Physical Sciences and Mathematics Commons^™

Gravity-Assist Trajectories To Venus, Mars, And The Ice Giants: Mission Design With Human And Robotic Applications, Kyle M. Hughes

Open Access Dissertations

Gravity-assist trajectories to Uranus and Neptune are found (with the allowance of impulsive maneuvers using chemical propulsion) for launch dates ranging from 2024 to 2038 for Uranus and 2020 to 2070 for Neptune. Solutions are found using a patched conic model with analytical ephemeris via the Satellite Tour Design Program (STOUR), originally developed at the Jet Propulsion Laboratory (JPL). Delivered payload mass is computed for all solutions for select launch vehicles, and attractive solutions are identified as those that deliver a specified amount of payload mass into orbit at the target body in minimum time. The best cases for each …

Redox-Active Ligand Uranium Complexes For Approaches To Multi-Electron Chemistry, John J. Kiernicki

Open Access Dissertations

While transition metal complexes are known to participate in multi-electron redox chemistry to facilitate important organometallic transformations, actinides, due to their low redox potentials, have a propensity to perform single electron chemistry. Because of its highly reducing nature, the ability to control the electronics of low-valent uranium is highly sought after as this may lead to unprecedented reactivity. Our lab has specifically been interested in mediating multi-electron transformations at uranium by employing redox-active ligands. Redox-active ligands can be used to facilitate multi-electron processes such as oxidative addition and reductive elimination at single metal centers. Using primarily 2,6-((Mes)N=CMe)2C5H3N) ( MesPDIMe) as …

Plasmonic Devices Based On Transparent Conducting Oxides For Near Infrared Applications, Kim Jongbum

Open Access Dissertations

In the past decade, there have been many breakthroughs in the field of plasmonics and nanophotonics that have enabled optical devices with unprecedented functionalities. Even though remarkable demonstration of at photonic devices has been reported, constituent materials are limited to the noble metals such as gold (Au) and silver (Ag) due to their abundance of free electrons which enable the support of plasmon resonances in the visible range. With the strong demand for extension of the optical range of plasmonic applications, it is now a necessity to explore and develop alternative materials which can overcome intrinsic issues of noble metals …

Hydrocode Modeling Of Oblique Impacts Into Terrestrial Planets, Jordan D. Kendall

Open Access Dissertations

The abundance of moderately siderophile elements (“iron-loving”; e.g., Co, Ni) in the Earth’s mantle is 10 to 100 times larger than predicted by chemical equilibrium between silicate melt and iron at low pressure, but it does match expectation for equilibrium at high pressure and temperature. Recent studies of differentiated planetesimal impacts assume that planetesimal cores survive the impact intact as concentrated masses that passively settle from a zero initial velocity and undergo turbulent entrainment in a global magma ocean; under these conditions, cores greater than 10 km in diameter do not fully mix without a sufficiently deep magma ocean. I …

Quantifying Terrestrial Ecosystem Carbon Dynamics With Mechanistically-Based Biogeochemistry Models And In Situ And Remotely Sensed Data, Shaoqing Liu

Open Access Dissertations

Terrestrial ecosystem plays a critical role in the global carbon cycle and climate system. Therefore, it is important to accurately quantify the carbon dynamics of terrestrial ecosystem under future climatic change condition. This dissertation evaluates the regional carbon dynamics by using upscaling approach, mechanistically-based biogeochemistry models and in situ and remotely sensed data.

The upscaling studies based on FLUXNET network has provided us the spatial and temporal pattern of the carbon fluxes but it fails to consider the atmospheric CO2 effect given its important physiological role in carbon assimilation. In the second chapter, we consider the effect of atmospheric CO2 …

The Cloud-Radiative Forcing Of The U.S. Landfalling Atmospheric Rivers, Qianwen Luo

Open Access Dissertations

Atmospheric rivers (ARs) are narrow channels in the atmosphere that transport an enormous amount of moisture from the tropics to the higher latitudes. Streaks of highly reflective clouds are observed along with the ARs in satellite imagery. These clouds both influence the moisture transport of ARs, as well as modify the Earth-Atmospheric energy budget through pathways such as cloud-radiative forcing (CRF). This dissertation studies the CRF of the U.S. Landfalling ARs in weather and climate scales. Three crucial questions are addressed. First, how do clouds produced by the ARs modulate the moisture and heat balance of the Earth-Atmospheric system? Even …

What Broke Where For Distributed And Parallel Applications — A Whodunit Story, Subrata Mitra

