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Articles 6781 - 6810 of 7361
Full-Text Articles in Physical Sciences and Mathematics
The Role Of Benthic Fluxes Of Dissolved Organic Carbon In Oceanic And Sedimentary Carbon Cycling, Davd J. Burdige, Marc J. Alperin, Juliana Homstead, Christopher S. Martens
The Role Of Benthic Fluxes Of Dissolved Organic Carbon In Oceanic And Sedimentary Carbon Cycling, Davd J. Burdige, Marc J. Alperin, Juliana Homstead, Christopher S. Martens
OES Faculty Publications
Benthic fluxes (sediment-water exchange) of dissolved organic carbon (DOC) represent a poorly quantified component of sedimentary and oceanic carbon cycling. In this paper we use pore water DOC data and direct DOC benthic flux measurements to begin to quantitatively examine this problem. These results suggest that marine sediments represent a significant source of DOC to the oceans, as a lower limit of the globally-integrated benthic DOC flux is comparable in magnitude to riverine inputs of organic carbon to the oceans. Benthic fluxes of DOC also appear to be similar in magnitude to other sedimentary processes such as organic carbon oxidation …
Boulder Streams, Debris Fans, And Pleistocene Climate Change In The Blue Ridge Mountains Of Central Virginia, G. Richard Whittecar, Derek W. Ryter
Boulder Streams, Debris Fans, And Pleistocene Climate Change In The Blue Ridge Mountains Of Central Virginia, G. Richard Whittecar, Derek W. Ryter
OES Faculty Publications
The west slope of the Blue Ridge mountains in central Virginia is a polygenetic landscape containing interglacial and periglacial features. This paper proposes a general model relating the distribution and origin of hillslope and toeslope Quaternary landforms to climatically influenced geomorphic processes. Two generations of interglacial debris fans in the study area differ in their degree of soil development and clast weathering. Boulder streams, which clog debris flow chutes for the upper debris fans, are interpreted as solifluction features formed during successive periglacial episodes. Growth of the boulder streams and associated talus slopes can influence the magnitude and frequency of …
Effect Of Magnetic And Density Fluctuations On The Propagation Of Lower Hybrid Waves In Tokamaks, George Vahala, Linda L. Vahala, Paul T. Bonoli
Effect Of Magnetic And Density Fluctuations On The Propagation Of Lower Hybrid Waves In Tokamaks, George Vahala, Linda L. Vahala, Paul T. Bonoli
Electrical & Computer Engineering Faculty Publications
Lower hybrid waves have been used extensively for plasma heating, current drive, and ramp-up as well as sawteeth stabilization, The wave kinetic equation for lower hybrid wave propagation is extended to include the effects of both magnetic and density fluctuations. This integral equation is then solved by Monte Carlo procedures for a toroidal plasma. It is shown that even for magnetic/density fluctuation levels on the order of 10-4, there are significant magnetic fluctuation effects on the wave power deposition into the plasma. This effect is quite pronounced if the magnetic fluctuation spectrum is peaked within the plasma. For …
Charge-State Equilibrium And Nonequilibrium Modeling Of The Carbon-Pellet Plasma Interaction, A. G. Elcashlan, G. A. Gerdin, L. L. Vahala, P. B. Parks
Charge-State Equilibrium And Nonequilibrium Modeling Of The Carbon-Pellet Plasma Interaction, A. G. Elcashlan, G. A. Gerdin, L. L. Vahala, P. B. Parks
Electrical & Computer Engineering Faculty Publications
Self-consistent equilibrium and nonequilibrium charge-state models are formulated for the spherical expansion of low-Z pellet vapor as an inviscid perfect gas of constant ratio of specific heats being heated volumetrically by the incident electrons of a thermonuclear plasma. The two models are found to be in agreement in the region where the ratio of the ionization length ζj to pellet radius rp is less than unity, but a single parameter, such as the magnitude of this ratio on the sonic surface, is insufficient to determine whether an equilibrium model will be valid for all regions of the ablatant …
Effect Of Fluctuations On Lower Hybrid Power Deposition And Hard X-Ray Detection, George Vahala, Linda L. Vahala, Paul T. Bonoli
Effect Of Fluctuations On Lower Hybrid Power Deposition And Hard X-Ray Detection, George Vahala, Linda L. Vahala, Paul T. Bonoli
Electrical & Computer Engineering Faculty Publications
The hard X-ray intensity radial profiles from lower hybrid current drive experiments are interpreted as being correlated with fluctuations in the bulk plasma. This view seems to be dictated by comparing the hard X-ray data for various n║ with the Monte Carlo solutions of the lower hybrid wave energy deposition on plasma electrons. Information on internal magnetic fluctuations may, under certain conditions, be unfolded from a n║ scan of the hard X-ray profiles.
