Physical Sciences and Mathematics Commons^™

Reduced Mediators Released By Cyanobacteria During Exoelectrogenesis Detected Using Differential Pulse Voltammetry, Laura T. Wey, Monica Brachi, Yagut Allahverdiyeva, Shelley D. Minteer

Chemistry Faculty Research & Creative Works

Cyanobacteria generate electrical current through exoelectrogenesis (extracellular electron transfer) downstream of photosynthesis, yet the identity of the endogenous redox mediator(s) responsible remains unresolved. Here, we apply differential pulse voltammetry (DPV) to detect and characterise redox-active species released by Synechocystis sp. PCC 6803 under illumination. To enable sensitive detection, we developed an electrolyte intermediate between BG11 (Blue-Green-11) growth medium and MOPS (3-(N-morpholino)propanesulfonic acid) buffer that minimises background electrochemical interference while maintaining short-term cellular functionality. DPV revealed multiple light-enhanced oxidation peaks (0.1–0.65 V vs. saturated calomel electrode (SCE)) that were not resolvable using cyclic voltammetry, providing evidence that cyanobacteria release reduced compounds …

Generative Ai Adoption And Solvers' Popularity On Supply-Driven Crowdsourcing Platforms: The Dual Role Of Price Signals, Zimeng Zhu, Carol Hsu, Fiona Fui-Hoon Nah, Na Liu

Research Collection School Of Computing and Information Systems

Purpose – We investigate the effect of solvers’ adoption of Generative AI (GenAI) on their popularity in a supply-driven crowdsourcing platform. We also examine the impact of price signals as well as their heterogeneous impact based on the solvers’ membership duration on the platform. Design/methodology/approach – Our analysis focuses on solvers who adopt GenAI for design-related gigs on the supply-driven crowdsourcing platform. By combining propensity score matching (PSM) with multi-period difference-in-differences (DID), we examine how GenAI adoption impacts solvers’ popularity and how price signals affect this main effect. Findings – Our findings reveal that solvers who adopt GenAI tend to …

Fair And Explainable Educational Recommendations With A Hybrid Graph-Gru Framework, Edmund Evangelista, Syed M.Salman Bukhari

All Works

Artificial Intelligence (AI) recommender systems are increasingly used in education to personalize learning and help students navigate large collections of digital learning resources. However, many existing approaches emphasize predictive accuracy over fairness, robustness, diversity, and transparency. This creates an important educational challenge. The students with limited participation histories may receive less reliable support, while highly popular resources may dominate recommendation lists and limit access to other useful learning materials. To address this challenge, this study aims to develop and evaluate a responsible educational recommender framework that supports personalized learning resource navigation while making recommendation behavior more fair, stable, diverse, and …

Computational Studies Of Triplet State Formation In Zinc Dipyrrin Complexes, Reuben Kwabla Adigbli

Electronic Theses and Dissertations

Zinc dipyrromethene complexes are promising earth-abundant photosensitizers due to their strong visible-light absorption and tunable excited states. To rationally design them for photocatalysis and photodynamic therapy, a molecular-level understanding of triplet-state formation is needed, but details of intersystem crossing remain unclear. To study the effect of π-extension, we synthesized an indole-substituted zinc dipyrrin complex: the dipyrromethane ligand was prepared from indole and mesitaldehyde, oxidized to the dipyrromethene, then coordinated with zinc. DFT and TD-DFT calculations determined ground and excited-state geometries and energies in different solvents, modeled absorption spectra, and visualized charge distributions. The results show how solvent polarity shifts energies …

Toward Optimizing Fruit Production In Utah Soils: Apple Salt Tolerance Screening And Tart Cherry Fertility Management, Kaitlin Dabbs

All Graduate Theses and Dissertations, Fall 2023 to Present

Fruit production in Utah can be challenging due to local climate and soil conditions. Tart cherries and apples are major fruit crops in Utah, and improvements to these cropping systems would be beneficial for farmers and local consumers. Two experiments were conducted to evaluate desired improvements for these crops. The first study looked for salt tolerance in ten new apple rootstocks. Salty soils can be found throughout the state limiting the land suitable for apple production. When grown in salty soils apple trees often have reduced growth and production potential. A specialized drip irrigation system was constructed in a greenhouse …

