Physical Sciences and Mathematics Commons^™

Investigation Of Climate Variability And Climate Change Impacts On Corn Yield In The Eastern Corn Belt, Usa, Ruoyu Wang

Open Access Dissertations

The increasing demand for both food and biofuels requires more corn production at global scale. However, current corn yield is not able to meet bio-ethanol demand without jeopardizing food security or intensifying and expanding corn cultivation. An alternative solution is to utilize cellulose and hemi-cellulose from perennial grasses to fulfill the increasing demand for biofuel energy. A watershed level scenario analysis is often applied to figure out a sustainable way to strike the balance between food and fuel demands, and maintain environment integrity. However, a solid modeling application requires a clear understanding of crop responses under various climate stresses. This …

Zephyr: A Social Psychology-Based Mobile Application For Long-Distance Romantic Partners, Dhiraj Bodicherla

Open Access Theses

Long-distance romantic relationships have become quite common nowadays. With CMC tools advancing day-by-day, their usage among LDRs is proliferating rapidly. Attachment-related anxiety and avoidance can block the ability to enjoy happy relationships. During such situations, remembering happy past moments can be comforting. In this study a mobile chat application that enables LDR couples to reminisce about happy moments was developed. This study primarily focuses on evaluating the usability of this mobile application using survey-based methods. System Usability Scale was considered to discuss the outcome of the study. The overall results provide useful recommendations for further improvements in the design of …

Extracting Cng Tls/Ssl Artifacts From Lsass Memory, Jacob M. Kambic

Open Access Theses

Currently, there is no publicly accessible, reliable, automated way to forensically decrypt Secure Socket Layer (SSL)/Transport Layer Security (TLS) connections that leverage ephemeral key negotiations as implemented by the modern Windows operating system. This thesis explores the Local Security Authority Sub-System (LSASS) process used for Key Isolation within the Windows 10 operating system in pursuit of identifying artifacts that would allow a solution to that problem, along with any other connection artifacts that could provide forensic value. The end result was the identication of TLS/SSL secrets from the key exchange and contextual artifacts that provide identication of the other party …

Analysis Of Scientific Argumentation In Two Physical Chemistry Classrooms Using The Pogil Approach, Alena C. Moon

Open Access Dissertations

The benefits of facilitating argumentation in science education have been well reported (Jimenez-Aleixandre & Erduran, 2007). Engaging in argumentation has shown to model authentic scientific inquiry as well as promote development of content knowledge. However, less emphasis has been placed on facilitating argumentation in upper level undergraduate courses, though it is important for evaluating undergraduate curricula to characterize upper level students’ scientific reasoning. This work considers two implementations of the POGIL physical chemistry curriculum and evaluates the classroom argumentation. The researchers aimed to consider the content of the arguments and dialectical features characteristic of socially constructed arguments (Nielson, 2013). To …

Grounding Robot Motion In Natural Language And Visual Perception, Scott Alan Bronikowski

Open Access Dissertations

The current state of the art in military and first responder ground robots involves heavy physical and cognitive burdens on the human operator while taking little to no advantage of the potential autonomy of robotic technology. The robots currently in use are rugged remote-controlled vehicles. Their interaction modalities, usually utilizing a game controller connected to a computer, require a dedicated operator who has limited capacity for other tasks.

I present research which aims to ease these burdens by incorporating multiple modes of robotic sensing into a system which allows humans to interact with robots through a natural-language interface. I conduct …

Development And Evaluation Of A Watershed-Scale Hybrid Hydrologic Model, Younghyun Cho

Open Access Dissertations

A watershed-scale hybrid hydrologic model (Distributed-Clark), which is a lumped conceptual and distributed feature model, was developed to predict spatially distributed short- and long-term rainfall runoff generation and routing using relatively simple methodologies and state-of-the-art spatial data in a GIS environment. In Distributed-Clark, spatially distributed excess rainfall estimated with the SCS curve number method and a GIS-based set of separated unit hydrographs (spatially distributed unit hydrograph) are utilized to calculate a direct runoff flow hydrograph, and time-varied SCS CN values and conditional unit hydrograph approach for different runoff depth-based flow convolution are also used to compute long-term rainfall-runoff flow hydrographs. …