Electromagnetic Wave Scattering From Magnetic Fluctuations In Tokamaks, L. L. Vahala, G. Vahala, N. Bretz
Electromagnetic Wave Scattering From Magnetic Fluctuations In Tokamaks, L. L. Vahala, G. Vahala, N. Bretz
Electrical & Computer Engineering Faculty Publications
Cross sections are calculated for electromagnetic wave scattering and mode transformation from magnetic and density fluctuations in a homogeneous plasma. For the special case of scattering perpendicular to the magnetic field, density fluctuations scatter ordinary to ordinary and extraordinary to extraordinary modes-but cannot transform these modes. On the other hand, magnetic fluctuations perpendicular to the field can transform modes but cannot scatter on a single branch. For incident frequencies on the order of the electron plasma frequency or gyrofrequency, the cross sections for scattering and transformation due to field and density fluctuations have a similar value. Estimates are given for …
Self-Consistent Determination Of Low-Za Pellet Ablation And Pellet Penetration, Linda L. Vahala, Glenn Gerdin, A. G. El Cashlan, Paul Parks
Self-Consistent Determination Of Low-Za Pellet Ablation And Pellet Penetration, Linda L. Vahala, Glenn Gerdin, A. G. El Cashlan, Paul Parks
Electrical & Computer Engineering Faculty Publications
The ablation dynamics of LiT pellets are solved self-consistently over a modest range of parameters using a surface dissociation model. The self-consistently determined parameters are then used to modify the standard low-Z pellet penetration codes. Since LiT pellets have certain advantages over carbon [in particular, Li conditioning of the walls and T for refueling a D-T reaction], the penetration of LiT into fusion plasmas is considered.
Solution Uniqueness And Stability Criteria For A Model Of Growth Factor Production, J. A. Adam
Solution Uniqueness And Stability Criteria For A Model Of Growth Factor Production, J. A. Adam
Mathematics & Statistics Faculty Publications
Uniqueness and stability criteria are established for the steady states of a nonlinear model of growth factor production. A specific expression for the nonlinearity is chosen, containing three parameters which can be adjusted to fit a specific biological context, but much of the analysis applies to a general class of source terms that exhibit the same qualitative behavior.
Temperature And Suction Effects On The Instability Of An Infinite Swept Attachment Line, D. G. Lasseigne, T. L. Jackson, F. Q. Hu
Temperature And Suction Effects On The Instability Of An Infinite Swept Attachment Line, D. G. Lasseigne, T. L. Jackson, F. Q. Hu
Mathematics & Statistics Faculty Publications
It is known that the incompressible, infinite swept attachment line flow is unstable to streamwise disturbances that originate in the boundary layer when the cross-flow exceeds a critical magnitude. Furthermore, a small degree of suction at the surface has a significant stabilizing influence while a small degree of blowing has a considerable destabilizing influence. This paper investigates the stabilizing and destabilizing effects of, respectively, cooling or heating the plate and the competing or enhancing effects of suction or blowing. A nonorthogonal flow with respect to the attachment line is also considered by adding a component of shear to the mean …
Numerical Solutions For Weakly Singular Hammerstein Equations And Their Superconvergence, Hideaki Kaneko, Richard D. Noren, Yuesheng Xu
Numerical Solutions For Weakly Singular Hammerstein Equations And Their Superconvergence, Hideaki Kaneko, Richard D. Noren, Yuesheng Xu
Mathematics & Statistics Faculty Publications
In the recent paper [7], it was shown that the solutions of weakly singular Hammerstein equations satisfy certain regularity properties. Using this result, the optimal convergence rate of a standard piecewise polynomial collocation method and that of the recently proposed collocationtype method of Kumar and Sloan [10] are obtained. Superconvergence of both of these methods are also presented. In the final section, we discuss briefly a standard productintegration method for weakly singular Hammerstein equations and indicate its superconvergence property. © 1992 Rocky Mountain Mathematics Consortium.
