenoic acid) were synthesised, and characterised by elemental analysis, IR, multinuclear (^1H, ^{13}C and ^{119}Sn) NMR, ^{119m}Sn Mössbauer spectroscopy and mass spectrometry. The biological activity of these compounds against various bacteria and fungi was investigated. All of the compounds were active against the fungi tested with a few exceptions. These compounds also showed significant antibacterial activity. LD_{50} data show that the investigated compounds have significant toxicity.
Terpenic And Phenolic Compounds From Sideritis Stricta, F. Pinar Şahi̇n, Nurten Ezer, İhsan Çaliş
Terpenic And Phenolic Compounds From Sideritis Stricta, F. Pinar Şahi̇n, Nurten Ezer, İhsan Çaliş
Turkish Journal of Chemistry
From the overground parts of an endemic Sideritis species, S. stricta, 4 diterpenes, sideridiol (1), isosidol (2), isolinearol (3), and linearol (4); 2 flavonoid glycosides, isoscutellarein 7-O-[6'''-O-acetyl-\beta -D-allopyranosyl-(1 \to 2)]-\beta -D-glucopyranoside (5), and isoscutellarein 7-O-[6'''-O-acetyl-\beta -D-allopyranosyl-(1 \to 2)]-6''-O-acetyl-\beta -D-glucopyranoside (6); a methoxyflavone, xanthomicrol (7); and a phenylethanoid glycoside, verbascoside (=acteoside) (8) were isolated. The structures of the isolated compounds were established based on spectroscopic evidence (UV, IR, 1D- and 2D-NMR, MS).
Synthesis And Biological Activities Of N-Alkyl Derivatives Of O-, M-, And P-Nitro (E)-4-Azachalcones And Stereoselective Photochemistry In Solution, With Theoretical Calculations, Nuretti̇n Yayli, Osman Üçüncü, Ahmet Yaşar, Murat Küçük, Nuran Yayli, Emi̇ne Akyüz, Şengül Alpay Karaoğlu
Synthesis And Biological Activities Of N-Alkyl Derivatives Of O-, M-, And P-Nitro (E)-4-Azachalcones And Stereoselective Photochemistry In Solution, With Theoretical Calculations, Nuretti̇n Yayli, Osman Üçüncü, Ahmet Yaşar, Murat Küçük, Nuran Yayli, Emi̇ne Akyüz, Şengül Alpay Karaoğlu
Turkish Journal of Chemistry
The N-alkyl derivatisation and photochemical dimerisation of 3 o-, m-, and p-nitro substituted 4-azachalcones (1-3) yielded 3 new o-, m-, and p-nitro substituted (E)-N-decyl-4-azachalconium bromides, (2E)-1-(2-nitrophenyl)-3-(N-decyl-4-pyridinium bromide)-2-propen-1-one (4), (2E)-1-(3-nitrophenyl)-3-(N-decyl-4-pyridinium bromide)-2-propen- 1-one (5), and (2E)-1-(4-nitrophenyl)-3-(N-decyl-4-pyridinium bromide)- 2-propen-1-one (6), and 3 new dimers in solution, (1\beta, 2\alpha)-di- (3-nitrobenzoyl)-(3\beta, 4\alpha)-di-(4-pyridinyl) cyclobutane (7), (1\beta, 2\alpha)-di-(4-nitrobenzoyl)-(3\beta,4\alpha)-di-(4-pyridinyl) cyclobutane (8a), and (1\beta, 2\beta)-di-(4-nitrobenzoyl)-(3\beta, 4\alpha)-di-(4-pyridinyl)cyclobutane (8b), stereoselectively. The monomeric compounds showed good antimicrobial activity against test micro-organisms. The most sensitive micro-organisms were Gram-positive bacteria. The monomers also showed high antioxidant activity, while the dimerisation products 7-8a,b were less active. Compound 6 was found to have similar or even …
Chemical Constituents Of Galium Tortumense, Zühal Güvenalp, Nurcan Kiliç, Cavi̇t Kazaz, Yusuf Kaya, L. Ömür Demi̇rezer
Chemical Constituents Of Galium Tortumense, Zühal Güvenalp, Nurcan Kiliç, Cavi̇t Kazaz, Yusuf Kaya, L. Ömür Demi̇rezer
Turkish Journal of Chemistry
From the aerial parts of Galium tortumense Ehrend & Schönb.-Tem., 8 iridoid glycosides, a flavonol glycoside, a oleanane-type triterpene acid, an ursan-type triterpene acid and a sterol were isolated. The structures of the compounds were elucidated by high field 1D and 2D NMR and EIMS spectroscopies.
