Physical Sciences and Mathematics Commons^™

Comparison Of Electrochemical Polishing Treatments Between Phosphoric Acid And A Deep Eutectic Solvent For High-Purity Copper, Tarek M. Abdel-Fattah, Jon Derek Loftis

VIMS Articles

This study investigated and compared the acid-free electropolishing of copper with the state-of-the-art acidic electropolishing process. The acid-free medium used in this study is based on a deep eutectic solvent comprised of 2:1 ethylene glycol and choline chloride. The electrochemical study included voltammetry and chronoamperometry tests during the electropolishing process. The characterization techniques used were atomic force microscopy (AFM) and digital microscopy, and surface morphology comparisons summarized the electropolishing efficiency of phosphoric acid and acid-free deep eutectic solvent treatments for high-purity copper. Electropolishing copper with a deep eutectic solvent resulted in a mirror finish and a post-treatment surface that was …

Long-Term Annual Aerial Surveys Of Submersed Aquatic Vegetation (Sav) Support Science, Management, And Restoration, Robert J. Orth, William C. Dennison, Cassie Gurbisz, (...), Kenneth A. Moore, Christopher J. Patrick, (..), David J. Wilcox, Richard A. Batiuk

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Aerial surveys of coastal habitats can uniquely inform the science and management of shallow, coastal zones, and when repeated annually, they reveal changes that are otherwise difficult to assess from ground-based surveys. This paper reviews the utility of a long-term (1984–present) annual aerial monitoring program for submersed aquatic vegetation (SAV) in Chesapeake Bay, its tidal tributaries, and nearby Atlantic coastal bays, USA. We present a series of applications that highlight the program’s importance in assessing anthropogenic impacts, gauging water quality status and trends, establishing and evaluating restoration goals, and understanding the impact of commercial fishing practices on benthic habitats. These …

The Spatio-Temporal Distribution And Transport Of Suspended Sediment In Laizhou Bay: Insights From Hydrological And Sedimentological Investigations, Bo Xie, Rui Bao, Dongxiao Yin, Et Al

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Suspended sediment transport and deposition are crucial physical processes controlling the geomorphological evolution of estuaries and bays. Specially, under the context of worldwide coastal erosion, knowledge of the spatio-temporal distribution of suspended sediment concentration (SSC) and its associated sediment load have become increasingly important for bay management. However, our understanding of the mechanisms of suspended sediment dynamics continues to be hampered by the lack of high-resolution observations. Here, we present a study of the transport mechanisms and controlling factors of suspended sediment over Laizhou Bay. For this, we conducted continuous measurements of SSC, salinity, temperature, and flow velocity at nine …

Seasonal Controls On Nearshore Dissolved Oxygen Variability And Hypoxia In A Coastal Embayment, Ryan K. Walter, Stephen A. Huie, (...), Piero L.F. Mazzini, Ian Robbins

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Declining dissolved oxygen (DO) is emerging as an increasingly important stressor in nearshore ecosystems, and there is a growing need to better understand DO dynamics and hypoxia risk in this highly variable environment. In this study, we collected data from monthly cruises on the inner shelf, continuous nearshore moorings inside and outside a small coastal upwelling embayment (San Luis Obispo Bay in Central California), and weekly phytoplankton measurements inside the bay during the upwelling season. Nearshore DO was generally dominated by low-frequency synoptic variability, with increased DO variance near the surface relative to the bottom and inside the bay compared …

Extreme Event Ecology Needs Proactive Funding, Christopher J. Patrick, Enie Hensel, John S. Kominoski, Beth A. Stauffer, William H. Mcdowell

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Commentary:

Extreme events such as wildfires, hurricanes, and floods have increased in frequency and intensity. It is no longer a question of if, but rather when and where these events will occur (Stott 2016), with adverse impacts on essential ecosystem
services including clean water, harvestable materials, and carbon sequestration. In some cases, extreme events such as wildfires may have positive impacts on populations and ecosystems. Managing these impacts requires understanding how environmental context as well as ecosystem and disturbance characteristics drive system responses (Hogan et al. 2020). However, funding for ecological extreme events research, such as through the US National …