A Paleoenvironmental Analysis Based On Ostracode Assemblages From The Late Pliocene Tuapaktushak And Middle Pleistocene Karmuk Members Of The Gubik Formation Of The Arctic Coastal Plain, Western Alaska, D. E. Loehrke
OES Theses and Dissertations
This study records and analyzes ostracode assemblages recovered from sediments assigned to the Late Pliocene Tuapaktushak and Middle Pleistocene Karmuk members of the Gubik Formation in the Skull Cliff area of the Arctic Coastal Plain in western Alaska. Forty-three species were identified from 47 samples (25 from the Tuapaktushak Member and 23 from the Karmuk Member). Samples were grouped by Q-mode cluster analysis and by member assignment for the purpose of analysis.
Paleoenvironmental analyses of ostracode assemblages representative of each cluster suggest all samples, regardless of cluster membership, were deposited in similar marine environments where water depths were in the …
Bounds On Constraint Weight Parameters Of Hopfield Networks For Stability Of Optimization Problem Solutions, Gursel Serpen
Bounds On Constraint Weight Parameters Of Hopfield Networks For Stability Of Optimization Problem Solutions, Gursel Serpen
Electrical & Computer Engineering Theses & Dissertations
The purpose of the presented research is to study the convergence characteristics of Hopfield network dynamics. The relation between constraint weight parameter values and the stability of solutions of constraint satisfaction and optimization problems mapped to Hopfield networks is investigated. A theoretical development relating constraint weight parameter values to solution stability is presented. The dependency of solution stability on constraint weight parameter values is shown employing an abstract optimization problem. A theorem defining bounds on the constraint weight parameter magnitudes for solution stability of constraint satisfaction and optimization problems is proved. Simulation analysis on a set of optimization and constraint …
Development And Standardization Of A Short-Term Assay For Evaluating Polluted Estuarine And Coastal Environments: The Medaka Embryo-Larval Assay, Michael Frederick Helmstetter
Development And Standardization Of A Short-Term Assay For Evaluating Polluted Estuarine And Coastal Environments: The Medaka Embryo-Larval Assay, Michael Frederick Helmstetter
OES Theses and Dissertations
The eggs of the Japanese medaka (Oryzias latipes) were employed in a number of studies to develop a routine, standardized assay which can assess the acute and sublethal impacts of individual toxicants and complex mixtures. The eggs of this Cyprinodont minnow were topically treated with each toxicant or mixture dissolved in membrane permeable dimethylsulfoxide (DMSO) solvent. Nine chemicals were initially evaluated with two, pentachlorophenol (PCP) and tributyltin chloride (TBTCl), subsequently selected for extensive evaluations of salinity tolerance and the accuracy of the topical exposure method for representing a typical immersion exposure. The amount of material actually penetrating the eggs was …
Spiny Lobster Recruitment In South Florida: Quantitative Experiments And Management Implications, Mark J. Butler Iv, William F. Herrnkind
Spiny Lobster Recruitment In South Florida: Quantitative Experiments And Management Implications, Mark J. Butler Iv, William F. Herrnkind
Biological Sciences Faculty Publications
Understanding recruitment and identifying factors critical to that process are imperative if adult spiny lobster Panulirus argus stocks are to be conserved and properly managed. The goal of our research has been to obtain ecological information linking inshore postlarval spiny lobster recruitment to later life stages, thereby providing the basic framework for assessing and predicting adult stock. Since 1983, we have investigated various aspects of spiny lobster recruitment including: postlarval time-to-metamorphosis, postlarval/juvenile habitat selection and selection cues, postlarval/juvenile crypticity and susceptibility to predation, juvenile food preference and emigration, juvenile sociality, and the effect of habitat degradation (i.e., siltration) on postlarval/juvenile …
Seasonal Phytoplankton Development Within Three Rivers In The Lower Chesapeake Bay Region, Harold G. Marshall, Lewis F. Affronti
Seasonal Phytoplankton Development Within Three Rivers In The Lower Chesapeake Bay Region, Harold G. Marshall, Lewis F. Affronti
Biological Sciences Faculty Publications
The seasonal and inter-annual concentrations of phytoplankton were studied over a 50 month period in the lower James, York and Rappahannock Rivers (USA). Differences in the onset, duration and magnitude of major seasonal growth periods varied from year to year. There was a tendency for spring, summer and fall maxima, with a winter period of reduced abundance. An additional study of picoplankton over a 12 month period indicated greatest abundance during summer and fall, with least development in winter.