Open Access Dissertations

Detection, diagnosis and mitigation of performance problems in today's large-scale distributed and parallel systems is a difficult task. These large distributed and parallel systems are composed of various complex software and hardware components. When the system experiences some performance or correctness problem, developers struggle to understand the root cause of the problem and fix in a timely manner. In my thesis, I address these three components of the performance problems in computer systems. First, we focus on diagnosing performance problems in large-scale parallel applications running on supercomputers. We developed techniques to localize the performance problem for root-cause analysis. Parallel applications, …

Functional Regression Models In The Frame Work Of Reproducing Kernel Hilbert Space, Simeng Qu

Open Access Dissertations

The aim of this thesis is to systematically investigate some functional regression models for accurately quantifying the effect of functional predictors. In particular, three functional models are studied: functional linear regression model, functional Cox model, and function-on-scalar model. Both theoretical properties and numerical algorithms are studied in depth. The new models find broad applications in many areas.

For the functional linear regression model, the focus is on testing the nullity of the slope function, and a generalized likelihood ratio test based on easily implementable data-driven estimate is proposed. The quality of the test is measured by the minimal distance between …

Graphlet Based Network Analysis, Mahmudur Rahman

Open Access Dissertations

The majority of the existing works on network analysis, study properties that are related to the global topology of a network. Examples of such properties include diameter, power-law exponent, and spectra of graph Laplacians. Such works enhance our understanding of real-life networks, or enable us to generate synthetic graphs with real-life graph properties. However, many of the existing problems on networks require the study of local topological structures of a network.

Graphlets which are induced small subgraphs capture the local topological structure of a network effectively. They are becoming increasingly popular for characterizing large networks in recent years. Graphlet based …

The Search For Dark Matter In Xenon: Innovative Calibration Strategies And Novel Search Channels, Shayne Edward Reichard

Open Access Dissertations

The direct detection dark matter experiment XENON1T became operational in early 2016, heralding the era of tonne-scale dark matter detectors. Direct detection experiments typically search for elastic scatters of dark matter particles off target nuclei. XENON1T's larger xenon target provides the advantage of stronger dark matter signals and lower background rates compared to its predecessors, XENON10 and XENON100; but, at the same time, calibration of the detector's response to backgrounds with traditional external sources becomes exceedingly more difficult.

A 220Rn source is deployed on the XENON100 dark matter detector in order to address the challenges in calibration of tonne-scale liquid …

Convicted By Memory: Automatically Recovering Spatial-Temporal Evidence From Memory Images, Brendan D. Saltaformaggio

Open Access Dissertations

Memory forensics can reveal “up to the minute” evidence of a device’s usage, often without requiring a suspect’s password to unlock the device, and it is oblivious to any persistent storage encryption schemes, e.g., whole disk encryption. Prior to my work, researchers and investigators alike considered data-structure recovery the ultimate goal of memory image forensics. This, however, was far from sufficient, as investigators were still largely unable to understand the content of the recovered evidence, and hence efficiently locating and accurately analyzing such evidence locked in memory images remained an open research challenge.

In this dissertation, I propose breaking from …

Modeling The Impact Of Land Surface Feedbacks On Post Landfall Tropical Cyclones, Subashini Subramanian

Open Access Dissertations

The land surface is an important component of numerical models. The land surface models are modules that control energy partitioning, compute surface exchange coefficients and form the only physical boundary in a regional scale numerical model. Thus, an accurate representation of land surface is critical to compute surface fluxes, represent the boundary layer evolution and affect changes in weather systems. Land surface can affect landfalling tropical cyclones in two ways: (i) when the cyclone is offshore and land can influence cyclones by introducing dry (or moist) air that can weaken (or strengthen) the organized convective structure of cyclones, and (ii) …

Differentially Private Data Publishing For Data Analysis, Dong Su

Open Access Dissertations

In the information age, vast amounts of sensitive personal information are collected by companies, institutions and governments. A key technological challenge is how to design mechanisms for effectively extracting knowledge from data while preserving the privacy of the individuals involved. In this dissertation, we address this challenge from the perspective of differentially private data publishing. Firstly, we propose PrivPfC, a differentially private method for releasing data for classification. The key idea underlying PrivPfC is to privately select, in a single step, a grid, which partitions the data domain into a number of cells. This selection is done using the exponential …