Iridoids, Flavonoids And Monoterpene Glycosides From Galium Verum Subsp. Verum, L. Ömür Demi̇rezer, Fi̇li̇z Gürbüz, Zühal Güvenalp, Karsten Ströch, Axel Zeeck
Iridoids, Flavonoids And Monoterpene Glycosides From Galium Verum Subsp. Verum, L. Ömür Demi̇rezer, Fi̇li̇z Gürbüz, Zühal Güvenalp, Karsten Ströch, Axel Zeeck
Turkish Journal of Chemistry
From the aerial parts of Galium verum subsp. verum L. were isolated 7 iridoid glycosides, asperuloside (1), asperulosidic acid (2), deacetyl-asperulosidic acid (3), monotropein (4), 6-O-epi-acetylscandoside (5), daphylloside (6) and deacetyl-daphylloside (7); 2 flavonol glycosides, astragalin [= kaempferol 3-O-\beta-glucopyranoside] (8) and rutin [= quercetin 3-O- rutinoside] (9); and 2 monoterpene glycosides, betulalbuside A (10) and (2E)-2,6-dimethyl-2,7-octadien-1,6-diol-6-O-\beta -glucopyranoside (11). The structures of the isolates were established by 1D and 2D NMR spectroscopy in combination with IR, UV and ESI-MS analysis.
The Impact Of Polyacrylamide Molecular Weight On Its Adsorption Behavior At The Gold/Acidic Solution Interface, Dragica B. Chamovska, Toma P. Grchev, Maja V. Cvetkovska
The Impact Of Polyacrylamide Molecular Weight On Its Adsorption Behavior At The Gold/Acidic Solution Interface, Dragica B. Chamovska, Toma P. Grchev, Maja V. Cvetkovska
Turkish Journal of Chemistry
Adsorption isotherms for polyacrylamide (PAA) on polycrystalline gold, from sulfuric acid (potential range 0-2.0 V/she; 293 K), were obtained by means of cyclic voltammetry with simultaneous monitoring of the double-layer capacity. The Frumkin isotherm indicates that relatively strong attractive forces are present (a = 0.8-1.0), and the Gibbs energies range between 43 and 56 kJ mol^{-1}. The coverage (\theta) of the metal surface with polymer molecules depends on the molar concentration of PAA, as well as on its molecular weight, and the size of the statistical polymer coil in the solution (R_G = 7.49 \times 10^{-3} \times M_n^{0.64}/nm). The adsorption …
Synthesis Of 1-Cyclohept-1,2-Dien-1-Yl Benzene From 1-(2-Iodo-, Chlorocyclohept-1-En-1-Yl)Benzene And 1-(2-Iodo-, Chlorocyclohept-2-En-1-Yl)Benzene: Its Trapping With Diphenylisobenzofuran, Mustafa Ceylan, Yakup Budak, Murat Ulukaya, M. Burcu Gürdere, Esra Findik
Synthesis Of 1-Cyclohept-1,2-Dien-1-Yl Benzene From 1-(2-Iodo-, Chlorocyclohept-1-En-1-Yl)Benzene And 1-(2-Iodo-, Chlorocyclohept-2-En-1-Yl)Benzene: Its Trapping With Diphenylisobenzofuran, Mustafa Ceylan, Yakup Budak, Murat Ulukaya, M. Burcu Gürdere, Esra Findik
Turkish Journal of Chemistry
The key compounds vinyl iodides 12a and 13a, for the generation of 1-cyclohept-1,2-dien-1-ylbezene (1), were synthesized from cycloheptanone (5). Bromobenzene was converted to the Grignard reagent, which was condensed with 5. Dehydration of alcohol 6 gave alkene 7. Hydroboration of 7 followed by oxidation with PCC afforded ketone 9, which was converted to hydrazone 10. Treatment of 10 with iodine resulted in the formation of 12a and 13a. The other precursors, 12b and 13b, were synthesized from the reaction of 9 with PCl_5. Reactions of 12a, b and 13a, b with KOtBu in a sealed tube at 185 °C gave …
Simple Synthesis Of \Alpha -Oxime Derivatives Of 2-Ketomethyl Quinolines Under Mild And Heterogeneous Conditions, Javad Safari, Mehdi Adib, Firouzeh Sheibani, Zahra Sadeghi
Simple Synthesis Of \Alpha -Oxime Derivatives Of 2-Ketomethyl Quinolines Under Mild And Heterogeneous Conditions, Javad Safari, Mehdi Adib, Firouzeh Sheibani, Zahra Sadeghi
Turkish Journal of Chemistry
2-Ketomethyl quinolines are converted to their \alpha-oximinoketone derivatives in quantitative yields using sodium nitrite in the presence of silica sulfuric acid as nitrosating agent under mild and heterogeneous conditions.
