Physical Sciences and Mathematics Commons^™

Chlorination Products Of Glycylphenylalanine In Model Solutions And A Wastewater, Daniel J. Keefe

Chemistry & Biochemistry Theses & Dissertations

Model solutions of the dipeptide glycylphenylalanine were chlorinated to five different chlorine-to-amino nitrogen (Cl/N) mole ratios and analyzed after 30 min by high performance liquid chromatography. At mole ratios of ≤ 1, N-chloroglycylphenylalanine (I) appeared to be the only major product. At a mole ratio ≤ 2, N, N-dichloroglycylphenylalanine (II) was the only product. Compound II decomposes in model solutions (t_1/2= 6.4 hr) at pH 7.0 to form a compound tentatively identified as an H-chloroaldimine (III). Compound III in turn decomposes (t_1/2= 36 hr) in model solutions at pH 7. o to (IV) . From ^{13 …}

A Study Of The Interface Between A Turbulent Boundary Layer And The Irrotational Free Stream, Shih-Chao Lin

Mechanical & Aerospace Engineering Theses & Dissertations

A mathematical model has been developed to simulate the events which occur at the interface between a turbulent boundary layer and the irrotational free stream. By assuming the streamwise velocity component of this interface to be constant and that the interface is uncontorted initially, the solution to the equations of motion is used to derive the position functions of a point element on the interface. This analysis is restricted to a fully developed incompressible turbulent boundary layer with zero pressure gradient. Vertical velocity disturbances which are periodic in the spanwise direction and restricted to small streamwise domains are assumed.

The …

Paleobathymetric Interpretation Of Pleistocene Sediments In The South Padre Island Area, Northwestern Gulf Of Mexico, Using Benthic Foraminiferal Morphology, Karen Ianthe Kruebbe-Belwood

OES Theses and Dissertations

This study tested the validity of using intraspecific variation in benthic foraminifera as a means for determining Pleistocene paleobathymetry. Canonical variate analysis was used as a means for determining visually undetectable but statistically significant differences in the morphology of selected species. Two species, Cassidulina subglobosa and Uvigerina peregrina, were collected from Pleistocene well cuttings from the northwest Gulf of Mexico. The canonical analysis involved comparing the intraspecific variation of these Pleistocene species to their counterparts occurring in the modern Gulf of Mexico, where intraspecific variation was previously analyzed and found to be sufficient to allow detection of bathymetric differences …

Paleocene To Miocene Foraminifera From A Well Near Gloucester, Virginia, Nelson Stanley Ford

OES Theses and Dissertations

Lithologic analysis of twenty-one core samples from a well near Gloucester, Virginia, when compared to published descriptions of formations occurring in the study area, indicates the presence of five formations. From oldest to youngest these units are the Aquia (late Paleocene), Nanjemoy (early Eocene), Chickahominy (late Eocene), Old Church (late Oligocene and early Miocene), and Eastover (late Miocene) formations. Comparison of the stratigraphic ranges of key planktic and benthic foraminifera from each of the core samples shows chronological agreement with previously published ages for each of these formations.

Paleoenvironmental analysis of each of the formations in the well is based …

The Effects Of Electron Radiation On The Glass Transition Temperature Of A Polyetherimide, Kristen Tulloch Kern

Physics Theses & Dissertations

The effects of electron radiation on a polyetherimide (PEI), Ultem*, were investigated. In particular, the changes in the glass transition temperature (T_g) with absorbed radiation dose were studied. The polymer was exposed to mono-energetic beams of 100-keV electrons and 1.0-MeV electrons for doses up to 100 megagray (MGy). Dosimetry for the exposures was based on Monte-Carlo simulations of the transfer of energy from an energetic electron to the polymer and on comparison to Nylon standards. Dynamic mechanical analysis was used to determine the (T_g) for non-exposed PEI and the changes in (T_g) resulting from …

Petrology Of A Large Granophyre-Rich Mesozoic Diabase Dike Near Farmville, Virginia, Philip Thomas Rogan

OES Theses and Dissertations

Up to 37% granophyre occurs in the center of a 150m-wide Mesozoic diabase dike near Farmville, Virginia. The exceptional abundance of granophyre compared with other Mesozoic diabase dikes suggests unusual petrogenetic processes are involved in formation of the dike. Petrographic analyses show that granophyre increases from 5-10% near the flanks of the dike to a maximum of 37% in the core of the dike, and that granophyre distribution is approximately symmetrical about the center of the dike. Major and trace element concentrations parallel variations in the modal abundance of granophyre, with SiO₂ , Na₂O and K_{2 …}

