Physical Sciences and Mathematics Commons^™

Determining The Impact Of Post-Harvest Water Management On Chironomid Abundance, Agrochemical Biomass And Potential Trophic Biomagnification, Mason Thomas

Theses and Dissertations

Agriculture has diminished shorebirds’ natural habitat in the Mississippi Alluvial Valley. Remaining natural stopover sites are supplemented with agricultural fields during the fall and winter. This study evaluates the impact of 4 different post-harvest water management strategies on shorebird food abundance and potential agrochemical biomagnification. Chironomid samples estimated abundance, biomass, and chironomid agrochemical concentration in each field. A risk assessment of agrochemical biomagnification to shorebirds was made across all treatments. Of treatments represented on all study sites, winter treatment had greatest chironomid abundance and biomass. Models indicated that days since flood initiation, start date, and temperature are significant predictors of …

Quantifying Seasonal And Annual Precipitation Variability On San Salvador Island, Bahamas Using Surface Observations And Satellite Estimates., John Bryson Wells

Theses and Dissertations

San Salvador Island is a small Bahamian island located in the subtropics just north of the Tropic of Cancer. Due to its subtropical location, the island is influenced by both mid-latitude and tropical weather patterns. These weather patterns vary in scale from localized convective uplift to synoptic-scale systems. This study compares satellite-derived estimates of precipitation and rain gauge observations from June 2019 through September 2021 to evaluate the relationship between the two datasets. This study then uses the satellite-derived estimates of precipitation over a 20-year period to quantify annual and seasonal variability in precipitation on San Salvador. Corroborating past research, …

Evaluating The Relationship Between Methane Seeps And Seafloor Geomorphology On The Northern Us Atlantic Margin, Gabriel Hernandez

Theses and Dissertations

Methane seeps are a transport pathway for carbon from seafloor sediments to the marine environment with important implications for global biogeochemical cycling. Accordingly, there is substantial interest in better understanding the processes that control seep location and predicting the distribution of seeps with existing seafloor datasets. Visual evaluation of methane seeps, in multibeam sonar water column data, suggests a spatial relationship between seeps and specific seafloor morphologic features such as ridge crests. In this thesis, seafloor geomorphology at 1996 seep detection sites on the US Atlantic margin was quantitatively characterized by geomorphologic phonotype, bathymetric position index, slope, rugosity, and aspect …

Variational And Adaptive Non-Local Image Denoising Using Edge Detection And K − Means Clustering, Shiraz Mujahid

Theses and Dissertations

With the increased presence of image-based data in modern applications, the need for robust methods of image denoising grows greater. The work presented herein considers two of the most ubiquitous approaches towards image denoising: variational and non-local methods. The effectiveness of these methods is assessed using quantitatively using peak signal-to-noise ratio and structural similarity index measure metrics. This study employs ��−means clustering, an unsupervised machine learning algorithm, to isolate the most dominant cluster centroids within the incoming data and propose the introduction of a new adaptive parameter into the non-local means framework. Motivated by the fact that a majority of …

Dynamics Of Redox-Driven Molecular Processes In Local And Systemic Plant Immunity, Philip Berg

Theses and Dissertations

The work here presents two main parts. In the first part, chapters 1 – 3 focus on dynamical systems modeling in plant immunity, whereas chapters 4 – 6 describe contributions to computational modeling and analysis of proteomics and genomics data. Chapter 1 investigates dynamical and biochemical patterns of reversibly oxidized cysteines (RevOxCys) during effector-triggered immunity (ETI) in Arabidopsis, examines the regulatory patterns associated with Arabidopsis thimet oligopeptidase 1 and 2’s (TOP1 and TOP2), roles in the RevOxCys events during ETI, and analyzes the redox phenotype of the top1top2 mutant. The second chapter investigates the peptidome dynamics during ETI …

Assessing Wood Failure In Plywood By Deep Learning/Semantic Segmentation, Ramon Ferreira Oliveira

Theses and Dissertations

The current method for estimating wood failure is highly subjective. Various techniques have been proposed to improve the current protocol, but none have succeeded. This research aims to use deep learning/semantic segmentation using SegNet architecture to estimate wood failure in four types of three-ply plywood from mechanical shear strength specimens. We trained and tested our approach on custom and commercial plywood with bio-based and phenol-formaldehyde adhesives. Shear specimens were prepared and tested. Photographs of 255 shear bonded areas were taken. Forty photographs were used to solicit visual estimates from five human evaluators, and the remaining photographs were used to train …