Undergraduate Students' Goals For Chemistry Laboratory Coursework, Brittland K. Dekorver

Open Access Dissertations

Chemistry laboratory coursework has the potential to offer many benefits to students, yet few of these learning goals are realized in practice. Therefore, this study seeks to characterize undergraduate students’ learning goals for their chemistry laboratory coursework. Data were collected by recording video of students completing laboratory experiments and conducting interviews with the students about their experiences that were analyzed utilizing the frameworks of Human Constructivism and Self-Regulated Learning. A cross-sectional sampling of students allowed comparisons to be made among students with varying levels of chemistry experience and interest in chemistry. The student goals identified by this study were compared …

Advances In Solid Phase Microextraction For The Analysis Of Volatile Compounds In Explosives, Tire Treatments, And Entomological Specimens, William D. Kranz

Open Access Dissertations

Solid phase microextraction is a powerful and versatile technique, well-suited to the analysis of numerous samples of forensic interest. The exceptional sensitivity of the SPME platform, combined with its adaptability to traditional GC-MS systems and its ability to extract samples with minimal work-up, make it appropriate to applications in forensic laboratories.

In a series of research projects, solid phase microextraction was employed for the analysis of explosives, commercial tire treatments, and entomological specimens. In the first project, the volatile organic compounds emanating from two brands of pseudo-explosive training aids for use in detector dog imprinting were determined by SPME-GC-MS, and …

Double Optical Feedback And Pt-Symmetry Breaking Induced Nonlinear Dynamics In Semiconductor Lasers, Joseph S. Suelzer

Open Access Dissertations

A central aim of this research is to probe the nonlinear dynamics that arise in a semiconductor laser due to optical feedback. We investigate two schemes of optical feedback. The first scheme subjects the laser to optical feedback from two external cavities (or two loops), wherein each cavity contains a spectral filter. Using two filtered optical feedbacks, we experimentally demonstrate the ability to elicit and control unique dynamics in the optical emission frequency (wavelength) of the laser. These results are compared to a deterministic model describing the evolution of the complex electric field and carrier density of the laser. As …

Quantifying The Global N2o Emissions From Natural Ecosystems Using A Mechanistically-Based Biogeochemistry Model, Tong Yu

Open Access Theses

Nitrous oxide (N2O) has a great influence on atmospheric chemistry and climate. It is not only a major greenhouse gas, but also one of the largest ozone-depleting substances emitted from the biosphere. Process-based biogeochemistry modeling constrained by site-level observations is a feasible approach to quantifying its emissions at large temporal and spatial scales. This study developed a process-based biogeochemistry model of N2O emissions based on an extant biogeochemistry model, the Terrestrial Ecosystem Model (TEM). The model development includes: 1) incorporating the effects of physical conditions on both nitrification and denitrification and 2) implementing principles of the stoichiometry of carbon and …

Learning From Minimally Labeled Data With Accelerated Convolutional Neural Networks, Aysegul Dundar

Open Access Dissertations

The main objective of an Artificial Vision Algorithm is to design a mapping function that takes an image as an input and correctly classifies it into one of the user-determined categories. There are several important properties to be satisfied by the mapping function for visual understanding. First, the function should produce good representations of the visual world, which will be able to recognize images independently of pose, scale and illumination. Furthermore, the designed artificial vision system has to learn these representations by itself. Recent studies on Convolutional Neural Networks (ConvNets) produced promising advancements in visual understanding. These networks attain significant …

Effect Of Bioenergy Crops And Fast Growing Trees On Hydrology And Water Quality In The Little Vermilion River Watershed, Tian Guo