A Case Study In Software Reuse: The Rntds Architecture, Barry J. Stevens
A Case Study In Software Reuse: The Rntds Architecture, Barry J. Stevens
Computer Science Theses & Dissertations
It has been asserted that the most significant gains in software productivity will come from increased levels of software reuse. Some economic models for predicting savings through software reuse exist, but none are based on actual project experience. This paper surveys those models and presents the results of a case study, the Restructured Naval Tactical Data Systems (RNTDS) architecture, in the light of those models. According to the models, software reuse via the RNTDS architecture has enabled the production of fourteen major computer programs at five to twenty-one percent of the cost to create them without software reuse. Organizational characteristics …
Study Of The Heavy Fermion/Spin-Glass System, Ce1-X GdX Al3, Using 155Gd Mossbauer Spectroscopy, Nicholas G. Ruggiero
Study Of The Heavy Fermion/Spin-Glass System, Ce1-X GdX Al3, Using 155Gd Mossbauer Spectroscopy, Nicholas G. Ruggiero
Physics Theses & Dissertations
The magnetic properties of Ce1-xGdx.Al3 have been studied using 155Gd Mossbauer spectroscopy. It has been shown that the magnetic moments of the host GdAl3 are constrained to the basal plane. The magnetic properties of GdAl3 can best be described in the framework of RKKY theory. Prior studies of Ce1-xGdxAl3, have revealed complex magnetic behavior throughout the series. As observed with Mossbauer spectroscopy magnetic ordering occurs for x ≥ 0.5, though not at the reported spin glass temperatures. For x = 0.23 and x = 0.18, the …
Vorticity Dynamics Of Seasonal Variations Of The Antarctic Circumpolar Current From A Modeling Study, John M. Klinck
Vorticity Dynamics Of Seasonal Variations Of The Antarctic Circumpolar Current From A Modeling Study, John M. Klinck
CCPO Publications
A one-layer numerical model was developed to analyze the vorticity dynamics of the seasonal variations of currents in the Southern Ocean. The model includes the continental geometry and bathymetry of the Southern Ocean and is forced by monthly climatological wind stress. Five cases are considered that compare (i) circulation over a flat bottom to that with bathymetry, (ii) effects of zonally averaged wind stress forcing versus the climatological forcing and (iii) anomaly wind stress (winds with the annual mean removed) versus the full stress. The individual terms in the vorticity conservation equation are calculated from the model solution along two …
Thermal Characterization Of Carbon Monoxide Oxidation Catalysts Using Thermogravimetric Analysts And Differential Scanning Calorimetry, Rene A. Bartgis
Thermal Characterization Of Carbon Monoxide Oxidation Catalysts Using Thermogravimetric Analysts And Differential Scanning Calorimetry, Rene A. Bartgis
Chemistry & Biochemistry Theses & Dissertations
Catalysts composed of platinum and/or palladium on tin (IV) oxide supports, with and without silica gel, as well as catalysts composed of gold on manganese oxide, have been developed for the recombination of carbon monoxide and oxygen to form carbon dioxide for use in carbon dioxide lasers. A thermogravimetric method and a differential scanning calorimetric method have been developed for the thermal characterization of these catalysts. The mass loss data and the enthalpy changes determined as the catalysts lost water were then related to existing activity data for these catalysts. No relationship was found between the thermal data and the …
Study Of Cathodoluminescence In Semiconductors, Mandakini V. Kale
Study Of Cathodoluminescence In Semiconductors, Mandakini V. Kale
Electrical & Computer Engineering Theses & Dissertations
Cathodoluminescence in Zn doped GaAs and ZnSe, the materials of interest for electron-beam controlled semiconductor switches, has been investigated. A new diagnostic technique, using telescopic setup of lenses, was developed to study the spatially resolved cathodoluminescence. The setup eliminated the light, other than rays from the sample, parallel to the optical axis, resulting in an enhanced spatial resolution. At high e-beam energies, light was detected, from the Zn layer region in the GaAs. It is proposed to be due to the radiative recombination of electron-hole pairs, created by the e-beam. For the polycrystalline ZnSe no light emission was detected. This …
Processes Affecting The Behavior Of Redox-Sensitive Elements In Chesapeake Bay, Maria Lourdes San Diego-Mcglone
Processes Affecting The Behavior Of Redox-Sensitive Elements In Chesapeake Bay, Maria Lourdes San Diego-Mcglone
OES Theses and Dissertations
Several processes can affect variations in the chemical composition of an estuary, including (1) biogeochemical reactions in the water column, (2) advective transport, and (3) diffusion from underlying sediments.