A Numerical Investigation Of Hurricane Florence-Induced Compound Flooding In The Cape Fear Estuary Using A Dynamically Coupled Hydrological-Ocean Model, Daoyang Bao, Z. George Xue, John C. Warner, Melissa Moulton, Dongxiao Yin, Et Al

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Hurricane-induced compound flooding is a combined result of multiple processes, including overland runoff, precipitation, and storm surge. This study presents a dynamical coupling method applied at the boundary of a processes-based hydrological model (the hydrological modeling extension package of the Weather Research and Forecasting model) and the two-dimensional Regional Ocean Modeling System on the platform of the Coupled-Ocean-Atmosphere-Wave-Sediment Transport Modeling System. The coupled model was adapted to the Cape Fear River Basin and adjacent coastal ocean in North Carolina, United States, which suffered severe losses due to the compound flood induced by Hurricane Florence in 2018. The model's robustness was …

Drivers And Seasonal Variability Of Redox-Sensitive Metal Chemistry In A Shallow Subterranean Estuary, Alison E. O'Connor, Elizabeth A. Canuel, Aaron J. Beck

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The subterranean estuary (STE) has been historically defined in terms of the mixing of saline and fresh water, in an analogy to surface estuaries. However, redox gradients are also a defining characteristic of the STE and influence its role as a source or sink for metals in the environment. Approaching the STE from a redox-focused biogeochemical perspective (e.g., considering the role of microbial respiration and availability of organic matter) provides the ability to quantify drivers of metal transport across spatial and temporal scales. This study measured the groundwater composition of a shallow STE over 2 years and used multiple linear …

Dynamical Controls Of The Eastward Transport Of Overwintering Calanus Finmarchicus From The Lofoten Basin To The Continental Slope, Huizi Dong, Meng Zhou, Walker O. Smith Jr., Et Al

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Diapausing populations of Calanus finmarchicus at depth in the Lofoten Basin (LB) return to the continental shelf and slope off the Lofoten-Vesterålen Islands during the phytoplankton spring bloom to feed and spawn, forming surface swarms with a great abundance. To study how overwintering populations of C. finmarchicus move with the deep currents and return to the shelf, Lagrangian transport characteristics of particles in deep water between 2008 and 2019 were analyzed using Global Ocean Reanalysis and Simulation re-analysis data and Lagrangian Coherent Structures (LCSs). Our analyses revealed that persistent eastward transport of diapausing C. finmarchicus between LB and continental slope …

Joint Effects Of Fragmentation And Mercury Contamination On Marsh Periwinkle (Littoraria Irrorata) Movement, Marcos Krull, Michael C. Newman

VIMS Articles

There are different ways contaminants can interact and enhance the effects of habitat fragmentation, such as modifying the movement of organisms. The present study tested the hypothesis that mercury exacerbates the effects of
fragmentation by affecting the movement of the marsh periwinkle Littoraria irrorata and reducing the probability of snails crossing fragmented microlandscape experimental systems. How these changes could affect the search efficiency of organisms in the long term was assessed using hidden Markov models and random walks simulations. Bayesian nonlinear
models were used to analyze the effects of fragmentation and contamination on the mean speed and mean directional change …

Benthic Biofilm Potential For Organic Carbon Accumulation In Salt Marsh Sediments, Kendall Valentine, Abbey Hotard, Tracy Elsey-Quirk, Giulio Mariotti

VIMS Articles

Coastal salt marshes are productive environments with high potential for carbon accumulation and storage. Even though organic carbon in salt marsh sediment is typically attributed to plant biomass, it can also be produced by benthic photosynthetic biofilms. These biofilms, generally composed of diatoms and their secretions, are known for their high primary productivity and contribution to the basal food web. The growth of biofilms and the preservation of carbon produced by biofilms depends on the amount of sedimentation; low sedimentation rates will favor decomposition, while high sedimentation rates could decrease biofilm productivity. In this study, we conducted laboratory experiments to …