Open Access Dissertations

Energy security and sustainability require a suite of biomass crops, including woody species. Short rotation woody crops (SRWCs) such as Populus have great potential as biofuel feedstocks. Quantifying biomass yields of bioenergy crop and hydrologic and water quality responses to growth is important should it be widely planted in the Midwestern U.S. Subsurface tile drainage systems enable the Midwest area to become highly productive agricultural lands, but also create environmental problems like nitrate-N contamination of the water it drains. The Soil and Water Assessment Tool (SWAT) has been used to model watersheds with tile drainage, but the new tile drainage …

Fabrication And Photonics Properties Of Iii-V Semiconductor Nanowire Structures, Tzu-Ging Lin

Open Access Dissertations

III-V semiconductor nanowires (NWs) have shown great potential to be building blocks for optical, optoelectronic, and electronic devices due to their special transverse confinement of electrons and photons along the nanowire axis. In addition, semiconductor nanowires with subwavelength structures exhibit strong optical Mie resonance, making them ideal platforms for realizing novel optical devices, such as extreme solar energy absorbers and broadband light trapping devices. This special 1D optical Mie resonance can be enhanced by using semiconductor-core dielectric-shell (CS) and metal-core semiconductor-shell dielectric-outer shell (CSS) nanowire heterostructures. Those advantages can be even leveraged up by utilizing nanowire arrays, attributing to the …

Learning In Vision And Robotics, Daniel P. Barrett

Open Access Dissertations

I present my work on learning from video and robotic input. This is an important problem, with numerous potential applications. The use of machine learning makes it possible to obtain models which can handle noise and variation without explicitly programming them. It also raises the possibility of robots which can interact more seamlessly with humans rather than only exhibiting hard-coded behaviors. I will present my work in two areas: video action recognition, and robot navigation. First, I present a video action recognition method which represents actions in video by sequences of retinotopic appearance and motion detectors, learns such models automatically …

A History Of African And South American Basins, Rebecca A. Bobick

Open Access Theses

As hydrocarbon development in Africa and South America continues to expand, understanding the geologic evolution as well as the geologic symmetry of each of the continent's coastal basins grows increasingly important. Unfortunately, there's currently no comprehensive database that contains the stratigraphic record, depositional environments, and tectonic evolution available for either Africa or South America. Therefore, the goal of my research is to create an extensive datapack and guide booklet for Africa's major sedimentary basins, complete the South America datapack that's currently being constructed, and correlate the western African conjugate basins to the eastern South American conjugate basins. To accomplish this, …

Purification And Preparation Of Intrinsically Disordered Proteins For Nmr Spectroscopy, Kyle Chamberlain

Open Access Theses

NMR spectroscopy has recently become a promising field for protein characterization and dynamic studies. As the technology and pulse sequences improve for tracking proteins, a greater demand for developing effective purification protocols to produce NMR grade protein samples have arisen. This thesis explores two proteins: histone H4 tail and Mucin 1; Two very different proteins that require different methods of expression and purification to achieve a high enough yield for NMR analysis. H4 is a water soluble protein that weighs ~2.7 kDa, and has no extinction coefficient. Since the protein is too small for many methods of expression and purification, …

Hardware Accelerated Redundancy Elimination In Network System, Kelu Diao

Open Access Theses

With the tremendous growth in the amount of information stored on remote locations and cloud systems, many service providers are seeking ways to reduce the amount of redundant information sent across networks by using data de-duplication techniques. Data de-duplication can reduce network traffic without the loss of information, and consequently increase available network bandwidth by reducing redundant traffic. However, due to the heavy computation required for detecting and reducing redundant data transmission, de-duplication itself can become a bottleneck in high capacity links. We completed two parts of work in this research study, Hardware Accelerated Redundancy Elimination in Network Systems (HARENS) …

Social Customer Relationship Management In Higher Education, Victorian A. Farnsworth