Time-Optimal Algorithms On Meshes With Multiple Broadcasting, Dharmavani Bhagavathi

Computer Science Theses & Dissertations

The mesh-connected computer architecture has emerged as a natural choice for solving a large number of computational tasks in image processing, computational geometry, and computer vision. However, due to its large communication diameter, the mesh tends to be slow when it comes to handling data transfer operations over long distances. In an attempt to overcome this problem, mesh-connected computers have recently been augmented by the addition of various types of bus systems. One such system known as the mesh with multiple broadcasting involves enhancing the mesh architecture by the addition of row and column buses. The mesh with multiple broadcasting …

Recognition Of Quadric Surfaces From Range Data: An Analytical Approach, Ivan X. D. D'Cunha

Electrical & Computer Engineering Theses & Dissertations

In this dissertation, a new technique based on analytic geometry for the recognition and description of three-dimensional quadric surfaces from range images is presented. Beginning with the explicit representation of quadrics, a set of ten coefficients are determined for various three-dimensional surfaces. For each quadric surface, a unique set of two-dimensional curves which serve as a feature set is obtained from the various angles at which the object is intersected with a plane. Based on a discriminant method, each of the curves is classified as a parabola, circle, ellipse, hyperbola, or a line. Each quadric surface is shown to be …

The Biogeochemistry Of Hydrogen Sulfide In The Open Ocean, Joël Radford-Knoery

OES Theses and Dissertations

Hydrogen sulfide is a poorly quantified component of the global sulfur cycle. In seawater, its dissolved species (dissolved sulfide) can react with trace metals to form dissolved complexes and insoluble compounds. Therefore, the study of dissolved° sulfide in the open ocean can yield a better understanding of the biogeochemical cycles of sulfur and trace metals.

The biogeochemical cycling of dissolved sulfide was examined using specially developed sampling and analytical methods. In the western North Atlantic and central Equatorial Pacific Oceans, total dissolved sulfide concentrations ranged from /L; they were highest, in the mixed layer and decreased with depth. The depth …

Modeling Nutrient And Plankton Processes In The California Coastal Transition Zone, John Roland Moisan

OES Theses and Dissertations

Two time- and space-dependent, physical-bio-optical models have been developed for the California Coastal Transition Zone (CTZ) region with the overall objective of understanding and quantifying the processes th at contribute to the spatial and temporal development of nutrient and plankton distributions in the CTZ. The first of these models considers only time- and vertical processes at specific locations in the CTZ. The model food web components include: silicate, nitrate, ammonium, two phytoplankton size fractions, copepods, doliolids, euphausiids and a detritus pool. The wavelength dependent attenuation of the subsurface irradiance field, due to sea water, phytoplankton pigment concentrations and dissolved organic …

Recent Benthic Foraminifera, Petrology, And Implications For Recent Transport In Wilmington And South Heyes Submarine Canyons, U.S. Atlantic Continental Margin, Jason James Lundquist

OES Theses and Dissertations

Two hundred and forty-six species of benthic foraminifera have been recognized in fourteen short cores (≤ 24cm) taken from within the Wilmington and South Heyes submarine canyons along the slope and rise of the United States Atlantic Continental Margin. Of these one hundred and forty-five species were identified to the species level, thirty were closely related to known species, sixty-six could not be assigned specific names, and five species were of uncertain generic placement. The petrologic character of the sediments was determined for each of the seventy-eight micropaleontogical samples.

Cluster analysis of benthic foraminiferal data identified twelve groups which, together …

Measurement Of The Casimir-Polder Force, C. I. Sukenik, M. G. Boshier, S. Cho, V. Sandoghdar, E. A. Hinds

Physics Faculty Publications

The authors have studied the deflection of ground-state sodium atoms passing through a micron-sized parallel-plate cavity by measuring the intensity of a sodium atomic beam transmitted through the cavity as a function of cavity plate separation. This experiment provides clear evidence for the existence of the Casimir-Polder force, which is due to modification of the ground-state Lamb shift in the confined space of a cavity. The results confirm the magnitude of the force and the distance dependence predicted by quantum electrodynamics.