Surficial Geologic Mapping Of The Starkville 7.5-Minute United States Geological Survey Quadrangle 33088d-7 In Oktibbeha County, Mississippi, Jonathan Leard

Theses and Dissertations

The Starkville Quadrangle is a hotspot for geological research. The Late Cretaceous is represented by the Demopolis Formation in the northeast corner of the quadrangle, followed by the Ripley Formation, and the Prairie Bluff Formation. The K-Pg boundary is exposed in the quadrangle, and the remarkable paleontology is of global importance. The Clayton Formation is the first Paleocene unit. Where the Clayton Formation channel sands are in contact with the underlying Prairie Bluff Formation, springs occur. Springs were a rare source of water in the Black Prairie and spurred the settlement of the area over 10,000 years ago. The Paleocene …

From The Sky To The Smartphone: Communicating Weather Information In A Digital Age, Cole M. Vaughn

Theses and Dissertations

As new technology has emerged in the digital era, the public can now choose from a variety of new media from which to get weather information. Weather applications (apps) and social media have emerged as some of the popular new media. This study sought to understand the extent to which these new media are used, how weather apps are perceived, how the news media used Twitter during Hurricane Irma, and how the public engaged with the news media’s tweets. A survey and dataset of tweets were used to evaluate the research questions and hypotheses of this research. The study found …

Towards Structured Planning And Learning At The State Fisheries Agency Scale, Caleb A. Aldridge

Theses and Dissertations

Inland recreational fisheries has grown philosophically and scientifically to consider economic and sociopolitical aspects (non-biological) in addition to the biological. However, integrating biological and non-biological aspects of inland fisheries has been challenging. Thus, an opportunity exists to develop approaches and tools which operationalize planning and decision-making processes which include biological and non-biological aspects of a fishery. This dissertation expands the idea that a core set of goals and objectives is shared among and within inland fisheries agencies; that many routine operations of inland fisheries managers can be regimented or standardized; and the novel concept that current information and operations can …

The Chemistry And Catalytic Activity Of Dehydrogenative Silylation And Hydroboration Of Complexes Bearing Semirigid Ligands With Group 14 Elements, Niroshani S. Abeynayake

Theses and Dissertations

Incorporation of silicon in the ligand backbone would yield electron-rich metal complexes upon coordination to transition metal complexes. The coordination chemistry of semirigid benzyl phosphines bearing a single or multiple phosphorus atoms and varying number of Si−H moieties has gained interest in recent years. This dissertation focuses on synthesizing silyl and germyl transition metal complexes of groups 9 and 10. Chapter II presents the synthesis of a family of four coordinated 14-electron rhodium complexes. The newly synthesized complexes were characterized in solution by multinuclear NMR spectroscopy and in the solid-state by single-crystal X-ray diffraction. These d⁶ complexes possess sawhorse …

Augmented Reality Fonts With Enhanced Out-Of-Focus Text Legibility, Mohammed Safayet Arefin

Theses and Dissertations

In augmented reality, information is often distributed between real and virtual contexts, and often appears at different distances from the viewer. This raises the issues of (1) context switching, when attention is switched between real and virtual contexts, (2) focal distance switching, when the eye accommodates to see information in sharp focus at a new distance, and (3) transient focal blur, when information is seen out of focus, during the time interval of focal distance switching. This dissertation research has quantified the impact of context switching, focal distance switching, and transient focal blur on human performance and eye fatigue in …

Mitigating The Shrink-Swell Capacities Of The Yazoo Clay Through Application Of Lime And Biochar, Austin Alan Brister

Theses and Dissertations

Shrinking and swelling in Yazoo Clay is a cause of concern for construction projects in Mississippi. This thesis investigated the effects of adding lime and Douglas Fir biochar on the shrinking and swelling capabilities of Yazoo Clay. Samples of Yazoo Clay were mixed with the additives in defined ratios and subjected to the free swell test and the COLE(rod) test. Biochar addition reduced the COLE(rod) of the samples a large amount, while increasing the swelling potential of the clay samples. The addition of lime slightly reduced both the shrinking and swelling potentials of the samples. The mineralogical variability of Yazoo …

Molecular Insights Into The Redox Of Atmospheric Mercury Through Laser Spectroscopy, Rongrong Wu Cohen