Synthesis And Properties Of Triazol-5-One Substituted Phthalocyanines By Microwave Irradiation, Bahatti̇n Kahveci̇, Selami̇ Şaşmaz, Musa Özi̇l, Ci̇han Kantar, Başak Koşar, Orhan Büyükgüngör
Synthesis And Properties Of Triazol-5-One Substituted Phthalocyanines By Microwave Irradiation, Bahatti̇n Kahveci̇, Selami̇ Şaşmaz, Musa Özi̇l, Ci̇han Kantar, Başak Koşar, Orhan Büyükgüngör
Turkish Journal of Chemistry
Triazol-5-one substituted phthalocyanines were prepared quickly by the reaction of 4-nitrophthalonitrile with anhydrous metal salts in DBU (1,8-diazabicyclo[5,4,0]undec-7-ene) and DMAE (dimethylaminoethanol) by microwave irradiation. Microwave yields were higher than those of the conventional synthesis methods. All of these complexes are insoluble in polar solvents such as ethanol, ethyl acetate and chloroform. The characterization of the compounds was accomplished by elemental analysis, ^1H NMR (for I and II), ^{13}C NMR (for I and II), IR and UV-Vis spectral data. In addition, the structure of the starting material (I) was determined by single crystal diffraction.
A New Method For The Preparation Of Pyridazine Systems: Experimental Data And Semiempirical Pm3 Calculations, Di̇lek Ünal, Emi̇n Saripinar, Yunus Akçamur
A New Method For The Preparation Of Pyridazine Systems: Experimental Data And Semiempirical Pm3 Calculations, Di̇lek Ünal, Emi̇n Saripinar, Yunus Akçamur
Turkish Journal of Chemistry
The reactions of 4-benzoyl-5-phenyl-2,3-furandione (1a) and 4-(4-methoxybenzoyl)-5-(4-methoxyphenyl)-2,3-furandione (1b) with acyl hydrazines (2) (namely hydrazides) are reported. From these reactions, novel pyridazinone systems (3a-g) are obtained as well as the cyclization product of 3g at high temperature (4). The electronic properties and conformational parameters for these molecules, such as bond lengths, bond angles, torsion angles and atom charges, are calculated with a semiempirical PM3 method. In order to determine the mechanism of the reaction between the model furandion (R1) and formic hydrazide (R2), the electronic properties, conformational parameters and imaginary frequencies of the reactants, transition states and intermediates are calculated at …
The Mechanism And Crystal Structure Of 2-Methoxy-2-Methyl-4-Phenyl-3,4,4a, 10b-Tetrahydro-2h,5h-Pyrano[3,2-C]Chromen-5-One. Acetal Of Warfarin Acid, Saira Shahzadi, Saqib Ali, Irum Asif, Rizwana Ashraf, Guo-Xin Jin
The Mechanism And Crystal Structure Of 2-Methoxy-2-Methyl-4-Phenyl-3,4,4a, 10b-Tetrahydro-2h,5h-Pyrano[3,2-C]Chromen-5-One. Acetal Of Warfarin Acid, Saira Shahzadi, Saqib Ali, Irum Asif, Rizwana Ashraf, Guo-Xin Jin
Turkish Journal of Chemistry
Acetal of warfarin acid has been synthesized via a hemi acetal intermediate and structurally characterized by X-ray diffraction. The crystal structure shows that the title compound was formed by the hydrolysis of warfarin acid in methanol at pH 3, with space group P2_1/n and unit cell parameters a = 5.859 (17), b =16.745 (5), c = 16.402 (5) Å, \alpha = 90.00; \beta = 94.853 (4), and \gamma = 90.00°.