Uncrewed Ocean Gliders And Saildrones Support Hurricane Forecasting And Research, Travis N. Miles, Dongxiao Zhang, Gregory R. Foltz, (...), Donglai Gong, Et Al

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In the United States alone, hurricanes have been responsible for thousands of deaths and over US$1 trillion in damages since 1980 (https://www.ncdc.noaa.gov/billions/). These impacts are significantly greater globally, particularly in regions with limited hurricane early warning systems and where large portions of the population live at or near sea level. The high socioeconomic impacts of tropical cyclones will increase with a changing climate, rising sea level, and increasing coastal populations. To mitigate these impacts, efforts are underway to improve hurricane track and intensity forecasts, which drive storm surge models and evacuation orders and guide coastal preparations. Hurricane track forecasts have …

Freshwater Transport In The Scotian Shelf And Its Impacts On The Gulf Of Maine Salinity, Z. Wang, D. Li, H. Xue, A. C. Thomas, Yinglong J. Zhang, F. Chai

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A 3D unstructured-grid ocean circulation model covering the continental shelf and coastal seas around New England is used to investigate freshwater transport (FWT) on the Scotian Shelf (SS) and its impact on the salinity in the Gulf of Maine (GoME). The model was first validated using observed elevation, velocity, temperature, and salinity at multiple locations, demonstrating generally high model skills. Intraseasonal variabilities of freshwater fluxes in 2017 and 2018 were then analyzed across different transects around SS and Browns Bank (BB). These indicated that the flow pattern in SS during 2017 was consistent with previous understanding: low salinity water flows …

A Geospatial Modeling Approach To Assess Site Suitability Of Living Shorelines And Emphasize Best Shoreline Management Practices, Karinna Nunez, Tamia Rudnicky, Pamela Mason, Christine Tombleson, Marcia Berman

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The Shoreline Management Model (SMM) is a novel geospatial approach used to assess conditions along a shoreline, and recommend best management practices for defended and undefended shorelines. The SMM models available spatial data in order to identify areas where the use of living shorelines would be suitable to address shoreline erosion. The model was developed to support and inform decision-making by shoreline managers responsible for management of shoreline resources, shorefront property owners, and tidal habitat restoration actions. Recommended erosion control strategies are based on scientific knowledge of how shorelines respond to natural conditions and anthropogenic measures used to stabilize shorelines. …

Bifurcate Responses Of Tidal Range To Sea-Level Rise In Estuaries With Marsh Evolution, Xun Cai, Qubin Qin, Jian Shen, Yinglong J. Zhang

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The response of tidal range in tidal marshes under sea-level rise (SLR) is essential to the marsh resilience, but how tidal ranges respond to different marsh evolutions remains unclear. Here, we show the existence of bifurcate responses of tidal range to SLR using both numerical model and theoretical analyses. The tidal range tends to increase if marsh accretion keeps pace with SLR; otherwise, the tidal range tends to decrease. As tidal range plays the key role in marsh evolution, the interactions between changing tidal range and marsh evolution lead to positive feedback on marsh resilience. If the marsh accretion can …

Adcp Observations Of Currents And Suspended Sediment In The Macrotidal Gulf Of Martaban, Myanmar, Courtney K. Harris, Jacob T. Wacht, Matthew J. Fair, Jessica M. Cote

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The Ayeyarwady and Thanlwin Rivers, which drain Myanmar, together form one of the largest point sources of freshwater and sediment to the global ocean. Combined, these rivers annually deliver an estimated 485 Mt of sediment to the northern Andaman Sea. This sediment contributes to a perennially muddy zone within the macro-tidal Gulf of Martaban, but little is known about the processes that dominate dispersal and trapping of sediment there, as very few water column observations are available. A research cruise in December 2017 provided a rare opportunity to obtain Acoustic Doppler Current Profiler (ADCP) data along transects from the Gulf …