Theses and Dissertations

The widespread pollution of mercury motivates research into its atmospheric chemistry and transport. Gaseous elemental mercury (Hg(0)) dominates mercury emission to the atmosphere, but the rate of its oxidation to mercury compound (Hg(II)) plays a significant role in controlling where and when mercury deposits to ecosystems. Atomic bromine is regarded as the main oxidant for Hg(0) oxidation, known to initiate the oxidation via a two-step process in the atmosphere – formation of BrHg (R1) and subsequent reactions of BrHg with abundant free radicals Y, i.e., NO2, HOO, etc. (R2), where the reaction of BrHg +Y could also lead to the …

Precise Measurement Of The Nuclear Dependence Of The Emc Effect In Light Nuclei, Abishek Karki, Abishek Karki

Theses and Dissertations

Measurements of inclusive electron scattering cross-section ratios from light nuclei over a wide range of the Björken �� (0.3 < �� < 1) up to �� 2 = 8.3 GeV² were made as part of experiment E10-10-008, which was conducted in Hall C at the Thomas Jefferson National Accelerator Facility. The measurements were performed using a beam energy of 10.602 GeV and an average beam current of 45 ��A. This dissertation provides a thorough description of the experiment as well as the extracted ratios of inclusive nuclear cross-sections with respect to the deuterium cross-sections (the EMC effect) for the targets ⁹ Be, ¹² C, ¹⁰ B, and ¹¹ B. The …

Geologic Mapping Of The Sparta 7.5-Minute Quadrangle In Northern Mississippi Via Remote Sensing, Traditional Geologic Survey, And Applied Geospatial Information Systems Methods, Rayford Dean Parnell

Theses and Dissertations

Traditional geologic mapping involves substantial time and labor in the field as geologic contacts are manually examined and interpreted. The processes of mapping geologic contacts can be condensed into a quicker and less laborious process using advances in remote sensing and GIS (geospatial information systems), including increased resolution and computerized data management and interpretation. Application of these advances reduces the costs and time of geologic mapping. The Sparta 7.5-minute quadrangle provides a mostly unaltered view of regional Paleocene and Upper Cretaceous geology due to its rural locale, lack of development, and stream topography. Recently LiDAR (Light Detection And Ranging) survey …

Immobilization Of Uranium And Iodine By Calcium Phosphate Minerals, Angel L. Jimenez-Arroyo

Theses and Dissertations

This dissertation is comprised of three independent but interconnected studies with the scope of further understanding uranium and iodine partitioning between apatite and fluid. The studies herein presented investigated: 1) brushite to apatite crystallization method; 2) the degree of uranium incorporation into apatite; 3) the degree of iodine incorporation into apatite. The importance of this work is assessing the role of apatite in immobilizing these elements, where uranium is a major component of spent nuclear fuel and iodine is a chemical analog of its radioactive isotope (¹²⁹I). Once we understand the incorporation mechanisms, we will provide data that …

The Effects Of Incorporating 0-500 M Srh Into The Violent Tornado Parameter, Jay Palmer Roberts

Theses and Dissertations

Between 2011-2021, violent tornadoes accounted for an average of 65% of all tornado-related fatalities. The Violent Tornado Parameter (VTP), created in 2018, attempts to address this forecast problem but has issues with false alarms. Storm Relative Helicity has historically been used in tornado forecasting. Recent studies have shown the 0-500 m effective layer SRH (ESRH) has skill in discerning significantly tornadic events from those that are not.

This study explored the effects of incorporating 0-500 m ESRH into the VTP and issues relating to the parameter’s false alarm rate by examining RUC/RAP forecast soundings for 302 U.S. tornadic events (83 …

Three Case Studies Of Using Hybrid Model Machine Learning Techniques In Educational Data Mining To Improve The Classification Accuracies, Sujan Poudyal

Theses and Dissertations

A multitude of data is being produced from the increase in instructional technology, e-learning resources, and online courses. This data could be used by educators to analyze and extract useful information which could be beneficial to both instructors and students. Educational Data Mining (EDM) extracts hidden information from data contained within the educational domain. In data mining, hybrid method is the combination of various machine learning techniques. Through this dissertation, the novel use of machine learning hybrid techniques was explored in EDM using three educational case studies. First, in consideration for the importance of students’ attention, on and off-task data …