Cerium(Iii) Ion-Selective Electrodes Based On 1,4,7-Trithiacyclononane, Hamid Reza Pouretedal, Abolfazl Semnani, Mohammad Hossein Keshavarz
Cerium(Iii) Ion-Selective Electrodes Based On 1,4,7-Trithiacyclononane, Hamid Reza Pouretedal, Abolfazl Semnani, Mohammad Hossein Keshavarz
Turkish Journal of Chemistry
Novel plasticized polymeric membrane (PPME) and coated platinum wire (CPWE) electrodes based on 1,4,7-trithiacyclononane and oleic acid, as a good lipophilic additive for highly selective determination of Ce^{3+} ions, have been developed. The electrodes exhibit a Nernstian slope of 19.4 mV/decade (for both electrodes) over a wide Ce^{3+} ion concentration range, from 5.0 \times 10^{-6}-5.0 \times 10^{-2} M and 1.0 \times 10^{-7}-1.0 \times 10^{-2} M for PPME and CPWE, respectively. The limits of detection were 3.5 \times 10^{-6} and 8.0 \times 10^{-8} M for PPME and CPWE, respectively. The electrodes possess a fast response time of 15 s, can be …
Hydrothermal And Microwave-Assisted Synthesis Of Boroarsenate, Baso_4, Abdulhadi̇ Baykal, Ayten Evren
Hydrothermal And Microwave-Assisted Synthesis Of Boroarsenate, Baso_4, Abdulhadi̇ Baykal, Ayten Evren
Turkish Journal of Chemistry
BAsO_4 was previously synthesized by solid-state reactions at 800 °C and was characterized by X-ray powder diffraction. Now, we succeeded in preparing BAsO_4 from H_3BO_3 and As_2O_5 using hydrothermal synthesis by heating at 160 °C for 3 days (a single-phase product) and using microwave-assisted synthesis, which takes only 5 min to transform a solid mixture of As_2O_5 and (NH_4)_2B_4O_7.4H_2O into the crystalline titled compound (a single-phase product). The crystallinity of the products is higher than that of the solid-state synthesized product given in the literature. Its X-ray powder diffraction patterns, and both Raman and IR spectra were in good agreement …
Synthesis, Spectroscopic (Ft-Ir, ^1h, ^{13}C, Mass Spectrometry), And Biological Investigation Of Five-Coordinated Germanium-Substituted Tricyclohexyl Antimony Dipropionates: Crystal Structure Of Tricyclohexylantimony Dibromide, Muhammad Kaleem Khosa, Muhammad Mazhar, Saqib Ali, Kieran C. Molloy, Sarim Dastgir, Farkhanda Shaheen
Synthesis, Spectroscopic (Ft-Ir, ^1h, ^{13}C, Mass Spectrometry), And Biological Investigation Of Five-Coordinated Germanium-Substituted Tricyclohexyl Antimony Dipropionates: Crystal Structure Of Tricyclohexylantimony Dibromide, Muhammad Kaleem Khosa, Muhammad Mazhar, Saqib Ali, Kieran C. Molloy, Sarim Dastgir, Farkhanda Shaheen
Turkish Journal of Chemistry
A series of five-coordinated germanium-substituted tricyclohexylantimony dipropionates have been synthesized and characterized by different instrumental techniques, such as elemental analyses, FT-IR, multinuclear NMR (^1H, ^{13}C) and mass spectrometry. These compounds have also been screened against different microbes and they showed good activity against different bacteria that was comparable to the reference drugs. The crystal structure of the precursor (C_6H_{11})_3SbBr_2 is reported here, which showed that the antimony atom in an asymmetric unit exists in trigonal bipyramidal geometry, having space group C2/c with the monoclinic crystal system.