Water Circulation Driven By Cold Fronts In The Wax Lake Delta (Louisiana, Usa), Q. Zhang, C. Li, W. Huang, Et Al

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: Atmospheric cold fronts can periodically generate storm surges and affect sediment transport in the Northern Gulf of Mexico (NGOM). In this paper, we evaluate water circulation spatiotemporal patterns induced by six atmospheric cold front events in the Wax Lake Delta (WLD) in coastal Louisiana using the 3-D hydrodynamic model ECOM-si. Model simulations show that channelized and inter-distributary water flow is significantly impacted by cold fronts. Water volume transport throughout the deltaic channel network is not just constrained to the main channels but also occurs laterally across channels accounting for about a quarter of the total flow. Results show that …

Measuring Organization Of Large Surficial Clasts In Heterogeneous Gravel Beach Sediments, Dennis C. Lees, Christopher J. Hein, Duncan M. Fitzgerald

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The natural stratification and interlocking “organization” of armored sediments in heterogeneous, coarse-grained, beaches provides protection and enhances habitat for borrowing sedentary megafauna and macrofauna such as hard-shelled clams. Here, we develop a novel metric for quantifying sediment organization of large surficial beach clasts through sedimentologic and photogrammetric analyses of 37 lower intertidal heterogeneous gravel beaches in western Prince William Sound, Alaska (USA). Grain size, photogrammetric, and Wolman Pebble Count clast-size data from 64, ~1-m² study plots are combined into a clast-size-independent “Organization Metric” to quantify the degree of organization in the meshed arrangement of larger surficial sediments. This metric …

Variability In Marsh Migration Potential Determined By Topographicrather Than Anthropogenic Constraints In The Chesapeake Bay Region, Grace D. Molino, Joel A. Carr, Neil K. Ganju, Matthew L. Kirwan

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Sea level rise (SLR) and saltwater intrusion are driving inland shifts in coastal ecosystems. Here, we make high-resolution (1 m) predictions of land conversion under future SLR scenarios in 81 watersheds surrounding Chesapeake Bay, United States, a hotspot for accelerated SLR and saltwater intrusion. We find that 1050–3748 km2 of marsh could be created by 2100, largely at the expense of forested wetlands. Predicted marsh migration exceeds total current tidal marsh area and is about 4x greater than historical observations. Anthropogenic land use in marsh migration areas is concentrated within a few watersheds and minimally impacts calculated metrics of marsh …

Contamination Of Finescale Strain Estimates Of Turbulent Kinetic Energy Dissipation By Frontal Physics, Laur Ferris, Donglai Gong, Sophia Merrifield, Louis St. Laurent

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Finescale strain parameterization (FSP) of turbulent kinetic energy dissipation rate has become a widely used method for observing ocean mixing, solving a coverage problem where direct turbulence measurements are absent but CTD profiles are available. This method can offer significant value, but there are limitations in its broad application to the global ocean. FSP often fails to produce reliable results in frontal zones where temperature–salinity (T/S) intrusive features contaminate the CTD strain spectrum, as well as where the aspect ratio of the internal wave spectrum is known to vary greatly with depth, as frequently occurs in …

Effects Of Shell Hash On Friction Angles Of Surficial Seafloor Sediments Near Oysters, Samuel T. Consolvo, Nina Stark, (...), Grace M. Massey

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Oysters are hypothesized to affect the shear strength of nearby surficial seafloor sediment as fragments of oyster shells (shell hash) are typically more angular relative to sand particles alone, among other differences. Resistance to shearing is well characterized by the friction angle, which is estimated in this study from vacuum triaxial laboratory and portable free-fall penetrometer field tests. Friction angles of sediment with shell hash were higher relative to those of sediment without shell hash (via hydrochloric acid treatment) on average by about 19% (36.0°–30.2°, respectively). Triaxial confining pressures ranged between 2.1 and 49.0 kPa to simulate subtidal and intertidal …