Classification Models For 2,4-D Formulations In Damaged Enlist Crops Through The Application Of Ftir Spectroscopy And Machine Learning Algorithms, Benjamin Blackburn

Theses and Dissertations

With new 2,4-Dichlorophenoxyacetic acid (2,4-D) tolerant crops, increases in off-target movement events are expected. New formulations may mitigate these events, but standard lab techniques are ineffective in identifying these 2,4-D formulations. Using Fourier-transform infrared spectroscopy and machine learning algorithms, research was conducted to classify 2,4-D formulations in treated herbicide-tolerant soybeans and cotton and observe the influence of leaf treatment status and collection timing on classification accuracy. Pooled Classification models using k-nearest neighbor classified 2,4-D formulations with over 65% accuracy in cotton and soybean. Tissue collected 14 DAT and 21 DAT for cotton and soybean respectively produced higher accuracies than the …

Improvement Value Of Forest Resources By Use Of Cottonseed Protein Meal As A Bio-Based Wood Adhesive For Hardwood Plywood Products, Edward David Entsminger

Theses and Dissertations

Literature shows that production of cottonseed adhesives is feasible to develop an environmentally friendly and competitive bio-based wood adhesive. Defatted cottonseed and water-washed cottonseed meals were prepared from glandless cottonseed and were used in adhesive formulations to produce three-ply yellow poplar (Liriodendron tulipifera) plywood panels as the first objective. These two cottonseed meals were compared with the properties of plywood panels made with an adhesive formulated from a commercial soybean meal, as a control. Adhesive resins were prepared from each protein meal with sodium metabisulfite (Na2S2O5) and one of two polyamido-amine-epichlorohydrin (PAE) wet strength agents, and the plywood panels were …

The Fermilab Spinquest Experiment: Commissioning And Plans Toward Production, Nuwan Chaminda Gunawardhana Waduge

Theses and Dissertations

E1039/SpinQuest, a transversely-polarized Drell-Yan experiment at Fermilab, plans to use the 120 GeV proton beam and polarized NH3 and ND3 cryogenic targets to study azimuthal asymmetries in dimuon production to extract the magnitude as well as sign of the sea quarks Sivers functions. The SpinQuest spectrometer is optimized to detect oppositely-charged muons with a series of tracking chambers and hodoscope stations. The scope of this manuscript is to highlight the physics goals and the experimental setup with a focus on the ongoing debugging and training of one of the tracking systems, mainly drift chambers, as preparation for the upcoming commissioning …

Rock-Fluid Interaction And The Incorporation Of Cations Into Calcite During Recrystallization In Multiple Hydrothermal Systems., Van Anh Nguyen

Theses and Dissertations

Fluid-rock interaction causes an exchange of isotopes or elements through various reactions. The rate of these reactions strongly depends on temperature. The interaction involves dissolution precipitation, chemical exchange reactions, redox reactions, diffusion, and their combinations. The goal of studying fluid-rock interaction is to understand the change in mineral chemistry of the rock materials when in contact with an aqueous solution. These processes occur in all regions of the Earth where aqueous solutions are found. This work is comprised of three independent studies which provide an understanding about crystallization processes under multiple hydrothermal conditions with geological and environmental applications.

In the …

Gpgpu Microbenchmarking For Irregular Application Optimization, Dalton R. Winans-Pruitt

Theses and Dissertations

Irregular applications, such as unstructured mesh operations, do not easily map onto the typical GPU programming paradigms endorsed by GPU manufacturers, which mostly focus on maximizing concurrency for latency hiding. In this work, we show how alternative techniques focused on latency amortization can be used to control overall latency while requiring less concurrency. We used a custom-built microbenchmarking framework to test several GPU kernels and show how the GPU behaves under relevant workloads. We demonstrate that coalescing is not required for efficacious performance; an uncoalesced access pattern can achieve high bandwidth - even over 80% of the theoretical global memory …

Defining Viable Solar Resource Locations In The Southeast United States Using The Satellite-Based Glass Product, Jolie Kavanagh

Theses and Dissertations

This research uses satellite data and the moment statistics to determine if solar farms can be placed in the Southeast US. From 2001-2019, the data are analyzed in reference to the Southwest US, where solar farms are located. The clean energy need is becoming more common; therefore, more locations than arid environments must be observed. The Southeast US is the main location of interest due to the warm, moist environment throughout the year. This research uses the Global Land Surface Satellite (GLASS) photosynthetically active radiation product (PAR) to determine viable locations for solar panels. A probability density function (PDF) along …