Template Synthesis And Structural Characterization Of Homo Binuclear Chromium(Iii), Manganese(Iii), Iron(Iii), Cobalt(Iii), And Ruthenium(Iii) Complexes With Octaazamacrocyclic Ligands, Vinod K. Sharma, Shipra Srivastava
Template Synthesis And Structural Characterization Of Homo Binuclear Chromium(Iii), Manganese(Iii), Iron(Iii), Cobalt(Iii), And Ruthenium(Iii) Complexes With Octaazamacrocyclic Ligands, Vinod K. Sharma, Shipra Srivastava
Turkish Journal of Chemistry
The Schiff base octaazamacrocyclic ligands derived from primary diamines and 3,6-dimethyl/diphenyl-4,5-diazaocta-3,5-diene-2,7-dione, and their binuclear complexes [M_2LCl_4]Cl_2 [M = Cr(III), Fe(III), Co(III), or Ru(III)] and [Mn_2L(AcO)_4](AcO)_2 were synthesized by template condensation reactions. Attempts to synthesize the corresponding metal-free macrocyclic ligands did not prove successful. The overall geometry and stereochemistry of these complexes were elucidated by elemental analyses, magnetic susceptibilities, electronic spectra, infrared spectra, molar conductance measurements, ^1H NMR, and thermogravimetric analysis. All the trivalent metal ion complexes appear to be 1:2 electrolytes. An octahedral geometry is proposed for all the complexes.
Electrochemical Copolymerization Of Thiophene Containing Pseudo-Polyether Cages With Pyrrole, Ati̇lla Ci̇haner, Ahmet M. Önal
Electrochemical Copolymerization Of Thiophene Containing Pseudo-Polyether Cages With Pyrrole, Ati̇lla Ci̇haner, Ahmet M. Önal
Turkish Journal of Chemistry
Conducting copolymers were synthesized via the electrochemical oxidation of pyrrole (Py) in the presence of the monomer 1,12-bis(2-thienyl)-2,5,8,11-tetraoxadodecane (I). The presence of monomer I in the electrolytic solution greatly changed the CV behavior of Py during its potensiodynamic polymerization. The electroactivity of poly(I-co-Py) increased with the increasing amount of I in the comonomer mixture. Copolymer films were prepared via constant potential electrolysis in an electrolytic solution containing 0.1 M tetrabutylammonium hexafluorophosphate (TBAPF_6) dissolved in acetonitrile. The spectroelectrochemical properties of the films were investigated using UV-VIS spectroscopy.
Attempted Synthesis Of 1-Cyclohepta-1,2-Dien-1-Ylbenzene And Wurtz-Like Condensation Products In The Reaction Of 1-(2,3-Dibromocyclohept-1-En-1-Yl)Benzene With Zinc, Mustafa Ceylan, Yakup Budak, M. Burcu Gürdere
Attempted Synthesis Of 1-Cyclohepta-1,2-Dien-1-Ylbenzene And Wurtz-Like Condensation Products In The Reaction Of 1-(2,3-Dibromocyclohept-1-En-1-Yl)Benzene With Zinc, Mustafa Ceylan, Yakup Budak, M. Burcu Gürdere
Turkish Journal of Chemistry
7,7-Dibromo-1-phenylbicyclo[4.1.0]heptane 4 was synthesized and its thermal and silver ion-catalyzed rearrangements were studied. Alcohol 8 was converted to 1-(2,3-dibromocyclohept-1-en-1-yl)benzene 6. The zinc-mediated elimination of 1-(2,3-dibromocyclohept-1-en-1-yl)benzene 6 resulted in the formation of 2 isomeric Wurtz-like condensation products 15 and 16 (whose structural assignments were based on ^1H-and ^{13}C-NMR spectral data) instead of the expected 1-cyclohepta-1,2-dien-1-ylbenzene 14.