Strong Large Deviation And Local Limit Theorms, Narasinga Rao Chaganty, Jayaram Sethuraman

Mathematics & Statistics Faculty Publications

Most large deviation results give asymptotic expressions for log P(Y_n ≥ y_n), where the event {Y_n ≥ y_n} is a large deviation event, that is, P(Y_n ≥ y_n) goes to 0 exponentially fast. We refer to such results as weak large deviation results. In this paper we obtain strong large deviation results for arbitrary random variables {Y_n}, that is, we obtain asymptotic expressions for P(Y_n ≥ y_n), where {Y_n ≥ y_n} is a large deviation event. These strong large deviation results …

The Sharp Lipschitz-Constants For Feasible And Optimal-Solutions Of A Perturbed Linear Program, Wu Li

Mathematics & Statistics Faculty Publications

The purpose of this paper is to derive the sharp Lipschitz constants for the feasible solutions and optimal solutions of a linear program with respect to right-hand-side perturbations. The Lipschitz constants are given in terms of pseudoinverses of submatrices of the matrices involved and are proven to be sharp.

Paschen's Law For A Hollow Cathode Discharge, H. Eichhorn, K. H. Schoenbach, T. Tessnow

Bioelectrics Publications

An expression for the breakdown voltage of a one‐dimensional hollow cathode discharge has been derived. The breakdown condition which corresponds to Paschen’s law contains, in addition to the first Townsend coefficient, and the secondary electron emission coefficient two parameters which characterize the reflecting action of the electric field and the lifetime of the electrons in the discharge. The breakdown voltage for a hollow cathode discharge in helium was calculated and compared to that of a glow discharge operating under similar conditions.

Determination Of The Neutron Spin Structure Function, P. L. Anthony, R. G. Arnold, H. R. Band, H. Borel, P.E. Bosted, V. Breton, G. D. Cates, T. E. Chupp, F. S. Dietrich, J. Dunne, R. Erbacher, J. Fellbaum, H. Fonvielle, R. Gearhart, R. Holmes, E. W. Hughes, J. R. Johnson, D. Kawall, C. Keppel, S. E. Kuhn, R. M. Lombard-Nelsen, J. Marroncle, T. Maruyama, W. Meyer, Z. E. Meziani, H. Middleton, J. Morgenstern, N. R. Newbury, G. G. Petratos, R. Pitthan, R. Prepost, Y. Roblin, S. E. Rock, S. H. Rokni, G. Shapiro, T. Smith, P. A. Souder, M. Spengos, F. Staley, L. M. Stuart, Z. M. Szalata, Y. Terrien, A. K. Thompson, J. L. White, M. Woods, J. Xu, C. C. Young, G. Zapalac, E142 Collaboration

Physics Faculty Publications

The spin structure function of the neutron g₁ⁿ has been determined over the range 0.03 < x < 0.6 at an average Q² of 2 (GeV/c)² by measuring the asymmetry in deep inelastic scattering of polarized electrons from a polarized ³He target at energies between 19 and 26 GeV. The integral of the neutron spin structure function is found to be f-¹₀ gⁿ₁(x)dx = -0.022 ± 0.011. Earlier reported proton results together with the Bjorken sum rule predict f-¹₀ gⁿ₁(x)dx = -0.059 ± 0.019.

Quasi-Brittle Graphs, A New Class Of Perfectly Orderable Graphs, Stephan Olariu

Computer Science Faculty Publications

A graph G is quasi-brittle if every induced subgraph H of G contains a vertex which is incident to no edge extending symmetrically to a chordless path with three edges in either Hor its complement H¯. The quasi-brittle graphs turn out to be a natural generalization of the well-known class of brittle graphs. We propose to show that the quasi-brittle graphs are perfectly orderable in the sense of Chvátal: there exists a linear order < on their set of vertices such that no induced path with vertices a, b, c, d and edges ab, bc, cd has a < b and d < c.