Dynamic Holography In Semiconductors And Biomedical Optics, Hao Sun

Open Access Dissertations

Three-dimensional scanning and display are rapidly-advancing new technologies with important commercial drivers such as 3D printing and remote imaging for big data applications. Holography is a natural approach to recording and displaying three-dimensional information because it uses phase-sensitive interferometry to record interference patterns when a reference beam encounters coherent light arriving from an object. The 3D information is contained in the values of wave optics. Holography is a broad field that goes beyond recording and displaying. For instance, holographic optical elements, which take advantage of holographic imaging principles, perform the functions of lenses, gratings or mirrors. Holographic interferometry is also …

Characterizing The Effects Of Repetitive Head Trauma In Female Soccer Athletes For Prevention Of Mild Traumatic Brain Injury, Diana Otero Svaldi

Open Access Dissertations

As participation in women’s soccer continues to grow and the longevity of female athletes’ careers continues to increase, prevention of mTBI in women’s soccer has become a major concern for female athletes as the long-term risks associated with a history of mTBI are well documented. Among women’s sports, soccer exhibits the highest concussion rates, on par with those of men’s football at the collegiate level. Head impact monitoring technology has revealed that “concussive hits” occurring directly before symptomatic injury are not predictive of mTBI, suggesting that the cumulative effect of repetitive head impacts experienced by collision sport athletes should be …

Divide And Recombined For Large Complex Data: Nonparametric-Regression Modelling Of Spatial And Seasonal-Temporal Time Series, Xiaosu Tong

Open Access Dissertations

In the first chapter of this dissertation, I briefly introduce one type of nonparametric regression method, namely local polynomial regression, followed by emphasis on one specific application of loess on time series decomposition, called Seasonal Trend Loess (STL). The chapter is closed by the introduction of D\&R; (Divide and Recombined) statistical framework. Data can be divided into subsets, each of which is applied with a statistical analysis method. This is an embarrassing parallel procedure since there is no communication between each subset. Then the analysis result for each subset are combined together to be the final analysis outcome for the …

Policy Design Tool For Managing Indoor Residential Water Demand In Water-Scarce Regions, Mujahed M. Thneibat

Open Access Dissertations

In view of population growth; climate change; and economic evolution, water resources in numerous parts of the world have reached their natural capacities. Consequently, the ability of many countries to grow; meet the basic needs of inhabitants; and protect the environment will be endangered like never before unless water resources are smartly handled and managed. ^ In the past few decades, many developed and developing countries have suffered from water scarcity, and more are certain to follow. The water security dilemma is much more challenging in developing countries. Water utilities have had to follow regulatory plans to manage demand on …

An Examination Of Geographic Patterns Of Soil Climate And Its Classification In The U.S. System Of Soil Taxonomy, Hans Edwin Winzeler

Open Access Dissertations

Soil climate, the record of temporal patterns of soil moisture and temperature, is an important component of the structure of U.S. Soil Taxonomy. The U.S. Soil Survey has used the Newhall Simulation Model (NSM) for estimating soil climate from atmospheric climate records at weather stations since the 1970s. The current soil climate map of the U.S. was published in 1994 by using NSM runs from selected weather stations along with knowledge-based hand-drawn mapping procedures. We developed a revised soil climate mapping methodology using the NSM and digital soil mapping techniques.

The new methodology is called Grid Element Newhall Simulation Model …

Unraveling The Fingerprints Of Nox Using Stable Isotopes: Implications For Nox Source Partitioning And Oxidation Chemistry, Wendell William Walters

Open Access Dissertations

The nitrogen (N) and oxygen (O) stable isotope composition (δ15N & δ18O) of nitrogen oxides (NOx )may be a useful tool for constraining NOx emission sources as well as for understanding the atmospheric oxidation pathways responsible for its removal if various NOx sources and sink processes exhibit characteristic isotopic compositions (“fingerprints”). However, this requires (1) an accurate and complete inventory of δ15N(NOx) values from major emission sources, (2) an assessment of the kinetic and equilibrium isotope effects that can impact δ15N and δ18O values of NOx, (3) and test these assumptions by conducting accurate in situ δ15N and δ18O measurements …

Preparative Mass Spectrometry Applications In Nanomaterials And Organic Synthesis, Michael Wleklinski

Open Access Dissertations

Preparative mass spectrometry was traditionally a vacuum based experiment where mass selected ion beams were deposited onto surfaces; however, recently ions have been manipulated in the open air to perform accelerated synthesis. The work of this dissertation focuses on the generation of charged ions from microdroplets and their use in organic synthesis and the preparation of atomically precise metal nanoclusters. First the mechanism for charging in the zero volt paper spray will be presented. This works builds a computational model based on the statistical fluctuation of positive and negative charges based on the theory of Dodd. It is found through …