A New Flame-Retardant Polyamide Containing Phosphine Oxide And N,N-(4,4-Diphenylether) Moieties In The Main Chain: Synthesis And Characterization, Khalil Faghihi
Turkish Journal of Chemistry
A new flame-retardant polyamide containing phosphine oxide moieties in the main chain was synthesized from the solution polycondensation reaction of bis(3-aminophenyl) phenyl phosphine oxide with N,N-(4,4-diphenylether) bis trimellitimide, using thionyl chloride, N-methyl-2-pyrolidone, and pyridine as condensing agents. This new polymer was obtained in high yield (92%), has high inherent viscosity (0.73 dL/g), and was characterized by elemental analysis, FT-IR spectroscopy, thermal gravimetric analysis (TGA and DTG), and solubility testing. Furthermore, another polyamide was prepared by the solution polycondensation reaction of N,N-(4,4-diphenylether) bis trimellitimide with 1,4-phenylene diamine, and its flame-retardant behavior was compared to that of the previous one.
Synthesis, Spectral And Thermal Characteristics Of Some Ten Coordinated Complexes Of Dioxouranium(Vi) Derived From Semicarbazones As Primary Ligand And Diphenyl Sulfoxide As Secondary Ligand, Ram K. Agarwal, Surendra Prasad
Synthesis, Spectral And Thermal Characteristics Of Some Ten Coordinated Complexes Of Dioxouranium(Vi) Derived From Semicarbazones As Primary Ligand And Diphenyl Sulfoxide As Secondary Ligand, Ram K. Agarwal, Surendra Prasad
Turkish Journal of Chemistry
The reactions of dioxouranium(VI) acetate with several semicarbazones derived from 4-aminoantipyrine in the presence of diphenyl sulfoxide (DPSO) led to the formation of complexes corresponding to the formulae [UO_2(CH_3COO)_2 (L).DPSO], where L = 4[N-(benzalidene)amino]antipyrinesemicarbazone (BAAPS), 4[N-(2'-hydroxybenzalidene)- amino]antipyrinesemicarbazone (HBAAPS) 4[N-(4'-methoxybenzalidene)amino] antipyrine semicarbazone (MBAAPS) 4[N-(4'-dimethylaminobenzalidene)amino]- antipyrinesemicarbazone (DABAAPS) 4[N-(2'-nitrobenzalidene)amino]antipyrine- semicarbazone (2'-NO_2 BAAPS) 4[N-(3'-nitrobenzalidene)amino]antipyrine- semicarbazone (3'-NO_2BAAPS) 4[N-(4'-nitrobenzalidene)amino]antipyrine- semicarbazone (4'-NO_2BAAPS), 4[N-(4'-hydroxy-3'-methoxybenzalidene)amino]- antipyrinesemicarbazone (HMBAAPS) 4[N-(2'-hydroxy-1'-naphthalidene)amino]- antipyrinesemicarbazone (HNAAPS) 4[N-(cinnamalidene)amino]antipyrine- semicarbazone (CAAPS)4[N-(3',4',5'-trimethoxybenzalidene)amino]antipyrine- semicarbazone (TMBAAPS) and 4[N-(furfural)amino]antipyrinesemicarbazone (FFAAPS). The complexes were characterised by means of elemental analyses, conductivity measurements, molecular weight, magnetic moments and infrared studies. The coordination number 10 is proposed for these complexes. Thermal properties of the …
Synthesis Of Vic-Dioxime Derivatives With Hydrazone Side Groups And Their Metal Complexes, İlknur Babahan, Hüseyi̇n Anil, Nursabah Sarikavakli
Synthesis Of Vic-Dioxime Derivatives With Hydrazone Side Groups And Their Metal Complexes, İlknur Babahan, Hüseyi̇n Anil, Nursabah Sarikavakli
Turkish Journal of Chemistry