Surface Chlorophyll Anomalies Induced By Mesoscale Eddy-Wind Interactions In The Northern Norwegian Sea, Huizi Dong, Meng Zhou, Roshin P. Raj, Walker O. Smith Jr., Et Al

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The substantial productivity of the northern Norwegian Sea is closely related to its strong mesoscale eddy activity, but how eddies affect phytoplankton biomass levels in the upper ocean through horizontal and vertical transport-mixing has not been well quantified. To assess mesoscale eddy induced ocean surface chlorophyll-a concentration (CHL) anomalies and modulation of eddy-wind interactions in the region, we constructed composite averaged CHL and wind anomalies from 3,841 snapshots of anticyclonic eddies (ACEs) and 2,727 snapshots of cyclonic eddies (CEs) over the period 2000-2020 using satellite altimetry, scatterometry, and ocean color products. Results indicate that eddy pumping induces negative (positive) CHL …

A Multi-Decadal Analysis Of River Discharge And Suspended Sediment Load In Three Texas Coastal Rivers In Relation To Hurricanes, Seasonal Rainfall, And Enso, Qiang Yao, Sanjeev Joshi, Kam-Biu Liu, Erika Rodrigues, Dongxiao Yin

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Coastal river discharge and sediment load exert major influence on the sustainability of coastal systems. Controlled by various hydroclimatic/hydrometeorological agents, they exhibit distinct trend/variability at different time scales. Coastal Texas, while being a major target for tropical cyclones over the past 6 decades, has been experiencing drought and flood cycles associated with ENSO in the long term. However, it is still unclear the temporal variability of river discharge and the associated sediment delivery over this area at different time scales, and the controlling factors behind it. In this study, a 58-years (1960–2017) dataset is compiled to analyze the influence of …

Primary Productivity Measurements In The Ross Sea, Antarctica: A Regional Synthesis, Walker O. Smith Jr.

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Polar systems are undersampled due to the difficulty of sampling remote and challenging environments; however, these systems are critical components of global biogeochemical cycles. Measurements on primary productivity in specific areas can quantify the input of organic matter to food webs and so are of critical ecological importance as well. However, long-term measurements using the same methodology are available only for a few polar systems. Primary productivity measurements using ¹⁴C-uptake incubations from the Ross Sea, Antarctica, are synthesized, along with chlorophyll concentrations at the same depths and locations. A total of 19 independent cruises were completed and 449 stations …

Clarifying Water Clarity: A Call To Use Metrics Best Suited To Corresponding Research And Management Goals In Aquatic Ecosystems, Jessica S. Turner, Kelsey A. Fall, Carl T. Friedrichs

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Water clarity is a subjective term and can be measured multiple ways. Different metrics such as light attenuation and Secchi depth vary in effectiveness depending on the research or management application. In this essay, we argue that different questions merit different water clarity metrics. In coastal and inland waters, empirical relationships to estimate light attenuation can yield clarity estimates that either under- or overestimate the underwater light climate for restoration goals, such as potential habitat available for submerged aquatic vegetation. Best practices in reporting water clarity measurements include regionally specific, temporally representative calibrations and communicating the metric that was actually …

Nutrient Function Over Form: Organic And Inorganic Nitrogen Additions Have Similar Effects On Lake Phytoplankton Nutrient Limitation, Sabrina N. Volponi, Heather L. Wander, (...), Brian S. Kim, Et Al

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The concentration of dissolved organic nitrogen (DON) is increasing in many northern hemisphere lakes, yet its use by phytoplankton and fate in the environment seldom have been quantified. We conducted 1 week, insitu, microcosm incubations across 25 lakes in northeastern North America to understand how DON, dissolved norganic nitrogen (DIN), and dissolved inorganic phosphorus (P) affected phytoplankton biomass. In addition,we tested whether lakes were limited by single macronutrients (N or P) or colimited by both. Phytoplankton biomass in 80% of lakes responded similarly to DON and DIN additions. Of the lakes where N form produced differential responses, the majority of …