The purpose of the study was to establish whether estuarine redox reactions are controlled by a complex interaction of processes 1 to 3. Short-term and long-term studies were conducted in Chesapeake Bay. Redox species involved in redox cycling include oxygen, iron, manganese, hydrogen sulfide, nitrogen species, arsenic and antimony species, while phosphate is indirectly involved in redox cycles. Silicate was used as a non-redox tracer.
For the short-term study, a Lagrangian …
Reactions Of Aqueous Chlorine With Valine In Model Solutions And In Wastewater, Erika Forrer Mccormick
Reactions Of Aqueous Chlorine With Valine In Model Solutions And In Wastewater, Erika Forrer Mccormick
Chemistry & Biochemistry Theses & Dissertations
Solutions of the amino acid valine were chlorinated to seven chlorine-to-nitrogen mole (Cl/N) ratios and analyzed by high performance liquid chromatography, gas chromatography/mass spectroscopy, infrared spectroscopy, and nuclear magnetic resonance spectroscopy. The chlorination products found were N-chlorovaline, isobutyraldehyde, isobutyronitrile, and N-chloroisobutyraldimine. Their product distribution depends on the level of chlorination and pH. The main products identified at the lower CI/N mole ratios were N-chlorovaline and isobutyraldehyde, whereas at the higher CI/N mole ratios isobutyronitrile and N-chloroisobutyraldimine were identified as the main products. The concentration and the chlorination products of valine in municipal wastewater were also determined. The chlorination products of …
The Geomorphology Of Alluvial Fan Deposits On The West Flank Of The Blue Ridge, Augusta County, Virginia, Debra Lynn Duffy
The Geomorphology Of Alluvial Fan Deposits On The West Flank Of The Blue Ridge, Augusta County, Virginia, Debra Lynn Duffy
OES Theses and Dissertations
Large coalescing alluvial fans mantle the carbonate and shale formations west of the Blue Ridge mountains near Stuarts Draft, Virginia. Fan sediments are predominantly boulder and cobble gravels derived from the Antietam Quartzite, The fan complex consists of three alluvial units of significantly different ages. The surface of each fan unit was mapped using relative geomorphic position, soil color, clay content and thickness of Bt horizons, clast weathering, and degree of removal of depositional surfaces by stream incision. A five-category quartzite clast weathering scale developed for this study was very effective as a measure to distinguish map units. Stratigraphic data …
Computer Simulation Techniques To Assess Bias And Precision In The Roving Creel Survey Estimator, David L. Wade
Computer Simulation Techniques To Assess Bias And Precision In The Roving Creel Survey Estimator, David L. Wade
Biological Sciences Theses & Dissertations
Fisheries scientists use roving creel survey methods to estimate total catch and total effort of recreational fisheries. Bias in the roving creel estimators had been known to the scientific community, but it had not been quantified. I developed a roving-creel-survey computer simulation model to investigate the bias and precision of roving creel estimators, and estimated parameters for the model based on field observations from the blue crab (Callinectes sapidus) fishery of the Chesapeake Bay. The computer model was used to identify bias in roving-creel effort and catch estimators and to demonstrate survey methods that will reduce this bias. …
The Identification, Distribution, And Status Of The Threatened Dismal Swamp Shrew (Sorex Longirostris Fisheri), Thomas M. Padgett
The Identification, Distribution, And Status Of The Threatened Dismal Swamp Shrew (Sorex Longirostris Fisheri), Thomas M. Padgett
Biological Sciences Theses & Dissertations
Southeastern shrews (Sorex longirostris) were trapped throughout southeastern Virginia and northeastern North Carolina to determine if any morphological characters could
be identified that would aid in the identification and distribution of the threatened subspecies Sorex l._ fisheri, endemic to the Great Dismal Swamp, the more upland nominate subspecies Sorex l. longirostris, and possible intergrades between the two subspecies. Animals were classified a priori into three groups, based on their location of capture. Animals collected from the Great Dismal Swamp National Wildlife Refuge (GDSNWR) and associated bottomland habitats were designated as "fisheri", animals collected farthest from the Swamp as "longirostris", and …
Domain Limitations And Interface Requirements For Expert Developed Knowledge Based Systems, Bernard Lee Lewis
Domain Limitations And Interface Requirements For Expert Developed Knowledge Based Systems, Bernard Lee Lewis
Engineering Management & Systems Engineering Theses & Dissertations
The expanded use of graphical, case-based and object oriented techniques in expert systems creation has made it more practical for domain experts to develop their own applications. This thesis focuses on the elements necessary in an expert/developer interface and looks at various forms and techniques that exemplify such an approach. The spreadsheet metaphor is used for an interface or managed set of interfaces that a domain expert can use in building his own expert system or prototype. criteria are established for such interfaces and recent commercial offerings that make expert-created knowledge-bases more practical are reviewed for techniques that qualify. Approaches …
Approaches To High Speed Networks, Frank Charles Paterra
Approaches To High Speed Networks, Frank Charles Paterra
Computer Science Theses & Dissertations
This work investigates possible methods by which existing potentially available communication bandwidth can be used by communication intensive applications. Presently fiber optic media are available that can provide multiple gigabits of throughput. Unfortunately, because of the computation overhead required to insure that data are reliably transmitted this capacity has not been tapped.