From Solitons To Chaos: Nonlinear Dynamics Of The Time-Fractional Modified Regularized Long-Wave Equation, Samsun Nahar Ananna, Chunhui Lu, Abdulla Al Mamun, Md Al Amin Meia, Nur Hasan Mahmud Shahen

School of Mathematical & Statistical Sciences Faculty Publications

This study investigates the nonlinear wave structures and complex dynamical behavior of the time-fractional modified regularized long-wave (mRLW) equation through an integrated analytical, numerical, and dynamical framework, with particular emphasis on connecting localized wave formation with perturbation-induced nonlinear dynamics. Within the adopted fractional framework, a Hirota-type bilinear approach is employed to construct one-wave, two-wave, three-wave, lump, one-lump–one-soliton, and one-lump–one-stripe structures, whose numerical consistency is subsequently examined using the Modified Variational Iteration (MVI) method through graphical comparisons and L 2 and L ∞ error norms. The periodically perturbed mRLW system is further investigated using phase portraits, Lyapunov exponents, bifurcation diagrams, Poincaré …

Long-Term Analysis Of Pm2.5 Elemental Composition And Source Contributions In Coastal Urban Environments Of Corpus Christi And Houston In Texas, Sai Deepak Pinakana, Jeremy A. Sarnat, Amit U. Raysoni

School of Earth, Environmental, & Marine Sciences Faculty Publications

Long-term assessments of fine particulate matter play a key role in identifying persistent and emerging emission contributors. Coastal urban areas are highly susceptible to transboundary dust and wildfire events in addition to local pollution sources. Multi-decadal assessments in these regions using chemical speciation data could offer insights into major pollutant sources and their trends. This study utilizes nearly two decades of PM2.5 elemental composition data at two major coastal cities in Texas: Houston and Corpus Christi. Fourteen trace elements were analyzed to characterize the seasonal variability and long-term source evolution using a combination of Spearman’s correlation analysis, principal component analysis, …

Study Of Fast Switching Metastable-State Photoacids And Controlled Drug Release From Polycaprolactone (Pcl) Vascular Scaffold, Rana Salman Abbood Abbood

Theses and Dissertations

Metastable-state photoacid (mPAH) has become a common tool for controlling and driving chemical processes with light. mPAHs with fast reverse reactions are desirable for precise temporal control or generating quick pulses of proton concentration. In this work, different approaches towards fast reversing mPAHs are studied. Experimental and computational results showed that stabilizing the charge–transfer intermediate is an effective way to increase the rate. A novel mPAH with a reverse reaction ≈500 times faster than the most widely used mPAH in methanol has been developed. Another water-soluble mPAH exhibited a reverse reaction with a rate constant of 7.8 s−1, the fastest …

How Leaders Build Employee Trust In Artificial Intelligence: Voice Opportunities, Humility, And Trust Transfer, Jack Mcguire, David De Cremer, Devesh Narayanan

Research Collection Lee Kong Chian School Of Business

Artificial intelligence is increasingly central to organizational work, yet employee trust in AI remains fragile. Although prior research has primarily explained trust in AI through technological characteristics such as transparency, reliability, and accuracy, we argue that trust in AI is also shaped by the social context in which employees encounter these systems. Drawing on affect-as-information theory and social information processing theory, we develop and test a model in which leader-provided voice opportunities reduce employees’ negative affect about AI-related work experiences, thereby enhancing perceptions of leader trustworthiness and, in turn, trust in AI. We further propose that this indirect effect depends …

The Downstream Effect Of Gender Bias On Academic Performance And Career Aspirations Amongst Female Students In Stem Via Gender-Professional Identity Integration (G-Pii), Chi-Ying Cheng, Shuna Shiann Khoo, Shih-Fen Cheng, Yeow Leong Lee, Vandana Ramachandra Rao

Research Collection School of Social Sciences

Background Gender imbalance in STEM, characterized by a significant underrepresentation of women, remains a significant challenge. Although gender bias is a well-known contributor to women’s attrition from STEM, the psychological mechanisms linking gender bias to departure are less well understood. Our research investigates early antecedents of attrition and the psychological processes that precede leaving the STEM pathway in tertiary education. Drawing upon identity integration research, we propose that perceived gender bias exerts undermines female STEM students’ academic performance and career aspirations by reducing their Gender-Professional Identity Integration (G-PII), a construct that captures individual differences in the perceived compatibility between a …