Intel Nx To Pvm 3.2 Message Passing Conversion Library, Trey Arthur, Michael L. Nelson

Computer Science Faculty Publications

NASA Langley Research Center has developed a library that allows Intel NX message passing codes to be executed under the more popular and widely supported Parallel Virtual Machine (PVM) message passing library. PVM was developed at Oak Ridge National Labs and has become the defacto standard for message passing. This library will allow the many programs that were developed on the Intel iPSC/860 or Intel Paragon in a Single Program Multiple Data (SPMD) design to be ported to the numerous architectures that PVM (version 3.2) supports. Also, the library adds global operations capability to PVM. A familiarity with Intel NX …

A Comparison Of Queueing, Cluster And Distributed Computing Systems, Joseph A. Kaplan, Michael L. Nelson

Computer Science Faculty Publications

Using workstation clusters for distributed computing has become popular with the proliferation of inexpensive, powerful workstations. Workstation clusters offer both a cost effective alternative to batch processing and an easy entry into parallel computing. However, a number of workstations on a network does not constitute a cluster. Cluster management software is necessary to harness the collective computing power. A variety of cluster management and queuing systems are compared: Distributed Queueing Systems (DQS), Condor, Load Leveler, Load Balancer, Load Sharing Facility (LSF - formerly Utopia), Distributed Job Manager (DJM), Computing in Distributed Networked Environments (CODINE), and NQS/Exec. The systems differ in …

Optimal Greedy Algorithms For Indifference Graphs, Peter J. Looges, Stephan Olariu

Computer Science Faculty Publications

A fundamental problem in social sciences and management is understanding and predicting decisions made by individuals, various groups, or the society as a whole. In this context, one important concept is the notion of indifference. We characterize the class of indifference graphs, that is, graphs which arise in the process of quantifying indifference relations. In particular, we show that these graphs are characterized by the existence of a special ordering of their vertices. As it turns out, this ordering leads naturally to optimal greedy algorithms for a number of computational problems, including coloring, finding a shortest path between two vertices, …

A Magnetic Suspension System With A Large Angular Range, Colin P. Britcher, Mehran Ghofrani

Mechanical & Aerospace Engineering Faculty Publications

In order to explore and develop technology required for the magnetic suspension of objects over large ranges of orientation, a small-scale laboratory system, the large-angle magnetic suspension test fixture (LAMSTF) has been constructed at NASA Langley Research Center. This apparatus falls into the category of large-gap, actively stabilized magnetic levitation systems. The hardware comprises five conventional electromagnets in a circular arrangement, each driven from a separate bipolar power amplifier. Electromagnet currents are commanded by a digital control system, implemented on a microcomputer, which in turn derives the position and attitude of the suspended element from an infrared optical system. The …

Glow-Discharge Enhanced Permeation Of Oxygen Through Silver, D. Wu, R. A. Outlaw, Robert L. Ash

Mechanical & Aerospace Engineering Faculty Publications

The permeation of oxygen through Ag0.05Zr over the temperature range of 300-650°C under glow-discharge conditions has been studied and compared to the permeation of thermally dissociated molecular oxygen. A low-energy dc glow-discharge in O₂ has been employed which produced approximately 10% atoms. The permeation rate during the glow discharge was found to be much higher (a factor of ∼10) than without the glow discharge. The small fraction of oxygen atoms generated appears to dominate the permeation because of much higher solution probabilities. Below 500°C, the activation energy for the permeation with glow discharge was found to be 15.5 kcal/mol …

Temporal Model Of An Optically Pumped Co-Doped Solid State Laser, T. G. Wangler, J. J. Swetits, A. M. Buoncristiani

Mathematics & Statistics Faculty Publications

Currently, research is being conducted on the optical properties of materials associated with the development of solid-state lasers in the 2 micron region. In support of this effort, a mathematical model describing the energy transfer in a holmium laser sensitized with thulium is developed. In this paper, we establish some qualitative properties of the solution of the model, such as non-negativity, boundedness, and integrability. A local stability analysis is then performed from which conditions for asymptotic stability are obtained. Finally, we report on our numerical analysis of the system and how it compares with experimental results.

The Scattering Potential For A Polytrope Of Degree-5, J. A. Adam

Mathematics & Statistics Faculty Publications

By regarding the study of radial and non-redial stellar oscillations as a problem in potential scattering theory, a standard form of the radial Schrödinger equation can be derived. After establishing some preliminary results of astrophysical interest, an analytic expression for the potential is derived for a truncated (i.e., finite radius) polytrope (or class of self-gravitating compressible spheres) of degree n = 5. Properties of the potential are discussed.