Multiple Dimensions Of Functional Diversity Affect Stream Fish Taxonomic Β-Diversity, Luke M. Bower, Lauren Stoczynski, Brandon K. Peoples, Christopher J. Patrick, Bryan L. Brown

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1. When investigating metacommunity dynamics, functional differences among
species are often assumed to be as important as environmental differences be-
tween sites in determining β-diversity. However, few studies have examined the
influence of functional diversity on β-diversity. We examine the relative importance of regional functional diversity partitioned by niche dimensions and environmental variation in structuring taxonomic β-diversity of stream fishes using a large dataset of stream fish assemblages (hereafter, simply β-diversity). We predicted that both functional diversity and environmental variation play a rolein determining β-diversity.
2. We tested this prediction by modelling the patterns of stream fish β-diversity as
a …

Enhancing Assessments Of Blue Carbon Stocks In Marsh Soils Using Bayesian Mixed-Effects Modeling With Spatial Autocorrelation — Proof Of Concept Using Proxy Data, Grace S. Chiu, Molly Mitchell, Julie Herman, Christian Longo, Kate Davis

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Our paper showcases the potential gain in scientific insights about blue carbon stocks (or total organic carbon) when additional rigor, in the form of a spatial autocorrelation component, is formally incorporated into the statistical model for assessing the variability in carbon stocks. Organic carbon stored in marsh soils, or blue carbon (BC), is important for sequestering carbon from the atmosphere. The potential for marshes to store carbon dioxide, mitigating anthropogenic contributions to the atmosphere, makes them a critical conservation target, but efforts have been hampered by the current lack of robust methods for assessing the variability of BC stocks at …

A Global Synthesis Of Human Impacts On The Multifunctionality Of Streams And Rivers, Mario Brauns, Daniel C. Allen, Iola G. Boëchat, Wyatt F. Cross, Verónica Ferreira, Daniel Graeber, Christopher J. Patrick, Et Al

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Human impacts, particularly nutrient pollution and land-use change, have caused significant declines in the quality and quantity of freshwater resources. Most global assessments have concentrated on species diversity and composition, but effects on the multifunctionality of streams and rivers remain unclear. Here, we analyse the most comprehensive compilation of stream ecosystem functions to date to provide an overview of the responses of nutrient uptake, leaf litter decomposition, ecosystem productivity, and food web complexity to six globally pervasive human stressors. We show that human stressors inhibited ecosystem functioning for most stressor-function pairs. Nitrate uptake efficiency was most affected and was inhibited …

Vertical Transport Timescale Of Surface-Produced Particulate Material In The Chesapeake Bay, Jilian Xiong, Jian Shen

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Accumulation and remineralization of surface-produced particulate organic matter (POM) in the water column and seabed link closely to hypoxia and the health of aquatic ecosystems. The POM retention time provides a key timescale to interpret biochemical reaction processes. In this study, we investigated the spatiotemporal variations in the vertical particulate age (VPA) of surface-produced POM, which is the mean time elapsed since the particulates last contact the surface, by incorporating major physical processes including sinking, resuspension, and deposition in the Chesapeake Bay. It was found that the vertical transport time for the particulates (i.e., VPA) is much longer than the …

Influence Of Salinity On Sav Distribution In A Series Of Intermittently Connected Coastal Lakes, A. Challen Hyman, Rom Lipcius, R. Gray, D. B. Stephens

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Intermittently closed and open lakes and lagoons (ICOLLs) are coastal lakes that intermittently exchange water with the sea and experience saline intrusions. Understanding effects of seawater exchange on local biota is important to preserve ecosystem functioning and ecological integrity. Coastal dune lakes of northwest Florida are an understudied group of ICOLLs in close geographic proximity and with entrance regimes operating along a frequency continuum. We exploited this natural continuum and corresponding water chemistry gradient to determine effects of water chemistry on resident submersed aquatic vegetation (SAV) distributions in these ecosystems. SAV distribution decreased with increases in salinity, but was unaffected …