Suicide Ideation Detection Using Social Media Data And Ensemble Machine Learning Model, Erol Kina, Jin Ghoo Choi, Abid Ishaq, Rahman Shafique, Monica Gracia Villar, Eduardo Silva Alvarado, Isabel De La Torre Diez, Imran Ashraf

Research outputs 2022 to 2026

Identifying the emotional state of individuals has useful applications, particularly to reduce the risk of suicide. Users’ thoughts on social media platforms can be used to find cues on the emotional state of individuals. Clinical approaches to suicide ideation detection primarily rely on evaluation by psychologists, medical experts, etc., which is time-consuming and requires medical expertise. Machine learning approaches have shown potential in automating suicide detection. In this regard, this study presents a soft voting ensemble model (SVEM) by leveraging random forest, logistic regression, and stochastic gradient descent classifiers using soft voting. In addition, for the robust training of SVEM, …

Bridg-Ics: Ai-Grounded Knowledge Graphs For Intelligent Threat Analytics In Industry 5.0 Cyber-Physical Systems, Padmeswari Nandiya, Ahmad Mohsin, Ahmed Ibrahim, Iqbal H. Sarker, Helge Janicke

Research outputs 2022 to 2026

Industry 5.0’s increasing integration of IT and OT systems is transforming industrial operations but also expanding the cyber–physical attack surface. Industrial Control Systems (ICS) face escalating security challenges as traditional siloed defenses fail to provide coherent, cross-domain threat insights. We present BRIDG-ICS (BRIDge for Industrial Control Systems), an AI-enriched Knowledge Graph (KG) framework for context-aware threat analysis and quantitative assessment of cyber resilience in smart manufacturing environments. BRIDG-ICS fuses heterogeneous industrial and cybersecurity data into an integrated Industrial Security Knowledge Graph linking assets, vulnerabilities, and adversarial behaviors with probabilistic risk metrics (e.g., exploit likelihood, attack cost). This unified graph representation …

Evaluating The Transformation Of Land Cover, Land Surface Temperature, And Urban Heat Island In Sylhet Division Through Geospatial Analysis, Md Fazle Rabbi Joy, Md Abdur Rahim, Md Mahfuzar Rahman, Sumiaya Amin Preota, Mohammed Mahathee Hossain

School of Earth, Environmental, & Marine Sciences Faculty Publications

Rapid and unplanned urbanization has significantly transformed land use/land cover (LULC), contributing to increased land surface temperature (LST) and the emergence of urban heat islands (UHIs), especially in ecologically fragile regions. This study focuses on the Sylhet Division of Bangladesh, assessing LULC changes, LST dynamics, and UHI expansion from 1994 to 2024 using Landsat satellite imagery, normalized difference vegetation index (NDVI), normalized difference water index (NDWI) indices, and field-based LST validation. Unsupervised classification reveals a 191.75% increase in settlement areas and a 25.65% loss in forest cover. Correspondingly, the highest LST zones (> 30 °C) were absent in 1994 but …

From Post-Hoc To Pre-Assessment Evaluation: Llms As Collaborative Partners For Simulating Student Performance, Siaw Ling Lo, Ping Fan Ke, Yi Meng Lau

Research Collection School Of Computing and Information Systems

Ensuring the quality of multiple-choice questions (MCQs) remains a complex challenge in higher education, as traditional post-hoc psychometric analyses often identify flaws only after students have been negatively impacted. While Large Language Models (LLMs) offer potential for simulating student performance to validate items before delivery, they are frequently hindered by a “high-accuracy bias” that prevents larger models from realistically mimicking student errors. This paper proposes the Triadic Pedagogical Fit (TPF) framework, which triangulates Model Scale, Task Complexity via Revised Bloom’s Taxonomy, and Instructional Persona to optimize pre-assessment evaluation. Through two studies, we demonstrate that while Mid-scale (12B) models effectively mirror …

A Critical Review Of Pharmaceutical Pollutants In Soil And Air: Ecotoxicological Impacts On Animal, Plant And Microbial Communities - Health Hazards And Waste Management, Md Faisal Amin, Md. Saydur Rahman

School of Integrative Biological & Chemical Sciences Faculty Publications

Pharmaceutical contamination in soil and air has become a critical environmental concern due to its widespread sources, complex behavior, and long-lasting ecological impacts. This review comprehensively explores the presence, fate, and effects of pharmaceutical compounds in soil, highlighting their entry routes, environmental persistence, and biological consequences. Pharmaceuticals infiltrate terrestrial and aquatic environments through various pathways, including agricultural application, pharmaceutical manufacturing waste, sewage sludge, hospital and household discharges, irrigation with contaminated water, and atmospheric deposition. A wide range of drug classes, such as antibiotics, analgesics, non-steroidal anti-inflammatory drugs, antidepressants, anticancer drugs, and hormones, have been identified in both soil and air …