Development And Characterization Of A Peanut-Shell Based Activated Carbon And The Outcomes Of A Hands-On Approach To Chemical Education, Danielle Pitre

Theses and Dissertations

Heavy metals are a recognized toxic environmental contaminant, even at very low concentrations. There have been well-known events in the last decade within the US of high amounts of lead in the drinking water supplies of cities, leading to detrimental effects within its population. Ways have been found to remove this metal, and others, from water with expensive adsorbents. The aim of the first part of this research was to create an inexpensive adsorbent from a waste material and modify it in such a way that it would be adept at removing heavy metals from water.

In Chapter I, we …

Success And Confidence In, Or Inclusive Of, Undergraduate Chemistry Students Surrounding A Collaborative Learning Intervention, Encouragement Of Metacognition, And A Multifaceted Scholarship Support Program, Maggie Erin Leake

Theses and Dissertations

Student success in chemistry has been linked to a wide range of factors. Some of these factors are familiar, easily quantified measures; colleges typically rely on factors like high school GPA and measures of aptitude to make admission decisions or set course prerequisites. Success in chemistry courses can be linked to these measures, and math aptitude scores in particular are often used as prerequisites for introductory chemistry courses. However, success in chemistry can also be affected by factors like motivation, peer interactions, sense of belonging, and metacognitive skill. Additionally, outcomes in chemistry and other STEM courses like math and physics …

Polyaniline-Derivatives Based On Poly (Heterocyclic Diphenylamine) With Improved Electrochemical Stability And Processability, Mohammed Noifa Almtiri

Theses and Dissertations

Today, smart innovation has become an essential part of human life; thus, contemporary technologies are always looking for intelligent, responsive, and efficient materials to satisfy these demands. Consequently, synthetic "metals" or, more precisely, intrinsically conducting polymers (CPs) have begun to find a place as valuable and practical materials for a new generation of devices. Amongst all intrinsic conducting polymers, polyaniline (PANI) has attracted significant attention due to its outstanding air and moisture stability, simple preparation technique, and high electrical conductivity (chapter I).

Chapter II represents the synthesis of a new PANI derivative that contains a phenoxazine unit co-polymerized with p-phenylenediamine …

An Investigation Of Geostationary Satellite Imagery To Compare Developing And Non-Developing African Easterly Waves, Jenna Bartlett

Theses and Dissertations

African easterly waves (AEWs) are known precursors to tropical cyclone (TC) formation, although it is not always clear which AEWs will develop and which AEWs will not. To investigate AEW evolution, this study examines novel observations from the geostationary Advanced Baseline Imager (ABI) during July-September 2019. Case studies are conducted for two AEWs: one that became Hurricane Dorian, the strongest and most devastating hurricane of the 2019 Atlantic hurricane season, and a long-lived September AEW that did not become a TC. Lower-level moisture and flow, and the strength and spatial distribution of convective activity, differed between these two waves. By …

Determining The Effects Of Elevated Carbon Dioxide On Soil Acidification, Cation Depletion, And Soil Inorganic Carbon And Mapping Soil Carbons Using Artificial Intelligence, Jannatul Ferdush

Theses and Dissertations

Soil carbon is the largest sink and source of the global carbon cycle and is disturbed by several natural, anthropogenic, and environmental factors. The global increase of atmospheric CO₂ affects soil carbon cycling through varied biogeochemical processes. The first chapter is a compilation of current information on potential factors triggering soil acidification and weathering mechanisms under elevated CO₂ and their consequences on soil inorganic carbon (SIC) pool and quality. Soil water content and precipitation were critical factors influencing elevated CO₂ effects on the SIC pool. The second chapter examines a detailed column experiment in which six soils …

X-Ray Vision At Action Space Distances: Depth Perception In Context, Nate Phillips

Theses and Dissertations

Accurate and usable x-ray vision has long been a goal in augmented reality (AR) research and development. X-ray vision, or the ability to comprehend location and object information when such is viewed through an opaque barrier, would be imminently useful in a variety of contexts, including industrial, disaster reconnaissance, and tactical applications. In order for x-ray vision to be a useful tool for many of these applications, it would need to extend operators’ perceptual awareness of the task or environment. The effectiveness with which x-ray vision can do this is of significant research interest and is a determinant of …