Two novel vic-dioxime (L^1H_2, L^2H_2) compounds bearing hydrazone side groups and their transition metal complexes Ni(II), Co(II), Cu(II), and Zn(II) were synthesized. The vic-dioxime ligands bearing hydrazone side groups were synthesized by reacting anti-glyoximehydrazine (GH_2) with 4-nitroacetophenone and 4-methylacetophenenone, respectively. Ligands form mononuclear complexes [(LH)_2M] with a metal to ligand ratio of 1:2 with M=Co(II)(H_2O)_2, Ni(II), and Cu(II). Zn(II) forms complexes [(LH)(H_2O)(Cl)Zn] with a metal to ligand ratio of 1:1. The Co(II) complexes of the ligands are proposed to be octahedral with water molecules as axial ligands, the Ni(II) and Cu(II) complexes are proposed to be square planar, and the …
Synthesis Of Some New Functionalized Octasilsesquioxane Hybrid Nanoclusters. Iii. Potential Of The Octameric Clusters As Hydraulic Lubricating Fluids, Enock O. Dare
Turkish Journal of Chemistry
The reaction of suitable organic compounds such as \omega -halo-1-alkenes, allyltrichlorosilane or 2-methyl-3-butyn-2-ol in combination with a well-defined inorganic silsesquioxane, H_8Si_8O_{12} A cores, leads to covalently bound organic-inorganic hybrid materials in high yields. The hydraulic fluid properties of these viscous hybrid materials were evaluated and compared with those of some commercially available hydraulic fluids: Mobil EAL 224H, Super-V (AP) and Puroil SHO. The results showed that most silsesquioxane semi-liquids possess hydraulic fluid properties comparable to those of the 3 commercial lubricants.
Superabsorbency, Ph-Sensitivity And Swelling Kinetics Of Partially Hydrolyzed Chitosan-G-Poly(Acrylamide) Hydrogels, Ali Pourjavadi, Gholam Reza Mahdavinia
Superabsorbency, Ph-Sensitivity And Swelling Kinetics Of Partially Hydrolyzed Chitosan-G-Poly(Acrylamide) Hydrogels, Ali Pourjavadi, Gholam Reza Mahdavinia
Turkish Journal of Chemistry
Acrylamide (AAm) monomer was directly grafted onto chitosan using ammonium persulfate (APS) as an initiator and methylenebisacrylamide (MBA) as a crosslinking agent under an inert atmosphere. Two factors affecting the swelling capacity of the obtained hydrogel, AAm and MBA concentrations, were studied. The polymer structures were characterized by FTIR spectroscopy. Water absorbencies of the hydrogels were compared between before and after the alkaline hydrolysis treatment. Saponification of chitosan-g-poly(acrylamide) (chitosan-g-PAAm) with a hot sodium hydroxide solution gave rise to a high water absorbency. Swelling of the hydrogel samples in saline solution (0.15 mol/L NaCl, CaCl_2 and AlCl_3) was examined. Swelling capacity …
Synthesis And Vibrational Spectroscopic Study Of Some Metal(Ii) Halide And Tetracyanonickelate Complexes Of Isonicotinic Acid, Ahmet Ataç, Fehmi̇ Bardak
Synthesis And Vibrational Spectroscopic Study Of Some Metal(Ii) Halide And Tetracyanonickelate Complexes Of Isonicotinic Acid, Ahmet Ataç, Fehmi̇ Bardak
Turkish Journal of Chemistry
The M(IN)_2Ni(CN)_4 [where M: Cu, Mn, Zn, IN: Isonicotinic acid, abbreviated to M-Ni-IN] tetracyanonickelate and some metal halide complexes with the following stoichiometries: Cu(IN)X_2 (X:Br,I), Cd(IN)_2X_2, (X:Cl,Br), and Zn(IN)_4X_2 (X:Br,I) were synthesized for the first time. Their FT-IR spectra were reported in the 4000-400 cm^{-1} region. Vibrational assignments were given for all the observed bands. The analysis of the vibrational spectra indicates that there are some structure-spectrum correlations. For a given series of isomorphous complexes, the sum of the difference between the values of the vibrational modes of uncoordinated isonicotinic acid that were coordinated to the metal ion isonicotinic acid …