Harnessing Digital Twin (Dt) Technology For Food Security And Climate Resilience In Sub-Saharan Africa (Ssa), Henri E.Z. Tonnang, Francis Chianu, Siyabusa Mkuhlani, Francis Muthoni, John Michael Humphries Choptiany, Franck B.N. Tonle, Bonoukpoe M. Sokame, Mercy Lung’Aho

All Peer-Reviewed Publications

Sub-Saharan Africa (SSA) faces chronic food insecurity despite possessing approximately 60% of the world’s uncultivated arable land. Field trials generate evidence but are costly and insufficiently scaled to address accelerating climate and demographic pressures. Digital twin (DT) technology, defined as the continuous, bidirectional virtual replication of physical systems using real-time data, supports monitoring, modelling, and optimisation of agrifood systems. To our knowledge, however, no published synthesis has examined DT agriculture research through the lens of SSA food systems or smallholder farming realities. A PRISMA-compliant systematic review was conducted across bibliographic databases using a pre-defined Boolean search and adapted PICOS eligibility …

Beyond Legacy Indices: A Critical Review Of The Modified Nemerow, Mean Enrichment Quotient, And Aggregated Multivariate Environmental Risk (Amer) Indices For Heavy Metal Pollution In Sediments, Md Shahnul Islam, Anjuman Ara

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Background: Heavy metal pollution in sediments poses persistent ecological risks due to metal toxicity, bioaccumulation, and potential for remobilization. Legacy indices have been widely used for decades but suffer from fundamental flaws, including arbitrary background dependence, lack of grain-size normalization, and poor ecological relevance.

Objective: This review critically evaluates three emerging sediment pollution indices, the Modified Nemerow, Mean Enrichment Quotient (MEQ), and Aggregated Multivariate Environmental Risk (AMER) index, to assess their methodological advances and potential to replace legacy approaches.

Methods: A structured literature search was conducted in Web of Science, Scopus, and Google Scholar (2010–2026). Using an adapted Birch framework, …

Extending Geometric Acoustic Ray Tracing To Multi-Room Environments: A Case Study On Gunshot Sound Transmission Between Adjacent Rooms, Tyler Ton

Theses and Dissertations

Accurate localization of gunshots in multi-room building environments remains a challenging problem in acoustic forensics and public safety applications. Existing approaches model sound propagation within a single room, neglecting the transmission of acoustic energy through walls and other building materials. This thesis presents a study on modeling multi-room gunshot acoustic transmission, combining geometric ray tracing with structural acoustic transmission-loss modeling to generate impulse responses for two horizontally adjacent rooms separated by a shared wall, providing a foundation for future inter-room gunshot localization work. The proposed system uses GSound-SIR, a geometric acoustics engine, to simulate sound propagation in both of the …

The Future Of Nature-Based Recreation In Warming Tropical Cities, Perrine Hamel, Emma E. Ramsay, Shawnda A. Morrison, Su Li Heng, Winston T. L. Chow, Beatrice H. Ho, Pearl Min Sze Tan, Moshe Mandelmilch, Lancy Sim, Jason Kai Wei Lee

Research Collection College of Integrative Studies

Nature-based recreation promotes health in tropical cities but is increasingly threatened by rising heat. This review presents recent evidence on the issue of humid heat stress and outdoor recreation in tropical cities and outlines key adaptation strategies – addressing hazard, exposure, and vulnerability – to enable ‘heat-smart’ nature-based activities. Despite existing solutions, critical research gaps remain, especially in integrating social, physiological, and technological insights to better address humid heat stress in tropical urban environments.