A survey of work toward enabling the use of the potential bandwidth is presented. The parallel paradigm is identified as a strong candidate for providing significant increases in system usable bandwidth. Performing communication processing in parallel, however, presents the developer with several implementation options. These options are considered …
Community Structure Of The Macrobenthos In Back Bay, Virginia, Michael F. Lane
Community Structure Of The Macrobenthos In Back Bay, Virginia, Michael F. Lane
Biological Sciences Theses & Dissertations
A study of the subtidal macrobenthos in Back Bay, Virginia was conducted to examine community structure in relation to sedimentary and water quality characteristics. Samples were collected in August and November of 1987 and February and May of 1988 at ten stations.
Three site groups and three temporal groups were identified by cluster analyses of species abundance. Species composition between site groups was relatively homogeneous and eight species accounted for most of the variation between site groups. A comparison of plots of the biological and physical data in discriminant space suggested that variations in the biological data between site groups …
Lava-Seawater Interactions At Shallow-Water Submarine Lava Flows, Francis J. Sansone, Joseph A. Resing, Gordon W. Tribble, Peter N. Sedwick, Kevin M. Kelly, Ken Hon
Lava-Seawater Interactions At Shallow-Water Submarine Lava Flows, Francis J. Sansone, Joseph A. Resing, Gordon W. Tribble, Peter N. Sedwick, Kevin M. Kelly, Ken Hon
OES Faculty Publications
Hydrothermal plumes associated with nearshore lava flows from Kilauea Volcano, Hawaii were studied on five occasions during 1989-1990 to address the current lack of data on direct lava-seawater interactions. The following enrichments were found in the sea-surface hydrothermal plumes above the active underwater lava flows: H2, 15,000x ambient seawater concentrations; Mn, 250x; and Si, 20x. Water temperatures reached 46°C. Lower concentrations and temperatures were observed in the plumes with increasing distance from shore, with H2, Si, and Mn concentrations linearly related to seawater temperature. Unlike deep sea spreading center hydrothermal plumes, no CH4 enrichment was …
A Diffuse Reflectance Infrared Fourier Transform Spectroscopic Study Of Platinum/Tin (Iv) Oxide Low-Temperature Carbon Monoxide Oxidation Catalysts, Donna Sue Duarte
A Diffuse Reflectance Infrared Fourier Transform Spectroscopic Study Of Platinum/Tin (Iv) Oxide Low-Temperature Carbon Monoxide Oxidation Catalysts, Donna Sue Duarte
Chemistry & Biochemistry Theses & Dissertations
Platinum-coated tin(IV) oxide catalysts have been developed for the recombination of carbon monoxide and oxygen at 55°C and 1 atmosphere of pressure in closed-cycle carbon dioxide lasers. A diffuse reflectance infrared fourier transform spectroscopic (DRIFTS) study of four of these catalysts during 5% carbon monoxide pretreatment at temperatures of 30°C, 100°c, 125°c, and 150°C has been performed. Evidence for the development of surface carbonate, bicarbonate, and formate species during pretreatment has been found. Dehydroxylation of the surface and loss of a partially charged hydrogen-bonded hydroxyl species have also been found to result from elevated temperature pretreatment. The four catalysts have …