Open Access Theses

Customer Relationship Management is a concept that has become a requirement for any successful entity to attract and retain desired constituents. It is a set of processes and tools that help track, analyze, and act upon customer related data. Over the last decade, the toolsets have evolved to include social media as another source of information and connection. Nowhere is this information and connection more important than in higher education where globalization and tighter budgets have created a competitive market. This research evaluated the use of this most recent social toolset and its effectiveness in a higher education institution, all …

User-Centric Workload Analytics: Towards Better Cluster Management, Suhas Raveesh Javagal

Open Access Theses

Effective management of computing clusters and providing a high quality customer support is not a trivial task. Due to rise of community clusters there is an increase in the diversity of workloads and the user demographic. Owing to this and privacy concerns of the user, it is difficult to identify performance issues, reduce resource wastage and understand implicit user demands. In this thesis, we perform in-depth analysis of user behavior, performance issues, resource usage patterns and failures in the workloads collected from a university-wide community cluster and two clusters maintained by a government lab. We also introduce a set of …

Economic And Environmental Impacts Of A Hypothetical Global Gmo Ban, Harrison H. Mahaffey

Open Access Theses

The objective of this research is to assess the global economic and greenhouse gas emission impacts of GMO crops. This is done by modeling two counterfactual scenarios and evaluating them apart and in combination. The first scenario models the impact of a global GMO ban. The second scenario models the impact of increased GMO penetration. The focus is on the price and welfare impacts, and land use change greenhouse gas (GHG) emissions associated with GMO technologies. Much of the prior work on the economic impacts of GMO technology has relied on a combination of partial equilibrium analysis and econometric techniques. …

Investigating U.S. Resident Perceptions Of Corporate Social Responsibility In Food And Agriculture, Carissa Jae Morgan

Open Access Theses

Corporations are prioritizing corporate social responsibility (CSR) activities by investing in and actively promoting their social practices. In the U.S. of the modern food supply chain creates a unique challenge for corporations to address concerns about social issues of consumers and non-consumers alike. This study is motivated by the need to better understand individuals’ perceptions of CSR as it pertains to the food supply chain. In April 2015 an online survey collected information from 1,201 U.S. residents with the objective of investigating individuals’ perceptions of relative importance of eight prominent CSR areas relevant to food and agriculture. Demographic, household consumption, …

Bridging Statistical Learning And Formal Reasoning For Cyber Attack Detection, Kexin Pei

Open Access Theses

Current cyber-infrastructures are facing increasingly stealthy attacks that implant malicious payloads under the cover of benign programs. Current attack detection approaches based on statistical learning methods may generate misleading decision boundaries when processing noisy data with such a mixture of benign and malicious behaviors. On the other hand, attack detection based on formal program analysis may lack completeness or adaptivity when modeling attack behaviors. In light of these limitations, we have developed LEAPS, an attack detection system based on supervised statistical learning to classify benign and malicious system events. Furthermore, we leverage control flow graphs inferred from the system event …

A Faster Version Of Louvain Method For Community Detection For Efficient Modeling And Analytics Of Cyber Systems, Sunanda Vivek Shanbhaq

Open Access Theses

Cyber networks are complex networks with various hosts forming the entities of the network and the communication between them forming the edges of the network. Most cyber networks exhibit a community structure. A community is a group of nodes that are densely connected with each other as compared to other nodes in the network. Representing an IP network in the form of communities helps in viewing the network from different levels of granularity and makes the visualization of the network cleaner and more pleasing to the eye. This will help significantly in cyber attack detection in large scale cyber networks. …

Unsupervised Learning Framework For Large-Scale Flight Data Analysis Of Cockpit Human Machine Interaction Issues, Abhishek B. Vaidya

Open Access Theses

As the level of automation within an aircraft increases, the interactions between the pilot and autopilot play a crucial role in its proper operation. Issues with human machine interactions (HMI) have been cited as one of the main causes behind many aviation accidents. Due to the complexity of such interactions, it is challenging to identify all possible situations and develop the necessary contingencies. In this thesis, we propose a data-driven analysis tool to identify potential HMI issues in large-scale Flight Operational Quality Assurance (FOQA) dataset. The proposed tool is developed using a multi-level clustering framework, where a set of basic …