A Projector-Rank Partition Theorem For Exact Degrees Of Freedom In Experimental Design, K. G. Nagananda

Mathematics and Statistics Faculty Publications and Presentations

In many experimental designs—split-plots, blocked or nested layouts, fractional factorials, and studies with missing or unequal replication—standard ANOVA procedures no longer tell us exactly how many independent pieces of information each effect truly contributes. We provide a general degrees of freedom (df) partition theorem that resolves this ambiguity. For N observations, we show that the total information in the data (i.e., N −1 df) can be split exactly across experimental effects and randomization strata by projecting the data onto each stratum and counting the df each effect contributes there. This yields integer df—not approximations—for any mix of fixed and random …

A Systematic Review Of Audio Deepfake Detection Techniques For Digital Investigation, Mahra Alnaqbi, Richard Adeyemi Ikuesan

All Works

Deepfake technology has been driven by advanced machine learning and revolutionized multimedia creation by synthesizing hyper-realistic content. It includes images, videos, and audio. While its creative applications in entertainment and accessibility are significant, the technology also poses critical risks, especially in fraud, disinformation, and identity theft. Audio deepfakes are a subset of this phenomenon that replicate human voices with enhanced precision, mimicking tone, accent, and subtle vocal nuances. This has raised concerns in security-sensitive domains like voice authentication and forensic investigations. This systematic literature review (SLR) adopts PRISMA guidelines to explore the state-of-the-art in audio deepfake detection. It examines existing …

A Performance-Optimized V2v Task Offloading Framework For Real-Time Vehicular Communication, Tariq Qayyum, Asadullah Tariq, Ikbal Taleb, Mohamed Adel Serhani, Zouheir Trabelsi

All Works

As vehicular applications become increasingly complex, their computational demands often exceed the capabilities of individual vehicles. Vehicular Edge Computing (VEC) alleviates this limitation by enabling task delegation to nearby edge resources; however, high mobility, dynamic topology, and fluctuating vehicle density make real-time offloading decisions challenging. To address these issues, we propose a performance-optimized Vehicle-to-Vehicle (V2V) task offloading framework for dense and dynamic Vehicular Ad-hoc Networks (VANETs). The framework follows a two-stage design: (i) context-aware edge-node selection based on live topology capture via periodic beaconing, and (ii) cumulative score-based dynamic priority queuing at the selected edge node. The priority score jointly …

Smart Medical System Integrating Clinical Workflows For Robust Skin Cancer Detection Across Heterogeneous Pathologies, Ahed Abugabah, Prashant Kumar Shukla, Suchi Mishra, Abhishek Dwivedi

All Works

Skin cancer is among the most prevalent and life-threatening dermatological diseases worldwide, with melanoma responsible for a substantial proportion of skin cancer–related deaths due to delayed and unreliable diagnosis. Conventional clinical screening based on visual inspection and expert interpretation is inherently subjective and often affected by inter-observer variability, lesion heterogeneity, and imaging artifacts, highlighting the need for accurate and generalizable automated diagnostic systems. This study proposes a novel hybrid deep learning architecture for skin cancer classification that integrates an attention-guided autoencoder with a transformer-inspired global context modeling module, forming a unified and robust representation learning framework. The encoder–decoder structure is …

Temporally Rigorous And Traceable Predictive Maintenance Via Joint Labeler-Model Optimization, Maytha Al-Ali, Ahmad Alharbi

All Works

Predictive maintenance (PdM) is a critical enabler of intelligent asset management in Industry 4.0, yet many existing frameworks remain difficult to operationalize due to methodological fragmentation. Common limitations include sacrificing temporal realism and class granularity for computational expediency, decoupling labeling strategy design from model hyperparameter optimization, and insufficient support for reproducibility and deployment traceability; particularly in rare-failure regimes. To address these challenges, we propose a unified, end-to-end, and fully traceable PdM framework that jointly optimizes labeling and model parameters while enforcing strict temporal fidelity. The proposed pipeline co-optimizes the failure lookahead window () and LightGBM hyperparameters within a single Bayesian …

Understanding The Out-Of-Distribution Generalization Of Chain-Of-Thought Reasoning In Llms, Nuojing Liang, Xiaotong Yuan, Pan Zhou

Research Collection School Of Computing and Information Systems

Chain-of-Thought (CoT) reasoning substantially improves Large Language Models (LLMs), yet its out-of-distribution (OOD) generalization mechanism remains theoretically underexplored. We study CoT as compositional OOD generalization: the target task lacks complete reasoning trajectories or direct input-output pairs, while training provides only in-distribution (ID) atomic step data. We show that CoT generalizes by repeatedly applying a shared single-step predictor to compose reusable ID transitions. Theoretically, the OOD task risk is controlled by the sum of ID subtask risks, scaled by a depth-independent hard-decoding coefficient Bℓ b = O(k) that is independent of the reasoning depth T. A Rademachercomplexity analysis further gives an …