A Mixed Methods Study: Evaluating The Relationship Of Project Manager Competencies And It Project Management Methodologies, Keith A. Mcdermott

Open Access Theses

Determining skillsets that are particularly important to the development of an effective project manager can be useful for a variety of applications. These applications range from the hiring of a new project manager for an organization to continued training for current employees. Past research has called upon current project managers to rate what skillsets they see as important to the cultivation of an optimal or effective project manager. Additional research has expanded this idea to determine how skillsets vary between project managers and functional managers (El-Sabaa, 2001). While this research is certainly important, skillset grouping can be further explored. This …

Deep Collective Inference, John A. Moore

Open Access Theses

Collective inference is widely used to improve classification in network datasets. However, despite recent advances in deep learning and the successes of recurrent neural networks (RNNs), researchers have only just recently begun to study how to apply RNNs to heterogeneous graph and network datasets. There has been recent work on using RNNs for unsupervised learning in networks (e.g., graph clustering, node embedding) and for prediction (e.g., link prediction, graph classification), but there has been little work on using RNNs for node-based relational classification tasks. In this paper, we provide an end-to-end learning framework using RNNs for collective inference. Our main …

Inter-Color Npr Lines: A Comparison Of Rendering Techniques, Donald G. Herring

Open Access Theses

Renders of 3D scenes can feature lines drawn automatically along sharp edges between colored areas on object textures, in order to imitate certain conventional styles of hand-drawn line art. However, such "inter-color lines" have been studied very little. Two algorithms for rendering these lines were compared in this study - a faster one utilizing lines baked into the textures themselves and a more complex one that dynamically generated the lines in image space on each frame - for the purpose of determining which of the two better imitated traditional, hand-drawn art styles and which was more visually appealing. Test subjects …

The Purdue Agro-Climatic (Pac) Dataset For The U.S. Corn Belt: Development And Initial Results, Xing Liu, Elin Jacobs, Anil Kumar, Larry Biehl, Jeff Andersen, Dev Niyogi

Department of Earth, Atmospheric, and Planetary Sciences Faculty Publications

This study is a result of a project titled ‘‘Useful to Usable (U2U): Transforming Climate Variability and Change Information for Cereal Crop Producers”. This paper responds to the project goal to improve farm resiliency and proftability in the U.S. Corn Belt region by transforming existing meteorological dataset into usable knowledge and tools for the agricultural community.

A high-resolution agro-climatic dataset that covers the U.S. Corn Belt was built for the U2U project based on a Land Data Assimilation System (LDAS) framework. This data referred to as the Purdue Agro-climatic (PAC) dataset is a gridded, continuous dataset suitable for agrocli- matic …

Nondestructive Testing And Structural Health Monitoring Based On Adams And Svm Techniques, Gang Jiang, Yi Ming Deng, Ji Tai Niu

The 8th International Conference on Physical and Numerical Simulation of Materials Processing

No abstract provided.

Thermodynamic Calculation Of The Liquidus Surface Projection Of Multi-Component Aluminum Alloys, Jingrui Zhao, Yong Du, Lijun Zhang, Jixue Zhou, Yuansheng Yang

The 8th International Conference on Physical and Numerical Simulation of Materials Processing

No abstract provided.

An Antireflective Tco Film For Czts Solar Cells, Feng Zhan

The 8th International Conference on Physical and Numerical Simulation of Materials Processing

No abstract provided.

A Parallel 3d Phase-Field Simulation Of Multi-Grain Growth Based On The Full Thread Tree, Ya-Jun Yin, Min Wang, Jian-Xin Zhou, Dun-Ming Liao, Xu Shen, Tao Chen

The 8th International Conference on Physical and Numerical Simulation of Materials Processing

No abstract provided.

White Light By Nano-Halo-Phosphor, Anuradha Ramesh Poddar, D. R. B. Sindhu Mahavidyalaya, S. C. Gedam, S. J. Dhoble

The 8th International Conference on Physical and Numerical Simulation of Materials Processing

No abstract provided.

A Measuring Method For Abundance Of Uranium Components Based On Active Source Of Neutron, Li Li, Gen Hu, Keqi Liu

The 8th International Conference on Physical and Numerical Simulation of Materials Processing

No abstract provided.