Targeted Metabolomics On The Shikimate And Aromatic Amino Acid Biosynthetic Pathways, Robert E. Wheeler

Open Access Theses

The shikimate and aromatic amino acid biosynthesis pathways are some of the most studied biosynthetic pathways in nature due to their fundamental importance. Interest in this field stems from synthesis of the essential amino acids, tryptophan, tyrosine and phenylalanine. The pathways also are important as generating the precursors of thousands of secondary metabolites and lignin. Inhibiting the pathway has led to discovery of herbicides, pesticides as well as tuberculosis drugs. However there is currently a lack of a comprehensive targeted method for detecting and quantifying the majority of the intermediates in these pathways. Often multiple extraction and detection methods are …

Enhancing The Campus Experience: Helping International Students To Adapt To North American Campus Life, Qiaoying Wang

Open Access Theses

This thesis investigates how culture adaption topic can be applied to a design solution by enhancing international students experience on North American campus. Each year more than half a million international students enroll in American colleges and universities. Many will spend several years on a campus working toward their degree. Most of them arrive with clear academic goals, but they may have no clue what their social lives will be like. In that case, a common phenomenon that most of the international students need to get along with is called “Culture Shock”, which involves culture and academic adapting difficulties, limited …

Tadpole Orbits In The L4/L5 Region: Construction And Links To Other Families Of Periodic Orbits, Alexandre G. Van Anderlecht

Open Access Theses

The equations of motion in the Circular Restricted Three-Body Problem (CR3BP) allow five equilibrium solutions, that is, the Lagrange or libration points. Two of the five equilibrium solutions are the triangular or equilateral libration points, L4 and L 5. As the secondary gravitational body moves in its orbit about the larger mass, L4 and L5 lead and trail the secondary by 60 degrees, respectively. This investigation focuses on periodic solutions in the vicinity of the triangular libration points, specifically horseshoe and tadpole orbits. Horseshoe orbits are symmetric periodic solutions in the plane of primary motion encompassing both …

Controlling Electronics For The Formation Of High Valent Uranium Imido Complexes, Nickolas H. Anderson

Open Access Dissertations

Known primarily for its single electron chemistry, controlling the electronics at uranium to facilitate multi-electron processes remains a fundamental challenge in the actinide sciences. Our group has implemented the use of redox-active ligands to assist in the stabilization of low-valent uranium analogues, capable of performing multi-electron chemistry at a single uranium center. Of particular interest to our group are high-valent imido complexes, which are ubiquitous in organometallic and coordination chemistry due to their unique bonding properties and their ability to mediate bond-forming reactions. Uranium imido complexes, in particular, are the subject of much research to determine the degree of f- …

Regularity Of Solutions And The Free Boundary For A Class Of Bernoulli-Type Parabolic Free Boundary Problems With Variable Coefficients, Thomas H. Backing

Open Access Dissertations

In this work the regularity of solutions and of the free boundary for a type of parabolic free boundary problem with variable coefficients is proved. After introducing the problem and its history in the introduction, we proceed in Chapter 2 to prove the optimal Lipschitz regularity of viscosity solutions under the main assumption that the free boundary is Lipschitz. In Chapter 3, we prove that Lipschitz free boundaries possess a classical normal in both space and time at each point and that this normal varies with a Hölder modulus of continuity. As a consequence, the viscosity solution is in fact …

End-To-End Security In Service-Oriented Architecture, Mehdi Azarmi

Open Access Dissertations

A service-oriented architecture (SOA)-based application is composed of a number of distributed and loosely-coupled web services, which are orchestrated to accomplish a more complex functionality. Any of these web services is able to invoke other web services to offload part of its functionality. The main security challenge in SOA is that we cannot trust the participating web services in a service composition to behave as expected all the time. In addition, the chain of services involved in an end-to-end service invocation may not be visible to the clients. As a result, any violation of client’s policies could remain undetected. To …