Drag As Evidence: Motion-Grounded Latent Recomposition For Drag-Based Editing, Xinyu Pu, Hongsong Wang, Jie Gui, Pan Zhou

Research Collection School Of Computing and Information Systems

Modern image editors excel at semantic manipulation and visual synthesis, yet remain limited in precise spatial control, motivating the development of drag-based editing. However, existing drag-based methods often struggle to balance drag accuracy with natural, plausible, and intent-aligned generation. We propose MoReDrag, a motion-grounded drag-based editing method. Our key insight is to treat pixel-space warping as coarse motion evidence, and to inject this evidence into the generative sampling trajectory. Specifically, MoRe-Drag performs region-aware latent recomposition over refinement, inpainting, and anchor regions, coupled with stage-adaptive conditioning that progressively shifts from motion-grounded structure formation to semantic refinement. We further support an instruction-free …

Llm-Enabled Applications Require System-Level Threat Monitoring, Yedi Zhang, Haoyu Wang, Xianglin Yang, Jin Song Dong, Jun Sun

Research Collection School Of Computing and Information Systems

LLM-enabled applications are rapidly reshaping the software ecosystem by using large language models as core reasoning components for complex task execution. This paradigm shift, however, introduces fundamentally new reliability challenges and significantly expands the security attack surface, due to the non-deterministic, learning-driven, and difficult-to-verify nature of LLM behavior. In light of these emerging and unavoidable safety challenges, we argue that such risks should be treated as expected operational conditions rather than exceptional events, necessitating a dedicated incident-response perspective. Consequently, the primary barrier to trustworthy deployment is not further improving model capability but establishing system-level threat monitoring mechanisms that can detect …

A Deep Learning Ensemble Framework For Multi-Subtype Renal Tumor Classification Using Contrast-Enhanced Ct, Hisham Abdeltawab, Ahmed Alksas, Mohamed Ghazal, Ashraf Khalil, Norah Saleh Alghamdi, Rasha T. Abouelkheir, Ahmed Elmahdy, Mohamed Abou El-Ghar, Sohail Contractor, Ayman El–Baz

All Works

Renal cell carcinoma (RCC) is considered the most aggressive and common form of renal cancer. Therefore, early detection is crucial to ensure appropriate and effective treatment planning. In our study, we propose a novel computer-aided diagnostic (CAD) approach which incorporates a deep learning ensemble to differentiate between five renal tumor subtypes, utilising the modality of contrast-enhanced computed tomography (CE-CT). The addressed renal lesions are malignant tumors (chromophobe RCC (chRCC), papillary RCC (pRCC), and clear cell RCC (ccRCC)) and benign tumors (renal oncocytoma (RO) and angiomyolipoma (AML)). Our study includes 280 patients who underwent renal biopsy, 112 patients were diagnosed with …

Ai-Driven Collision Risk Prediction And Debris Optimization In Low Earth Orbit, Emad Alkhazraji, Mohamed E. Yahia, R. E. Tolba, N. S. Alharthi

All Works

Debris congestion and collision in low Earth orbit have become a major point of concern due to the rapid expansion of activities in that region. In this work, an AI-driven framework is developed and deployed to predict, analyze, and optimize collision risk across the altitude inclination space. Local debris object population, mass density distribution, and conjunction derived risk are computed. Then, an AI surrogate model, viz., gradient-boosted decision trees, was trained to predict collision conjunction relative probabilities and risk. Thereafter, data analysis and explain ability techniques are utilized to uncover underlying risk drivers and reveal how altitude, inclination, mass loading, …

Stimuli-Responsive Proton Transfer: Photoacid Design, Co2 Sorbent Regeneration, And Polymer Applications, Melyse Ava Laud

Theses and Dissertations

Control over proton transfer enables the regulation of many pH-dependent chemical and material processes. Stimuli-responsive functional materials provide a means of achieving this control. Functional materials such as Metastable-state photoacids (mPAHs) reversibly release large amounts of protons when stimulated by light from a weakly acidic site within their structure. However, the dark acidities of previously reported mPAHs limit their use under basic conditions. To address this limitation, a benzimidazole-type mPAH was developed with an improved ground-state pKa of 11.9 and a metastable-state pKa of 9.8, enabling reversible proton transfer under mildly basic conditions. Additional mPAHs were examined to determine how …