Phytoplankton Relationships To Water Quality In Lake Drummond And Two Drainage Ditches, Christine G. Phillips, Harold G. Marshall

Biological Sciences Faculty Publications

A twelve-month phytoplankton study was conducted in Lake Drummond and Washington and Jericho Ditches from December 1988 to November 1989. Four dominant phytoplankton groups were identified at these sites. These were the Bacillariophyceae, Cyanophyceae, Cryptophyceae and an autotrophic picoplankton component. Over the past 20 years there has been a decrease in the mean pH levels of Lake Drummond and the replacement of one its former major components, the Chlorophyceae, by the Cyanophyceae. Based on water quality analysis results and species diversity indices, Lake Drummond is classified as in an early eutrophic stage of development.

A Comparison Of Gulf Stream Sea Surface Height Fields Derived From Geosat Altimeter Data And Those Derived From Sea Surface Temperature Data, Tal Ezer, George L. Mellor, Dong-Shan Ko, Ziv Sirkes

CCPO Publications

Two types of satellite data, Geosat altimeter data and sea surface temperature data (SST), are compared and evaluated for their usefulness in assimilation into a numerical model of the Gulf Stream region. Synoptic sea surface height (SSH) fields are derived from the SST data in the following way: first three-dimensional temperature and salinity analysis fields are obtained through the Optimum Thermal Interpolation System (OTIS), and then SSH fields are calculated using a primitive equation, free-surface, numerical model running in a diagnostic mode. The aforementioned SSH fields are compared with SSH fields obtained from the Geosat altimeter data. Use of Geosat …

Temporal Development Of Electric Field Structures In Photoconductive Gaas Switches, K. H. Schoenbach, J. S. Kenney, F.E. Peterkin, R. J. Allen

Bioelectrics Publications

The temporal development of the electric field distribution in semi‐insulating GaAs photoconductive switches operated in the linear and lock‐on mode has been studied. The field structure was obtained by recording a change in the absorption pattern of the switch due to the Franz–Keldysh effect at a wavelength near the band edge of GaAs. In the linear mode, a high field layer develops at the cathode contact after laser activation. With increasing applied voltage, domainlike structures become visible in the anode region and the switch transits into the lock‐on state, a permanent filamentary electrical discharge. Calibration measurements show the field intensity …

The Dynamics Of Growth-Factor-Modified Immune-Response To Cancer Growth: One-Dimensional Models, J. A. Adam

Mathematics & Statistics Faculty Publications

By characterizing the effect of tumor growth factors as deviations from normal logistic-type growth rates, the spatio-temporal dynamics for a one-dimensional model of cancer growth incorporating immune response are studied. The growth rates considered are classified respectively as normal, activated, inhibited and delay activated. The homogeneous steady states are defined by relative extrema of a ''free energy'' function V(x) for each of the above four cases. This function is of particular importance in studying the coexistence of tumoral and cancer-free steady states, and in identifying the nature (progressive or regressive) of travelling wave solutions to the nonlinear partial differential equation …

Instability Waves In The Gulf Stream Front And Its Thermocline Layer, Sang-Ki Lee

OES Theses and Dissertations

Linear instability calculations were carried out on a three layer Gulf Stream front model in an attempt to elucidate the interaction of the thermocline layer with surface slopewater shoreward of the front. The basic state is geostrophic balance and constant potential vorticity in the two active layers, but the perturbations are ageostrophic. The flow is found to be unstable to long wave perturbations, the wavelength of the most unstable wave to be of order 10 radii of deformation. The instability is mainly baroclinic, 75-85% of the energy supply to the growing perturbation coming from basic flow potential energy. Calculated wavelengths …

Multidimensional Approach To Implementation Of Continuous Process Improvement Utilizing Small Run Analysis In A Shipyard Environment, Paul Ray Hollandsworth

Engineering Management & Systems Engineering Theses & Dissertations

Nationally, both public and private shipyards are experiencing a high rework rate (over 40%) in the fabrication of plug connectors used for electronic systems onboard Navy vessels. The shipyard's survival depends on acquiring the elements necessary to maintain a major industry in a position of continuous improvement that produces a better product than their competitors, at less cost, in a safe manner, and on schedule.

This research addresses the complex problem of how to introduce quality control methodologies within a job shop environment that assists in identifying variables that influence the rework rate of plug fabrication process over a four …